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71. 发明授权

US5863337A Apparatus for coating a moving glass substrate 失效
标题翻译：用于涂覆移动玻璃基板的装置
公开(公告)号：US5863337A
公开(公告)日：1999-01-26
申请号：US464113
申请日：1995-06-05
申请人： George A. Neuman , John F. Sopko , Douglas S. Dauson
发明人： George A. Neuman , John F. Sopko , Douglas S. Dauson
IPC分类号： C03C17/00 , C03C17/245 , C03C17/34 , C23C16/40 , C23C16/44 , C23C16/453 , C23C16/54 , C23C16/00
CPC分类号： C03C17/002 , C03C17/245 , C03C17/2453 , C03C17/3417 , C23C16/401 , C23C16/402 , C23C16/4412 , C23C16/453 , C23C16/545 , C03C2217/213 , C03C2217/23 , C03C2218/152
摘要： An apparatus for coating a moving substrate which provides means for directing a coating composition vapor toward a substrate surface and moving portions of the vapor in opposite directions. The apparatus of the present invention may have the exhaust means on either side of the vapor directing means spaced at different distances from the vapor directing means, or the exhaust means may be spaced equally from the vapor directing means, but at different distances from the substrate surface. In another embodiment, the apparatus comprises the means to alter the flow volume of the vapor directing means and the two exhaust means such that the flow volume of the first and second exhaust means are not equal, such as by the exhaust means having openings of unequal surface area, wherein the exhaust means may be spaced equally or unequally from the vapor directing means at the same or different distances from the substrate surface. In another embodiment, the apparatus further comprises a structural element bridging the space between the vapor directing means and the exhaust means, which may be spaced equally or unequally from the vapor directing means, and at the same or different distances from the substrate surface.
摘要翻译：一种用于涂覆移动衬底的装置，其提供用于将涂料组合物蒸气引向衬底表面并使蒸气沿相反方向移动的装置。本发明的装置可以在蒸汽引导装置的任一侧上具有与蒸汽引导装置不同距离间隔开的排气装置，或者排气装置可以与蒸气引导装置间隔开，但距衬底不同的距离表面。在另一个实施例中，该装置包括改变蒸汽导向装置和两个排气装置的流量的装置，使得第一和第二排气装置的流量不相等，例如具有不等的开口的排气装置表面积，其中所述排气装置可以与所述蒸气引导装置以相同或不同的距离与所述基板表面间隔开或不等间隔。在另一个实施例中，该装置还包括桥接蒸气引导装置和排气装置之间的空间的结构元件，其可以与蒸气引导装置相等或不相等地间隔开，并且距离衬底表面相同或不同。

72. 发明授权

US5744215A Reduction of haze in transparent coatings 失效
标题翻译：减少透明涂料中的雾度
公开(公告)号：US5744215A
公开(公告)日：1998-04-28
申请号：US582795
申请日：1996-01-04
申请人： George A. Neuman
发明人： George A. Neuman
IPC分类号： B05D5/06 , B05D7/00 , B05D7/24 , C03C17/00 , C03C17/34 , B32B3/26
CPC分类号： C03C17/00 , C03C17/3417 , Y10S428/913 , Y10T428/24355 , Y10T428/24479 , Y10T428/24521 , Y10T428/24612 , Y10T428/2462
摘要： Surface haze resulting from a rough surface of a substrate e.g. a fluorine doped tin oxide coated glass piece is reduced by coating the rough surface with a smooth surface coating of sufficient thickness to smooth out the rough surface e.g. coating the tin oxide layer with a silica film having a thickness of about 100 to 2000 Angstroms.
摘要翻译：由基底的粗糙表面产生的表面雾度，例如通过用足够厚度的光滑表面涂层涂覆粗糙表面来平滑粗糙表面，例如，通过涂覆氟掺杂的氧化锡涂覆的玻璃片。用厚度约为100至2000埃的二氧化硅膜涂覆氧化锡层。

