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81. 发明授权

US06528683B1 Method for producing shell catalysts for the catalytic vapor-phase oxidation of aromatic hydrocarbons and catalysts obtained in such a manner 失效
标题翻译：用于生产用于芳烃的催化气相氧化的壳催化剂和以这种方式获得的催化剂的方法
公开(公告)号：US06528683B1
公开(公告)日：2003-03-04
申请号：US09701517
申请日：2000-11-30
申请人： Thomas Heidemann , Frank Rosowski , Gerd Linden , Michael Seufert , Gerhard Hefele , Peter Michael Lorz
发明人： Thomas Heidemann , Frank Rosowski , Gerd Linden , Michael Seufert , Gerhard Hefele , Peter Michael Lorz
IPC分类号： C07C5116
CPC分类号： B01J37/0232 , B01J23/22 , B01J37/0219 , B01J37/0223 , C07C51/265 , Y10T428/31935 , C07C63/16
摘要： The invention relates to a method for producing shell catalysts for the catalytic vapor-phase oxidation of aromatic carboxylic acids and/or carboxylic acid anhydrides comprised of a supporting core and of catalytically active metal oxides which are deposited in a shell-shaped manner on said supporting core. The inventive catalysts are obtained by spraying an aqueous active mass suspension, said suspension containing the active metal oxides, at higher temperatures onto the hot supporting material which has a temperature ranging from 50 to 450° C. The aqueous active mass suspension contains 1 to 10 wt. %, with regard to the solid content of the active mass suspension, a binding agent comprised of A) a polymerizate obtained by radical polymerization, containing 5 to 100 wt. % of monomers (a) in the form of ethylenically unsaturated acid anhydrides or ethylenically unsaturated dicarboxylic acids whose carboxyl groups can form an anhydride and containing 0 to 95 wt. % monoethylenically unsaturated monomers (b) with the provision that the monomers (a) and (b) comprise, on average, a maximum of 6 carbon atoms which are not functionalized with groups containing oxygen, and of B) an alkanolamine having at least 2 OH groups, a maximum of 2 nitrogen atoms and a maximum of 8 C-atoms, whereby the weight ratio A:B ranges from 1:0.05 to 1:1.
摘要翻译：本发明涉及一种用于制备用于催化气相氧化芳族羧酸和/或羧酸酐的壳催化剂的方法，所述芳族羧酸和/或羧酸酐由支撑芯和催化活性金属氧化物组成，其以壳形方式沉积在所述支撑核心。本发明的催化剂是通过将含水活性物质悬浮液（含有活性金属氧化物的悬浮液）在较高温度下喷洒到温度为50-450℃的热支撑材料上而获得的。水性活性悬浮液含有1至10 重量％，关于活性悬浮液的固体含量，结合剂由A）通过自由基聚合获得的聚合物，其含有5〜100重量％％的烯属不饱和酸酐或烯属不饱和二羧酸形式的单体（a），其羧基可以形成酸酐并含有0至95重量％％单烯属不饱和单体（b），条件是单体（a）和（b）平均包含不含有氧的基团不被官能化的最多6个碳原子，和B）具有至少2个的链烷醇胺 OH基团，最多2个氮原子和最多8个C原子，其中重量比A:B的范围为1:0.05至1:1。

82. 发明授权

US08933254B2 Process for making ethylene oxide 有权
标题翻译：制备环氧乙烷的方法
公开(公告)号：US08933254B2
公开(公告)日：2015-01-13
申请号：US13003995
申请日：2009-07-13
申请人： Radwan Abdallah , Torsten Mäurer , Tobias Rosendahl , Frank Rosowski , Gerhard Theis , Terry Mazanec , Soumitra Deshmukh , Laura J. Silva
发明人： Radwan Abdallah , Torsten Mäurer , Tobias Rosendahl , Frank Rosowski , Gerhard Theis , Terry Mazanec , Soumitra Deshmukh , Laura J. Silva
IPC分类号： C07D301/03 , C07D301/10
CPC分类号： C07D301/10
摘要： This invention relates to a process, comprising reacting ethylene and oxygen or a source of oxygen in the presence of a catalyst in a reactor to form a product comprising ethylene oxide, wherein the catalyst contains silver or silver compound and a support and the catalyst is in the form of particulate solids having a mean particle diameter from 1 to 1000 μm and wherein the molar ratio of oxygen to ethylene is from 1:4 to 10:1.
摘要翻译：本发明涉及一种方法，包括在反应器中在催化剂存在下使乙烯和氧气或氧源反应形成包含环氧乙烷的产物，其中催化剂含有银或银化合物和载体，催化剂在平均粒径为1-1000μm的颗粒固体的形式，其中氧与乙烯的摩尔比为1:4至10:1。

