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    • 73. 发明公开
    • METHOD FOR FULLERENE DERIVATIVE AND THE FULLERENE DERIVATIVE, PROTON CONDUCTOR AND ELECTROCHEMICAL DEVICE
    • “VERFAHREN ZUR HERSTELLUNG EINES FULLERENDERIVATS,FULLERENDERIVAT,PROTONENLEITER UND ELEKTROCHEMISCHE VORRICHTUNG”
    • EP1354864A4
    • 2005-12-07
    • EP01994997
    • 2001-12-25
    • SONY CORP
    • NUBER BERTHOLD
    • C01B3/00C07B61/00C07C35/44C07C303/02C07C303/24C07C305/20C07C309/25H01M8/02H01M8/10
    • C07C305/20C07C35/44C07C309/25C07C2604/00H01M8/1016H01M8/1023Y02E60/324Y02P70/56Y10S977/734Y10S977/735Y10S977/74
    • A method for preparing a fullerene derivative, wherein a fullerene derivative having a group capable of liberating a proton introduced to a carbon atom constituting the fullerene molecule is formed by using a halogenated fullerene formed by halogenating a fullerene molecule as a precursor; a method for preparing a polymerized fullerene derivative, wherein a plurality of fullerene molecules are reacted with an aromatic compound molecule to form a polymer comprising a plurality of fullerene molecules which are bound to one another via the aromatic group of the aromatic compound; a novel and useful proton conductor obtained by using the method; and an electrochemical device, such as a fuel cell, using the proton conductor. The above methods allow the efficient preparation of a fullerene having OH groups or SO3H groups such as fullerenol suitable as a proton conductor. A fullerene derivative prepared by these production methods acts as a proton conductor. The electrochemical device is free from the restriction of atmosphere and thus can be miniaturized and simplified.
    • 本发明提供一种有效地制备引入了OH基团或SO 3 H基团的富勒烯的方法,例如富勒烯醇或其衍生物,富勒烯及其衍生物作为质子导体是优选的,以及由式 方法。 此外,提供了使用诸如燃料电池等的质子导体的电化学装置。 在富勒烯衍生物的制造方法中,通过使富勒烯分子卤化获得的卤代富勒烯用作前体,富勒烯衍生物通过将一个或多个质子离解基团引入到富勒烯分子的至少一个碳原子中来制备。 此外,在聚合的富勒烯衍生物的制造方法中,通过使多种富勒烯衍生物与芳香族化合物反应,多个富勒烯衍生物通过芳香族化合物的芳香族基团彼此键合。 通过这些方法中任一种获得的富勒烯衍生物用作质子导体,并且使用诸如燃料电池的质子导体的电化学装置可以在没有气氛限制的情况下被小型化和简化。
    • 77. 发明授权
    • THERMISCH STABILE FULLERENDERIVATE UND VERFAHREN ZU IHRER HERSTELLUNG
    • 温哥华ZU IHRER HERSTELLUNG
    • EP0680462B1
    • 1997-04-09
    • EP94903862.4
    • 1993-12-22
    • HOECHST AKTIENGESELLSCHAFT
    • GÜGEL, AndreasBELIK, PavelMÜLLEN, Klaus
    • C07C13/62C07C43/215C07C205/45C07C69/157C07C205/58C07D213/55C07C225/22
    • C07D213/79C07C13/32C07C13/70C07C43/215C07C69/00C07C205/58C07C225/22C07C2603/00C07C2604/00Y10S977/737Y10S977/738Y10S977/74Y10S977/833Y10S977/84
    • A fullerene derivate has formula (I), in which the symbols and indexes have the following meaning: F is a fullerene residue having the formula (C20+2m), in which m equals 1 to 50; R1 to R8 are the same or different and represent H, CO¿2R?9, CN, COR10, Cl, Br, J, F, OR11, C1-C20 alkyl, which may be substituted by Cl, J, Br and F, C3-C8 cycloalkyl, aryl, heteroaryl, in which R?9 to R11¿ represent C¿1?-C20 alkyl, phenyl or H; R?1-R4¿ and/or R5, R7 may also be part of a cycloaliphatic, cycloaromatic or cycloheteroaromatic system, which in turn is substituted by C¿1?-C20 alkyl, aryl, carboxyl, carbonyl, alkoxy, aryloxy, halogen, nitro, alcohol or amine; or R?1 and R2, R2 and R3, R3 and R4¿ may represent together (a) or (b), in which R15-R18 are H, C¿1?-C20 alkyl, F, Cl, Br, J or phenyl, and AR is the residue of an annelated cycloaromatic system; R?5 to R8¿ may also stand for the structural element having formula (V), in which i is a number from 2 to 20 and k is a number greater than 1; R?5 and R7¿ may also form together an -O- bridge, and n equals 1 to 20. Also disclosed is a process for producing this derivate.
