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71. 发明授权

US08057577B2 Desulfurizer for fuel gas for fuel cell and desulfurization method using the same 有权
标题翻译：燃料电池用燃气脱硫装置及其脱硫方法
公开(公告)号：US08057577B2
公开(公告)日：2011-11-15
申请号：US11656377
申请日：2007-01-23
申请人： Doo-hwan Lee , Soon-ho Kim , Hyun-chul Lee , Eun-duck Park , Eun-yong Ko , Chan-ho Pak , Woo-sung Jeon
发明人： Doo-hwan Lee , Soon-ho Kim , Hyun-chul Lee , Eun-duck Park , Eun-yong Ko , Chan-ho Pak , Woo-sung Jeon
IPC分类号： E04H15/36 , B01D53/02 , B01D53/52 , C01G56/00 , C22B11/00
CPC分类号： B01D53/0407 , B01D2253/108 , B01D2253/1085 , B01D2253/30 , B01D2257/30 , B01D2257/306 , B01D2258/0208 , B01D2259/402 , H01M8/0675 , Y02C20/20 , Y02P10/146
摘要： A desulfurizer for fuel gas for a fuel cell includes: a first adsorption tank including an adsorber having selective adsorption capacity for a thiophene-based compound and a second adsorption tank including an adsorber having selective adsorption capacity for a mercaptan-based compound. The desulfurizer uses separate adsorbers having selective adsorption capacity for a thiophene-based compound and a mercaptan-based compound, in multiple stages to perform a more efficient and economical desulfurizing of a fuel gas to remove various sulfur compounds, especially thiophene-based compounds and mercaptan-based compounds compared to a desulfurizer using a single adsorber.
摘要翻译：燃料电池用燃料气体脱硫装置包括：具有对噻吩系化合物具有选择吸附能力的吸附剂的第一吸附槽和具有对硫醇类化合物具有选择性吸附容量的吸附剂的第二吸附槽。脱硫剂使用对噻吩类化合物和硫醇类化合物具有选择性吸附容量的分离吸附剂，其分级为多级，以进行更有效和经济的燃料气脱硫以除去各种硫化合物，特别是噻吩类化合物和硫醇与使用单一吸附器的脱硫剂相比。

72. 发明授权

US08017282B2 Carbon nanotube, support catalyst, method of preparing the support catalyst and a fuel cell comprising the support catalyst 有权
标题翻译：碳纳米管，载体催化剂，制备载体催化剂的方法和包含载体催化剂的燃料电池
公开(公告)号：US08017282B2
公开(公告)日：2011-09-13
申请号：US11897144
申请日：2007-08-28
申请人： Jae-young Choi , Chan-ho Pak , Seok-gwang Doo , Jeong-hee Lee , Young-hee Lee , Kay-hyeok An , Sung-jin Kim
发明人： Jae-young Choi , Chan-ho Pak , Seok-gwang Doo , Jeong-hee Lee , Young-hee Lee , Kay-hyeok An , Sung-jin Kim
IPC分类号： H01M4/36
CPC分类号： H01M4/8605 , B01J21/185 , B01J23/42 , B01J35/006 , B01J37/06 , B01J37/346 , B82Y30/00 , B82Y40/00 , C01B32/168 , H01M4/9008 , H01M4/9041 , H01M4/9083 , H01M8/086 , H01M2008/1095 , Y10S977/948
摘要： Carbon nanotubes have an R value of at least 1.3, where R is defined as the ratio (ID/IG) of an integral value of D band intensity (ID) to an integral value of G band intensity (IG) in the Raman spectrum. Such carbon nanotubes can be used to form a support catalyst with good catalyst activity because the surface defects on the carbon nanotubes promote improved catalyst distribution in that the support catalyst includes catalyst particles having a small mean particle size and a slight variation in particle size. Such a support catalyst has particularly useful properties when used as a catalyst layer for a fuel cell electrode.
摘要翻译：碳纳米管的R值至少为1.3，其中R被定义为拉曼光谱中D带强度（ID）的积分值与G带强度（IG）的积分值的比（ID / IG）。这种碳纳米管可用于形成具有良好催化剂活性的载体催化剂，因为碳纳米管上的表面缺陷促进了催化剂分布的改善，因为载体催化剂包括具有小的平均粒径和微小粒度变化的催化剂颗粒。当用作燃料电池电极的催化剂层时，这种载体催化剂具有特别有用的特性。