83. 发明授权

US08618336B2 Process for long-term operation of a heterogeneously catalyzed partial gas phase oxidation of propene to acrolein 有权
标题翻译：长期运行丙烯醛异丙烯催化部分气相氧化丙烯的方法
公开(公告)号：US08618336B2
公开(公告)日：2013-12-31
申请号：US13271448
申请日：2011-10-12
申请人： Josef Macht , Klaus Joachim Mueller-Engel , Frank Rosowski
发明人： Josef Macht , Klaus Joachim Mueller-Engel , Frank Rosowski
IPC分类号： C07C45/28
CPC分类号： C07C45/35 , C07C47/22
摘要： A process for long-term operation of a heterogeneously catalyzed partial gas phase oxidation of propene to acrolein, in which the propene present in the reaction gas input mixture is partially oxidized as this gas mixture passes through the fixed catalyst bed which is accommodated in two spatially successive temperature zones A, B, and, in long-term operation, as a measure to counteract the reduction in the quality of the fixed catalyst bed, the temperature of at least one of the two temperature zones is increased such that the difference TB−TA becomes increasingly greater, where TB is the temperature of temperature zone B, and TA the temperature of temperature zone A.
摘要翻译：长期运行丙烯到丙烯醛的非均相催化的部分气相氧化丙烯醛的方法，其中存在于反应气体输入混合物中的丙烯被部分氧化，因为该气体混合物通过固定的催化剂床，该催化剂床容纳在空间上连续的温度区域A，B，并且在长期运行中，作为抵消固定催化剂床的质量降低的措施，两个温度区域中的至少一个的温度增加，使得TB- TA变得越来越大，其中TB是温度区B的温度，TA是温度区A的温度。

84. 发明申请

US20120071671A1 CATALYST AND METHOD FOR PARTIALLY OXIDIZING HYDROCARBONS 审中-公开
标题翻译：催化剂和部分氧化氢氧化物的方法
公开(公告)号：US20120071671A1
公开(公告)日：2012-03-22
申请号：US13375019
申请日：2010-05-28
申请人： Andrey Karpov , Hartmut Hibst , Christine Deißler , Cornelia Katharina Dobner , Frank Rosowski , Nadine Brem , Stephan Schunk
发明人： Andrey Karpov , Hartmut Hibst , Christine Deißler , Cornelia Katharina Dobner , Frank Rosowski , Nadine Brem , Stephan Schunk
IPC分类号： C07D307/89 , B01J27/199 , B01J23/68
CPC分类号： B01J23/686 , B01J23/002 , B01J23/687 , B01J23/8993 , B01J27/199 , B01J37/0045 , B01J2523/00 , C07C51/265 , C07C63/16 , C07C63/26 , B01J2523/18 , B01J2523/305 , B01J2523/55 , B01J2523/68 , B01J2523/51 , B01J2523/3712 , B01J2523/53 , B01J2523/54 , B01J2523/17 , B01J2523/69 , B01J2523/15 , B01J2523/56 , B01J2523/842
摘要： The invention relates to a catalyst for partially oxidizing hydrocarbons in the gas phase, containing a multi-metal oxide of the general formula (I), AgaMObVcMdOe.f H2O (I), wherein M stands for at least one element selected from among Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr, Ba, B, Al, Ga, In, Si, Sn, Pb, P, Sb, Bi, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Au, Zn, Cd, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and U, a has a value of 0.5 to 1.5, b has a value of 0.5 to 1.5, c has a value of 0.5 to 1.5, a+b+c has the value 3, d has a value of less than 1, e means a number that is determined by the valence and frequency of the elements other than oxygen in the formula (I), f has a value of 0 to 20, which multi-metal oxide exists in a crystal structure, the X-ray powder diffractogram of which is characterized by diffraction reflections at a minimum of 5 lattice distances selected from among d=4.53, 3.38, 3.32, 3.23, 2.88, 2.57, 2.39, 2.26, 1.83, 1.77 AA (+−0.04 AA).
摘要翻译：本发明涉及一种用于部分氧化气相中的烃的催化剂，其含有通式（I）的多金属氧化物，AgaMObVcMdOe.fH 2 O（I），其中M代表至少一种选自Li， Na，K，Rb，Cs，Be，Mg，Ca，Sr，Ba，B，Al，Ga，In，Si，Sn，Pb，P，Sb，Bi，Y，Ti，Zr，Hf， Ta，Cr，W，Mn，Re，Fe，Ru，Os，Co，Rh，Ir，Ni，Pd，Pt，Cu，Au，Zn，Cd，La，Ce，Pr，Nd，Sm，Eu， Tb，Dy，Ho，Er，Tm，Yb，Lu和U，a的值为0.5〜1.5，b为0.5〜1.5，c为0.5〜1.5，a + b + c为值3，d的值小于1，e表示式（I）中除氧以外的元素的化合价和频率所决定的数，f为0〜20，金属氧化物存在于晶体结构中，其X射线粉末衍射图的特征在于从d = 4.53,3.33,3.32,3.23,28.88,2.57,2.39,2.26,1中的至少5个晶格距离的衍射反射 .83,1.77AA（±0.04A）。

