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71. 发明申请

WO2009063177A1 PROCESS FOR PRODUCING TRIPTANE 审中-公开
标题翻译：生产TRIPTANE的方法
公开(公告)号：WO2009063177A1
公开(公告)日：2009-05-22
申请号：PCT/GB2008/003772
申请日：2008-11-07
申请人： BP P.L.C. , DANIEL, Berian, John , LAW, David, John , MAUNDERS, Barry, Martin , SUNLEY, John, Glenn , VAN DER WAAL, Jan, Cornelis
发明人： DANIEL, Berian, John , LAW, David, John , MAUNDERS, Barry, Martin , SUNLEY, John, Glenn , VAN DER WAAL, Jan, Cornelis
IPC分类号： C07C1/20 , C07C9/16 , C07C11/02 , B01J29/06
CPC分类号： C07C29/151 , C07C1/20 , C07C2529/08 , C07C2529/12 , C07C2529/14 , C07C2529/16 , C07C2529/18 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/70 , C07C2529/74 , C07C2529/76 , C07C2529/78 , Y02P20/52 , C07C9/16 , C07C11/02 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12
摘要： A process for producing triptane and/or triptene from methanol and/or one or more derivatives thereof, and optionally one or more further alcohols and/or derivatives thereof at a temperature in the range of from 150 to 400 °C, in the presence of a zeolite catalyst having Brønsted acidity, in which all the carbon atoms in the triptane and/or triptene are derived from the methanol and/or one or more derivatives thereof and the optional further alcohols and/or derivatives thereof, the zeolite catalyst being selected from: i. zeolites having frameworks comprising silicon and aluminium atoms at a Si: Al mole ratio of greater than (2), which zeolites also have a channel structure comprising a ring size of (12) or more non-oxygen atoms in (2) or (3) dimensions; and ii. zeolites having frameworks comprising silicon and aluminium atoms, and which have a framework ring comprising (12) or more non-oxygen-atoms accessible on the external surface of the zeolite and a pore structure in which all of the channels have a ring-size of less than (12) non-oxygen atoms. There is also described a process for producing triptane and/or triptene wherein the zeolite catalyst is zeolite X, the reaction composition additionally comprises a C 3 alcohol and/or one or more derivatives thereof, in which the mole ratio of C 3 alcohol : methanol present in the reaction composition, or derivable from the one or more derivatives thereof present in the reaction composition, is greater than 0.23 : 10, and the temperature of the process is in the range of greater than 200° to 400 °C.
摘要翻译：在150-400℃的温度范围内，在甲醇和/或其一种或多种衍生物和任选的一种或多种其它醇和/或其衍生物的存在下，在具有布朗斯台德酸性的沸石催化剂，其中所述三庚烷和/或三丁烯中的所有碳原子来自甲醇和/或其一种或多种衍生物和任选的其它醇和/或衍生物，所述沸石催化剂选自：一世。具有Si：Al摩尔比大于（2）的硅和铝原子的骨架的沸石，该沸石还具有在（2）或（3）中具有包含（12）以上非氧原子的环尺寸的通道结构）尺寸; 和ii。具有包含硅和铝原子的框架的沸石，并且具有包含可在沸石的外表面上的（12）或更多个非氧原子的骨架环和其中所有通道的环状尺寸为小于（12）个非氧原子。还描述了一种制备三庚烷和/或三丁烯的方法，其中沸石催化剂是沸石X，反应组合物另外包含C3醇和/或其一种或多种衍生物，其中存在于C 3醇：甲醇中的摩尔比反应组合物或衍生自反应组合物中的一种或多种衍生物的反应组合物大于0.23:10，并且该方法的温度在大于200-400℃的范围内。