73. 发明授权

US07867941B2 Sulfur-containing mesoporous carbon, method of manufacturing the same, and fuel cell using the mesoporous carbon 有权
标题翻译：含硫介孔碳，其制造方法以及使用介孔碳的燃料电池
公开(公告)号：US07867941B2
公开(公告)日：2011-01-11
申请号：US11966266
申请日：2007-12-28
申请人： Sang Hoon Joo , Chan-ho Pak , Hyuk Chang , Ji-man Kim , Hyung-ik Lee
发明人： Sang Hoon Joo , Chan-ho Pak , Hyuk Chang , Ji-man Kim , Hyung-ik Lee
IPC分类号： B01J21/18 , C01B31/00 , H01M4/64
CPC分类号： B01J37/0018 , B01J21/18 , B01J35/1061 , B01J37/084 , C01B32/00 , H01M4/92 , H01M4/926 , H01M8/1011 , Y02E60/523 , Y02P70/56
摘要： A sulfur-containing mesoporous carbon that has mesopores with an average diameter of 2 to 10 nm, a method of preparing the same, a catalyst containing the mesoporous carbon as a catalyst support, and a fuel cell using the catalyst in which the sulfur-containing mesoporous carbon has a good affinity for and adhesion to catalyst particles so as to strongly support the catalyst particles due to the sulfur atoms substituting for carbons in an OMC carbon skeleton structure. The growth of metal catalyst particles is prevented when heat-treating the metal catalyst particles. The catalyst using the sulfur-containing mesoporous carbon can be applied to a fuel cell to prevent a reduction in catalytic activity due to increased particle size by an accumulation of catalyst particles. The catalyst containing the sulfur-containing mesoporous carbon as a catalyst support can be used to manufacture a fuel cell having an improved performance.
摘要翻译：具有平均直径为2〜10nm的介孔的含硫中孔碳，其制备方法，含有介孔碳作为催化剂载体的催化剂，以及使用该催化剂的燃料电池，其中，含硫中孔碳对催化剂颗粒具有良好的亲和性和粘附性，从而由于在OMC碳骨架结构中用硫原子代替碳而强烈地支持催化剂颗粒。当对金属催化剂颗粒进行热处理时，可防止金属催化剂颗粒的生长。使用含硫介孔碳的催化剂可以应用于燃料电池，以防止由于催化剂颗粒的积聚引起的粒度增加导致的催化活性降低。含有含硫介孔碳作为催化剂载体的催化剂可用于制造具有改进性能的燃料电池。

