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81. 发明授权

US6143684A Components and catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US6143684A
公开(公告)日：2000-11-07
申请号：US146368
申请日：1998-09-03
申请人： Giampiero Morini , Yuri V. Gulevich , Giulio Balbontin
发明人： Giampiero Morini , Yuri V. Gulevich , Giulio Balbontin
IPC分类号： C08F4/654 , C08F4/02 , C08F4/64 , C08F4/651 , C08F4/658 , C08F10/00 , B01J31/00 , B01J37/00 , C08F4/60
CPC分类号： C08F10/00
摘要： The invention relates to solid catalyst components for the polymerization of olefins CH.sub.2 .dbd.CHR, in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Ti, Mg, halogen and an electron donor compound selected from cyanoesters of formula (1): ##STR1## wherein R.sub.1 is a C.sub.1 -C.sub.20 linear or branched alkyl, alkenyl, cycloalkyl, cycloalkylalkyl, alkylcycloalkyl, aryl, arylalkyl or alkylaryl group; n is 0, 1, 2 or 3; R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are independently selected from hydrogen or C.sub.1 -C.sub.20 linear or branched alkyl, alkenyl, cycloalkyl, cycloalkylalkyl, alkylcycloalkyl, aryl, arylalkyl or alkylaryl groups; two or more of R.sub.2 and R.sub.3, and R.sub.4 and R.sub.5, can be joined to form a cycle. Said catalyst components when used in the polymerization of olefins are characterized by an excellent response to hydrogen and capability to produce polymers with broad Molecular Weight Distribution.
摘要翻译：本发明涉及用于烯烃CH2 = CHR聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，其包含Ti，Mg，卤素和选自式（1）的氰酯的电子给体化合物）：其中R1是C1-C20直链或支链烷基，烯基，环烷基，环烷基烷基，烷基环烷基，芳基，芳基烷基或烷基芳基; n为0,1,2或3; R 2，R 3，R 4和R 5独立地选自氢或C 1 -C 20直链或支链烷基，烯基，环烷基，环烷基烷基，烷基环烷基，芳基，芳基烷基或烷基芳基; R2和R3中的两个或更多个，以及R4和R5可以连接形成一个循环。当用于烯烃聚合时，所述催化剂组分的特征在于对氢的优异响应和产生具有宽分子量分布的聚合物的能力。

82. 发明授权

US09056929B2 Catalyst for the polymerization of olefins 有权
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US09056929B2
公开(公告)日：2015-06-16
申请号：US12996018
申请日：2009-06-05
申请人： Masaki Fushimi , Marc Oliver Kristen , Martin Schneider , Giampiero Morini
发明人： Masaki Fushimi , Marc Oliver Kristen , Martin Schneider , Giampiero Morini
IPC分类号： C08F4/50 , C08F10/02 , C08F10/00
CPC分类号： C08F10/02 , C08F10/00 , C08F4/6493
摘要： The present invention relates to catalysts systems for the polymerization of olefins CH2═CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising (A) a solid catalyst component comprising Ti, Mg, and halogen (B) an aluminum alkyl compound and (C) a brominated cyclic hydrocarbon. Said catalyst systems have improved polymerization activity.
摘要翻译：本发明涉及用于烯烃CH 2 = CHR聚合的催化剂体系，其中R是具有1-12个碳原子的烷基，环烷基或芳基，其包含（A）包含Ti，Mg和卤素（B ）烷基铝化合物和（C）溴化环状烃。所述催化剂体系具有改善的聚合活性。

