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    • 78. 发明授权
    • Oxygen-doped n-type gallium nitride freestanding single crystal substrate
    • 氧掺杂n型氮化镓独立单晶衬底
    • US07012318B2
    • 2006-03-14
    • US10846526
    • 2004-05-17
    • Kensaku MotokiMasaki Ueno
    • Kensaku MotokiMasaki Ueno
    • H01L29/207
    • C30B23/00C30B23/02C30B25/00C30B25/02C30B29/403C30B29/406C30B29/60C30B33/00H01L21/02389H01L21/02395H01L21/02433H01L21/0254H01L21/02576H01L21/02609H01L21/0262H01L29/2003H01L29/207
    • Oxygen can be doped into a gallium nitride crystal by preparing a non-C-plane gallium nitride seed crystal, supplying material gases including gallium, nitrogen and oxygen to the non-C-plane gallium nitride seed crystal, growing a non-C-plane gallium nitride crystal on the non-C-plane gallium nitride seed crystal and allowing oxygen to infiltrate via a non-C-plane surface to the growing gallium nitride crystal. Otherwise, oxygen can be doped into a gallium nitride crystal by preparing a C-plane gallium nitride seed crystal or a three-rotationally symmetric plane foreign material seed crystal, supplying material gases including gallium, nitrogen and oxygen to the C-plane gallium nitride seed crystal or the three-rotationally symmetric foreign seed crystal, growing a faceted C-plane gallium nitride crystal having facets of non-C-planes on the seed crystal, maintaining the facets on the C-plane gallium nitride crystal and allowing oxygen to infiltrate via the non-C-plane facets to the gallium nitride crystal.
    • 可以通过制备非C面氮化镓晶体,向非C面氮化镓晶种提供包括镓,氮和氧的材料气体,将氧可以掺杂到氮化镓晶体中,生长非C面 在非C面氮化镓晶种上的氮化镓晶体,并且使得氧经由非C面表面渗入生长的氮化镓晶体。 否则,可以通过制备C面氮化镓晶种或三旋转对称平面异物籽晶将氧气掺杂到氮化镓晶体中,将包括镓,氮和氧的材料气体供应到C面氮化镓晶种 晶体或三旋转对称的外来晶种,在晶种上生长具有非C面的小面的C面氮化镓晶体,保持C面氮化镓晶体上的刻面,并允许氧渗透通过 非C面面到氮化镓晶体。