74. 发明授权

US07585584B2 Carbon nanotubes for fuel cells, method for manufacturing the same, and fuel cell using the same 有权
标题翻译：燃料电池用碳纳米管及其制造方法以及使用该碳纳米管的燃料电池
公开(公告)号：US07585584B2
公开(公告)日：2009-09-08
申请号：US10601872
申请日：2003-06-24
申请人： Won-bong Choi , Jae-uk Chu , Chan-ho Pak , Hyuk Chang
发明人： Won-bong Choi , Jae-uk Chu , Chan-ho Pak , Hyuk Chang
IPC分类号： H01M4/00
CPC分类号： H01M4/8605 , B82Y30/00 , B82Y40/00 , C01B32/162 , H01M4/9083 , H01M4/926 , H01M2008/1095 , Y10S977/70 , Y10S977/701 , Y10S977/72 , Y10S977/743 , Y10S977/843 , Y10S977/847
摘要： Carbon nanotubes for use in a fuel cell, a method for fabricating the same, and a fuel cell using the carbon nanotubes for its electrode are provided. The internal and external walls of the carbon nanotubes are doped with nano-sized metallic catalyst particles uniformly to a degree of 0.3-5 mg/cm2. The carbon nanotubes are grown over a carbon substrate using chemical vapor deposition or plasma enhanced chemical vapor deposition. Since the carbon nanotubes have a large specific surface area, and metallic catalyst particles are uniformly distributed over the internal and external walls thereof, the reaction efficiency in an electrode becomes maximal when the carbon nanotubes are used for the electrode of a fuel cell. The carbon nanotubes fabricated using the method can be applied to form a large electrode. The carbon nanotubes grown over the carbon substrate can be readily applied to an electrode of a fuel cell, providing economical advantages and simplifying the overall electrode manufacturing process. A fuel cell using as the carbon nanotubes for its electrode provides improved performance.
摘要翻译：提供了用于燃料电池的碳纳米管，其制造方法和使用该碳纳米管作为其电极的燃料电池。碳纳米管的内壁和外壁均匀掺杂有纳米尺寸的金属催化剂颗粒至0.3-5mg / cm2的程度。使用化学气相沉积或等离子体增强化学气相沉积在碳衬底上生长碳纳米管。由于碳纳米管具有大的比表面积，并且金属催化剂颗粒均匀地分布在其内壁和外壁上，所以当将碳纳米管用于燃料电池的电极时，电极中的反应效率最大。使用该方法制造的碳纳米管可以应用于形成大电极。生长在碳基板上的碳纳米管可以容易地应用于燃料电池的电极，提供经济的优点并简化整个电极的制造过程。使用作为其电极的碳纳米管的燃料电池提供改进的性能。

75. 发明申请

US20090098442A1 HIERARCHICAL MESOPOROUS CARBON, METHOD OF MANUFACTURING THE SAME, AND FUEL CELL USING THE SAME 有权
标题翻译：分层多孔碳，其制造方法和使用其的燃料电池
公开(公告)号：US20090098442A1
公开(公告)日：2009-04-16
申请号：US12168284
申请日：2008-07-07
申请人： Chan-ho Pak , Hyuk Chang , Ji-man Kim
发明人： Chan-ho Pak , Hyuk Chang , Ji-man Kim
IPC分类号： B01J21/18 , C01B31/02 , H01M4/02
CPC分类号： B01J21/18 , B01J29/0308 , B01J35/1066 , B01J37/0018 , C01B32/00 , H01M4/9016 , H01M4/9083 , H01M8/1011 , Y02E60/523 , Y02P70/56
摘要： A hierarchical mesoporous carbon is provided in which a total volume of mesopores of the hierarchical mesoporous carbon is 80% or greater of a total volume of pores of the hierarchical mesoporous carbon; a volume of mesopores with a average diameter greater than 20 nm and no greater than 50 nm is 3% or greater of the total volume of the pores; and a volume of mesopores with a average diameter greater than 2 nm and no greater than 10 nm is 65% or greater of the total volume of the pores. The hierarchical mesoporous carbon, which also contains macropores, has an optimized mesoporous distribution characteristic, and has an increased total volume of pores, thereby having a significantly improved catalytic activity when used as a catalyst support. When such a supported catalyst including the hierarchical mesoporous carbon as a support is used in a fuel cell, supply of fuel and transporting of byproducts are facilitated.
摘要翻译：提供了分级介孔碳，其中分层介孔碳的介孔的总体积为分级介孔碳的总体积的80％或更大; 平均直径大于20nm且不大于50nm的介孔的体积为孔的总体积的3％或更大; 并且平均直径大于2nm且不大于10nm的体积的介孔为孔的总体积的65％或更大。还含有大孔的层状中孔碳具有优化的介孔分布特征，并且具有增加的孔体积，从而当用作催化剂载体时具有显着改善的催化活性。当在燃料电池中使用包含分层介孔碳作为载体的这种负载型催化剂时，燃料的供给和副产物的输送变得容易。

