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71. 发明授权

KR101272170B1 고 과산화물 자가석출 바스 有权
标题翻译：高过氧化物自动沉积浴
公开(公告)号：KR101272170B1
公开(公告)日：2013-06-10
申请号：KR1020097013719
申请日：2007-11-30
申请人： 니혼 파커라이징 가부시키가이샤
发明人： 세크하란마네쉬나두파람빌 , 아흐멧바시르 , 프리스태드윌리엄이 , 아부샤나브오마르 , 허드직니콜라스 , 마빈브라이언
IPC分类号： C23C18/54 , C23C18/31 , C23C18/16
CPC分类号： C09D5/088 , B05D7/142
摘要： 본 발명은 (a) 적어도 하나의 폴리머, (b) 적어도 하나의 유화제, (c) 선택적으로 적어도 하나의 가교제, (d) 산, 산화제 및/또는 착화제와 같은 적어도 하나의 촉진제 성분, (e) 적어도 100ppm의 H
2 O
2 의 평균 최소 농도, (f) 선택적으로, 적어도 하나의 충전제 및/또는 착색제, (g) 선택적으로, 적어도 하나의 조막제 및 (h) 물을 포함하는 자가석출 바스 조성물을 제공한다.
자가석출 바스, 폴리머, 유화제, 가교제, 촉진제, 충전제, 조막제

72. 发明公开

KR1020040106466A 수성 금속표면처리 조성물 失效
标题翻译：水性金属表面处理组合物
公开(公告)号：KR1020040106466A
公开(公告)日：2004-12-17
申请号：KR1020047017755
申请日：2003-05-03
申请人： 로오드 코포레이션
发明人： 쿠세라,헬무트,더블유. , 아베이,킬크,제이. , 트로우톤,에네스트,비.,주니어
IPC分类号： C09D5/08 , C08G8/28 , C23C22/83
CPC分类号： C09D5/088 , C08G8/28 , C09D161/06 , C23C22/83
摘要： 본 발명은 수성 금속 처리 조성물에 관한 것으로서,
하기 성분, 즉 (A) (i) 페놀 수지 전구물질 : (ii) 조절제가 페놀 수지 전구 물질과 반응하게 하는 최소한 하나의 기능 부분에 결합되는 하이드로 카르빌 부분, 및 황 또는 인을 함유하는 이온 가능한 기로 구성되는 최소한 하나의 이온성 부분으로 구성되는 조절제 : 및 (iii) 최소한 하나의 멀티-하이드록시 페놀 화합물의 반응 생성물을 포함하는 페놀 수지의 수성 분산제 : 및 (B) 상기 반응 생성물(A)이 두개 이상의 반응성 페놀 메틸올기를 함유할때 (iii)가 (A)에서 선택적인 임의의 산으로 구성되어 있다.

73. 发明公开

KR1020160030552A 기판의 금속 표면을 코팅하기 위한 방법 및 상기 방법에 따라 코팅된 물체 审中-实审
标题翻译：用于涂覆基材的金属表面的方法和根据所述方法涂覆的物体
公开(公告)号：KR1020160030552A
公开(公告)日：2016-03-18
申请号：KR1020167003276
申请日：2014-07-10
申请人： 케메탈 게엠베하
发明人： 바서팔렌,다니엘 , 슈밤브,미하엘 , 프렌켈,알리악산드르 , 소트케,베라 , 브렘서,볼프강 , 드롤,마르틴 , 제발트,올리버 , 아이린크호프,론 , 게롤트,스테파니 , 니젠,예브게니아 , 샤히치에크,라르스 , 트라우트,마누엘
IPC分类号： B05D7/14 , C09D5/08 , B05D1/18 , B05D3/02 , B05D3/00
CPC分类号： C09D5/08 , B05D1/18 , B05D3/0254 , B05D7/14 , C09D5/088 , C25D13/04 , C25D13/16
摘要： 본발명은표면을코팅하기위한방법, 상응하는코팅, 및상기방법에따라코팅된물체의용도에관한것이다. 본발명은 I. 세정된금속표면을지니는기판을공급하는단계, II. 금속표면을분산물및/또는현탁물형태의수성조성물과접촉시키고코팅하는단계, III. 임의로, 유기코팅을헹구는(rinsing) 단계, 및 IV. 유기코팅을건조시키고/거나베이킹(baking)하는단계, 또는 V. 임의로, 유기코팅을건조시키고, 건조과정및/또는베이킹과정전에동일한유형의코팅조성물또는추가의코팅조성물로코팅하는단계를포함하거나이로구성되는, 기판의금속표면을코팅하기위한방법으로서, 단계 II에서, 코팅이 2.5 내지 45 wt%의하나이상의비이온적으로안정화된결합제및 0.1 내지 2.0 wt%의겔화제를함유하는분산물및/또는현탁물형태의수성조성물로수행되고, 수성조성물이 0.5 내지 7 범위의 pH 값을지니고, 전처리단계에서및/또는단계 II에서의접촉동안에금속표면으로부터용출되는양이온과함께이오노겐겔을기반으로하는코팅이형성되는방법에관한것이다.