83. 发明申请

US20120165483A1 Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom 失效
标题翻译：二氯化镁 - 醇加合物和由其获得的催化剂组分
公开(公告)号：US20120165483A1
公开(公告)日：2012-06-28
申请号：US13394042
申请日：2010-09-03
申请人： Simona Guidotti , Dario Liguori , Giampiero Morini , Joachim T.M. Pater
发明人： Simona Guidotti , Dario Liguori , Giampiero Morini , Joachim T.M. Pater
IPC分类号： C08F4/654 , C08F110/06
CPC分类号： C08F110/06 , C08F10/06 , C08F4/022 , C08F4/651 , C08F4/6545
摘要： Solid adducts comprising a MgCl2, ethanol and a compound (A), said compounds being present in molar ratios defined by the following formula MgCl2.(EtOH)n(A)p in which n is from 0.1 to 6, p ranges from 0.001 to 0.5 and A is a compound selected from cyclic hydrocarbon structures which are substituted with at least two hydroxy groups.
摘要翻译：包含MgCl 2，乙醇和化合物（A）的固体加合物，所述化合物以下式MgCl 2（EtOH）n（A）p定义的摩尔比存在，其中n为0.1至6，p为0.001至 0.5和A是选自被至少两个羟基取代的环状烃结构的化合物。

84. 发明申请

US20110082270A1 Pyridazine-modified ziegler-natta catalyst system 审中-公开
标题翻译：哒嗪改性齐格勒 - 纳塔催化剂体系
公开(公告)号：US20110082270A1
公开(公告)日：2011-04-07
申请号：US12587187
申请日：2009-10-02
申请人： Sandor Nagy , Joachim T.M. Pater , Giampiero Morini
发明人： Sandor Nagy , Joachim T.M. Pater , Giampiero Morini
IPC分类号： C08F4/76 , C08F4/04 , B01J37/04
CPC分类号： C08F10/00 , C08F210/16 , C08F4/6555 , C08F4/6495 , C08F4/651 , C08F210/08 , C08F2500/12 , C08F2500/04 , C08F2500/21
摘要： A modified Ziegler-Natta catalyst system, a method for preparing the catalyst system, and a process for polymerizing an olefin in the presence of the catalyst system are disclosed. The catalyst system comprises a titanium or vanadium compound, an aluminum compound, and a pyridazine. Improved properties such as increased molecular weight and narrowed molecular weight distribution are obtained.
摘要翻译：公开了改进的齐格勒 - 纳塔催化剂体系，制备催化剂体系的方法和在催化剂体系存在下使烯烃聚合的方法。催化剂体系包括钛或钒化合物，铝化合物和哒嗪。获得了改进的性能，例如分子量增加和分子量分布变窄。

85. 发明申请

US20110082268A1 Indazole-modified ziegler-natta catalyst system 审中-公开
标题翻译：吲唑改性齐格勒 - 纳塔催化剂体系
公开(公告)号：US20110082268A1
公开(公告)日：2011-04-07
申请号：US12587148
申请日：2009-10-02
申请人： Sandor Nagy , Joachim T.M. Pater , Giampiero Morini
发明人： Sandor Nagy , Joachim T.M. Pater , Giampiero Morini
IPC分类号： C08F4/76 , C08F4/52 , B01J37/04
CPC分类号： C08F10/00 , C08F210/16 , C08F4/651 , C08F4/6495 , C08F4/6555 , C08F210/08 , C08F2500/12 , C08F2500/04 , C08F2500/21
摘要： A modified Ziegler-Natta catalyst system, a method for preparing the catalyst system, and a process for polymerizing an olefin in the presence of the catalyst system are disclosed. The catalyst system comprises a titanium or vanadium compound, an aluminum compound, and an indazole. Improved comonomer incorporation and the ability to regulate molecular weight are achieved in the manufacture of polyolefins.
摘要翻译：公开了改进的齐格勒 - 纳塔催化剂体系，制备催化剂体系的方法和在催化剂体系存在下使烯烃聚合的方法。催化剂体系包括钛或钒化合物，铝化合物和吲唑。在聚烯烃的制造中实现改进的共聚单体掺入和调节分子量的能力。

