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81. 发明公开

EP2970159A4 STABILIZER AND INHIBITOR FOR CHLOROPROPENES, SUCH AS TETRACHLOROPROPENE 1,1,2,3-TETRACHLOROPROPENE (1230xa), USED IN THE MANUFACTURE OF 2,3,3,3-TETRAFLUOROPROPENE (1234yf) 审中-公开
标题翻译：稳定剂和抑制剂的如何CHLORPROPENE氯丙烯或1,1,2,3-五氯丙烷（1230xa的）用以进行2,3,3,3-四氟丙烯（1234yf的）生产
公开(公告)号：EP2970159A4
公开(公告)日：2016-10-12
申请号：EP14773552
申请日：2014-03-13
申请人： HONEYWELL INT INC
发明人： KOPKALLI HALUK , WANG HAIYOU , TUNG HSUEH SUNG , MERKEL DANIEL C
IPC分类号： C07D265/30 , C07C17/42 , C07C21/04 , C07D265/28
CPC分类号： C09K15/30 , C07C17/087 , C07C17/202 , C07C17/206 , C07C17/25 , C07C17/42 , C07C21/04 , C07C19/10

82. 发明公开

EP2817380A4 AZEOTROPIC COMPOSITIONS OF 1,1,3,3-TETRACHLORO-1-FLUOROPROPANE AND HYDROGEN FLUORIDE 有权转让
标题翻译：作者1,1,3,3-四氯-1-丙烷FLUOR和氢氟酸的共沸组合物
公开(公告)号：EP2817380A4
公开(公告)日：2015-10-07
申请号：EP13752004
申请日：2013-02-13
申请人： HONEYWELL INT INC
发明人： MERKEL DANIEL C , POKROVSKI KONSTANTIN A , PHAM HANG T , TUNG HSUEH SUNG , HULSE RYAN
IPC分类号： C09K3/00 , C01B7/19 , C07C19/10 , C09K3/30 , C09K5/04 , C11D7/50
CPC分类号： C07C19/10 , C09K3/30 , C09K5/044 , C11D7/5045
摘要： Provided are azeotropic or azeotrope-like mixtures of 1,1,3,3-tetrachloro-1-fluoropropane (HCFC-241fa) and hydrogen fluoride. Such compositions are useful as an intermediate in the production of HFC-245fa and HCFO-1233zd.

83. 发明公开

EP2814795A4 PROCESS FOR THE PRODUCTION OF HCFC-1233zd 有权转让
标题翻译： VERFAHREN ZUR HERSTELLUNG VON HCFC-1233ZD
公开(公告)号：EP2814795A4
公开(公告)日：2015-09-30
申请号：EP13748643
申请日：2013-02-11
申请人： HONEYWELL INT INC
发明人： COTTRELL STEPHEN A , TUNG HSUEH SUNG , POKROVSKI KONSTANTIN A , WANG HAIYOU , MERKEL DANIEL C
IPC分类号： C07C17/20 , C07B61/00 , C07C21/18
CPC分类号： C07C17/23 , C07C17/20 , C07C17/206 , C07C17/25 , C07C17/38 , C07C17/383 , C07C21/18
摘要： A process for the manufacture of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) at commercial scale from the reaction of HCC-240 and HF is disclosed. In one embodiment, HCC-240fa and HF are fed to a reactor operating at high pressure. Several different reactor designs useful in this process include; a stirred-tank reactor (batch and/or continuous flow); a plug flow reactor; a static mixer used as a reactor; at least one of the above reactors operating at high pressure; optionally combined with a distillation column running at a lower pressure; and combinations of the above; and/or with a distillation column. The resulting product stream consisting of 1233zd, HCl, HF, and other byproducts is partially condensed to recover HF by phase separation. The recovered HF phase is recycled to the reactor. The HCl is scrubbed from the vapor stream and recovered as an aqueous solution. The remaining organic components including the desired HCFC-1233zd are scrubbed, dried and distilled to meet commercial product specifications.
摘要翻译：公开了从HCC-240和HF的反应制备商业规模的1-氯-3,3,3-三氟丙烯（HCFC-1233zd）的方法。在一个实施方案中，将HCC-240fa和HF加入到在高压下操作的反应器中。在这个过程中有用的几种不同的反应器设计包括：搅拌釜反应器（批次和/或连续流动）; 活塞流反应器; 用作反应器的静态混合器; 上述反应器中的至少一个在高压下运行; 任选地与在较低压力下运行的蒸馏塔组合; 和上述的组合; 和/或用蒸馏塔。由1233zd，HCl，HF和其他副产物组成的产物流部分冷凝，通过相分离回收HF。将回收的HF相再循环到反应器中。将HCl从蒸汽流中洗涤并作为水溶液回收。将包含所需HCFC-1233zd的剩余有机组分进行洗涤，干燥和蒸馏以满足商业产品规格。