74. 发明公开

KR1020090113255A 고 과산화물 자가석출 바스 有权
标题翻译：高过氧化物自动沉积浴
公开(公告)号：KR1020090113255A
公开(公告)日：2009-10-29
申请号：KR1020097013719
申请日：2007-11-30
申请人： 니혼 파커라이징 가부시키가이샤
发明人： 세크하란마네쉬나두파람빌 , 아흐멧바시르 , 프리스태드윌리엄이 , 아부샤나브오마르 , 허드직니콜라스 , 마빈브라이언
IPC分类号： C23C18/54 , C23C18/31 , C23C18/16
CPC分类号： C09D5/088 , B05D7/142
摘要： This invention provides an autodeposition bath composition and process capable of coating zinciferous metal surfaces with minimal pinhole formation, comprising (a) at least one polymer, (b) at least one emulsifier, (c) optionally at least one cross-linker, (d) at least one accelerator component such as acid, oxidizing agent and/or complexing agents, (e) an average minimum concentration of H2O2 of at least 100 pars per million, (f) optionally, at least one filler and/or colorant, (g) optionally, at least one coalescing agent, and (h) water.
摘要翻译：本发明提供了一种自动沉积浴组合物和方法，其能够以最小的针孔形成涂覆含锌金属表面，包括（a）至少一种聚合物，（b）至少一种乳化剂，（c）任选的至少一种交联剂，（d ）至少一种促进剂组分，例如酸，氧化剂和/或络合剂，（e）H 2 O 2的平均最小浓度为至少100ppm /百万，（f）任选的至少一种填料和/或着色剂（ g）任选的至少一种聚结剂，和（h）水。

75. 发明公开

KR1020030026844A 자가증착 조성물 失效
标题翻译：自动组合
公开(公告)号：KR1020030026844A
公开(公告)日：2003-04-03
申请号：KR1020020052264
申请日：2002-08-31
申请人： 니혼 파커라이징 가부시키가이샤
发明人： 웰러크리스토퍼지 , 시에버트엘리자베쓰제이 , 양지퀴 , 애가왈래자트케이
IPC分类号： C09D163/00
CPC分类号： C09D5/088 , B05D3/0254 , B05D7/142 , C09D163/00 , Y10T428/31511 , Y10T428/31522 , Y10T428/31529 , Y10T428/31938 , C08L2666/04
摘要： PURPOSE: Provided is an autodeposition composition for polymeric coatings containing a blend of acrylic and epoxy resins, which has reduced gloss, good corrosion resistance and uniform appearance. CONSTITUTION: The autodeposition composition comprises: (a) water; (b) at least one epoxy resin of dispersed form; (c) at least one acrylic resin of dispersed form; and (d) at least one epoxy curing agent. Particularly, the epoxy resin, the acrylic resin, and the epoxy curing agent are present in a weight ratio of acrylic resin: (epoxy resin + epoxy curing agent) of 5:95 - 60:40. The autodeposition composition optionally further comprises at least one component selected from the group consisting of a surfactant, an autodeposition accelerator, a colorant, a coalescing solvent and a leveling agent.
摘要翻译：目的：提供含有丙烯酸和环氧树脂共混物的聚合物涂层的自沉积组合物，其具有降低的光泽度，良好的耐腐蚀性和均匀的外观。构成：自沉积组合物包括：（a）水; （b）分散形式的至少一种环氧树脂; （c）至少一种分散形式的丙烯酸树脂; 和（d）至少一种环氧固化剂。特别地，环氧树脂，丙烯酸树脂和环氧固化剂以5:95-60:40的丙烯酸树脂：（环氧树脂+环氧固化剂）的重量比存在。自动沉积组合物任选地还包含至少一种选自表面活性剂，自沉积促进剂，着色剂，聚结溶剂和流平剂的组分。