73. 发明授权

US5464657A Method for coating a moving glass substrate 失效
标题翻译：涂覆移动玻璃基板的方法
公开(公告)号：US5464657A
公开(公告)日：1995-11-07
申请号：US264816
申请日：1994-06-23
申请人： Patricia R. Athey , Douglas S. Dauson , David E. Lecocq , George A. Neuman , John F. Sopko , Royann L. Stewart-Davis
发明人： Patricia R. Athey , Douglas S. Dauson , David E. Lecocq , George A. Neuman , John F. Sopko , Royann L. Stewart-Davis
IPC分类号： B32B9/00 , B32B17/06 , C03C17/00 , C03C17/23 , C03C17/245 , C03C17/30 , C03C17/34 , C07C7/04 , C23C16/40 , C23C16/44 , C23C16/453 , C23C16/455 , C23C16/54 , C23C16/00
CPC分类号： C03C17/245 , C03C17/002 , C03C17/2453 , C03C17/3417 , C23C16/401 , C23C16/4412 , C23C16/453 , C23C16/545 , C03C2217/211 , C03C2217/212 , C03C2217/213 , C03C2217/215 , C03C2217/216 , C03C2217/218 , C03C2217/219 , C03C2217/228 , C03C2217/23 , C03C2217/241 , C03C2217/244 , C03C2218/152
摘要： A method for coating a moving substrate provides a coating having a chemical composition which varies continuously from the interface with the substrate to the opposite surface of the coating. The method involves directing a vapor coating composition toward a substrate surface and moving portions of the vapor in opposite directions. A vapor coating mixture may include a tin-containing precursor and a silicon-containing precursor. An accelerant, e.g. a phosphorus-containing precursor, may be used with the metal-containing precursors to increase the deposition rate of the coating. The coating deposited on the substrate has regions of continuously varying weight percent of silicon oxide and tin oxide as the distance from the substrate-coating interface increases, with the surface of the coating farthest from the substrate-coating interface being predominantly tin oxide. The regions of varying composition provide the coating with varying indices of refraction to eliminate iridescence to provide a coated article, particularly a tin oxide coated glass article, with a neutral color.
摘要翻译：涂覆移动衬底的方法提供了具有从衬底到衬底的相对表面连续变化的化学组成的涂层。该方法包括将蒸气涂料组合物引向衬底表面，并使蒸汽的相反方向移动。蒸气涂覆混合物可以包括含锡前体和含硅前体。促进剂，例如。含磷前体可以与含金属的前体一起使用以增加涂层的沉积速率。沉积在基板上的涂层具有连续改变重量百分比的氧化硅和氧化锡的区域，这是随着与基板 - 涂层界面的距离增加，涂层表面离基材 - 涂层界面最远的地方主要是氧化锡。不同组成的区域为涂层提供了不同的折射率，以消除虹彩以提供具有中性色的涂层制品，特别是涂有氧化锡的玻璃制品。

74. 发明授权

US4857361A Haze-free infrared-reflecting coated glass 失效
标题翻译：无雾红外反射镀膜玻璃
公开(公告)号：US4857361A
公开(公告)日：1989-08-15
申请号：US182643
申请日：1988-04-18
申请人： Karl H. Bloss , James A. Davis , George A. Neuman
发明人： Karl H. Bloss , James A. Davis , George A. Neuman
IPC分类号： C03C17/245 , C23C16/40
CPC分类号： C23C16/407 , C03C17/2453
摘要： A novel organotin coating composition comprising tributyltin dimethylpropionate is disclosed, along with a method for preparing it and a method for pyrolyzing it to form a tin oxide film on the surface of a substrate.
摘要翻译：公开了一种包含三丁基锡二甲基丙酸酯的新型有机锡涂料组合物及其制备方法及其在基材表面上热解以形成氧化锡膜的方法。

75. 发明授权

US5395698A Neutral, low emissivity coated glass articles and method for making 失效
标题翻译：中性，低辐射涂层玻璃制品及其制造方法
公开(公告)号：US5395698A
公开(公告)日：1995-03-07
申请号：US072792
申请日：1993-06-04
申请人： George A. Neuman , Royann L. Stewart-Davis
发明人： George A. Neuman , Royann L. Stewart-Davis
IPC分类号： B05D5/06 , B32B7/02 , B32B15/06 , B32B17/00 , C03C17/23 , C03C17/245 , C03C17/34 , G02B1/10 , B32B15/00
CPC分类号： G02B1/10 , C03C17/3417 , Y10T428/24942 , Y10T428/24975 , Y10T428/265
摘要： A coated article and method of producing it are disclosed wherein the iridescence caused by the difference between the refractive index of a transparent substrate and the refractive index of a metal oxide coating is reduced by means of two intermediate layers, the first of which, closest to the substrate, has a refractive index higher than the refractive index of the substrate but lower than the refractive index of the second, and the second has a refractive index higher than the refractive index of the first but lower than the refractive index of the metal oxide coating. The thicknesses of the two intermediate layers for optimizing a neutral appearance are determined by the thickness and refractive index of the metal oxide coating.
摘要翻译：公开了一种涂覆制品及其制造方法，其中由透明基材的折射率与金属氧化物涂层的折射率之间的差异引起的虹彩通过两个中间层而减少，其中第一个最接近基板具有比基板的折射率高的折射率，但低于第二折射率的折射率，第二折射率的折射率比第一折射率高，但低于金属氧化物的折射率涂层。用于优化中性外观的两个中间层的厚度由金属氧化物涂层的厚度和折射率决定。

76. 发明授权

US4965093A Chemical vapor deposition of bismuth oxide 失效
标题翻译：化学气相沉积氧化铋
公开(公告)号：US4965093A
公开(公告)日：1990-10-23
申请号：US219693
申请日：1988-07-05
申请人： George A. Neuman , Karl H. Bloss
发明人： George A. Neuman , Karl H. Bloss
IPC分类号： C01G29/00 , C03C17/245 , C23C16/40
CPC分类号： C03C17/245 , C23C16/407 , C03C2217/228 , C03C2218/152
摘要： Novel organometallic coating compositions comprising organo bismuth compounds are disclosed, along with a method for chemical vapor deposition to form bismuth oxide films on the surface of a substrate such as glass.

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