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81. 发明专利

AT144273T 未知
公开(公告)号：AT144273T
公开(公告)日：1996-11-15
申请号：AT92104743
申请日：1992-03-19
申请人： BASF AG
发明人： BESECKE SIEGMUND DR , SEITZ FRIEDRICH DR , GUENTHERBERG NORBERT DR , ZIMMER GUENTER DR
IPC分类号： C08L25/12 , C08L33/12

82. 发明专利

DE59107857D1 未知
公开(公告)号：DE59107857D1
公开(公告)日：1996-07-04
申请号：DE59107857
申请日：1991-10-19
申请人： BASF AG
发明人： NEUMANN RAINER DR , MUEHLBACH KLAUS DR , RUPPMICH KARL , BUESCHL RAINER DR , SEITZ FRIEDRICH DR , NIESSNER NORBERT DR
IPC分类号： C08K5/521 , C08L69/00

83. 发明专利

DE59204581D1 未知
公开(公告)号：DE59204581D1
公开(公告)日：1996-01-18
申请号：DE59204581
申请日：1992-09-05
申请人： BASF AG
发明人： NIESSNER NORBERT DR , SEITZ FRIEDRICH DR
IPC分类号： C08L25/08 , C08F285/00 , C08L25/00 , C08L25/12 , C08L33/04 , C08L33/06 , C08L33/08 , C08L33/18 , C08L33/20 , C08L33/24 , C08L35/00 , C08L35/06 , C08L51/00 , C08L51/04 , C08L51/06 , C08L69/00

84. 发明专利

ES2073609T3 未知
公开(公告)号：ES2073609T3
公开(公告)日：1995-08-16
申请号：ES91104981
申请日：1991-03-28
申请人： BASF AG
发明人： SEITZ FRIEDRICH DR , RUPPMICH KARL , GUENTHERBERG NORBERT DR , NIESSNER NORBERT DR
IPC分类号： C08F265/06 , C08F265/00 , C08F265/02 , C08F265/04 , C08F279/00 , C08F279/02 , C08L25/12 , C08L51/00 , C08L51/04 , C08L51/06
摘要： A particulate graft polymer comprising A: from 30 to 80% by weight of at least one elastomeric polymer A having a mean particle size of from 30 to 1000 nm and made from - based on A - A1: from 85 to 99.8% by weight of at least one alkyl acrylate A1 having 1 to 8 carbon atoms in the alkyl radical, A2: from 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A2 and A3: from 0.1 to 10% by weight of at least one monomer A3 containing one or more acidic groups, or A11: up to 100% by weight of a diene A11, A12: up to 50% by weight of at least one vinyl aromatic monomer A12 A13: up to 10% by weight of at least one monomer A13 containing one or more acidic groups, as the graft base, and B: from 20 to 70% by weight of a graft shell B which is grafted on to the elastomeric polymer A and is made from - based on B - B1: from 50 to 89.9% by weight of at least one vinyl aromatic monomer B1, B2: from 10 to 49.9% by weight of at least one polar, copolymerisable, ethylenically unsaturated monomer B2 and B3: from 0.1 to 10% by weight of at least one monomer B3 containing one or more basic groups. i

85. 发明专利

DE59105819D1 未知
公开(公告)号：DE59105819D1
公开(公告)日：1995-08-03
申请号：DE59105819
申请日：1991-03-28
申请人： BASF AG
发明人： SEITZ FRIEDRICH DR , RUPPMICH KARL , GUENTHERBERG NORBERT DR , NIESSNER NORBERT DR
IPC分类号： C08F265/06 , C08F265/00 , C08F265/02 , C08F265/04 , C08F279/00 , C08F279/02 , C08L25/12 , C08L51/00 , C08L51/04 , C08L51/06
摘要： A particulate graft polymer comprising A: from 30 to 80% by weight of at least one elastomeric polymer A having a mean particle size of from 30 to 1000 nm and made from - based on A - A1: from 85 to 99.8% by weight of at least one alkyl acrylate A1 having 1 to 8 carbon atoms in the alkyl radical, A2: from 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A2 and A3: from 0.1 to 10% by weight of at least one monomer A3 containing one or more acidic groups, or A11: up to 100% by weight of a diene A11, A12: up to 50% by weight of at least one vinyl aromatic monomer A12 A13: up to 10% by weight of at least one monomer A13 containing one or more acidic groups, as the graft base, and B: from 20 to 70% by weight of a graft shell B which is grafted on to the elastomeric polymer A and is made from - based on B - B1: from 50 to 89.9% by weight of at least one vinyl aromatic monomer B1, B2: from 10 to 49.9% by weight of at least one polar, copolymerisable, ethylenically unsaturated monomer B2 and B3: from 0.1 to 10% by weight of at least one monomer B3 containing one or more basic groups. i

86. 发明专利

DE59103615D1 未知
公开(公告)号：DE59103615D1
公开(公告)日：1995-01-12
申请号：DE59103615
申请日：1991-03-27
申请人： BASF AG
发明人： SEITZ FRIEDRICH DR , RUPPMICH KARL , VIETMEIER JUERGEN DR
IPC分类号： C08L25/00 , C08L25/02 , C08L25/12 , C08L33/00 , C08L33/04 , C08L33/12 , C08L33/24 , C08L35/00 , C08L35/06 , C08L51/00 , C08L51/04 , C08L51/06
摘要： Thermoplastic molding materials which have high gloss and are readily colored and comprise a first graft copolymer A of an elastomeric, crosslinked acrylate polymer as the graft base and a graft shell made from a vinyl-aromatic monomer and a polar, copolymerizable, ethylenically unsaturated monomer, and a second separately prepared graft copolymer B of an elastomeric crosslinked acrylate polymer as the graft base, which is different from that in A and has a larger mean particle diameter than the graft base of copolymer A, having a first graft shell of a vinyl-aromatic monomer and a second graft shell of a mixture of a vinyl aromatic monomer and a polar-copolymerizable, ethylenically unsaturated monomer, and a hard matrix C.

