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71. 发明授权

US07507503B2 Long life lithium batteries with stabilized electrodes 有权
标题翻译：长寿命的锂电池具有稳定的电极
公开(公告)号：US07507503B2
公开(公告)日：2009-03-24
申请号：US11297120
申请日：2005-12-08
申请人： Khalil Amine , Jun Liu , Donald R. Vissers , Wenquan Lu
发明人： Khalil Amine , Jun Liu , Donald R. Vissers , Wenquan Lu
IPC分类号： H01M6/16
CPC分类号： H01M10/0567 , H01M4/13 , H01M4/366 , H01M4/505 , H01M4/5825 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M10/0569
摘要： The present invention relates to non-aqueous electrolytes having electrode stabilizing additives, stabilized electrodes, and electrochemical devices containing the same. Thus the present invention provides electrolytes containing an alkali metal salt, a polar aprotic solvent, and an electrode stabilizing additive. In some embodiments the additives include a substituted or unsubstituted cyclic or spirocyclic hydrocarbon containing at least one oxygen atom and at least one alkenyl or alkynyl group. When used in electrochemical devices with, e.g., lithium manganese oxide spinel electrodes or olivine or carbon-coated olivine electrodes, the new electrolytes provide batteries with improved calendar and cycle life.
摘要翻译：本发明涉及具有电极稳定添加剂，稳定电极和含有这些电极的电化学装置的非水电解质。因此，本发明提供了含有碱金属盐，极性非质子溶剂和电极稳定添加剂的电解质。在一些实施方案中，添加剂包括含有至少一个氧原子和至少一个烯基或炔基的取代或未取代的环状或螺环烃。当用于具有例如锂锰氧化物尖晶石电极或橄榄石或碳涂覆的橄榄石电极的电化学装置中时，新的电解质提供具有改善的日历和循环寿命的电池。

72. 发明授权

US07390594B2 Anode material for lithium batteries 有权
标题翻译：锂电池阳极材料
公开(公告)号：US07390594B2
公开(公告)日：2008-06-24
申请号：US10741248
申请日：2003-12-18
申请人： Ilias Belharouak , Khalil Amine
发明人： Ilias Belharouak , Khalil Amine
IPC分类号： H01M4/58
CPC分类号： C01G23/003 , C01P2002/72 , C01P2002/77 , C01P2006/40 , H01M4/366 , H01M4/485 , H01M4/625 , H01M10/0567 , H01M10/4235 , H01M2004/027
摘要： Primary and secondary Li-ion and lithium-metal based electrochemical cell system. The suppression of gas generation is achieved through the addition of an additive or additives to the electrolyte system of respective cell, or to the cell itself whether it be a liquid, a solid- or plastized polymer electrolyte system. The gas suppression additives are primarily based on unsaturated hydrocarbons.
摘要翻译：一次和二次锂离子和锂金属基电化学电池系统。气体产生的抑制是通过向相应电池的电解质体系中添加添加剂或添加剂，或者将其添加到电池本身来实现的，无论它是液体，固体或塑化的聚合物电解质体系。气体抑制添加剂主要基于不饱和烃。

73. 发明申请

US20080026297A1 ELECTROLYTES, CELLS AND METHODS OF FORMING PASSIVATON LAYERS 审中-公开
标题翻译：电解质，细胞和形成钝化层的方法
公开(公告)号：US20080026297A1
公开(公告)日：2008-01-31
申请号：US11843889
申请日：2007-08-23
申请人： Zonghai Chen , Khalil Amine
发明人： Zonghai Chen , Khalil Amine
IPC分类号： H01M6/16
CPC分类号： H01M10/052 , H01M4/131 , H01M4/133 , H01M10/0567 , H01M10/0568
摘要： An electrolyte comprising at least one organic aprotic solvent, at least one salt and at least one chelatoborate additive. A method of forming an SEI layer in a cell comprising a positive electrode, a negative electrode and an electrolyte, said method comprising the step of overcharging the electrolyte prior to fabricating the cell, or said cell during the formation cycle.
摘要翻译：包含至少一种有机非质子溶剂，至少一种盐和至少一种螯合硼酸盐添加剂的电解质。一种在包括正极，负极和电解质的电池中形成SEI层的方法，所述方法包括在制造电池或在形成循环期间所述电池之前对电解液进行过充电的步骤。

