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71. 发明授权

US07144632B2 Aliphatic-aromatic polyetherester compositions, articles, films, coating and laminates and processes for producing same 有权
标题翻译：脂肪族 - 芳族聚醚酯组合物，制品，薄膜，涂层和层压材料及其制造方法
公开(公告)号：US07144632B2
公开(公告)日：2006-12-05
申请号：US10459161
申请日：2003-06-11
申请人： Richard Allen Hayes
发明人： Richard Allen Hayes
IPC分类号： B32B27/00
CPC分类号： B32B27/06 , B32B27/28 , B32B27/36 , B32B2439/70 , C08G63/6886 , C08L3/02 , C08L67/00 , C08L67/025 , C08L67/04 , C08L69/00 , C08L77/12 , C09D167/00 , D21H19/28 , D21H27/10 , Y10T428/31504 , Y10T428/31565 , Y10T428/31786 , Y10T442/2139 , Y10T442/2221 , C08L2666/26 , C08L2666/14
摘要： Aliphatic-aromatic polyetherester compositions, articles made from the aliphatic-aromatic polyetherester compositions, and processes for producing the aliphatic-aromatic polyetherester compositions and articles are provided. Articles that can be made from the aliphatic-aromatic polyetherester compositions include films, coatings and laminates. Some of the compositions and articles are biocompostable. The films can further be used to form shaped articles such as sheets, food packaging such as sandwich wraps, thermoformed containers, and coatings for, for example, films and other substrates. The aliphatic-aromatic polyetheresters are based on copolyesters produced from a mixture of aromatic dicarboxylic acids, aliphatic dicarboxylic acids, poly(alkyene ether) glycols, and glycols.
摘要翻译：提供脂肪族 - 芳族聚醚酯组合物，由脂族 - 芳族聚醚酯组合物制成的制品，以及制备脂族 - 芳族聚醚酯组合物和制品的方法。可以由脂族 - 芳族聚醚酯组合物制成的制品包括薄膜，涂料和层压材料。一些组合物和制品是可生物相容的。这些膜还可用于形成诸如片材的成形制品，诸如夹心包装的食品包装，热成型容器以及用于例如薄膜和其它基材的涂层。脂族 - 芳族聚醚酯基于由芳族二羧酸，脂族二羧酸，聚（烷基醚）二醇和二醇的混合物制备的共聚酯。

72. 发明授权

US06818730B2 Process to produce polyesters which incorporate isosorbide 失效
标题翻译：生产掺入异山梨醇的聚酯的方法
公开(公告)号：US06818730B2
公开(公告)日：2004-11-16
申请号：US10134136
申请日：2002-04-26
申请人： Charles J. Brandenburg , Richard Allen Hayes
发明人： Charles J. Brandenburg , Richard Allen Hayes
IPC分类号： C08G6302
CPC分类号： C08G63/668
摘要： The present invention provides a process to produce isosorbide-containing polyesters. The process allows for higher isosorbide incorporation than previously found while maintaining high polymeric molecular weights.
摘要翻译：本发明提供了生产含异山梨醇的聚酯的方法。该方法允许比先前发现的更高的异山梨醇掺入，同时保持高聚合物分子量。