85. 发明申请

US20110118487A1 PROCESS FOR MAKING ETHYLENE OXIDE 有权
标题翻译：制造乙烯氧化物的方法
公开(公告)号：US20110118487A1
公开(公告)日：2011-05-19
申请号：US13003995
申请日：2009-07-13
申请人： Radwan Abdallah , Torsten Mäurer , Tobias Rosendahl , Frank Rosowski , Gerhard Theis , Terry Mazanec , Soumitra Deshmukh , Laura J. Silva
发明人： Radwan Abdallah , Torsten Mäurer , Tobias Rosendahl , Frank Rosowski , Gerhard Theis , Terry Mazanec , Soumitra Deshmukh , Laura J. Silva
IPC分类号： C07D301/04
CPC分类号： C07D301/10
摘要： This invention relates to a process, comprising reacting ethylene and oxygen or a source of oxygen in the presence of a catalyst in a reactor to form a product comprising ethylene oxide, wherein the catalyst contains silver or silver compound and a support and the catalyst is in the form of particulate solids having a mean particle diameter from 1 to 1000 μm and wherein the molar ratio of oxygen to ethylene is from 1:4 to 10:1.
摘要翻译：本发明涉及一种方法，包括在反应器中在催化剂存在下使乙烯和氧气或氧源反应形成包含环氧乙烷的产物，其中催化剂含有银或银化合物和载体，催化剂在平均粒径为1-1000μm的颗粒固体的形式，其中氧与乙烯的摩尔比为1:4至10:1。

86. 发明申请

US20110028740A1 METHOD FOR STARTING A GAS PHASE OXIDATION REACTOR THAT CONTAINS A CATALYTICALLY ACTIVE SILVER-VANADIUM OXIDE BRONZE 审中-公开
标题翻译：启动含有催化活性银 - 氧化钒的气相氧化反应器的方法
公开(公告)号：US20110028740A1
公开(公告)日：2011-02-03
申请号：US12936648
申请日：2009-04-07
申请人： Cornelia Dobner , Ulf Dietrich , Thomas Mackewitz , Sebastian Storck , Hagen Wilmer , Frank Rosowski , Andreas Tenten
发明人： Cornelia Dobner , Ulf Dietrich , Thomas Mackewitz , Sebastian Storck , Hagen Wilmer , Frank Rosowski , Andreas Tenten
IPC分类号： C07D307/89 , C07D307/36 , C07C51/347 , C07C63/00 , C07C63/04
CPC分类号： C07C51/265 , C07C63/16
摘要： What is described is a method for starting a gas phase oxidation reactor that contains a bed of a first catalyst whose active material comprises a catalytically active silver-vanadium oxide bronze, and at least one bed of a second catalyst whose catalytically active material comprises vanadium pentoxide and titanium dioxide, and whose temperature is controllable by means of a heat transfer medium. In the operating state, a gas stream which comprises a loading cop of a hydrocarbon and molecular oxygen is passed through the reactor over the bed of the first and second catalyst at a temperature Top of the heat transfer medium. For the startup, a) a gas stream is passed through the reactor with a starting loading c0 which is less than cop, and at a starting temperature T0 of the heat transfer medium which is less than Top, and b) the temperature of the heat transfer medium is brought to Top and the loading of the gas stream to cop. The process combines a short startup time without exceedance of emissions or quality requirements, long catalyst lifetime, high yield and low formation of by-products.
摘要翻译：描述的是一种起始气相氧化反应器的方法，该反应器含有一种第一催化剂床，其活性物质包含催化活性的银 - 钒氧化物青铜，以及至少一个第二催化剂床，其催化活性物质包含五氧化二钒和二氧化钛，其温度可通过传热介质控制。在操作状态下，在传热介质的温度Top下，将包含烃和分子氧的负载管的气流在第一和第二催化剂的床上通过反应器。对于启动，a）气流通过反应器，起动负载c0小于保护时间，并且传热介质的起始温度T0小于Top，b）热量的温度转移介质被带到顶部并将气流装载到管路中。该过程结合了启动时间短，而不会超过排放或质量要求，长催化剂寿命，高产率和低副产物形成。