86. 发明申请

US20110077368A1 CATALYST FOR THE POLYMERIZATION OF OLEFINS 有权
标题翻译：烯烃聚合催化剂
公开(公告)号：US20110077368A1
公开(公告)日：2011-03-31
申请号：US12996018
申请日：2009-06-05
申请人： Masaki Fushimi , Marc Oliver Kristen , Martin Schneider , Giampiero Morini
发明人： Masaki Fushimi , Marc Oliver Kristen , Martin Schneider , Giampiero Morini
IPC分类号： C08F4/642 , B01J31/14
CPC分类号： C08F10/02 , C08F10/00 , C08F4/6493
摘要： The present invention relates to catalysts systems for the polymerization of olefins CH2═CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising (A) a solid catalyst component comprising Ti, Mg, and halogen (B) an aluminum alkyl compound and (C) a brominated cyclic hydrocarbon. Said catalyst systems have improved polymerization activity.
摘要翻译：本发明涉及用于烯烃CH 2 = CHR聚合的催化剂体系，其中R是具有1-12个碳原子的烷基，环烷基或芳基，其包含（A）包含Ti，Mg和卤素（B ）烷基铝化合物和（C）溴化环状烃。所述催化剂体系具有改善的聚合活性。

87. 发明申请

US20100324241A1 CATALYST FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：烯烃聚合催化剂
公开(公告)号：US20100324241A1
公开(公告)日：2010-12-23
申请号：US12735660
申请日：2009-02-02
申请人： Masaki Fushimi , Martin Schneider , Giampiero Morini
发明人： Masaki Fushimi , Martin Schneider , Giampiero Morini
IPC分类号： C08F4/76 , B01J31/02
CPC分类号： C08F10/02 , C08F110/06 , C08F4/6492 , C08F4/6494 , C08F2500/12
摘要： The present invention relates to catalysts systems for the polymerization of ethylene and its mixtures with olefins CH2═CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising (A) a solid catalyst component comprising Ti, Mg, halogen, (B) an aluminum alkyl compound and (C) an an acetal of formula HnC(OR1)4-n where n is O, 1 or 2 and R1 is C1-C10 hydrocarbon group.
摘要翻译：本发明涉及用于乙烯及其与烯烃CH 2 = CHR的混合物的聚合的催化剂体系，其中R是具有1-12个碳原子的烷基，环烷基或芳基，其包含（A）固体催化剂组分，其包含Ti，Mg ，卤素，（B）烷基铝化合物和（C）式为HnC（OR1）4-n的缩醛，其中n为0,1或2，R1为C1-C10烃基。

88. 发明申请

US20100120998A1 CATALYST COMPONENT FOR THE POLYMERIZATION OF OLEFINS 失效
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：US20100120998A1
公开(公告)日：2010-05-13
申请号：US12312592
申请日：2007-11-14
申请人： Masaki Fushimi , Giampiero Morini , Maria Schmitt , Mfartin Schneider
发明人： Masaki Fushimi , Giampiero Morini , Maria Schmitt , Mfartin Schneider
IPC分类号： C08F4/52 , B01J31/38 , B01J31/02 , C08F2/01
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/651 , C08F4/6494 , C08F2500/12 , C08F2500/18 , C08F210/08
摘要： A catalyst component for the polymerization of olefins comprises Mg, Ti, halogen, and an alpha-omega-diether represented by the general formula: (RO)—(CR1R2)n—(OR), wherein the number of n is from 5 to 10, R is an alkyl, cycloalkyl or aryl radical containing 1 to 12 carbons, and R1 and R2 are independently from each other hydrogen, an alkyl, cycloalkyl or aryl radical containing 1 to 12 carbons. The catalysts prepared with such component provide a high mileage for the production of polyolefins with a high bulk density of the polymer produced in gas-phase polymerization process or in slurry polymerization process. Such catalyst produces narrower MWD PE, if compared with other catalyst systems.
摘要翻译：用于烯烃聚合的催化剂组分包括由通式（RO） - （CR 1 R 2）n - （OR）表示的Mg，Ti，卤素和α-ω-二醚，其中n的数目为5〜 10，R为含有1至12个碳的烷基，环烷基或芳基，R 1和R 2彼此独立地为氢，含有1至12个碳的烷基，环烷基或芳基。用这种组分制备的催化剂为在气相聚合法或淤浆聚合方法中生产的聚合物的高堆积密度的聚烯烃的生产提供了很高的里程。如果与其他催化剂体系相比，这种催化剂产生较窄的MWD PE。

