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    • 82. 发明公开
    • Thermographic recording material with improved image tone
    • Thermographisches Aufzeichnungsmaterial mit verbicultem Bildton
    • EP1059560A1
    • 2000-12-13
    • EP00201851.3
    • 2000-05-25
    • AGFA-GEVAERT N.V.
    • Dooms, Philip, Agfa-Gevaert N.V.Michiels, Peter, Agfa-Gevaert N.V.Geuens, Ingrid, Agfa-Gevaert N.V.
    • G03C1/498
    • G03C1/49809G03C1/49845G03C1/4989
    • A substantially light-insensitive black and white thermographic recording material comprising a thermosensitive element and a support, the thermosensitive element containing at least one substantially light-insensitive organic silver salt, at least one organic reducing agent therefor in thermal working relationship therewith, a binder, at least one stabilizer and optionally an α,ω-alkyldicarboxylic acid with a straight chain alkyl group having at least 4 carbon atoms which may be substituted, however neither including 3,5-dihydroxybenzoic acid as acidic reagent nor di-tert-butyl-p-cresol as a sole organic reducing agent, characterized in that the at least one stabilizer is represented by formula (I):

              R 1 -(O=C)-R 2 -(C=O)-R 3      (I)

      wherein R 2 is a divalent straight chain saturated hydrocarbon group with 2 or 3 carbon atoms which may be substituted with one or more of =O, =S, =CR 4 R 5 , an alkyl group, a cycloalkyl group, a hydroxy group, a thiol group, a -(C=O)R 6 group or two of the substituents of R 2 may together form a closed non-aromatic carbocyclic or heterocyclic ring; R 4 and R 5 are independently hydrogen or an alkyl, substituted alkyl, hydroxy, thiol, -(C=O)R 7 group or R 4 and R 5 together may form a closed carbocyclic or heterocyclic group; R 1 , R 3 , R 6 and R 7 are independently a hydroxy or -NHR 8 group or R 1 and R 3 together is an oxygen atom forming an anhydride group; R 8 is hydrogen or a hydroxy, alkyl, aryl or -SO 2 R 9 group; R 9 is an alkyl, substituted alkyl, cycloalkyl, substituted cycloalkyl, heterocyclic, substituted heterocyclic, aryl, substituted aryl, heteroaryl, substituted heteroaryl, an -OR 10 , or a -NR 11 R 12 group; R 10 and R 11 are independently an alkyl, substituted alkyl, cycloalkyl, substituted cycloalkyl, aryl or substituted aryl group; R 12 is hydrogen or an alkyl, substituted alkyl, cycloalkyl, substituted cycloalkyl, aryl or substituted aryl group; and R 11 and R 12 may together form a closed carbocyclic or heterocyclic group; and wherein the concentration of the at least one stablizer and the α,ω-alkyldicarboxylic acid, if present, is together at least 20 mol% with respect to the organic silver salts; and a recording process therefor.
    • 包含热敏元件和载体的基本上不透光的黑白热成像记录材料,所述热敏元件含有至少一种基本上不光敏的有机银盐,至少一种与其热加工关系的有机还原剂,粘合剂, 至少一种稳定剂和任选具有至少可以被取代的具有至少4个碳原子的直链烷基的α,ω-烷基二羧酸,但不包括3,5-二羟基苯甲酸作为酸性试剂,也不包括二叔丁基-p - 甲酚作为唯一的有机还原剂,其特征在于所述至少一种稳定剂由式(I)表示:R 1 - (O = C)-R 2 - (C = O)-R 3 其中R 2是具有2或3个碳原子的二价直链饱和烃基,其可以被= O,= S,= CR 4 R 5中的一个或多个取代,烷基, 环烷基,羟基,硫醇基, - (C = O)R 6基团或tw R 2的取代基的O可以一起形成封闭的非芳族碳环或杂环; R 4和R 5独立地是氢或烷基,取代的烷基,羟基,硫醇, - (C = O)R 7基团或R 4和R 5一起可以形成封闭的碳环 或杂环基; R 1,R 3,R 6和R 7独立地是羟基或-NHR 8基团,或者R 1和R 3一起是形成酸酐基团的氧原子; R 8是氢或羟基,烷基,芳基或-SO 2 R 9基团; R 9是烷基,取代的烷基,环烷基,取代的环烷基,杂环,取代的杂环,芳基,取代的芳基,杂芳基,取代的杂芳基,-OR 10或-NR 11 R 12基团 ; R 10和R 11独立地是烷基,取代的烷基,环烷基,取代的环烷基,芳基或取代的芳基; R 12是氢或烷基,取代的烷基,环烷基,取代的环烷基,芳基或取代的芳基; R 11和R 12可以一起形成封闭的碳环或杂环基; 并且其中所述至少一种稳定剂和所述α,ω-烷基二羧酸(如果存在)的浓度相对于所述有机银盐为至少20mol%; 及其记录过程。