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71. 发明授权

US06784263B2 Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst 失效
标题翻译：用于将烯烃聚合成多峰分子量分布聚合物的催化剂组合物，催化剂的生产和使用方法
公开(公告)号：US06784263B2
公开(公告)日：2004-08-31
申请号：US10052326
申请日：2002-01-18
申请人： Orass Hamed , Akhlaq Moman , Atieh Abu-Raqabah
发明人： Orass Hamed , Akhlaq Moman , Atieh Abu-Raqabah
IPC分类号： C08F444
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F110/02 , C08F210/16 , C08F4/65904 , C08F4/65916 , C08F2500/05 , C08F210/14
摘要： A solid catalyst component comprises a transition metal-containing metallocene compound, a non-cyclopentadienyl transition metal compound, a magnesium compound and a polymeric material which acts as a support. The catalyst component is combined with co-catalyst organoaluminum compound or a mixture of organoaluminum compounds to provide a catalyst composition useful for olefin polymerization, e.g., to produce linear low, medium and high density polyethylenes or copolymerization of ethylene with alpha-olefins. Product polyolefin polymers have a varied range of molecular weight distributions. The catalyst composition is prepared by a process comprising combining polymer support particles, magnesium compound, transition metal-containing metallocene compound, and non-cyclopentadienyl transition metal compound to provide a solid catalyst component, and, combining the solid catalyst component with a cocatalyst compound to provide a polyolefin polymerization catalyst composition.
摘要翻译：固体催化剂组分包含含过渡金属的茂金属化合物，非环戊二烯基过渡金属化合物，镁化合物和作为载体的聚合物。将催化剂组分与助催化剂有机铝化合物或有机铝化合物的混合物组合以提供可用于烯烃聚合的催化剂组合物，例如产生线性低，中和高密度聚乙烯或乙烯与α-烯烃的共聚。产品聚烯烃聚合物具有不同范围的分子量分布。催化剂组合物通过包括将聚合物载体颗粒，镁化合物，含过渡金属的茂金属化合物和非环戊二烯基过渡金属化合物组合以提供固体催化剂组分的方法制备，并且将固体催化剂组分与助催化剂化合物组合以提供聚烯烃聚合催化剂组合物。

72. 发明授权

US06770718B2 Continuous process for the preparation of solid catalyst components for the polymerization of &agr;-olefins 有权
标题翻译：用于制备用于α-烯烃聚合的固体催化剂组分的连续方法
公开(公告)号：US06770718B2
公开(公告)日：2004-08-03
申请号：US10181336
申请日：2002-07-17
申请人： Massimo Covezzi , Anna Fait , Almerinda Di Benedetto
发明人： Massimo Covezzi , Anna Fait , Almerinda Di Benedetto
IPC分类号： C08F444
CPC分类号： C08F10/00 , C08F110/06 , C08F4/6543 , C08F2500/15 , C08F2500/18
摘要： A process is provided for the preparation of a solid catalyst component for the polymerization of olefins, comprising continuously feeding a liquid containing a titanium compound having at least one titanium-halogen bond into a vessel containing a solid comprising a magnesium halide and continuously discharging liquid from the vessel, whereby the concentration of the solid is maintained within the range of between 80 and 300 g/l, and the product between the average residence time of the liquid in the vessel and the concentration of the solid is maintained below 10,000 min*g/l. An advantage of the process is the reduced time and reactor volume necessary to prepare the catalysts, which show good activity and stereospecificity.
摘要翻译：提供了一种用于制备用于烯烃聚合的固体催化剂组分的方法，包括将含有至少一个钛 - 卤键的钛化合物的液体连续地进料到含有卤化镁的固体的容器中，并从其中固体的浓度保持在80-300g / l的范围内，并且液体在容器中的平均停留时间与固体的浓度之间的乘积保持在10,000分钟以下* g / l。该方法的优点是制备催化剂所需的时间和反应器体积减小，这表现出良好的活性和立体定向性。

