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81. 发明专利

JP2006213870A Thermoplastic resin composite composition and method for producing the same 审中-公开
标题翻译：热塑性树脂复合组合物及其制造方法
公开(公告)号：JP2006213870A
公开(公告)日：2006-08-17
申请号：JP2005029824
申请日：2005-02-04
申请人： Du Pont Mitsui Fluorochem Co Ltd , Univ Nagoya , 三井・デュポンフロロケミカル株式会社 , 国立大学法人名古屋大学
发明人： RI TEISHO , TAKEDA KUNIHIKO , TANAHASHI MITSURU , KANAYAMA NAOKI , MATSUDA NARIHIRO , HIROSE MAKI
IPC分类号： C08L101/00 , C08K3/00
CPC分类号： C08J3/201 , C08J5/10
摘要： PROBLEM TO BE SOLVED: To provide a thermoplastic resin composite composition containing inorganic fine particles dispersed to a primary particle level, and having excellent mechanical properties, dimensional stability and the like.
SOLUTION: The thermoplastic resin composite composition is obtained by melt-mixing an aggregate of inorganic fine particles obtained as follows with a thermoplastic resin, and contains the inorganic fine particles having ≤1 μm average particle diameter dispersed in the resin. The aggregate is obtained by drying a mixed liquid of the inorganic fine particles and an inorganic salt to afford a solidified product, and removing the inorganic salt from the solidified product with a solvent, and is formed by a cohesive power to each other of the inorganic fine particles provided by the drying at a temperature at which the surface fusion with each other of the fine particles is not caused.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：提供一种包含分散在一次粒子水平的无机微粒并具有优异的机械性能，尺寸稳定性等的热塑性树脂复合组合物。解决方案：热塑性树脂复合组合物通过将如下获得的无机细颗粒的聚集体与热塑性树脂熔融混合而获得，并且包含分散在树脂中的平均粒径≤1μm的无机细颗粒。通过干燥无机细颗粒和无机盐的混合液来获得凝固产物，并且用溶剂从固化产物中除去无机盐，并且通过粘合力彼此形成无机物形成聚集体在不产生彼此表面熔融的温度下通过干燥而提供的微粒子。版权所有（C）2006，JPO＆NCIPI

82. 发明专利

JP2006077042A Azeotrope-like composition 有权
标题翻译： AZEOTROPE-LIKE组合物
公开(公告)号：JP2006077042A
公开(公告)日：2006-03-23
申请号：JP2004259295
申请日：2004-09-07
申请人： Du Pont Mitsui Fluorochem Co Ltd , 三井・デュポンフロロケミカル株式会社
发明人： YOKOZAWA MICHINORI , KIKUCHI HIDEAKI
IPC分类号： C11D7/28 , C09K3/00
摘要： PROBLEM TO BE SOLVED: To provide a new azeotrope-like composition exhibiting an azeotropic property or behavior (an azeotrope-like property) close to the azeotrope and capable of replacing a cleaning agent suitably used for degreasing of grease, processed oil, etc., used for metal components as processing or rust prevention and removal of flux in production of a semiconductor and other applications such as a foaming agent, a working medium, a dispersing agent, an electrical insulating agent by using, as a base, a hydrofluoro ether free from fear disrupting an ozone layer and not containing chlorine.
SOLUTION: The azeotrope-like composition is composed of a nonafluorobutylmethyl ether and tetrafluoropropanol. The azeotrope-like composition is preferably composed of 80-99.5 wt.% nonafluorobutyl methyl ether and 20-0.5 wt.% 2,2,3,3-tetrafluoropropanol.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种在共沸物附近表现出共沸性或行为（类共沸物性）的新型共沸混合物组合物，并能够替代适合用于润滑脂，加工油的脱脂剂的清洗剂，等等，用于金属组分作为半导体生产中的助熔剂的防锈和除锈，以及诸如发泡剂，工作介质，分散剂，电绝缘剂的其它应用，例如通过以下方式使用：氢氟醚不受破坏臭氧层而不含氯的恐惧。解决方案：类共沸组合物由九氟丁基甲基醚和四氟丙醇组成。类似共沸物组合物优选由80-99.5重量％的九氟丁基甲基醚和20-0.5重量％的2,2,3,3-四氟丙醇组成。版权所有（C）2006，JPO＆NCIPI