72. 发明申请

WO2008052445A1 甲苯择形歧化反应催化剂审中-公开
公开(公告)号：WO2008052445A1
公开(公告)日：2008-05-08
申请号：PCT/CN2007/003120
申请日：2007-11-02
申请人：中国石油化工股份有限公司 , 中国石油化工股份有限公司上海石油化工研究院 , 谢在库 , 孔德金 , 朱志荣 , 李卫 , 陈庆龄 , 张荣
发明人：谢在库 , 孔德金 , 朱志荣 , 李卫 , 陈庆龄 , 张荣
IPC分类号： B01J29/46 , B01J29/42 , B01J29/40 , B01J29/48 , B01J37/04 , B01J37/02 , B01J37/30 , C07C6/12 , C07C15/04
CPC分类号： B01J37/0009 , B01J21/063 , B01J21/08 , B01J29/405 , B01J29/46 , B01J29/48 , B01J35/023 , B01J37/0207 , B01J37/08 , B01J37/30 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C6/12 , C07C2529/46 , Y02P20/52 , C07C15/08
摘要： A toluene selective disproportionation catalyst comprises: a) 45-95wt% ZSM-5 molecular sieve with average particle diameter of 0.3-6 micron and SiO 2 /Al 2 O 3 mole ratio of 20-120; b) 0.01-30wt% at least one metal or oxide thereof selected from the group consisting of group ? B, group ? B, rare earth, and group ? other than Ni of periodic table of elements; c) 0-20wt% at least one metal or oxide thereof selected from the group consisting of group ? A, group ? B or alkaline earth metal of periodic table of elements; d) 1-25wt% inert face coating of silica derived from organopolysiloxane; and e) 1-50wt% binder. A method for toluene selective disproportionated to paraxylene includes contacting the reactants comprising toluene with the catalyst under the condition for toluene selective disproportionation.

73. 发明申请

WO2008021602A2 STRUCTURES INCLUDING CATALYTIC MATERIALS DISPOSED WITHIN POROUS ZEOLITE MATERIALS, SYSTEMS AND METHODS FOR USING THE SAME, AND METHODS OF FABRICATING CATALYTIC STRUCTURES 审中-公开
标题翻译：包括分布在多孔沸石材料中的催化材料的结构，使用该材料的系统和方法以及制造催化结构的方法
公开(公告)号：WO2008021602A2
公开(公告)日：2008-02-21
申请号：PCT/US2007/069005
申请日：2007-05-16
申请人： BATTELLE ENERGY ALLIANCE, LLC
发明人： ROLLINS, Harry, W. , PETKOVIC, Lucia , GINOSAR, Daniel, M.
IPC分类号： B01J29/04 , C01B39/00
CPC分类号： B01J29/061 , B01J29/005 , B01J29/035 , B01J29/041 , B01J29/072 , B01J29/40 , B01J29/46 , B01J29/80 , B01J37/0018 , C07C1/20 , C07C2529/46 , C07C2529/84 , C07C2529/85 , C10G3/45 , C10G3/47 , C10G3/49 , C10G3/50 , C10G2400/20 , C10G2400/22 , Y02P30/40 , C07C11/02
摘要： Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing the formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing the formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by the crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.
摘要翻译：催化结构包括设置在沸石材料内的催化材料。催化材料可以能够催化从一氧化碳和/或二氧化碳形成甲醇，并且该沸石材料可以能够催化从甲醇形成烃分子。催化材料可以包括铜和氧化锌。沸石材料可以包括基本上由沸石材料的晶体结构限定的第一多个孔和分散在整个沸石材料中的第二多个孔。用于合成烃分子的系统也包括催化结构。用于合成烃分子的方法包括使氢和一氧化碳和二氧化碳中的至少一种与这种催化结构接触。通过至少部分地围绕模板结构形成沸石材料，去除模板结构并将催化材料引入沸石材料来制造催化结构。

74. 发明公开

US20240217900A1 SYSTEMS AND METHODS FOR REFORMING A HEAVY AROMATIC STREAM 审中-公开
公开(公告)号：US20240217900A1
公开(公告)日：2024-07-04
申请号：US18601930
申请日：2024-03-11
申请人： Virent, Inc.
发明人： Paul G. Blommel , Matthew Van Straten , Brice Dally
IPC分类号： C07C4/18 , B01D3/14 , C07C1/22 , C07C5/11 , C07C7/00 , C07C7/04
CPC分类号： C07C4/18 , B01D3/143 , C07C1/22 , C07C5/11 , C07C7/005 , C07C7/04 , C07C2523/14 , C07C2523/28 , C07C2523/30 , C07C2523/44 , C07C2529/46
摘要： Processes, catalysts, and reactor systems for reforming heavy aromatic compounds (C11+) into C6-8 aromatic compounds are disclosed. Also disclosed are processes, catalysts, and reactor systems for producing aromatic compounds and liquid fuels from oxygenated hydrocarbons, such as carbohydrates, sugars, sugar alcohols, sugar degradation products, and the like.