87. 发明申请

US20090156835A1 PREPARATION OF PHTHALIC ANHYDRIDE BY GAS PHASE OXIDATION OF O-XYLENE IN A MAIN REACTOR AND POSTREACTOR 有权
标题翻译：通过气相氧化在主反应器和载体中制备邻苯二甲酸二异氰酸酯
公开(公告)号：US20090156835A1
公开(公告)日：2009-06-18
申请号：US12301370
申请日：2007-05-18
申请人： Thomas Mackewitz , Frank Rosowski , Andreas Tenten
发明人： Thomas Mackewitz , Frank Rosowski , Andreas Tenten
IPC分类号： C07D307/89
CPC分类号： C07D307/89 , C07C51/265 , C07C63/16
摘要： A process is described for preparing phthalic anhydride by catalytic gas phase oxidation of o-xylene, in which a gaseous mixture of o-xylene and an oxygenous gas is converted in a main reactor to a gaseous intermediate reaction product which comprises unconverted o-xylene, phthalic anhydride underoxidation products and phthalic anhydride, the heat of reaction which arises in the main reactor being removed at least partly by indirect cooling with a heat carrier medium, and the intermediate reaction product being introduced into a postreactor. The concentration of unconverted o-xylene in the intermediate reaction product is at least 1% by weight, and the sum of the concentrations of phthalic anhydride underoxidation products in the intermediate reaction product is at least 0.5% by weight. The process allows an increase in the overall yield of phthalic anhydride without or without significant deterioration in the product quality.
摘要翻译：描述了通过邻二甲苯的催化气相氧化制备邻苯二甲酸酐的方法，其中邻二甲苯和氧气的气体混合物在主反应器中转化为包含未转化的邻二甲苯的气态中间体反应产物，邻苯二甲酸酐脱氧产物和邻苯二甲酸酐，至少部分通过用载热介质间接冷却除去主反应器中产生的反应热，并将中间反应产物引入后反应器中。中间反应产物中未转化的邻二甲苯的浓度为至少1重量％，中间反应产物中邻苯二甲酸酐未氧化产物的浓度之和为至少0.5重量％。该方法允许邻苯二甲酸酐的总产率提高，而不会产生质量的显着劣化。

88. 发明申请

US20090118531A1 NOVEL SUPPORTED CATALYST FOR AMMOXIDATION 审中-公开
标题翻译：新型支持的氧化催化剂
公开(公告)号：US20090118531A1
公开(公告)日：2009-05-07
申请号：US12298806
申请日：2007-04-23
申请人： Hartmut Hibst , Sabine Huber , Frank Rosowski
发明人： Hartmut Hibst , Sabine Huber , Frank Rosowski
IPC分类号： C07C253/28 , B01J23/22
CPC分类号： B01J23/22 , B01J21/04 , B01J23/002 , B01J23/30 , B01J35/023 , B01J37/0201 , B01J37/0205 , B01J2523/00 , C07C253/28 , B01J2523/15 , B01J2523/53 , B01J2523/55 , B01J2523/69 , C07C255/51 , C07C255/50
摘要： Supported catalysts comprising a support having a mean diameter of ≦78 μm, a vanadium oxide, an antimony oxide, one or more alkali metal or alkaline earth metal oxides, and one or more oxides of tungsten, molybdenum, titanium, iron, cobalt, nickel, manganese, potassium, copper or mixtures thereof; processes for preparing said catalysts; and processes for preparing an aromatic or heteroaromatic nitrile in the presence of such a supported catalyst.
摘要翻译：包含平均直径<=78μm，氧化钒，氧化锑，一种或多种碱金属或碱土金属氧化物的载体和一种或多种钨，钼，钛，铁，钴，镍，锰，钾，铜或其混合物; 制备所述催化剂的方法; 以及在这种负载催化剂存在下制备芳族或杂芳族腈的方法。