83. 发明专利

JP2005212318A Laminate including fluorocarbon resin coat and coat forming fluorocarbon resin 有权
标题翻译：层压板包括氟树脂涂层和涂层形成氟碳树脂
公开(公告)号：JP2005212318A
公开(公告)日：2005-08-11
申请号：JP2004022915
申请日：2004-01-30
申请人： Du Pont Mitsui Fluorochem Co Ltd , E I Du Pont De Nemours & Co , イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company , 三井・デュポンフロロケミカル株式会社
发明人： HAYAKAWA OSAMU , RYU GYOKUKEI , MOCHIZUKI YUJI
IPC分类号： B32B27/30 , C08F214/18 , C08F214/26 , C08F216/14
摘要： PROBLEM TO BE SOLVED: To provide a laminate with a fluorocarbon resin coat formed which has flexibility while keeping heat resistance and non-adhesive properties on a substrate such as a roll or a belt of a copying machine, a printer, or the like and a coat forming fluorocarbon resin.
SOLUTION: The laminate includes the substrate containing a metal oxide and a functional group-containing fluorocarbon resin covering layer formed on the substrate. The coat forming fluorocarbon resin comprises a fluorocarbon resin containing the functional groups. A fluorocarbon resin containing phosphate groups or a mixture of the fluorocarbon resin containing the phosphate groups and a fluorocarbon resin having no functional group is a good example of the fluorocarbon resin containing the functional groups. As the fluorocarbon resin containing the phosphate groups, a tetrafluoroethylene/trifluorovinyl ether group-containing dihydrogenphosphate compound/fluorine-containing comonomer copolymer resin is named appropriately.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了提供具有氟树脂涂层的层压体，其具有柔性，同时保持耐热性和非粘合性，例如在诸如复印机，打印机或打印机的卷筒或带的基板上和涂层形成氟碳树脂。解决方案：层压体包括含有金属氧化物的基板和在基板上形成的含官能团的氟碳树脂覆盖层。涂层形成氟碳树脂包括含有官能团的氟碳树脂。含有磷酸酯基的氟碳树脂或含有磷酸酯基的氟碳树脂和不含官能团的氟碳树脂的混合物是含有官能团的氟碳树脂的良好实例。作为含有磷酸酯基的氟碳树脂，适当地列举含有四氟乙烯/三氟乙烯基醚基的磷酸二氢化合物/含氟共聚单体共聚物树脂。版权所有（C）2005，JPO＆NCIPI

84. 发明专利

JP2005075880A Low-electrostatic heat fusable fluororesin composition 审中-公开
标题翻译：低电导率热熔氟烷基酯组合物
公开(公告)号：JP2005075880A
公开(公告)日：2005-03-24
申请号：JP2003306028
申请日：2003-08-29
申请人： Du Pont Mitsui Fluorochem Co Ltd , 三井・デュポンフロロケミカル株式会社
发明人： RI TEISHO
IPC分类号： B32B27/30 , C08L27/12 , C09D127/12 , D01F6/12 , D01F6/48 , D03D15/12 , D04H1/4318 , D04H1/42
CPC分类号： C08L27/12 , C08L2205/02 , C09D127/12 , C08L2666/04
摘要： PROBLEM TO BE SOLVED: To provide a low-electrostatic heat fusable fluororesin which, while maintaining properties of heat fusable fluororesin such as heat resistance and chemical resistance, has antistatic function, and to provide a molded article obtained therefrom.
SOLUTION: The low-electrostatic, heat fusable fluororesin composition consists of (A) 99.5-0 wt% of a heat fusable fluororesin and (B) 0.5-100 wt% of a heat fusable fluororesin having at least one functional group selected from a carboxylic acid group or its derivative, hydroxy group, nitrile group, cyanato group, carbamoyloxy group, phosphonoxy group, halophosphonoxy group, sulfonic acid group or its derivative, and sulfohalide group. The molded article obtained from it is also provided.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种低温静电热熔融氟树脂，其在保持耐热性和耐化学性等耐热可熔性氟树脂的性能的同时具有抗静电功能，并提供由其获得的模塑制品。解决方案：低静电热熔氟树脂组合物由（A）99.5-0重量％的热熔氟树脂和（B）0.5-100重量％的具有至少一个选自官能团的热熔氟树脂组成羧基或其衍生物，羟基，腈基，氰基，氨基甲酰氧基，膦酰氧基，卤代膦酰氧基，磺酸基或其衍生物和磺酰卤基。还提供了从其获得的模塑制品。版权所有（C）2005，JPO＆NCIPI