74. 发明授权

US07314684B2 Layer cathode methods of manufacturing and materials for Li-ion rechargeable batteries 有权
标题翻译：锂离子可再充电电池的制造和材料的层阴极方法
公开(公告)号：US07314684B2
公开(公告)日：2008-01-01
申请号：US10800292
申请日：2004-03-12
申请人： Sun-Ho Kang , Khalil Amine
发明人： Sun-Ho Kang , Khalil Amine
IPC分类号： H01M4/58 , H01M4/00 , H01M4/50 , C01D1/02 , C01G23/00
CPC分类号： H01M4/525 , C01G45/1228 , C01G53/50 , C01P2002/54 , C01P2002/72 , C01P2002/76 , C01P2006/40 , H01M4/505 , H01M10/0525 , Y02T10/7011
摘要： A positive electrode active material for lithium-ion rechargeable batteries of general formula Li1+xNiαMnβAγO2 and further wherein A is Mg, Zn, Al, Co, Ga, B, Zr, or Ti and 0
摘要翻译： 1.一种用于锂离子可再充电电池的正极活性材料，其通式为Li 1 + x Ni 2 O 3，并且其中A是Mg，Zn，Al，Co，Ga，B，Zr或Ti，0

75. 发明申请

US20070292763A1 Cathode material for lithium batteries 有权
标题翻译：锂电池阴极材料
公开(公告)号：US20070292763A1
公开(公告)日：2007-12-20
申请号：US11455358
申请日：2006-06-19
申请人： Sang-Ho Park , Khalil Amine
发明人： Sang-Ho Park , Khalil Amine
IPC分类号： H01M4/48 , C01G39/02
CPC分类号： H01M4/131 , C01G45/006 , C01G45/1228 , C01G51/006 , C01G51/50 , C01G53/006 , C01G53/50 , C01P2002/52 , C01P2002/72 , C01P2002/77 , C01P2004/03 , C01P2004/32 , C01P2004/61 , C01P2006/11 , C01P2006/40 , H01M4/485 , H01M4/505 , H01M4/525 , H01M10/052 , H01M10/0525 , H01M10/056 , H01M10/0568 , H01M10/0569 , Y02E60/122 , Y02T10/7011
摘要： A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.
摘要翻译：锂电池阴极（正极）材料制品的制造方法。阴极材料是一种锂钼复合过渡金属氧化物材料，它是通过将固体状态的中间体钼复合过渡金属氧化物和锂源混合来制备的。对混合物进行热处理以获得锂钼复合过渡金属氧化物阴极材料。

76. 发明申请

US20060099508A1 Lithium metal oxide electrodes for lithium cells and batteries 有权
标题翻译：用于锂电池和电池的锂金属氧化物电极
公开(公告)号：US20060099508A1
公开(公告)日：2006-05-11
申请号：US11271462
申请日：2005-11-10
申请人： Michael Thackeray , Christopher Johnson , Khalil Amine
发明人： Michael Thackeray , Christopher Johnson , Khalil Amine
IPC分类号： H01M4/50 , H01M4/52
CPC分类号： H01M4/485 , H01M4/131 , H01M4/1391 , H01M4/505 , H01M4/525 , H01M10/052
摘要： A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO2.(1−x)Li2M′O3 in which 0
摘要翻译：公开了一种非水锂电池用锂金属氧化物正极。电池在其初始放电状态下制备，并具有通式xLiMO 2（1-x）Li 2 M'O 3 N 其中0

77. 发明授权

US07026074B2 Lithium ion battery with improved safety 有权
标题翻译：锂离子电池安全性提高
公开(公告)号：US07026074B2
公开(公告)日：2006-04-11
申请号：US10077569
申请日：2002-02-15
申请人： Chun-hua Chen , Yoo Eup Hyung , Donald R. Vissers , Khalil Amine
发明人： Chun-hua Chen , Yoo Eup Hyung , Donald R. Vissers , Khalil Amine
IPC分类号： H01M10/40
CPC分类号： H01M10/0567 , H01M10/052 , H01M10/0525 , H01M10/4235
摘要： A lithium battery with improved safety that utilizes one or more additives in the battery electrolyte solution wherein a lithium salt is dissolved in an organic solvent, which may contain propylene, carbonate. For example, a blend of 2 wt % triphenyl phosphate (TPP), 1 wt % diphenyl monobutyl phosphate (DMP) and 2 wt % vinyl ethylene carbonate additives has been found to significantly enhance the safety and performance of Li-ion batteries using a LiPF6 salt in EC/DEC electrolyte solvent. The invention relates to both the use of individual additives and to blends of additives such as that shown in the above example at concentrations of 1 to 4-wt % in the lithium battery electrolyte. This invention relates to additives that suppress gas evolution in the cell, passivate graphite electrode and protect it from exfoliating in the presence of propylene carbonate solvents in the electrolyte, and retard flames in the lithium batteries.
摘要翻译：一种电池电解液中使用一种或多种添加剂的安全性提高的锂电池，其中锂盐溶解在可能含有丙烯，碳酸盐的有机溶剂中。例如，已经发现，使用2重量％磷酸三苯酯（TPP），1重量％磷酸二苯基丁酯（DMP）和2重量％乙烯基碳酸亚乙酯添加剂的混合物可显着提高使用LiPF的锂离子电池的安全性和性能 EC / DEC电解质溶剂中的盐。本发明涉及在锂电池电解质中单独添加剂的使用和上述实施例中所示的添加剂的混合物的浓度为1至4重量％。本发明涉及抑制电池中的气体逸出的添加剂，钝化石墨电极，并且在电解质中存在碳酸丙烯酯溶剂的情况下保护其免于脱落，并延缓锂电池中的火焰。