73. 发明授权

US06734267B2 Polymerization catalyst systems, their production and use 失效
标题翻译：聚合催化剂体系，其生产和使用
公开(公告)号：US06734267B2
公开(公告)日：2004-05-11
申请号：US10430962
申请日：2003-05-06
申请人： Main Chang
发明人： Main Chang
IPC分类号： C08F444
CPC分类号： C08F10/00 , C08F4/61912 , C08F4/61916 , C08F110/02 , Y10S526/943
摘要： This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported metallocene catalyst formed by vacuum or pressurized impregnation.
摘要翻译：本发明通常涉及用于聚合烯烃的负载型催化剂体系。支持本发明的催化剂的方法提供了通过真空或加压浸渍形成的负载金属茂催化剂。

74. 发明授权

US06730756B1 Catalyst and process for olefin polymerization 失效
标题翻译：催化剂和烯烃聚合方法
公开(公告)号：US06730756B1
公开(公告)日：2004-05-04
申请号：US09857370
申请日：2001-10-09
申请人： Ove Andell , Kalle Kallio , Hikka Knuuttitila
发明人： Ove Andell , Kalle Kallio , Hikka Knuuttitila
IPC分类号： C08F444
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F2500/03 , C08F2500/18 , C08F210/14 , C08F2500/12
摘要： Olefin polymerization may be catalysed by a wide range of catalytic materials. Described herein is a heterogeneous olefin polymerization catalyst comprising a porous paniculate support material having impregnated therein a metallocene catalyst the metal atom whereof is bound to an amide group which is not bound to an &eegr;-ligand of the metallocene, or the reaction product of a said metallocene catalyst and a co-catalyst.
摘要翻译：烯烃聚合可以由各种催化材料催化。本文描述的是一种异质烯烃聚合催化剂，其包含多孔颗粒载体材料，其中浸渍有茂金属催化剂，其金属原子结合到不与茂金属的η - 配位体结合的酰胺基，或所述金属茂催化剂的反应产物茂金属催化剂和助催化剂。

75. 发明授权

US06716939B2 Components and catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的组分和催化剂
公开(公告)号：US06716939B2
公开(公告)日：2004-04-06
申请号：US09937884
申请日：2001-10-01
申请人： Giampiero Morini , Giulio Balbontin , Peter A. A. Klusener
发明人： Giampiero Morini , Giulio Balbontin , Peter A. A. Klusener
IPC分类号： C08F444
CPC分类号： C08F10/00 , C08F4/6465 , C08F4/6543 , C08F4/651
摘要： The present invention relates to a solid catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from substituted succinates of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.
摘要翻译：本发明涉及用于烯烃CH 2 = CHR的聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和选自特定的取代的琥珀酸盐的电子给体式。当用于烯烃聚合，特别是丙烯时，所述催化剂组分能够以高产率和高二甲苯不溶性表现的高全同立构指数得到聚合物。

76. 发明授权

US06677412B2 Process for preparing a highly active metallocene catalyst supported on polymer bead for olefin polymerization 失效
标题翻译：制备负载于聚合物珠粒上用于烯烃聚合的高活性金属茂催化剂的方法
公开(公告)号：US06677412B2
公开(公告)日：2004-01-13
申请号：US10118617
申请日：2002-04-02
申请人： Son-Ki Ihm , Ki-Soo Lee , O-Yong Jeong
发明人： Son-Ki Ihm , Ki-Soo Lee , O-Yong Jeong
IPC分类号： C08F444
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/6592 , C08F110/02 , Y10S502/507 , Y10S526/904 , C08F4/65916
摘要： The present invention relates to a process for preparing a highly active metallocene catalyst supported on polymer bead for olefin polymerization, a metallocene catalyst prepared by the said process and a method for alkylene polymerization by employing the said catalyst. The process for preparing a highly active metallocene catalyst supported on polymer bead for olefin polymerization which comprises the steps of: dissolving divinylbenzene, vinylbenzylchloride, and an initiator in an organic solvent, mixing it with a suspension stabilizer of aqueous phase, and carrying out suspension-polymerization at the temperature of 40 to 80° C. to obtain polystyrene; swelling the polystyrene in dialcoholamine dissolved in an organic solvent at ambient temperature for 1 to 3 days, to give a polymer having a functional group of dialcoholamine; and, reacting the polymer with a metallocene compound (CpM*Cl3) dissolved in an organic solvent. The metallocene catalyst of the present invention can be used widely for ethylene polymerization, styrene polymerization and copolymerization, while replacing the conventional homogeneous catalysts.
摘要翻译：本发明涉及一种负载在用于烯烃聚合的聚合物珠上的高活性茂金属催化剂的方法，通过所述方法制备的茂金属催化剂和通过使用所述催化剂进行亚烷基聚合的方法。制备负载在用于烯烃聚合的聚合物珠子上的高活性金属茂催化剂的方法，该方法包括以下步骤：将二乙烯基苯，乙烯基苄基氯和引发剂溶解在有机溶剂中，将其与水相的悬浮稳定剂混合，在40〜80℃的温度下进行聚合，得到聚苯乙烯; 在环境温度下溶解在有机溶剂中的二元醇胺中使聚苯乙烯溶胀1至3天，得到具有二醇胺官能团的聚合物; 并使聚合物与溶解在有机溶剂中的茂金属化合物（CpM * Cl3）反应。本发明的茂金属催化剂可以广泛用于乙烯聚合，苯乙烯聚合和共聚，同时代替常规的均相催化剂。