84. 发明公开

EP2665695A4 INTEGRATED PROCESS TO CO-PRODUCE TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE, TRANS-1,3,3,3-TETRAFLUOROPROPENE, AND 1,1,1,3,3-PENTAFLUOROPROPANE 审中-公开
标题翻译： INTEGRATED PROCESS FOR TRANS-1-氯-3,3,3-三氟丙烯的同时生产，反式-1,3,3,3-四氟丙烯和1,1,1,3,3-五氟丙烷
公开(公告)号：EP2665695A4
公开(公告)日：2015-07-01
申请号：EP12782678
申请日：2012-01-12
申请人： HONEYWELL INT INC
发明人： MERKEL DANIEL C , WANG HAIYOU , POKROVSKI KONSTANTIN A , TUNG HSUEH SUNG , SHANKLAND IAN
IPC分类号： C07C17/20 , C07C17/087 , C07C17/25 , C07C19/08 , C07C19/10 , C07C21/18
CPC分类号： C07C17/25 , C07C17/087 , C07C17/206 , Y02P20/125 , Y02P20/582 , C07C21/18 , C07C19/10 , C07C19/08
摘要： Disclosed is an integrated process to co-produce trans-1-chloro-3,3,3-trifluoro-propene (1233zd(E)), trans-1,3,3,3-tetrafluoropropene (1234ze(E)), and 1,1,1,3,3-pentafluoropropane (245fa). Overall the co-production is a three-step process. The chemistry involves the steps of: (1) the reaction of 240fa with anhydrous HF in excess in a liquid-phase catalyzed reactor in such a way as to co-produce primarily 1233zd(E) and 244fa (plus byproduct HCl); (2) the 244fa stream can then be used to directly produce any of the three desired products; (3a) the 244fa stream can be dehydrochlorinated to produce the desired second product 1234ze(E); and/or (3b) the 244fa stream can be dehydrofluorinated to produce 1233zd(E) if more of that product is desired; and/or (3c) the 244fa stream can be further fluorinated to form 245fa.
摘要翻译：公开了一个集成的过程中共同产生反式-1-氯-3,3,3-三氟丙烯（丙烯（1233zd E）），反式-1,3,3,3-四氟丙烯（1234ze的（E）），和 1,1,1,3,3-五氟丙烷（245fa的）。总体来说，合作生产是一个三步骤的过程。化学包括以下步骤：在寻求一种方式，以共同产生主要的1233zd（E）和244fa脱（加上副产物HCl）（1）的240fa与无水HF在液相反应中过量的催化反应器中; （2）使244fa流然后可以用于产生任何三个直接所需产物; （3a）中的244fa脱流可被脱氯化氢以产生所述第二期望的产物1234ze的（E）; 和/或（3b）的所述244fa脱流可以脱氟化氢以产生的1233zd（E）如果有更多的产品没有期望; 和/或（3c）的所述流的244fa能够进一步氟化以形成245fa的。

85. 发明公开

EP2344434A4 AZEOTROPE-LIKE COMPOSITIONS OF 1,1,2,3-TETRACHLOROPROPENE AND HYDROGEN FLUORIDE 有权转让
标题翻译：共沸物组成1,1,2,3-五氯丙烷和氢氟酸
公开(公告)号：EP2344434A4
公开(公告)日：2013-11-13
申请号：EP09824103
申请日：2009-10-29
申请人： HONEYWELL INT INC
发明人： TUNG HSUEH S , PHAM HANG T , SINGH RAJIV R , MERKEL DANIEL C , JOHNSON ROBERT
IPC分类号： C07C19/01 , B01D3/36 , C01B7/19 , C07C17/25 , C07C17/386
CPC分类号： C07C21/18 , C01B7/191 , C07C17/206 , C07C17/386 , C07C21/04 , C09K3/30 , C11D7/5059 , C23G1/00
摘要： An azeotrope-like composition consisting essentially of 1,1,2,3-tetrachloropropene and hydrogen fluoride is provided, as well as methods that involve such an azeotrope-like composition.