75. 发明申请

US20180243731A1 ALKYLAROMATIC CONVERSION CATALYST 审中-公开
公开(公告)号：US20180243731A1
公开(公告)日：2018-08-30
申请号：US15752963
申请日：2016-08-16
申请人： SHELL OIL COMPANY
发明人： Yuriy YANSON , Hong-Xin LI , Anton PETUSHKOV
IPC分类号： B01J29/44 , B01J29/46 , B01J29/48 , B01J21/08 , B01J35/10 , C07C4/18 , C07C15/04
CPC分类号： B01J29/44 , B01J21/08 , B01J29/042 , B01J29/045 , B01J29/46 , B01J29/48 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0203 , B01J2229/20 , B01J2229/40 , B01J2229/42 , C07C4/18 , C07C15/04 , C07C2521/08 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C10G35/095 , Y02P20/52 , C07C11/04
摘要： Alkylaromatic conversion catalyst which comprises a) a carrier which comprises of from 20 to 70 wt % of a refractory oxide binder, of from 30 to 80 wt % of ZSM-5 having a mesopore volume of from 0.1 to 1.0 ml/g, a crystallite size of from 3 to 100 nm and a silica to alumina molar ratio in the range of from 20 to 200, all percentages being on the basis of total catalyst; b) an amount of from 0.001 to 5 wt % of one or more metals chosen from the group consisting of Groups 6, 9 and 10; and c) optionally a metal chosen from Group 14 in an amount up to 0.5 wt %, on the basis of total catalyst, and a process for the preparation of such catalyst.

76. 发明授权

US10058853B2 Catalyst compositions and use in heavy aromatics conversion processes 有权
公开(公告)号：US10058853B2
公开(公告)日：2018-08-28
申请号：US15004623
申请日：2016-01-22
申请人： ExxonMobil Chemical Patents Inc.
发明人： Wenyih F. Lai , Christine N. Elia , Jane C. Cheng , Shifang L. Luo , Hari Nair , Joshua I. Cutler , Doron Levin , Chuansheng Bai
IPC分类号： C07C6/12 , C07C4/18 , B01J29/80 , B01J35/10 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J8/04 , B01J37/18 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/76 , B01J35/00 , B01J35/02 , C01B39/26
CPC分类号： B01J29/80 , B01J8/04 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7461 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/76 , B01J29/7646 , B01J29/7653 , B01J29/7661 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1033 , B01J35/1052 , B01J35/108 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2208/027 , B01J2229/186 , B01J2229/42 , C01B39/265 , C07C4/18 , C07C6/126 , C07C15/06 , C07C2521/04 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/80 , C07C2529/87 , C10G45/62 , C10G45/64 , C10G45/70 , C10G2300/1096 , C10G2300/70 , C10G2400/30 , Y02P20/52
摘要： Disclosed is a catalyst composition and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst composition comprises a mordenite zeolite synthesized from TEA or MTEA, optionally at least one first metal of Group 10 of the IUPAC Periodic Table, and optionally at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said mordenite zeolite has a mesopore surface area of greater than 30 m2/g and said mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.