85. 发明专利

JP2004161921A Fluorine-containing resin having flexibility and moldable by melt-extrusion molding, and article using the same 有权
标题翻译：具有柔软性和通过熔融挤出成型成型的含氟树脂和使用其的制品
公开(公告)号：JP2004161921A
公开(公告)日：2004-06-10
申请号：JP2002330617
申请日：2002-11-14
申请人： Du Pont Mitsui Fluorochem Co Ltd , 三井・デュポンフロロケミカル株式会社
发明人： IWASAKI TAKAHIKO
IPC分类号： C08F214/26 , C08F8/20
摘要： PROBLEM TO BE SOLVED: To provide a fluorine-containing resin that has flexibility and can be molded by melt-extrusion molding.
SOLUTION: The fluorine-containing resin is produced as a binary copolymer consisting of a tetrafluoroethylene having a measurement value of a storage elastic modulus (G') at 200°C of 20 MPa or less as measured by a dynamic viscoelasticity measuring device (ARES) and an elastic modulus at 25°C of 200 MPa or more and a perfluoroalkyl vinyl ether.
COPYRIGHT: (C)2004,JPO
摘要翻译：待解决的问题：提供一种具有柔软性并可通过熔融挤出成型模塑的含氟树脂。解决方案：含氟树脂是由二维共聚物制成的，该二元共聚物由具有200℃下的储能弹性模量（G'）的测定值为20MPa以下的四氟乙烯构成，通过动态粘弹性测定装置（ARES），25℃下的弹性模量为200MPa以上，全氟烷基乙烯基醚。版权所有（C）2004，JPO

86. 发明专利

JP2003082187A Electroconductive fluororesin composition and its manufacturing method 有权
标题翻译：电磁荧光素组合物及其制备方法
公开(公告)号：JP2003082187A
公开(公告)日：2003-03-19
申请号：JP2002187359
申请日：2002-06-27
申请人： Du Pont Mitsui Fluorochem Co Ltd , 三井・デュポンフロロケミカル株式会社
发明人： RI TEISHO , KONDO SHOSAKU , ISHII KASUKE , SATO HAJIME , SUZUKI NORIYUKI
IPC分类号： C08J3/20 , C08K3/04 , C08L27/12 , H01B1/24
摘要： PROBLEM TO BE SOLVED: To obtain an electroconductive fluororesin composition comprising a hot-melt fluororesin powder and an electroconductive carbon black, which composition gives a molded article having stable electric resistance and a smooth and precise surface state and is suitably employable for a holding jig and a tube used in a semiconductor-manufacturing apparatus and for a roll and a tube of an OA equipment, and to provide its manufacturing method.
SOLUTION: The electroconductive fluororesin composition comprises the electroconductive carbon black and the hot-melt fluororesin powder, and exhibits two crystallization peaks as observed by a DSC apparatus, where the height ratio of the crystallization peaks (higher temperature peak/lower temperature peak) is at least 0.65 and/or the ratio of the area of the higher temperature crystallization peak [higher temperature peak area/(higher temperature peak area + lower temperature peak area)] is at least 0.18, or the glass transition temperature of the composition as measured by a dynamic viscoelastic measuring device is lower by at least 3°C than that of the neat fluororesin.
COPYRIGHT: (C)2003,JPO
摘要翻译：要解决的问题为了获得包含热熔性氟树脂粉末和导电性炭黑的导电性氟树脂组合物，该组合物赋予具有稳定的电阻和平滑且精确的表面状态的成型体，并且适合用于保持夹具和用于半导体制造装置中的管和用于OA设备的辊和管的管，并提供其制造方法。解决方案：导电氟树脂组合物包含导电炭黑和热熔氟树脂粉末，并且通过DSC装置观察到两个结晶峰，其中结晶峰（高温峰/低温峰）的高度比在至少0.65和/或较高温度结晶峰的面积比[较高温度峰面积/（较高温度峰面积+较低温度峰面积）]至少为0.18，或组合物的玻璃化转变温度动态粘弹性测量装置比纯氟树脂低至少3度。