87. 发明专利

DE59103305D1 未知
公开(公告)号：DE59103305D1
公开(公告)日：1994-12-01
申请号：DE59103305
申请日：1991-02-12
申请人： BASF AG
发明人： SEITZ FRIEDRICH DR , RUPPMICH KARL
IPC分类号： C08L25/08 , C08L25/02 , C08L51/00 , C08L51/04 , C08L51/06
摘要： Toughened acrylate-styrene-acrylonitrile (ASA) moulding materials comprise (based on 100 pts wt (A)+(B)+(C)): (A) 1-30 wt% of an elastomeric polymer of ave particle size 30-1000 nm contg (A1) 50-99.9 wt% of an alkyl acrylate with 1-8C in the alkyl gp; (A2) 0.1-5 wt% of a polyfunctional crosslinking monomer; and (A3) 3-50 wt% of a monoethylenically unsatd monomer; (B) 5-40 wt% grafted on polymer (A) of (B1) 30-90 (pref 4.5-80) wt% of a vinyl aromatic monomer; (B2) 5-40 (pref 10-30) wt% of a polar ethylenically unsatd comonomer; and (B3) 5-30 (pref 10-25) wt% of an alkyl acrylate with 7-20 (pref 8-12)C in the alkyl gp; and (C) 30-94 wt% of a copolymer of (i) a vinyl aromatic monomer and (ii) a polar, ethylenically unsatd monomer (pref acrylonitrile).

88. 发明专利

DE4309545A1 未知
公开(公告)号：DE4309545A1
公开(公告)日：1994-09-29
申请号：DE4309545
申请日：1993-03-24
申请人： BASF AG
发明人： GOTTSCHALK AXEL DR , SEITZ FRIEDRICH DR , LOTZ ANDREAS , HEITZ WALTER PROF DR
IPC分类号： C08G65/44

89. 发明专利

DE4316024A1 Copolymers of 4-vinyl:phthalic acid, anhydride or ester(s) - are useful as components of polymer alloys 未知
公开(公告)号：DE4316024A1
公开(公告)日：1993-11-25
申请号：DE4316024
申请日：1993-05-13
申请人： BASF AG
发明人： GOTTSCHALK AXEL DR , SEITZ FRIEDRICH DR , MUEHLBACH KLAUS DR , RECTANUS SABINE , STADLER RAIMUND PROF DR , WEBER MARTIN DR
IPC分类号： C08F222/00 , C08L25/18
摘要： The use of copolymers (I) contg. 0.1-99.9 wt% 4-vinylphthalic anhydride, 4-vinyl-phthalic acid and/or dialkyl 4-vinylphthalate ester (II) and 99.9-0.1 wt% vinyl and/or diene comonomer(s) (III) as components of polymer alloys is claimed. ADVANTAGE - (I) have a desirable combination of properties as components of polymer alloys, e.g. markedly better heat distortion temp. than corresp. styrene homopolymers, together with the possibility of reactive phase coupling (via acid or anhydride gps.) (I) are therefore useful as compatibilisers in polymer alloys and for the prodn. of polymeric networks; copolymers contg. more than 50 wt% 4-vinylphthalic acid units are soluble in aq. alkali and are therefore also useful for the prodn. of resist materials. In an example, 4-Vinylphthalic acid was prepd. by bromination of phthalic acid with bromine in aq. NaOH soln., followed by reaction with ethylene for 16 hrs. at 100 deg. C and 40 bar in the presence of Et3N, Pd(OAc)2, tri-o-tolyl-phosphine and DMF, pptn. with CaCl2, soln. and acidifcation. The acid obtd. was sublimed at 90 deg. C and 0.03 mbar to give 4-vinylphthalic anhydride (VPA). A copolymer contg. 10.5 wt% VPA and 89.5 wt% styrene (by FT-IR analysis) was prepd. by radical polymerisation in acetonitrile with AIBN as initiator, followed by re-pptn. from THF/methanol. The prod. had Mn, 5700; Tg, 91 deg. C (cf. 4900, 74 deg. C for 100% styrene homopolymer); a copolymer of 67.4 wt% VPA and 32.6 wt% styrene was soluble in aq. NaOH soln., with Mn = 2200 and Tg = 160 deg. C.

90. 发明专利

DE4201845A1 未知
公开(公告)号：DE4201845A1
公开(公告)日：1993-07-29
申请号：DE4201845
申请日：1992-01-24
申请人： BASF AG
发明人： WEBER MARTIN DR , MUEHLBACH KLAUS DR , SEITZ FRIEDRICH DR
IPC分类号： C08J11/06 , C08L23/10

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