89. 发明申请

US20070282083A1 Process for the (Co) Polymerization of Ethylene 有权
标题翻译：乙烯（Co）聚合方法
公开(公告)号：US20070282083A1
公开(公告)日：2007-12-06
申请号：US10581983
申请日：2004-11-24
申请人： Pietro Baita , Massimo Covezzi , Gabriele Mei , Giampiero Morini , Joachim Pater
发明人： Pietro Baita , Massimo Covezzi , Gabriele Mei , Giampiero Morini , Joachim Pater
IPC分类号： C08F10/02 , C08F2/00 , C08F2/34 , C08F4/654
CPC分类号： C08F10/00 , C08F10/02 , C08F210/16 , C08F4/6494 , C08F4/651 , C08F2/001 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F2500/07 , C08F210/08
摘要： A process for preparing a broad molecular weight polyethylene carried out in the presence of a catalyst system comprising (i) a solid catalyst component comprising Mg, Ti, halogen, and optionally an internal electron donor compound, and (ii) an Al-alkyl cocatalyst said process comprising at least two step of polymerization (a) and (b), in which: in a first step (a) ethylene is polymerized in the presence of a molecular weight regulator in order to produce a ethylene (co)polymer, and in a further step (b), which is carried out in the presence of an external electron donor compound added to this polymerization step as a fresh reactant, ethylene is copolymerized with an alpha olefin of formula CH2═CHR, in which R is a C1-C20 hydrocarbon group, to produce an ethylene copolymer having a molecular weight higher than that of the copolymer produced in step (b).
摘要翻译：一种制备在催化剂体系存在下进行的宽分子量聚乙烯的方法，包括（i）包含Mg，Ti，卤素和任选的内电子给体化合物的固体催化剂组分，和（ii）Al-烷基助催化剂所述方法包括至少两个聚合步骤（a）和（b）），其中：在第一步（a）中，在分子量调节剂存在下使乙烯聚合以产生乙烯（共）聚合物，和在另外的步骤（b）中，其在作为新的反应物加入到该聚合步骤中的外部电子给体化合物的存在下进行，乙烯与式CH 2 -CHR的α-烯烃共聚，其中R是C1 -C 20烃基，得到分子量高于步骤（b）中制备的共聚物的乙烯共聚物。

90. 发明授权

US07049377B1 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers 失效
标题翻译： 1,3-二醚和用于烯烃聚合的组分和催化剂，其含有所述二醚
公开(公告)号：US07049377B1
公开(公告)日：2006-05-23
申请号：US08603497
申请日：1996-02-20
申请人： Giampiero Morini , Enrico Albizzati , Giulio Balbontin , Giovanni Baruzzi , Antonio Cristofori
发明人： Giampiero Morini , Enrico Albizzati , Giulio Balbontin , Giovanni Baruzzi , Antonio Cristofori
IPC分类号： C08F4/44
CPC分类号： C08F10/00 , C07C41/16 , C07C43/162 , C07C2601/10 , C07C2602/08 , C07C2603/18 , C07C2603/24 , C07C2603/28 , C07D311/82 , C07F7/081 , C08F110/06 , C08F4/651 , C08F4/6494 , C08F2500/12 , C08F2500/17
摘要： Cyclopolyenic 1,3-diethers wherein the carbon atom in position 2 belongs to a particular cyclic or polycyclic structure containing two or three unsaturations, solid catalyst components and catalysts therefrom, the catalysts comprising the reaction product of: i. a solid catalyst component containing an internal donor; ii. an Al-alkyl compound, and optionally iii. an external donor; the internal donor and/or the external donor being cyclopolyenic 1,3-diethers. The catalysts are useful for the polymerization of alpha-olefins.
摘要翻译：其中位置2的碳原子属于特定的含有两个或三个不饱和的环状或多环结构的环多烯1,3-二醚，固体催化剂组分和催化剂，所述催化剂包含以下反应产物：含有内给体的固体催化剂组分; ii。烷基铝化合物，和任选的iii。外部供体; 内给体和/或外供体是环多取代1,3-二醚。该催化剂可用于α-烯烃的聚合。

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