    • PCT No.PCT / EP93 / 03658 371日期1995年9月15日 102(e)日期1995年9月15日PCT 1993年12月22日PCT公布。 第WO94 / 17018号公报 日期1994年8月4日具有式I的富勒烯衍生物其中符号和指数具有以下含义:+ E,crc F + EE是式(C20 + 2m)的富勒烯基,其中m是数 1至50个R 1至R 8相同或不同,各自为H,CO 2 R 9,CN,COR 10,Cl,Br,I,F,OR 11,C 1 -C 20烷基,苯基或H,R 1 -R 4和/或R 5, R7也可以是环脂酰,环芳烃或环杂芳族体系的一部分,其又被C1-C20烷基,芳基,羧基,羰基,烷氧基,芳氧基,卤素,硝基,醇或胺取代,或R1和R2,R2和 R 3,R 3和R 4可以一起为,其中R 15 -R 18各自为H,C 1 -C 20 - 烷基,F,Cl,Br,I或苯基,+ E,crc AR + EE为稠环 芳族体系,n为1〜20,其制备方法为。
    • 78. 发明公开
    • THERMISCH STABILE FULLERENDERIVATE UND VERFAHREN ZU IHRER HERSTELLUNG
    • 温哥华ZU IHRER HERSTELLUNG的THERMISCH STABILE FULLERENDERIVATE UND VERFAHREN ZU IHRER HERSTELLUNG。
    • EP0680462A1
    • 1995-11-08
    • EP94903862.0
    • 1993-12-22
    • HOECHST AKTIENGESELLSCHAFT
    • GÜGEL, AndreasBELIK, PavelMÜLLEN, Klaus
    • C07C13C07C23C07C25C07C43C07C69C07C205C07C225C07D213
    • C07D213/79C07C13/32C07C13/70C07C43/215C07C69/00C07C205/58C07C225/22C07C2603/00C07C2604/00Y10S977/737Y10S977/738Y10S977/74Y10S977/833Y10S977/84
    • A fullerene derivate has formula (I), in which the symbols and indexes have the following meaning: F is a fullerene residue having the formula (C20+2m), in which m equals 1 to 50; R1 to R8 are the same or different and represent H, CO¿2R?9, CN, COR10, Cl, Br, J, F, OR11, C1-C20 alkyl, which may be substituted by Cl, J, Br and F, C3-C8 cycloalkyl, aryl, heteroaryl, in which R?9 to R11¿ represent C¿1?-C20 alkyl, phenyl or H; R?1-R4¿ and/or R5, R7 may also be part of a cycloaliphatic, cycloaromatic or cycloheteroaromatic system, which in turn is substituted by C¿1?-C20 alkyl, aryl, carboxyl, carbonyl, alkoxy, aryloxy, halogen, nitro, alcohol or amine; or R?1 and R2, R2 and R3, R3 and R4¿ may represent together (a) or (b), in which R15-R18 are H, C¿1?-C20 alkyl, F, Cl, Br, J or phenyl, and AR is the residue of an annelated cycloaromatic system; R?5 to R8¿ may also stand for the structural element having formula (V), in which i is a number from 2 to 20 and k is a number greater than 1; R?5 and R7¿ may also form together an -O- bridge, and n equals 1 to 20. Also disclosed is a process for producing this derivate.
    • PCT No.PCT / EP93 / 03658 371日期1995年9月15日 102(e)日期1995年9月15日PCT 1993年12月22日PCT公布。 第WO94 / 17018号公报 日期1994年8月4日具有式I的富勒烯衍生物其中符号和指数具有以下含义:+ E,crc F + EE是式(C20 + 2m)的富勒烯基,其中m是数 1至50个R 1至R 8相同或不同,各自为H,CO 2 R 9,CN,COR 10,Cl,Br,I,F,OR 11,C 1 -C 20烷基,苯基或H,R 1 -R 4和/或R 5, R7也可以是环脂酰,环芳烃或环杂芳族体系的一部分,其又被C1-C20烷基,芳基,羧基,羰基,烷氧基,芳氧基,卤素,硝基,醇或胺取代,或R1和R2,R2和 R 3,R 3和R 4可以一起为,其中R 15 -R 18各自为H,C 1 -C 20 - 烷基,F,Cl,Br,I或苯基,+ E,crc AR + EE为稠环 芳族体系,n为1〜20,其制备方法为。