76. 发明授权

US09718092B2 Off-white and gray autodeposition coatings 有权
公开(公告)号：US09718092B2
公开(公告)日：2017-08-01
申请号：US14479867
申请日：2014-09-08
申请人： Henkel AG & Co. KGaA
发明人： Omar Lufti Abu-Shanab , Bashir Ahmed , Manesh Nadupparambil Sekharan , William E. Fristad , Nicholas Herdzik
IPC分类号： B05D1/18 , C09D109/02 , C09D127/06 , C09D109/06 , C09D127/18 , C09D175/04 , C09D133/00 , C09D123/06 , C09D163/00 , C09D125/14 , C09D5/02 , C09D5/08 , C01G25/02 , C01G23/047 , C08K3/22 , C08K9/04 , C08K9/02 , C09C1/30 , C09D7/12
CPC分类号： B05D1/18 , C01G23/047 , C01G25/02 , C01P2004/84 , C08K3/22 , C08K9/02 , C08K9/04 , C09C1/3045 , C09D5/024 , C09D5/088 , C09D7/62 , C09D109/02 , C09D109/06 , C09D123/06 , C09D125/14 , C09D127/06 , C09D127/18 , C09D133/00 , C09D163/00 , C09D175/04 , Y10T428/254 , Y10T428/256 , Y10T428/257 , Y10T428/31529 , Y10T428/31544 , Y10T428/31605 , Y10T428/31678 , Y10T428/31692 , Y10T428/31696 , Y10T428/31699
摘要： A method for coating a metal substrate with a white, off-white or gray colored autodeposited coating comprising water, polymeric resin, HF and pigment particles comprising a core of titanium dioxide, an intermediate zirconia and/or alumina layer, and an outer organic layer, optionally the particles are treated with an anionic surfactant.

77. 发明授权

US09556523B2 Method for coating metallic surfaces of substrates, and objects coated according to said method 有权
标题翻译：用于涂覆基材的金属表面的方法，以及根据所述方法涂覆的物体
公开(公告)号：US09556523B2
公开(公告)日：2017-01-31
申请号：US14377048
申请日：2013-02-07
申请人： Chemetall GmbH
发明人： Daniel Wasserfallen , Michael Schwamb , Aliaksandr Frenkel , Vera Sotke , Wolfgang Bremser , Martin Droll , Oliver Seewald , Ron Eilinghoff , Stephanie Gerold , Evgenija Niesen , Lars Schachtsiek , Manuel Traut
IPC分类号： C23C18/16 , B05D7/16 , C09D5/08 , C09D133/14 , C23C18/18 , B05D7/14 , B05D1/18
CPC分类号： C23C18/1637 , B05D1/18 , B05D7/14 , B05D7/142 , B05D7/16 , C09D5/088 , C09D133/14 , C23C18/1692 , C23C18/1803
摘要： A method and composition for coating surfaces, a corresponding coating and the use of objects coated according to said method. A cleaned, metallic surface is contacted with an aqueous composition that is a dispersion or suspension, and drying and/or baking the organic coating or optionally, drying the organic coating and coating with an equivalent or additional coating composition prior to a drying and/or baking. The aqueous composition has a pH of 4 to 11 and contains an anionic polyelectrolyte in a quantity of 0.01 to 5.0 wt. % relative to the total mass of the composition, which may have a solids content of from 2 to 40 wt. %. The solids have an average particle size from 10 to 1000 nm. A coating forms on the basis of an ionogenic gel which binds cations released from the metallic surface that originate from a pretreatment stage or from the contacting.
摘要翻译：用于涂覆表面的方法和组合物，相应的涂层以及根据所述方法涂覆的物体的使用。将清洁的金属表面与作为分散体或悬浮液的水性组合物接触，并干燥和/或烘烤有机涂层或任选地在干燥之前干燥有机涂层和用相当的或附加的涂料组合物涂覆和/或烘烤水性组合物的pH为4〜11，含有0.01〜5.0重量％的阴离子性聚电解质。相对于组合物的总质量，其可以具有2至40重量％的固体含量。％。固体的平均粒度为10〜1000nm。基于结合起始于预处理阶段或接触的金属表面释放的阳离子的离子发生凝胶形成涂层。