77. 发明授权

US06630546B1 Process for the preparation of a polyolefin 失效
标题翻译：制备聚烯烃的方法
公开(公告)号：US06630546B1
公开(公告)日：2003-10-07
申请号：US10104745
申请日：2002-03-22
申请人： Abbas Razavi , Liliane Peters
发明人： Abbas Razavi , Liliane Peters
IPC分类号： C08F444
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F10/02 , C08F110/02 , Y10S526/905 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/19 , C08F210/14 , C08F2500/08 , C08F2500/18
摘要： Use of a catalyst system comprising a metallocene catalyst component of general formula R″(CpRm) (Cp′R′n)MQ2 supported on an inert support in the slurry phase production of linear low density polyolefin, wherein Cp is a cyclopentadienyl moiety, Cp′ is a substituted or unsubstituted fluorenyl ring; R″ is a structural bridge imparting stereorigidity to the component; each R is independently hydrogen or hydrocarbyl having 1 to 20 carbon atoms in which 0≦m≦4; each R′ is independently hydrocarbyl having 1 to 20 carbon atoms in which 0≦n≦B; M is a Group IVB transition metal or vanadium; and each Q is hydrocarbyl having 1 to 20 carbon atoms or halogen; the metallocene having a centroid-M-centroid angle in the range 105° to 125°.
摘要翻译：在线性低密度聚烯烃的浆料相中制备包括负载在惰性载体上的通式R“（CpRm）（Cp'R'n）MQ2的茂金属催化剂组分的催化剂体系的用途，其中Cp是环戊二烯基部分， Cp'是取代或未取代的芴基环; R“是赋予组分立体刚性的结构桥; 每个R独立地是氢或具有1至20个碳原子的烃基，其中0≤m≤4; 每个R'独立地为具有1至20个碳原子的烃基，其中0≤n≤B; M是IVB族过渡金属或钒; 并且每个Q是具有1至20个碳原子的烃基或卤素; 茂金属具有在105°至125°范围内的质心M-心形角。