73. 发明授权

US06746779B2 Sulfonated aliphatic-aromatic copolyesters 失效
标题翻译：磺化脂肪族 - 芳族共聚酯
公开(公告)号：US06746779B2
公开(公告)日：2004-06-08
申请号：US09927731
申请日：2001-08-10
申请人： Richard Allen Hayes , Leonard Edward Kosinski
发明人： Richard Allen Hayes , Leonard Edward Kosinski
IPC分类号： B32B2706
CPC分类号： C08G63/6886 , C08G63/6884 , Y10T428/31786
摘要： A copolyester having an inherent viscosity of equal to or greater than about 0.3 formed from about 20 to about 60 mole percent based on the amount of aromatic dicarboxylic acid of one or more of isophthalic dicarboxylic acid or an alkyl diester thereof, about 40 to about 80 mole percent based on the amount of aromatic dicarboxylic acid of one or more of terephthalic acid or 2,6-naphthalene dicarboxylic acid or an alkyl diester thereof, about 10 to about 60 mole based on the total amount of dicarboxylic acids of one or more aliphatic dicarboxylic acids or an alkyl diester, about 0.1 to about 5 mole percent based on the moles of total dicarboxylic acid of one or more alkali or alkaline earth metal salts of 5-sulfoisophthalic dicarboxylic acid or an alkyl diester thereof, about 90 to 100 mole percent based on the total amount of glycols of one or more aliphatic glycols, and 0 to about 10 mole percent based on the total amount of glycols of one or more of di(ethylene glycol) and tri(ethylene glycol). The copolyesters are useful to form films and coatings.
摘要翻译：一种具有等于或大于约0.3的特性粘度为约20至约60摩尔％的共聚酯，基于一种或多种间苯二甲酸二羧酸或其烷基二酯的芳族二羧酸的量约40至约80摩尔％基于一种或多种对苯二甲酸或2,6-萘二甲酸或其烷基二酯的芳族二羧酸的量，基于一个或多个脂族的二羧酸的总量为约10至约60摩尔二羧酸或烷基二酯，基于一种或多种5-磺基间苯二甲酸二羧酸或其烷基二酯的碱金属或碱土金属盐的总二羧酸的摩尔数为约0.1至约5摩尔％，约90-100摩尔％基于一种或多种脂肪族二醇的二醇的总量，和基于二（乙二醇）和三（乙）的一种或多种的二醇的总量为0至约10摩尔％新乙二醇）。共聚酯可用于形成薄膜和涂料。

74. 发明授权

US06706396B1 Processes for producing very low IV polyester resin 有权
标题翻译：生产非常低的IV聚酯树脂的方法
公开(公告)号：US06706396B1
公开(公告)日：2004-03-16
申请号：US10273835
申请日：2002-10-18
申请人： Richard Allen Hayes , Gregory W. Hoffmann
发明人： Richard Allen Hayes , Gregory W. Hoffmann
IPC分类号： B32B1502
CPC分类号： C08J3/12 , B29B9/06 , B29B9/065 , B29K2067/00 , C08G63/181 , C08G63/20 , C08G63/78 , C08J2367/02 , Y10T428/2982
摘要： The present invention provides processes for producing certain very low inherent viscosity polyesters. Also provided are the low inherent viscosity polyesters in discrete particulate form, and processes for producing the particulate polyesters. The discrete particulate materials are desirable for use in further processes.
摘要翻译：本发明提供了生产某些非常低的特性粘度的聚酯的方法。还提供了离散颗粒形式的低特性粘度聚酯和用于生产颗粒聚酯的方法。离散的颗粒材料是期望用于进一步的工艺。

75. 发明授权

US06368710B1 Sulfonated aliphatic-aromatic copolyesters 失效
标题翻译：磺化脂肪族 - 芳族共聚酯
公开(公告)号：US06368710B1
公开(公告)日：2002-04-09
申请号：US09740739
申请日：2000-12-19
申请人： Richard Allen Hayes
发明人： Richard Allen Hayes
IPC分类号： D02G300
CPC分类号： C08G63/668 , C08G63/6884 , D01H1/427 , Y10T428/29 , Y10T428/2913
摘要： A sulfonated copolyester of the reaction product of: (a) one or more aromatic dicarboxylic acids or an ester thereof; (b) one or more aliphatic dicarboxylic acids or an ester thereof; (c) one or more sulfonated compound; and (d) isosorbide. The polyesters are useful to form articles of increased biodegradability.
摘要翻译：反应产物的磺化共聚酯：（a）一种或多种芳族二羧酸或其酯; （b）一种或多种脂族二羧酸或其酯; （c）一种或多种磺化化合物; 和（d）异山梨醇。聚酯可用于形成增加生物降解性的制品。