78. 发明授权

US09539610B2 Method for coating surfaces and use of the objects coated using said method 有权
标题翻译：用于涂覆表面的方法和使用所述方法涂覆的物体的使用
公开(公告)号：US09539610B2
公开(公告)日：2017-01-10
申请号：US13820591
申请日：2011-09-12
申请人： Daniel Wasserfallen , Martin Droll , Oliver Seewald , Wolfgang Bremser , Michael Schwamb , Cindy Ettrich , Vera Sotke
发明人： Daniel Wasserfallen , Martin Droll , Oliver Seewald , Wolfgang Bremser , Michael Schwamb , Cindy Ettrich , Vera Sotke
IPC分类号： B05D3/00 , B05D7/14 , B05D7/16 , B05D7/00 , C09D5/08 , C23C18/54 , C25D13/00 , B05D1/18
CPC分类号： B05D3/002 , B05D1/18 , B05D7/142 , B05D7/16 , B05D7/51 , B05D7/54 , C09D5/088 , C23C18/54 , C25D13/00 , Y10T428/24975 , Y10T428/265
摘要： A method for electroless coating of a substrate by applying an activating coat of polyelectrolyte or salt with a first aqueous composition, rinsing of the activating coat such that the activating coat is not entirely removed The activated surface that has remained after rinsing is then contacted with an aqueous composition in the form of a solution, emulsion or suspension to form an organic secondary coat (precipitation coat), and drying. The activating coat contains at least one cationic polyelectrolyte or at least one cationic salt in solution in water. The aqueous composition which forms the secondary coat contains constituents which can be precipitated, deposited and/or salted out and which are anionically, zwitterionically, sterically or cationically stabilized. The dry film formed in the process, which is made of the activating coat and the secondary coat, has a thickness of at least 1 μm.
摘要翻译：一种通过用第一水性组合物施加聚电解质或盐的活化涂层来对基材进行无电涂覆的方法，冲洗活化涂层，使得活化涂层不被完全除去。然后冲洗后保留的活化表面与水溶液形式的溶液，乳液或悬浮液形成有机二次涂层（沉淀涂层），并干燥。活化涂层在水溶液中含有至少一种阳离子聚电解质或至少一种阳离子盐。形成第二层的水性组合物含有可沉淀，沉积和/或盐析的组分，阴离子，两性离子，空间或阳离子稳定。由活化涂层和二次涂层制成的在该工艺中形成的干膜具有至少1μm的厚度。

