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    • 73. 发明专利
    • SILICONE RUBBER COMPOSITION
    • JPS63150350A
    • 1988-06-23
    • JP29611486
    • 1986-12-12
    • SHINETSU CHEMICAL CO
    • ITO KUNIOIMAI SEIFUKUDA TAKESHI
    • C08K3/36C08K5/02C08K5/06C08K5/103C08K5/54C08L83/04
    • PURPOSE:To provide the title compsn. which has excellent elongation and flexural fatigue properties and is useful for dynamic use such as rubber contact, etc., in electronic calculators, touch-tone telephone sets, etc., by blending a specified organopolysiloxane with reinforcing silica and a fluorinated org. compd. CONSTITUTION:100pts.wt. organopolysiloxane (A) of formula I [wherein R is a (substd.)monovalent hydrocarbon group; a=1.90-2.05], pref. a raw rubber having an average degree of polymn. of not lower than 3,000, is blended with 10-100pts.wt. reinforcing silica (B) having a specific surface area of not lower than 50m /g and pref. a treated surface (e.g., fumed silica) and 0.05-20pts.wt. fluorinated org. compd. (C) which is composed of a low polymer of a fluoromonomer, is liquid at room temp. or wax having an m.p. of not higher than 100 deg.C and selected from the group consisting of organopolysiloxanes having a 3,3,3-trifluoropropyl group, chlorotrifluoroethylene polymers of formula II (wherein l is 4-12), perfluoropolyether compds. of formula III (wherein m is 2-100), perfluoroalkyl compds. of formula IV (wherein Rf is a perfluoroalkyl; n is 2-100) and organopolysiloxane having perfluoro groups, represented by formula V (wherein x is 2-200; y is 0-1,000).