76. 发明申请

US20070172721A1 MESOPOROUS CARBON MOLECULAR SIEVE AND SUPPORTED CATALYST EMPLOYING THE SAME 有权
标题翻译：多孔碳分子筛和支持相同的催化剂
公开(公告)号：US20070172721A1
公开(公告)日：2007-07-26
申请号：US11688537
申请日：2007-03-20
申请人： Chan-ho Pak , Hyuk Chang , Ji-man Kim
发明人： Chan-ho Pak , Hyuk Chang , Ji-man Kim
IPC分类号： H01M4/96 , B01J21/18
CPC分类号： B01J35/1061 , B01J21/18 , B01J23/42 , B01J29/0308 , B01J37/06 , B01J37/084 , C01B32/00 , H01M4/9083 , H01M4/926
摘要： The present invention is related to a mesoporous carbon molecular sieve, which can be used as a catalyst carrier capable of improving the activity of a supported catalyst and a method of preparing the same. Additionally, the invention is related to a supported catalyst employing the mesoporous carbon molecular sieve as a carrier, and a fuel cell employing the supported catalyst. The mesoporous carbon molecular sieve has an average primary particle size of less than about 500 nm, an average mesopore size in the range of about 3 nm to about 6 nm, and a surface area in the range of about 500 m2/g to about 2000 m2/g.
摘要翻译：本发明涉及可用作能够提高负载型催化剂的活性的催化剂载体的介孔碳分子筛及其制备方法。另外，本发明涉及使用中孔碳分子筛作为载体的负载催化剂和使用负载型催化剂的燃料电池。介孔碳分子筛的平均一次粒径小于约500nm，平均中孔尺寸在约3nm至约6nm的范围内，表面积在约500μm2范围内， /约至约2000m 2 / g。

77. 发明申请

US20070116625A1 Mesoporous carbon, manufacturing method thereof, and fuel cell using the mesoporous carbon 有权
标题翻译：介孔碳，其制造方法和使用中孔碳的燃料电池
公开(公告)号：US20070116625A1
公开(公告)日：2007-05-24
申请号：US11445235
申请日：2006-06-02
申请人： Sang Joo , Chan-ho Pak
发明人： Sang Joo , Chan-ho Pak
IPC分类号： C01B31/02 , H01M4/96 , B01J21/18
CPC分类号： B01J21/18 , B01J29/0308 , B01J37/0018 , B82Y30/00 , C01B32/00 , H01M4/921 , H01M4/926 , H01M2008/1095
摘要： A method of preparing a mesoporous carbon includes mixing a mesophase pitch, a carbon precursor, an acid, and a solvent to obtain a carbon precursor mixture; impregnating an ordered mesoporous silica (OMS) with the carbon precursor mixture; heat-treating and carbonizing the impregnated OMS to form an OMS-carbon composite; and removing the OMS from the OMS-carbon composite. The mesoporous carbon uses the mesophase pitch and the carbon precursor to reduce sheet resistance, and thus can efficiently transfer electric energy. Such mesoporous carbon can be used as a conductive material of electrodes for fuel cells. When the mesoporous carbon is used as a support for catalysts of electrodes, a supported catalyst containing the support can be used to manufacture a fuel cell having high efficiency.
摘要翻译：制备介孔碳的方法包括混合中间相沥青，碳前体，酸和溶剂以获得碳前体混合物; 用碳前体混合物浸渍有序介孔二氧化硅（OMS）; 对浸渍的OMS进行热处理和碳化以形成OMS-碳复合材料; 并从OMS-碳复合材料中除去OMS。中孔碳使用中间相沥青和碳前体来降低薄层电阻，从而可以有效地转移电能。这种介孔碳可以用作燃料电池用电极的导电材料。当介孔碳用作电极催化剂的载体时，可以使用含有载体的载体催化剂来制造高效率的燃料电池。

78. 发明申请

US20060062712A1 Method of preparing carbon nanocages 失效
公开(公告)号：US20060062712A1
公开(公告)日：2006-03-23
申请号：US11140979
申请日：2005-06-01
申请人： Chan-ho Pak , Hyuk Chang , Jian Wang
发明人： Chan-ho Pak , Hyuk Chang , Jian Wang
IPC分类号： C01B31/02
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/18 , Y10S977/843
摘要： The present invention provides a simple method of mass producing high purity carbon nanocages. The method of preparing carbon nanocages comprises introducing an inert gas into a reactor equipped with a spray nozzle and raising the temperature of the reactor to a pyrolysis temperature of a catalyst compound. The method further comprises spraying a reactant including the catalyst compound and a carbon-containing compound into the reactor through the spray nozzle, wherein the ratio of a space velocity of the inert gas to a space velocity of the reactant is 100 or more.