86. 发明公开

EP2406177A4 METHODS AND REACTOR DESIGNS FOR PRODUCING PHOSPHORUS PENTAFLUORIDE 审中-公开
标题翻译：方法和反应器设计用于生产磷五氟化
公开(公告)号：EP2406177A4
公开(公告)日：2013-05-08
申请号：EP10751458
申请日：2010-03-12
申请人： HONEYWELL INT INC
发明人： LULY MATTHEW H , SMITH ROBERT A , NAIR HARIDASAN K , DEPRATO PHILIP , POKROVSKI KONSTANTIN A , MERKEL DANIEL C , UHRICH KEVIN , COTTRELL STEPHEN A , BRENNER DANIEL J
IPC分类号： C01B25/10 , B01J12/00 , B01J19/26 , C01B9/08 , C01B25/455
CPC分类号： C01B25/10 , B01J4/002 , B01J12/00 , B01J19/24 , C01B25/455

87. 发明公开

EP3104965A4 REACTOR FOR LIQUID PHASE FLUORINATION REACTIONS 有权
标题翻译： REAKTORFÜRFLUORIERUNGSREAKTIONEN DER DERFLÜSSIGPHASE
公开(公告)号：EP3104965A4
公开(公告)日：2017-08-02
申请号：EP15747067
申请日：2015-02-06
申请人： HONEYWELL INT INC
发明人： MERKEL DANIEL C , MAHLER BARRY , TUNG HSUEH SUNG , NAPPA MARIO JOSEPH
IPC分类号： B01J8/38 , C07C17/087 , C07C19/10
CPC分类号： C07C17/087 , B01J19/18 , B01J19/1868 , C07C17/20 , C07C17/206 , C07C17/25 , C07C19/10
摘要： The present invention relates to a hydrofluorinating process which comprises reacting a fluoroolefin with hydrogen fluoride in the liquid phase in the presence of a hydrofluorination catalyst in the reaction zone of a reactor, said reactor comprised of a reactor body having a length to diameter ratio of about 2:1 or greater; a stirred reaction zone containing said hydrofluorination catalyst, which may be prepared in situ, at least one inlet for supplying said hydrogen fluoride and fluoroolefin to the reaction zone and at least one outlet for recovering said fluoroalkane, said stirrer disposed in the reaction zone and comprising a plurality of blades fixedly attached to shaft drivable by a motor, said blades extending from about the bottom of the reaction zone to about the top of the reaction zone and said shaft extending on a longitudinal axis from the bottom of the reactor to the top of the reactor, said stirrer being rotated at a speed sufficient to promote a swirling of the liquid to effect the occurrence of hydrofluorination reaction and minimize overfluorination. The present invention also relates to said hydrofluorination reactor.
摘要翻译：本发明涉及氢氟酸化方法，其包括在反应器的反应区中在氢氟化催化剂存在下使氟代烯烃与氟化氢在液相中反应，所述反应器包含长度与直径之比为约 2：1或更大; 包含可以原位制备的所述氢氟化催化剂的搅拌反应区，用于将所述氟化氢和氟代烯烃供应到反应区的至少一个入口和用于回收所述氟代烷的至少一个出口，所述搅拌器设置在反应区中并且包含多个叶片，其固定地连接到可由马达驱动的轴上，所述叶片从反应区的底部附近延伸到反应区的顶部附近，并且所述轴在纵轴上从反应器的底部延伸到反应器中，所述搅拌器以足以促进液体涡旋的速度旋转以实现氢氟化反应的发生并使过氟化作用最小化。本发明还涉及所述氢氟化反应器。