76. 发明授权

US09488310B2 Highly abrasion-resistant polyolefin pipe 有权
标题翻译：高耐磨聚烯烃管
公开(公告)号：US09488310B2
公开(公告)日：2016-11-08
申请号：US12610886
申请日：2009-11-02
申请人： Richard Allen Hayes
发明人： Richard Allen Hayes
IPC分类号： B32B37/04 , B32B37/06 , F16L57/06 , B32B1/08 , B32B27/12 , B32B27/32 , F16L9/127 , B32B5/02 , B32B15/08 , B32B15/18 , B32B15/20 , B32B25/08 , B32B25/14 , B32B27/08 , B32B27/20 , B32B27/28 , B32B27/34 , B32B27/36
CPC分类号： F16L9/147 , B32B1/08 , B32B5/024 , B32B5/026 , B32B15/08 , B32B15/085 , B32B15/18 , B32B15/20 , B32B25/08 , B32B25/14 , B32B27/08 , B32B27/12 , B32B27/20 , B32B27/281 , B32B27/32 , B32B27/34 , B32B27/36 , B32B37/06 , B32B2262/0269 , B32B2262/101 , B32B2262/106 , B32B2264/102 , B32B2264/108 , B32B2274/00 , B32B2307/308 , B32B2307/554 , B32B2307/71 , B32B2307/714 , B32B2307/72 , B32B2597/00 , F16L9/127 , F16L57/06 , Y10T137/0318
摘要： A pipe- or tube-shaped article having an innermost layer is disclosed which comprises a polyolefin composition comprising a polyolefin comprising ethylene and an α-olefin. The article provides long lifetime, highly abrasion-resistant pipes for mining and other transportation uses. Also disclosed are methods for preparing the article and transporting abrasive materials.
摘要翻译：公开了一种具有最内层的管状或管状制品，其包括含有包含乙烯和α-烯烃的聚烯烃的聚烯烃组合物。该文章为采矿和其他运输用途提供长寿命，高耐磨性的管道。还公开了制备物品和运输磨料的方法。

77. 发明授权

US08841379B2 Method to form an aqueous dispersion of an ionomer-polyolefin blend 有权
标题翻译：形成离聚物 - 聚烯烃共混物的水性分散体的方法
公开(公告)号：US08841379B2
公开(公告)日：2014-09-23
申请号：US13290415
申请日：2011-11-07
申请人： Richard Allen Hayes
发明人： Richard Allen Hayes
IPC分类号： C08J3/05 , C08J3/03 , C08L23/08 , C08L33/02 , C08L33/04
CPC分类号： C08L23/08 , C08L23/0876 , C08L2201/54 , C08L2205/025 , C08L2205/03 , C08L23/0869
摘要： Disclosed is a method to form an aqueous dispersion comprising a blend composition comprising or consisting essentially of about 75 to about 99.9 weight % of an ionomer composition and about 0.1 to about 25 weight % of an ethylene acrylate ester copolymer composition, a grafted polyolefin composition or a combination thereof, the method comprising mixing the solid blend composition with water heated to a temperature from about 80 to about 100° C.
摘要翻译：公开了一种形成水分散体的方法，其包含共混组合物，其包含或基本上由约75至约99.9重量％的离聚物组合物和约0.1至约25重量％的乙烯丙烯酸酯共聚物组合物，接枝聚烯烃组合物或该方法包括将固体共混组合物与加热至约80至约100℃的水混合

78. 发明申请

US20130225750A1 HIGH VISCOSITY BLENDS OF AN IONOMER AND POLY(VINYL ALCOHOL) 审中-公开
标题翻译：离子和聚（乙烯醇）的高粘度混合物
公开(公告)号：US20130225750A1
公开(公告)日：2013-08-29
申请号：US13407896
申请日：2012-02-29
申请人： Elliott Echt , Richard Allen Hayes
发明人： Elliott Echt , Richard Allen Hayes
IPC分类号： C08L29/04
CPC分类号： C08L29/04 , C08L23/0876
摘要： Disclosed is a blend composition comprising a combination of (a) about 99 to about 1 weight %, based on the combination of (a) and (b), of a poly(vinyl alcohol) characterized by a hydrolysis level of from about 85 to about 93 mol % and a 4 weight % aqueous viscosity of 16 to about 75 centipoise; and (b) about 1 to about 99 weight % of an ionomer comprising a parent acid copolymer that comprises ethylene and about 18 to about 30 weight % of acrylic acid or methacrylic acid, the acid copolymer having a melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts comprising potassium and/or sodium cations. Also disclosed are aqueous dispersions, methods to prepare the aqueous dispersions and articles comprising the blend composition.
摘要翻译：公开了一种共混组合物，其包含基于（a）和（b）的组合的（a）约99至约1重量％的聚（乙烯醇）的组合，其特征在于水解度为约85至约93摩尔％和4重量％水溶液粘度为16至约75厘泊; 和（b）约1至约99重量％的包含包含乙烯和约18至约30重量％丙烯酸或甲基丙烯酸的母体酸共聚物的离聚物，所述酸共聚物的熔体流动速率为约200至约 1000克/ 10分钟，其中约50％至约70％的共聚物的羧酸基团被中和到包含钾和/或钠阳离子的羧酸盐。还公开了水分散体，制备水分散体的方法和包含共混组合物的制品。

