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    • 73. 发明专利
    • MANUFACTURE OF OXIDE SUPERCONDUCTING WIRE ROD
    • JPH0436910A
    • 1992-02-06
    • JP14296290
    • 1990-05-31
    • TOSHIBA CORP
    • NAKAYAMA SHIGEO
    • C04B35/00C01B13/14C01G1/00C04B35/45H01B12/04H01B13/00
    • PURPOSE:To provide a practicable critical current density and also decrease dispersion of the critical current density by a method wherein the reduction of area of a metal tube filled with superconducting powder is performed after the metal tube is made to pass through a magnetic field at a temperature lower than the critical temperature of an oxide superconductor when the area of the metal tube is reduced to a desired shape of wire rod to manufacture an oxide superconducting wire rod. CONSTITUTION:Immediately after a magnetic field treatment at a temperature of liquid nitrogen is applied to a silver pipe filled with oxide superconducting powder, reduction-of-area work of the silver pipe is performed. A magnetic field at liquid nitrogen to be used for magnetic field treatment is formed by arranging a magnet 2 of 7500 gausses at the lower part of a glass tube 1 having an inlet 1a of liquid nitrogen and flowing liquid nitrogen into the glass tube 1. Then, the silver pipe 4 filled with the oxide superconducting powder 3 is cooled by liquid nitrogen and also made to pass through the inside of the glass tube 1 to which magnetic field is applied by a permanent magnet 2, and immediately thereafter, the silver pipe 4 is made to pass through between a pair of working rollers 5 to perform reduction of area and make a strand 6 or the prototype of an oxide superconducting wire rod.
    • 77. 发明专利
    • MANUFACTURE OF OXIDE SUPERCONDUCTIVE WIRE
    • JPH01163914A
    • 1989-06-28
    • JP32172487
    • 1987-12-19
    • TOSHIBA CORP
    • YAMADA MINORUNAKAYAMA SHIGEOKOIZUMI MISAOMURASE AKIRA
    • B28B1/00C01G1/00C04B35/45H01B12/04H01B13/00
    • PURPOSE:To prevent the generation of bores and cracks, and to manufacture a superconductive wire of a high critical current density by introducing a columnar body formed by applying a pressure to an oxide superconductor powder, or a sintered body made by applying a heat treatment after such a pressure-formation, in a metal pipe, a surface reduction process is applied to the metal pipe, and heat-treating in the oxygen ambiance as it is or after the metal pipe is removed. CONSTITUTION:When an oxide superconductive wire is manufactured by using no reinforcement material, an oxide superconductor powder is formed by applying a pressure to make into a columnar body 2a with the outer diameter a little smaller than the inner diameter of a metal pipe 1, and the columnar body 2a is led in the metal pipe 1. Or, plural short column bodies 2b formed in the same way, or divided bodies 2c divided plurally are led in the metal tube 1 in series. On the other hand, when a reinforcement is used, a columnar body 2d with the outer diameter a little smaller than the inner diameter of the metal pipe and with holes 4 to insert reinforcements in the form of rotus root is formed by applying a pressure to the oxide superconductor powder, and linear reinforcement materials 3a are inserted to the holes 4, as well as the columnar body 2d is inserted to the metal pipe 1.
    • 78. 发明专利
    • MANUFACTURE OF OXIDE SUPERCONDUCTIVE WIRE
    • JPH01163913A
    • 1989-06-28
    • JP32171187
    • 1987-12-19
    • TOSHIBA CORP
    • YAMADA MINORUNAKAYAMA SHIGEOMURASE AKIRA
    • H01B12/02B28B1/00H01B13/00
    • PURPOSE:To make the volume contraction of an oxide superconductor smooth and to improve the critical current density of a superconductive wire by arranging a metallic core material in a metal pipe in the longitudinal direction, filling an oxide superconductor powder between the core material and the metal pipe, removing the metal layer at the outer periphery after a wiredrawing process is applied, and heat-treating in the ambiance including oxygen. CONSTITUTION:A perovskite structure oxide superconductor powder 1 with a specific ratio of the diameter to the thickness is filled in a copper pipe 3, in which a silver core wire 2 has been arranged in the longitudinal direction, and one end has been sealed with a copper material. The other end of the copper pipe 3 is sealed with a copper material after that. Then, a wiredrawing process is applied to obtain a raw wire, the copper layer around the raw wire is removed, and a heat treatment is applied in the ambiance including oxygen. And an oxide superconductor layer 5 is formed around the silver layer 4, and a superconductive wire 6 is manufactured. The metallic core material is made of silver, gold, platinum, paradium, or an alloy of them, and the volume contraction of the oxide superconductor can be made smoothly, the mechanical strength is improved, and the critical current density is increased.
    • 80. 发明专利
    • MANUFACTURE OF OXIDE SUPERCONDUCTING WIRE
    • JPH01161620A
    • 1989-06-26
    • JP32043387
    • 1987-12-18
    • TOSHIBA CORP
    • KOIZUMI MISAOYAMADA MINORUNAKAYAMA SHIGEO
    • B28B1/00H01B12/02H01B13/00
    • PURPOSE:To obtain a superconducting wire with sufficient mechanical strength and high superconductive characteristic by sticking a raw material solution synthesizing a compound superconductor to a reinforcing material such as a tape, stack-winding it on a core, evaporating an organic solvent, removing the core, and applying heat treatment in the oxygen atmosphere. CONSTITUTION:A solution 4 obtained by solving a raw material capable of synthesizing an oxide compound superconductor with an organic solvent is stuck to a reinforcing material made of a tape 2, a sheet or threads formed with carbon fibers or quartz fibers, the reinforcing material is stack-wound on a core 6 to form a stack-wound layer 8. The stack-wound layer 8 is dried, the organic solvent is evaporated, the core 6 is removed, heat treatment is applied to the stack-wound layer 8 in the oxygen atmosphere, and a compound superconductor is synthesized with the raw material. Since the reinforcing material abundant in heat resistance is incorporated, cracks generated at the time of heat treatment are suppressed, and a superconducting wire with high superconductive characteristic and abundant in mechanical strength is obtained.