88. 发明公开

EP2970061A4 AN IMPROVED INTEGRATED PROCESS TO PRODUCE 2,3,3,3-TETRAFLUOROPROPENE 无效
标题翻译： VERBESSERTES INTEGRIERTES VERFAHREN ZUR HERSTELLUNG VON 2,3,3,3-TETRAFLUORPROPEN
公开(公告)号：EP2970061A4
公开(公告)日：2016-11-09
申请号：EP14770468
申请日：2014-03-13
申请人： HONEYWELL INT INC
发明人： WANG HAIYOU , BEKTESEVIC SELMA , MERKEL DANIEL C , TUNG HSUEH SUNG , POKROVSKI KONSTANTIN A
IPC分类号： C07C17/383 , C07C17/07 , C07C17/25 , C07C21/18
CPC分类号： C07C17/206 , C07C17/087 , C07C17/25 , C07C17/38 , C07C17/386 , C07C19/01 , C07C19/08 , C07C19/10 , C07C21/04 , C07C21/18 , Y02P20/125 , Y02P20/582
摘要： The invention relates to a separation process whereby 2-chloro-3,3,3-trifluoropropene (1233xf) is separated from a mixture containing other fluorinated organics and high boiling materials such as dimers using azeotropes of HF formed by adding appropriate amounts to the mixture which facilitate separation by, e.g. distillation.
摘要翻译：本发明涉及一种分离方法，其中将2-氯-3,3,3-三氟丙烯（1233xf）从含有其它氟化有机物和高沸点物质如二聚体的混合物中分离，使用通过向混合物中加入适量的所形成的HF的共沸物这有利于通过例如蒸馏。

89. 发明公开

EP2970052A4 PROCESS TO MANUFACTURE 2-CHLORO-1,1,1,2-TETRAFLUOROPROPANE (HCFC-244bb) 有权
标题翻译： PROCESS FOR 2-氯-1,1,1,2-四氟丙烷的制备（HCFC-244bb）脱氯化氢
公开(公告)号：EP2970052A4
公开(公告)日：2016-11-02
申请号：EP14768936
申请日：2014-03-13
申请人： HONEYWELL INT INC
发明人： KOPKALLI HALUK , MERKEL DANIEL C , ROOF RON JOSEPH
IPC分类号： C07C17/04 , C07C17/38 , C07C19/12
CPC分类号： C07C17/08 , C07C17/087 , C07C17/206 , C07C17/23 , C07C17/25 , C07C19/10 , C07C21/18 , C07C19/08

90. 发明公开

EP2970057A4 A METHOD FOR MITIGATING HFC-245CB FORMATION DURING HCFO-1233XF HYDROFLUORINATION TO HCFC-244BB 有权
标题翻译：在HCFC-244BB中加氢合成HCFO-1233XF过程中预防HFC-245CB的形成
公开(公告)号：EP2970057A4
公开(公告)日：2016-10-26
申请号：EP14778098
申请日：2014-03-11
申请人： HONEYWELL INT INC
发明人： WANG HAIYOU , MERKEL DANIEL C , TUNG HSUEH SUNG , KOPKALLI HALUK
IPC分类号： C07C17/25 , C07C17/087 , C07C19/08 , C07C21/18
CPC分类号： C07C17/23 , C07C17/087 , C07C17/206 , C07C17/25 , C07C19/10 , C07C21/18
摘要： The present process relates to a method for minimizing the formation of 1,1,1,2,2-pentafluoropropane in a liquid phase reaction of 2-chloro-3,3,3-trifluoropropene and HF in the presence of a hydrofluorination catalyst comprising: (a) reacting HF with sufficient amount of 2-chloro-3,3,3-trifluoropropene in the presence of a hydrofluorination catalyst under conditions effective to form 2-chloro-1,1,1,2-tetrafluoropropane, the hydrofluorination catalyst being present in sufficient amounts to catalyze said reaction and the 2-chloro-1,1,1,2-tetrafluoropropane being formed with both a conversion of greater than 80% and a 1,1,1,2,2-pentafluoropropane selectivity lower than 20%; and (b) maintaining the 2-chloro-1,1,1,2-tetrafluoropropane being formed with both a conversion of about 80% or more and a 1,1,1,2,2-pentafluoropropane selectivity of about 20% or less by adding said hydrofluorination catalyst to the reactor in small increments.

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