87. 发明专利

JPS61135714A Molding of copolymer of tetrafluoroethylene and molding mold therefor 失效
标题翻译：四氟乙烯共聚物的模塑及其模塑
公开(公告)号：JPS61135714A
公开(公告)日：1986-06-23
申请号：JP25732784
申请日：1984-12-07
申请人： Du Pont Mitsui Fluorochem Co Ltd , Yoshida S K T:Goushi
发明人： YOSHIDA YOSHITAKA , ISHII KASUKE
IPC分类号： B29C39/02 , B29C33/62 , B29C39/26 , B29C39/36 , B29C45/26 , B29K27/18 , C08F214/26
摘要： PURPOSE:To prevent the adhesion of copolymer of tetrafluoroethylene to the mold as well as the foaming of molded product by a method wherein the copolymer of tetrafluoroethylene and one or two kinds of comonomer, shown by the formula I, is heated to melt it, thereafter, the copolymer is cooled and solidified in the metallic mold, coated by polyallylenesulfide (PAS). CONSTITUTION:The dispersion coating medium or powder coating medium of PAS is coated on the metallic mold by the conventional technique such as spraying, dipping, brushing, roller coating, fludization dip coating or the like and, subsequently, is baked at the temperature of 300-450 deg.C. Heating and melting are effected outside of the metallic mold or in a barrel in case of injection molding while they are effected in a pot in case of transfer molding. Successively, the molten copolymer is poured into the metallic mold coated by PAS. On the other hand, the copolymer is heated and molten in the metallic mold, coated by PAS, in case of compression molding, rotary molding or the like and, successively, is cooled and solidified in the metallic mold.
摘要翻译：目的：为了防止四氟乙烯共聚物与模具的发泡以及模制产品的发泡，其中将通式I所示的四氟乙烯与一种或两种共聚单体的共聚物加热熔化，之后，共聚物在金属模具中被冷却并固化，被聚烯丙基（PAS）涂覆。构成：PAS的分散涂料介质或粉末涂料介质通过常规技术如喷涂，浸涂，刷涂，辊涂，除污浸涂等涂覆在金属模上，随后在300℃的温度下烘烤 -450摄氏度在注射成型的情况下，在金属模具的外部或在桶中进行加热和熔融，而在传送模塑的情况下它们在罐中进行。接着将熔融共聚物倒入由PAS涂覆的金属模具中。另一方面，在压缩成型，旋转成型等的情况下，在金属模具中加热熔融共聚物，并用PAS涂布，并在金属模具中冷却固化。

88. 发明专利

JPS59198118A Manufacture of heat fluidized fluorocarbon resin- covered cylindrical article 失效
标题翻译：热流化氟化烃树脂包装制品的制造
公开(公告)号：JPS59198118A
公开(公告)日：1984-11-09
申请号：JP7151183
申请日：1983-04-25
申请人： Du Pont Mitsui Fluorochem Co Ltd
发明人： OGURA MASATSUNE
IPC分类号： G03G15/20 , B29C51/00 , B29C61/00 , B29C63/00 , B29C63/18 , B29C63/42 , C08F8/20
CPC分类号： B29C61/003 , B29C63/18 , B29K2027/12 , B29K2027/18 , B29L2031/324
摘要： PURPOSE:To form a fluorocarbon resin film containing a filler with a smooth surface by a method wherein a heat shrinkable tube made of a heat-fluid fluorocarbon resin containing a specified amount of a filler is shrunk and fixed on a cylindrical article at a specified temperature and then, fusing it thereon. CONSTITUTION:A heat-shrink tube made of a heat-fluid fluorocarbon resin (preferably, a copolymer with a specific melt viscosity of 5X10 -1X10 poise produced from tetrafluoroethylene and a fluorinated ethylene-like insaturated compound) is shrinked and fixed on a cylindrical article (e.g. alminum product) above 60 deg.C but below the melting point of the resin and then, fused thereon at the temperature exceeding the melting point of the resin. USE:The product is used for thermal fixing rollers for electronic copying machines.
摘要翻译：目的：通过以下方法形成含有具有光滑表面的填料的氟碳树脂膜，其中将含有特定量的填料的热流体氟碳树脂制成的热收缩管在规定温度下收缩并固定在圆筒状物品上然后将其熔合在其上。构成：由热流体氟碳树脂（优选地，由四氟乙烯和含氟乙烯类不饱和化合物制成的具有5×10 4 -1×10 -6泊的特定熔体粘度的共聚物）制成的热收缩管被收缩并固定在高于60℃但低于树脂熔点的圆柱形制品（例如铝产品）上，然后在超过树脂熔点的温度下熔化。用途：本产品用于电子复印机的热定影辊。