79. 发明申请

US20130344310A1 METHOD FOR COATING SURFACES AND USE OF THE ARTICLES COATED USING SAID METHOD 有权
标题翻译：用表面涂覆方法和使用涂覆方法的文章的使用方法
公开(公告)号：US20130344310A1
公开(公告)日：2013-12-26
申请号：US13820686
申请日：2011-09-12
申请人： Daniel Wasserfallen , Michael Schwamb , Cindy Ettrich , Vera Sotke , Martin Droll , Oliver Seewald , Wolfgang Bremser , Aliaksandr Frenkel
发明人： Daniel Wasserfallen , Michael Schwamb , Cindy Ettrich , Vera Sotke , Martin Droll , Oliver Seewald , Wolfgang Bremser , Aliaksandr Frenkel
IPC分类号： C23C18/54 , C25D13/00
CPC分类号： B05D3/002 , B05D1/18 , B05D7/142 , B05D7/16 , B05D7/51 , B05D7/54 , C09D5/088 , C23C18/54 , C25D13/00 , Y10T428/24975 , Y10T428/265
摘要： A method for electroless coating of substrates by applying an activating coat of polyelectrolyte or salt with a first aqueous composition; rinsing the activating coat such that the activating coat not being entirely removed; contacting and coating of the activated surfaces that have remained after rinsing with an aqueous composition in the form of a solution, emulsion or suspension, to form an organic secondary coat; and drying. The activating coat is a solution, emulsion or suspension containing a anionic polyelectrolyte or at least one anionic salt in solution in water. The aqueous composition forming the secondary coat has constituents which can be precipitated, deposited or salted out and which are anionically, zwitterionically, sterically or cationically stabilized. The dry film formed in the process, comprising the activating coat and the secondary coat, has a thickness of at least 1 μm.
摘要翻译：一种通过用第一含水组合物施加聚电解质或盐的活化涂层来对基底进行无电涂覆的方法; 冲洗活化涂层，使得活化涂层不被完全去除; 用溶液，乳液或悬浮液形式的水性组合物冲洗后残留的活化表面的接触和涂覆以形成有机二次涂层; 并干燥。活化涂层是在水溶液中含有阴离子聚电解质或至少一种阴离子盐的溶液，乳液或悬浮液。形成二次涂层的水性组合物具有沉淀，沉积或盐析的成分，阴离子，两性离子，空间或阳离子稳定。在该方法中形成的包含活化涂层和第二涂层的干膜具有至少1um的厚度。

80. 发明申请

US20110135913A1 Surface Treatment Solution For Autodeposition Coating of Metallic Material and Autodeposition Coating Treatment Method 失效
标题翻译：表面处理溶液用于金属材料自动沉积涂层和自动沉积涂层处理方法
公开(公告)号：US20110135913A1
公开(公告)日：2011-06-09
申请号：US12957750
申请日：2010-12-01
申请人： Takaomi Nakayama , Hideki Takakuwa , Takahiro Fujino
发明人： Takaomi Nakayama , Hideki Takakuwa , Takahiro Fujino
IPC分类号： B32B27/06 , B05D3/10 , B05D3/02 , B05D7/14 , C09D175/04
CPC分类号： C23C22/34 , C08G18/3215 , C08G18/7621 , C08G18/8077 , C09D5/088 , C09D175/04
摘要： A surface treatment solution for autodeposition coating treatment of a metallic material, which is an aqueous solution comprising at least one tannin, at least one crosslinking agent having a crosslinking group capable of thermosetting reaction with a phenolic hydroxyl group and/or a phenolic nucleus, ferric ions, soluble type elemental fluorine, and an oxidizing agent, wherein the solids mass concentration ratio of the tannin to the crosslinking agent is in the range of from 1:1 to 1:10, the molar concentration of the soluble type elemental fluorine is at least 3-fold the molar concentration of the ferric ions, and the pH of the solution is from 2 to 6. The surface treatment solution allows shorter process length as compared with conventional coating processes, generates less environmentally harmful by-products such as sludge, has excellent throwing power at the interior of a pocket structure, does not use environmentally harmful components such as chromium compounds, has corrosion resistance, and allows overcoating of a baking finish on the obtained coating film.
摘要翻译：一种用于自动沉积涂覆处理金属材料的表面处理溶液，其是包含至少一种单宁的水溶液，至少一种具有能够与酚羟基和/或酚核心进行热固化反应的交联基团的交联剂，三价铁离子，可溶型元素氟和氧化剂，其中单宁与交联剂的固体质量浓度比在1:1至1:10的范围内，可溶型元素氟的摩尔浓度为三价铁离子的摩尔浓度至少为3倍，溶液的pH为2〜6。表面处理溶液与常规涂布方法相比，加工时间缩短，生成较少的环境有害副产物如污泥，在口袋结构的内部具有优异的抛光力，不使用环境有害的成分，如铬化合物，具有腐蚀性并且允许在所获得的涂膜上涂覆烤漆。

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