79. 发明申请

US20130224505A1 IONOMER-POLY(VINYLALCOHOL) COATINGS 有权
标题翻译：离子聚（乙烯醇）涂料
公开(公告)号：US20130224505A1
公开(公告)日：2013-08-29
申请号：US13407858
申请日：2012-02-29
申请人： Elliott Echt , Richard Allen Hayes
发明人： Elliott Echt , Richard Allen Hayes
IPC分类号： C08L29/04 , B32B15/082 , B32B27/10 , B05D3/02
CPC分类号： C09D129/04 , B32B27/10 , Y02P20/582 , Y10T428/249921 , Y10T428/249992 , Y10T428/31688 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , C08L29/04 , C08L23/0876
摘要： Disclosed are methods to form coatings on a substrate, the coatings comprising a blend of a poly(vinyl alcohol) composition comprising a poly(vinyl alcohol) characterized by (i) a hydrolysis level of from about 85 to about 93 mol % and a 4 weight % aqueous viscosity of 15 centipoise (cp) or less; or (ii) a hydrolysis level of about 95 mol % to 100%; and an ionomer comprising a parent acid copolymer that comprises ethylene and about 18 to about 30 weight % of acrylic acid or methacrylic acid, the acid copolymer having a melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts comprising potassium cations, sodium cations or combinations thereof. Multilayer structures comprising the blend composition on a substrate are also disclosed.
摘要翻译：公开了在基材上形成涂层的方法，该涂层包含聚（乙烯醇）组合物的混合物，其包含聚（乙烯醇），其特征在于（i）水解度为约85-约93摩尔％，和4 重量％水溶液粘度为15厘泊（cp）或更低; 或（ii）约95mol％至100％的水解度; 和包含乙烯和约18至约30重量％的丙烯酸或甲基丙烯酸的母体酸共聚物的离聚物，所述酸共聚物的熔体流动速率为约200至约1000g / 10min，其中约50％约70％的共聚物的羧酸基团被中和到包含钾阳离子，钠阳离子或其组合的羧酸盐中。还公开了包含基底上的共混组合物的多层结构。

80. 发明授权

US08497005B1 Highly abrasion-resistant grafted polyolefin pipe 有权
标题翻译：高耐磨接枝聚烯烃管
公开(公告)号：US08497005B1
公开(公告)日：2013-07-30
申请号：US13534058
申请日：2012-06-27
申请人： Richard Allen Hayes , Qin Lin
发明人： Richard Allen Hayes , Qin Lin
IPC分类号： B32B1/08 , B32B15/085 , B32B15/18 , B32B15/20 , B67D99/00 , F16L9/14 , F17D1/00
CPC分类号： C08F255/00 , C08F255/02 , C08L51/06 , C09D151/06 , Y10T137/0318 , Y10T428/1314 , Y10T428/1352 , Y10T428/1355 , Y10T428/1362 , Y10T428/1366 , Y10T428/1372 , Y10T428/1386 , Y10T428/1393 , Y10T442/102 , Y10T442/172 , Y10T442/184 , Y10T442/198 , C08L2666/02
摘要： A pipe or tube article comprising an innermost comprising a grafted polyolefin composition made from a grafted polyolefin composition is disclosed which can provide long lifetime, highly abrasion-resistant pipes for mining and other transportation uses. Methods for preparing the article and transporting abrasive materials through the article are also described.
摘要翻译：公开了包含由接枝聚烯烃组合物制成的接枝聚烯烃组合物的最内层的管或管制品，其可以为采矿和其它运输用途提供长寿命，高耐磨性的管道。还描述了制备物品并通过制品运送磨料的方法。

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