79. 发明申请

US20050129604A1 Mesoporous carbon molecular sieve and supported catalyst employing the same 有权
标题翻译：介孔碳分子筛和采用其的负载型催化剂
公开(公告)号：US20050129604A1
公开(公告)日：2005-06-16
申请号：US10992211
申请日：2004-11-19
申请人： Chan-ho Pak , Hyuk Chang , Ji-man Kim
发明人： Chan-ho Pak , Hyuk Chang , Ji-man Kim
IPC分类号： B01J29/03 , B01J21/18 , B01J32/00 , B01J35/10 , B01J37/00 , B01J37/06 , B01J37/08 , C01B31/00 , C01B31/02 , C01B37/02 , H01M4/96 , H01M8/10
CPC分类号： B01J35/1061 , B01J21/18 , B01J23/42 , B01J29/0308 , B01J37/06 , B01J37/084 , C01B32/00 , H01M4/9083 , H01M4/926
摘要： The present invention is related to a mesoporous carbon molecular sieve, which can be used as a catalyst carrier capable of improving the activity of a supported catalyst and a method of preparing the same. Additionally, the invention is related to a supported catalyst employing the mesoporous carbon molecular sieve as a carrier, and a fuel cell employing the supported catalyst. The mesoporous carbon molecular sieve has an average primary particle size of less than about 500 nm, an average mesopore size in the range of about 3 nm to about 6 nm, and a surface area in the range of about 500 m2/g to about 2000 m2/g.
摘要翻译：本发明涉及可用作能够提高负载型催化剂的活性的催化剂载体的介孔碳分子筛及其制备方法。另外，本发明涉及使用中孔碳分子筛作为载体的负载催化剂和使用负载型催化剂的燃料电池。介孔碳分子筛的平均一次粒径小于约500nm，平均中孔尺寸在约3nm至约6nm的范围内，表面积在约500μm2范围内， /约至约2000m 2 / g。

80. 发明授权

US09123976B2 Catalyst including active particles, method of preparing the catalyst, fuel cell including the catalyst, electrode including the active particles for lithium air battery, and lithium air battery including the electrode 有权
标题翻译：包括活性颗粒的催化剂，制备催化剂的方法，包括催化剂的燃料电池，包括用于锂空气电池的活性颗粒的电极和包括电极的锂空气电池
公开(公告)号：US09123976B2
公开(公告)日：2015-09-01
申请号：US13350369
申请日：2012-01-13
申请人： Seon-ah Jin , Chan-ho Pak , Kang-hee Lee , Kyung-jung Kwon
发明人： Seon-ah Jin , Chan-ho Pak , Kang-hee Lee , Kyung-jung Kwon
IPC分类号： H01M4/02 , H01M4/36 , H01M4/90 , H01M4/92 , H01M4/94 , B01J23/00 , H01M12/08 , H01M4/86 , H01M8/10 , B01J21/06 , B01J23/40 , B01J37/16 , B01J37/34 , B01J35/00
CPC分类号： H01M12/08 , B01J21/063 , B01J23/40 , B01J35/0033 , B01J35/008 , B01J37/16 , B01J37/348 , H01M4/8657 , H01M4/9016 , H01M4/92 , H01M4/921 , H01M2008/1095 , Y02E60/128 , Y02E60/50
摘要： A catalyst including active particles that have a core including a first metal oxide, and a shell including an alloy of a second metal with a reduction product of the first metal oxide; a method of preparing the catalyst; a fuel cell including the catalyst; an electrode for lithium air battery that includes the active particles; and a lithium air battery including the electrode.
摘要翻译：一种催化剂，包括具有包含第一金属氧化物的芯的活性颗粒和包含第二金属与第一金属氧化物的还原产物的合金的壳; 制备催化剂的方法; 包括催化剂的燃料电池; 包含活性颗粒的锂空气电池用电极; 以及包含该电极的锂空气电池。

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