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    • 83. 发明公开
    • MATERIAUX ELASTIQUES
    • 柔性材料
    • EP1848776A1
    • 2007-10-31
    • EP06709330.2
    • 2006-02-14
    • ARKEMA France
    • TOURNILHAC, FrançoisLEIBLER, LudwikCORDIER, PhilippeSOULIE-ZIAKOVIC, Corinne
    • C08L101/02C08F8/30
    • C08L101/025C08F8/30C08F8/34C08G83/008
    • The invention relates to materials having rubber-like elasticity and comprising molecules with a mass of between 9 and 9000 g/mole, all or part of said molecules having at least three groups (also known as associative groups) that can associate by means of noncovalent interactions. The inventive material, which comprises non-polymerised and non-chemically-crosslinked small molecules, has rubber-like elasticity properties. In one embodiment of the invention, the material has rubber-like elasticity at ambient temperature. Above a certain temperature, the material flows like a simple liquid. The material is thermoreversible, i.e. a material with rubber-like elasticity can be obtained once again by means of cooling. In addition, the invention comprises a self-healing material that is potentially recyclable, which is never the case with a chemically-crosslinked elastomer. According to one embodiment of the invention, the molecules forming the inventive material bear associative groups having formula (1), in which A denotes oxygen, sulphur or NH, whereby the carbon atoms on formula (1) can be substituted. A preferably denotes oxygen. Advantageously, the material comprises (i) molecules having at least 3 associative groups and (ii) molecules having a single associative group. Moreover, the molecules are preferably obtained from fatty acid derivatives.