77. 发明授权

US10011539B2 Process for conversion of acyclic C5 compounds to cyclic C5 compounds and catalyst composition for use therein 有权
公开(公告)号：US10011539B2
公开(公告)日：2018-07-03
申请号：US15288447
申请日：2016-10-07
申请人： ExxonMobil Chemical Patents Inc.
发明人： Larry L. Iaccino , Jeremy W. Bedard , Wenyih F. Lai , Robert T. Carr , Jane C. Cheng
IPC分类号： C07C5/327 , C07C5/32 , C07C5/333 , C07C5/373 , B01J29/44
CPC分类号： C07C5/373 , B01J29/44 , B01J29/46 , B01J29/62 , C07C5/42 , C07C2529/44 , C07C2529/46 , C07C2529/62 , C07C2601/06 , C07C2601/10 , C07C13/10 , C07C13/12 , C07C13/15
摘要： Disclosed is a process for the conversion of acyclic C5 feedstock to a product comprising cyclic C5 compounds, such as, for example, cyclopentadiene, and catalyst compositions for use in such process. The process comprises the steps of contacting said feedstock and, optionally, hydrogen under acyclic C5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprising a microporous crystalline aluminosilicate having a constraint index in the range of 3 to 12, a Group 10 metal, and, optionally, a Group 11 metal, in combination with a Group 1 alkali metal and/or a Group 2 alkaline earth metal.

78. 发明授权

US09802181B2 Catalyst system and use in heavy aromatics conversion processes 有权
公开(公告)号：US09802181B2
公开(公告)日：2017-10-31
申请号：US15004662
申请日：2016-01-22
申请人： ExxonMobil Chemical Patents Inc.
发明人： Christine N. Elia , Shifang L. Luo , Hari Nair , Wenyih F. Lai , Robert G. Tinger
IPC分类号： C07C6/12 , C07C4/18 , B01J29/80 , B01J35/10 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J8/04 , B01J37/18 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/76 , B01J35/00 , B01J35/02 , C01B39/26
CPC分类号： B01J29/80 , B01J8/04 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7461 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/76 , B01J29/7646 , B01J29/7653 , B01J29/7661 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1033 , B01J35/1052 , B01J35/108 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2208/027 , B01J2229/186 , B01J2229/42 , C01B39/265 , C07C4/18 , C07C6/126 , C07C15/06 , C07C2521/04 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/80 , C07C2529/87 , Y02P20/52
摘要： Disclosed are a catalyst system and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst system comprises (a) a first catalyst bed comprising a first catalyst composition, said first catalyst composition comprising a zeolite having a constraint index of 3 to 12 combined (i) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (ii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table; and (b) a second catalyst bed comprising a second catalyst composition, said second catalyst composition comprising (i) a meso-mordenite zeolite, combined (ii) optionally with at least one first metal of Group 10 of the IUPAC Periodic Table, and (iii) optionally with at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said meso-mordenite zeolite is synthesized from TEA or MTEA and having a mesopore surface area of greater than 30 m2/g and said meso-mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.

79. 发明申请

US20170247300A1 Hydrocarbon Conversion 有权
公开(公告)号：US20170247300A1
公开(公告)日：2017-08-31
申请号：US15593984
申请日：2017-05-12
申请人： ExxonMobil Chemical Patents Inc.
发明人： Paul F. Keusenkothen , Juan D. Henao , Abhimanyu O. Patil , Guang Cao
IPC分类号： C07C2/86
CPC分类号： C07C2/864 , C07C2/76 , C07C2/865 , C07C2529/06 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/87 , C07C15/00
摘要： This disclosure relates to the conversion of methane to higher molecular weight (C5+) hydrocarbon, including aromatic hydrocarbon, to materials and equipment useful in such conversion, and to the use of such conversion for, e.g., natural gas upgrading.

80. 发明授权

US09682900B2 Hydrocarbon conversion 有权
公开(公告)号：US09682900B2
公开(公告)日：2017-06-20
申请号：US14543405
申请日：2014-11-17
申请人： ExxonMobil Chemical Patents Inc.
发明人： Paul F. Keusenkothen , Juan D. Henao , Abhimanyu O. Patil , Guang Cao
IPC分类号： C07C2/76 , C07C2/86
CPC分类号： C07C2/864 , C07C2/76 , C07C2/865 , C07C2529/06 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/87 , C07C15/00
摘要： This disclosure relates to the conversion of methane to higher molecular weight (C5+) hydrocarbon, including aromatic hydrocarbon, to materials and equipment useful in such conversion, and to the use of such conversion for, e.g., natural gas upgrading.

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