89. 发明专利

JPS5927928A Foaming composition of modified polyphenylene oxide and its production 失效
标题翻译：改性聚氧乙烯氧化物的发泡组合物及其生产
公开(公告)号：JPS5927928A
公开(公告)日：1984-02-14
申请号：JP13628182
申请日：1982-08-06
申请人： Du Pont Mitsui Fluorochem Co Ltd
发明人： AKANO AKIYOSHI , HONDA TAKAYUKI
IPC分类号： C08J9/04 , C08J9/14
摘要： PURPOSE: The titled foaming composition capable of forming low-expansion ratio foams having a smooth surface and excellent paintability in good molding workability, prepared by impregnating modified polyphenylene oxide with chlorodifluoromethane.
CONSTITUTION: A modified polyphenylene oxide (modified PPO) (a resin prepared by graft-polymerizing PPO with styrene or the like, e.g., Noryl FN-215-J, a product of Engineering Plastic Co.) is sealed within a pressure vessel. Then, this vessel is fed with gaseous chlorodifluoromethane, and the pressure is kept at 1.5W10kg/cm
2 to impregnate the modified PPO with 0.5W10wt% chlorodifluoromethane.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：通过用氯二氟甲烷浸渍改性聚苯醚制备的能够形成具有光滑表面的低膨胀比泡沫和优异的可涂漆性的良好模塑加工性的标题发泡组合物。构成：将改性聚苯醚（改性PPO）（通过PPO与苯乙烯等接枝聚合制备的树脂，例如，Engineering Plastic Co.的产品Noryl FN-215-J）密封在压力容器内。然后，向该容器中加入氯代二氟甲烷气体，并将压力保持在1.5-10kg / cm 2，以0.5-10重量％氯二氟甲烷浸渍改性PPO。

90. 发明专利

JPS57126430A Preparation of lower perfluoroalkane 失效
标题翻译：较低的全氟烷烃的制备
公开(公告)号：JPS57126430A
公开(公告)日：1982-08-06
申请号：JP963081
申请日：1981-01-27
申请人： Du Pont Mitsui Fluorochem Co Ltd , E I Du Pont De Nemours & Co
发明人： COUTURE MAURICE J , HAYASHI DAN
IPC分类号： C07C17/02 , C07C17/00 , C07C17/04 , C07C17/361 , C07C19/08 , C07C21/18 , C07C67/00
CPC分类号： C07C17/04 , C07C17/361 , C07C19/08
摘要： PURPOSE: To obtain the titled compound, i.e. CF
4 and C
2 F
6 , useful as a cryogenic refrigerant, electrical insulating gas, etc., safely, in high purity, yield and conversion, with simple process, by heating a mixed gas of C
2 F
4 and CO
2 having a specific mixing ratio at high temperature.
CONSTITUTION: Lower perfluoroalkane, i.e. CF
4 (perfluoromethane), C
2 F
6 (perfluoroethane) or their mixture, can be prepared by heating a mixture of C
2 F
4 (tetrafluoroethylene) and CO
2 at >900°C, pref. 950W1,500°C under positive or reduced pressure. The molar ratio of C
2 F
4 /CO
2 is ≤4/1, pref. 3/1W1/10.
EFFECT: Since CO
2 acts as the diluent of C
2 F
4 , the explosion and carbonization can be prevented. There is no carbon deposition to the reaction tube, and little clogging of the reactor and lowering of the heat transfer coefficient. The troublesome operations such as cleaning of the reaction tubes are not necessary.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：通过加热C2F4和二氧化碳的混合气体，以简单的方法获得用作低温制冷剂，电绝缘气体等的标题化合物即低温制冷剂，电绝缘气体等，以高纯度，产率和转化率，高温下的比混合比。构成：低级全氟烷烃，即CF4（全氟甲烷），C2F6（全氟乙烷）或其混合物可以通过在> 900℃，优选加热C2F4（四氟乙烯）和CO 2的混合物来制备。在正压或低压下为950-1,500℃。 C2F4 / CO2的摩尔比为≤4/ 1，优选。 3 / 1-1 / 10。效果：由于CO2作为C2F4的稀释剂，因此可以防止爆炸和碳化。反应管没有碳沉积，反应器堵塞少，传热系数降低。不需要诸如清洁反应管的麻烦的操作。

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