89. 发明授权

US07462727B2 Multimetal oxide containing silver, vanadium and a promoter metal and use thereof 失效
标题翻译：含有银，钒和助催化剂金属的多金属氧化物及其用途
公开(公告)号：US07462727B2
公开(公告)日：2008-12-09
申请号：US10566019
申请日：2004-07-23
申请人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck
发明人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck
IPC分类号： C07D307/89 , C07C51/255 , C07C51/16 , B01J23/00
CPC分类号： C07C51/313 , B01J23/002 , B01J23/682 , B01J23/688 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J37/0045 , B01J37/0223 , B01J2523/00 , C01G31/006 , C07C51/265 , C07C63/16 , B01J2523/18 , B01J2523/3712 , B01J2523/55 , B01J2523/72 , B01J2523/47
摘要： A multimetal oxide of the formula I, Aga-cQbMcV2Od*e H2O, I where a is from 0.3 to 1.9, Q is an element selected from among P, As, Sb and/or Bi, is from 0 to 0.3, M is a metal selected from among Nb, Ce, W, Mn, Ta, Pd, Pt, Ru and/or Rh, c is from 0.001 to 0.5, with the proviso that (a-c)≧0.1, d is a number which is determined by the valence and abundance of the elements other than oxygen in the formula I and e is from 0 to 20, and also precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are described.
摘要翻译：式I的多金属氧化物，<？in-line-formula description =“In-Line Formulas”end =“lead”→> Aga-cQbMcV2Od * e H2O，I <？in-line-formula description =“In- 其中a为0.3〜1.9，Q为选自P，As，Sb和/或Bi的元素，为0〜0.3，M为选自Nb， Ce，W，Mn，Ta，Pd，Pt，Ru和/或Rh，c为0.001至0.5，条件是（ac）> = 0.1，d为由化合价描述了式I中的氧以外的元素和e为0至20，并且还描述了由其制备的用于芳族烃的部分氧化的预催化剂和催化剂。

90. 发明申请

US20080227992A1 Catalyst and Methods for Producing Maleic Anhydride 审中-公开
标题翻译：用于生产马来酸酐的催化剂和方法
公开(公告)号：US20080227992A1
公开(公告)日：2008-09-18
申请号：US11997023
申请日：2006-07-21
申请人： Cornelia Dobner , Mark Duda , Andreas Raichle , Hagen Wilmer , Frank Rosowski , Markus Holzle
发明人： Cornelia Dobner , Mark Duda , Andreas Raichle , Hagen Wilmer , Frank Rosowski , Markus Holzle
IPC分类号： C07D307/60 , B01J27/198 , B01J27/16
CPC分类号： B01J37/0009 , B01J23/002 , B01J23/8472 , B01J27/198 , B01J35/002 , B01J37/031 , B01J37/04 , B01J37/16 , B01J2523/00 , C07C51/215 , C07C57/145 , B01J2523/51 , B01J2523/55 , B01J2523/842
摘要： Catalysts comprising a catalytically active composition, the catalytically active composition comprising vanadium, phosphorus, iron and oxygen, wherein the catalytically active composition has an iron:vanadium atomic ratio of 0.005 to
摘要翻译：包含催化活性组合物的催化剂，包含钒，磷，铁和氧的催化活性组合物，其中催化活性组合物的铁：钒原子比为0.005至0.05，并且其中催化活性组合物中的铁衍生自铁原料，包含磷酸铁（III）; 并描述了制备这种催化剂的方法及其用途来制备马来酸酐。

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