78. 发明授权

US06617405B1 Process for the preparation of polyethylene 失效
标题翻译：制备聚乙烯的方法
公开(公告)号：US06617405B1
公开(公告)日：2003-09-09
申请号：US09353207
申请日：1999-07-14
申请人： Robert James Jorgensen
发明人： Robert James Jorgensen
IPC分类号： C08F444
CPC分类号： C08F10/02 , C08F210/16 , Y02P20/52 , C08F4/6425 , C08F4/6543 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/24 , C08F210/08
摘要： A process of polymerizing ethylene or ethylene and one or more comonomers in one or more fluidized bed reactors with a catalyst system comprising (i) a supported or unsupported magnesium/titanium based precursor in slurry form, said precursor containing an electron donor; and (ii) an activator containing aluminum in an amount sufficient to essentially complete the activation of the precursor is disclosed. In the process, the precursor and the activator are mixed prior to introduction into the reactor in at least one mixing procedure, and then the mixture is contacted again with additional activator to essentially complete activation of the precursor. In the method, the atomic ratio of aluminum to titanium is in the range of about 1:1 to about 15:1 and the mole ratio of activator to electron donor is about 1:1 to about 2:1, and no additional activator is introduced into the reactor(s).
摘要翻译：一种在一个或多个流化床反应器中用催化剂体系聚合乙烯或乙烯和一种或多种共聚单体的方法，所述催化剂体系包括（i）以浆料形式的负载或未负载的镁/钛基前体，所述前体含有电子给体; 并且（ii）含有足以基本上完成前体活化的量的含铝的活化剂被公开。在该方法中，在将至少一种混合程序引入反应器之前将前体和活化剂混合，然后将混合物再与另外的活化剂接触以基本上完全活化前体。在该方法中，铝与钛的原子比在约1:1至约15:1的范围内，活化剂与电子给体的摩尔比为约1:1至约2:1，并且不另外的活化剂为引入反应器中。

79. 发明授权

US06583243B2 Polyolefin production 失效
公开(公告)号：US06583243B2
公开(公告)日：2003-06-24
申请号：US10062877
申请日：2002-01-31
申请人： Abbas Razavi , Olivier Miserque
发明人： Abbas Razavi , Olivier Miserque
IPC分类号： C08F444
CPC分类号： C07F17/00 , C08F4/63908 , C08F4/63912 , C08F4/63916 , C08F4/6392 , C08F110/06 , Y10S526/943 , C08F2500/03 , C08F2500/15
摘要： A metallocene compound having the general formula: CpAXMQ1Q2Cp′A′X′M′Q1′Q2′ wherein Cp and Cp′ are each independently a substituted or unsubstituted cyclopentadienyl moiety; M and M′ are each independently a metal chosen from Group IV B transition metals and vanadium, and coordinate to Cp and Cp′ respectively; X and X′ are each independently a substituted or unsubstituted Group VA or VIA heteroatom and coordinate to M and M″ respectively; A and A′ are bridging groups between Cp and X and between Cp′ and X′ respectively and are independently chosen from —SiR′2—O—SiR′2—, —SinR′m—, —CnR′m— and —CR′2—SiR′2—CR′2—SiR′2—, in which each R′ is independently H or hydrocarbyl having 1 to 20 carbon atoms, n is an integer in the range 1 to 4 and m=2n; each Q1, Q2 and Q1′ and Q2′ is independently a coordinating group which is hydrogen, halogen or hydrocarbyl having 1 to 20 carbon atoms and each of Q1 and Q1′ is coordinated to both M and M′.

80. 发明授权

US06583238B1 Catalyst system, method for the production thereof, and the utilization thereof for the polymerization of olefins 失效
标题翻译：催化剂体系，其制备方法及其在烯烃聚合中的应用
公开(公告)号：US06583238B1
公开(公告)日：2003-06-24
申请号：US09646177
申请日：2000-09-14
申请人： Markus Göres , Hans Bohnen
发明人： Markus Göres , Hans Bohnen
IPC分类号： C08F444
CPC分类号： C08F10/00 , C08F4/65912 , Y10S526/943 , C08F4/65927
摘要： A catalyst system with at least one specifically substituted metallocene which contains a cationic group as a substituent, a process for preparing such a catalyst system and its use in the polymerization of olefins. In particular, said catalyst system has (a) at least one support, (b) at least one cocatalyst and (c) at least one metallocene of the formula where M1, R1, R2, R3, m, m′, A, k and X are defined herein.
摘要翻译：具有至少一种含有阳离子基团作为取代基的具体取代的金属茂的催化剂体系，制备这种催化剂体系的方法及其在烯烃聚合中的应用。特别地，所述催化剂体系具有（a）至少一种载体，（b）至少一种助催化剂和（c）至少一种茂金属，所述茂金属在M1，R1，R2，R3，m，m'，A， X在本文中定义。

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