78. 发明申请

US20050106470A1 Battery having electrolyte including one or more additives 审中-公开
标题翻译：具有包含一种或多种添加剂的电解质的电池
公开(公告)号：US20050106470A1
公开(公告)日：2005-05-19
申请号：US10962125
申请日：2004-10-07
申请人： Sang Yoon , Hiroshi Nakahara , Khalil Amine
发明人： Sang Yoon , Hiroshi Nakahara , Khalil Amine
IPC分类号： H01M2/16 , H01M10/052 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/40
CPC分类号： H01M10/052 , H01M2/16 , H01M10/0567 , H01M10/0568 , H01M10/0569
摘要： A battery is disclosed. The battery includes an electrolyte activating one or more anodes and one or more cathodes. The electrolyte includes one or more salts and one or more additives in a solvent. The solvent includes a silane or a siloxane. The one or more additives form a passivation layer on at least one of the anodes. In some instances, the additives include vinyl carbonate (VC), and/or vinyl ethylene carbonate (VEC).
摘要翻译：公开了电池。电池包括激活一个或多个阳极和一个或多个阴极的电解质。电解质包括溶剂中的一种或多种盐和一种或多种添加剂。溶剂包括硅烷或硅氧烷。一种或多种添加剂在至少一个阳极上形成钝化层。在一些情况下，添加剂包括碳酸乙烯酯（VC）和/或碳酸乙烯酯碳酸酯（VEC）。

79. 发明申请

US20050019656A1 Method for fabricating composite electrodes 审中-公开
标题翻译：复合电极的制造方法
公开(公告)号：US20050019656A1
公开(公告)日：2005-01-27
申请号：US10496231
申请日：2003-03-20
申请人： Sang Yoon , Bookeun Ph , Khalil Amine
发明人： Sang Yoon , Bookeun Ph , Khalil Amine
IPC分类号： H01G9/025 , H01M4/04 , H01M4/13 , H01M4/139 , H01M4/52 , H01M4/62 , H01M10/058 , H01M10/40
CPC分类号： H01M4/62 , H01M4/0426 , H01M4/13 , H01M4/139 , H01M4/621 , H01M4/622 , H01M10/058 , H01M10/4235 , Y10T29/4911 , Y10T29/49115
摘要： Disclosed is a method for manufacturing electrodes (100) for electrochemical devices such as batteries and capacitors in which a viscous polysiloxane polymer electrolyte (116) is incorporated into the slurry of materials forming the electrode (100). The optional addition of protective additives (218) to the slurry is also disclosed. A follow-on vacuum impregnation step (228) is disclosed to further improve penetration and wetting by the electrolyte (116).
摘要翻译：公开了一种用于制造诸如电池和电容器的电化学装置的电极（100）的方法，其中粘性聚硅氧烷聚合物电解质（116）被引入到形成电极（100）的材料的浆料中。还公开了向浆料中添加保护添加剂（218）。公开了随后的真空浸渍步骤（228），以进一步改善电解质（116）的渗透和润湿。

80. 发明授权

US06677082B2 Lithium metal oxide electrodes for lithium cells and batteries 有权
标题翻译：用于锂电池和电池的锂金属氧化物电极
公开(公告)号：US06677082B2
公开(公告)日：2004-01-13
申请号：US09887842
申请日：2001-06-21
申请人： Michael M. Thackeray , Christopher S. Johnson , Khalil Amine , Jaekook Kim
发明人： Michael M. Thackeray , Christopher S. Johnson , Khalil Amine , Jaekook Kim
IPC分类号： H01M450
CPC分类号： C01G45/1257 , C01G23/002 , C01G25/006 , C01G45/1221 , C01G45/1228 , C01G53/42 , C01P2002/22 , C01P2002/52 , C01P2002/72 , C01P2004/82 , C01P2006/40 , H01M4/485 , H01M4/505 , H01M4/525 , H01M2004/021
摘要： A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO2.(1-x)Li2M′O3 in which 0
摘要翻译：公开了一种非水锂电池用锂金属氧化物正极。电池以其初始放电状态制备，具有通式xLiMO2（1-x）Li2M'O3，其中0

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