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71. 发明授权

US06313250B1 Polyfunctionally reactive polymer substances 失效
标题翻译：多官能反应性聚合物物质
公开(公告)号：US06313250B1
公开(公告)日：2001-11-06
申请号：US09101185
申请日：1999-04-06
申请人： Rainer Blum , Lukas Haeussling , Wolfgang Reich
发明人： Rainer Blum , Lukas Haeussling , Wolfgang Reich
IPC分类号： C08F1000
CPC分类号： C08G59/245 , C08G59/1455 , C08G65/329
摘要： The invention relates to polyfunctionally reactive polymeric substances which contain at least two structural units of the general formulae (I) and/or (II) in the molecule and whose polymer backbone linkages are C—C bonds, ether bonds, urethane bonds, amide bonds, ketone bonds or combinations thereof. The substances are useful as binders for various applications.
摘要翻译：本发明涉及在分子中含有通式（I）和/或（II）的至少两个结构单元并且其聚合物主链键为CC键，醚键，氨基甲酸酯键，酰胺键，酮的多官能反应性聚合物质键或其组合。这些物质可用作各种应用的粘合剂。

72. 发明授权

US06294591B1 Method for producing polymers cross-linkable by radiation, acrylic or methacrylic acid esters 失效
标题翻译：生产通过辐射，丙烯酸或甲基丙烯酸酯交联的聚合物的方法
公开(公告)号：US06294591B1
公开(公告)日：2001-09-25
申请号：US09331062
申请日：1999-06-16
申请人： Rainer Blum , Peter Keller
发明人： Rainer Blum , Peter Keller
IPC分类号： C08F248
CPC分类号： C08F20/18 , C08F8/00 , Y10S522/904 , Y10S522/905 , C08F20/12
摘要： A process is described for preparing radiation-crosslinkable polymeric acrylates and methacrylates, which involves reacting an acrylate or methacrylate copolymer containing units having a reactive side group with a compound that contains a group which is capable of reacting with the reactive side group and also a group which is capable of forming free radicals under the action of actinic radiation. The preparation of the modified, photoactive polymers by polymer-analogous reaction makes it possible to do without the laborious handling of aggressive, specially synthesized monomers, especially acrylic esters. The products of the process can be employed widely as radiation-curable coating materials.
摘要翻译：描述了制备辐射交联聚合物丙烯酸酯和甲基丙烯酸酯的方法，其包括使含有具有反应性侧基的单元的丙烯酸酯或甲基丙烯酸酯共聚物与能够与反应性侧基反应的基团的化合物和基团其能够在光化辐射的作用下形成自由基。通过聚合物 - 类似反应制备改性的光活性聚合物使得可以在不侵蚀性，特别合成的单体，特别是丙烯酸酯的情况下进行操作。该方法的产品可广泛用作可辐射固化的涂料。

73. 发明授权

US6146717A Method of impregnating components 有权
标题翻译：浸渍组分的方法
公开(公告)号：US6146717A
公开(公告)日：2000-11-14
申请号：US308116
申请日：1999-06-23
申请人： Klaus-Wilhelm Lienert , Rainer Blum , Gunter Hegemann , Manfred Eichhorst
发明人： Klaus-Wilhelm Lienert , Rainer Blum , Gunter Hegemann , Manfred Eichhorst
IPC分类号： B05D1/18 , B05D3/06 , B05D5/12 , B05D7/26 , B29C35/08 , C08J3/24 , C08J3/28 , C08J7/04 , C08K5/06 , C08K5/08 , C08K5/10 , C08K5/14 , C08K5/23 , C08K5/5313 , C08L45/00 , C08L63/00 , C08L67/06 , H01F41/12 , H02K15/12
CPC分类号： H01F41/127 , B05D1/18 , B05D3/0209 , B05D3/0254 , B05D3/0493 , B05D3/067
摘要： The invention comprises a process for impregnating components with polymerizable impregnants which are liquid at room temperature or can be liquefied by heating and are cured by combined use of heat and high-energy radiation, wherein the components are impregnated at ambient temperature or in a preheated state and, after impregnation, are heated in the impregnant until partial gelation occurs, are treated with high-energy radiation before full curing and are then fully cured by thermal means.
摘要翻译： PCT No.PCT / EP97 / 06325 Sec。 371日期1999年6月23日第 102（e）日期1999年6月23日PCT 1997年11月13日PCT公布。第WO98 / 22962号公报日期1998年5月28日本发明包括用室温下为液体的可聚合浸渍剂浸渍组分或可通过加热液化并通过组合使用热能和高能辐射固化的组分的方法，其中组分在环境温度下浸渍或在预热状态下，并且在浸渍之后，在浸渍剂中加热直到发生部分凝胶化，在完全固化之前用高能量辐射进行处理，然后通过热均匀完全固化。

74. 发明授权

US6133337A Use of reactive prepolymeric organic compounds 失效
标题翻译：使用反应性预聚物有机化合物
公开(公告)号：US6133337A
公开(公告)日：2000-10-17
申请号：US101243
申请日：1998-09-30
申请人： Rainer Blum , Thomas Loerzer , Gunther Hegemann , Gunther Baumgarten
发明人： Rainer Blum , Thomas Loerzer , Gunther Hegemann , Gunther Baumgarten
IPC分类号： C08L67/07 , C08F2/48 , C08F299/04 , C08G18/68 , C08G63/553 , C08K5/00 , C08L67/06 , C09D167/06 , C08F2/46
CPC分类号： C08K5/0025 , C08G18/686 , C08G63/553 , C08L67/06 , C09D167/06
摘要： The invention relates to the use of reactive prepolymeric organic compounds, containing structural units having at least one readily abstractable hydrogen with a bond energy of not more than 397 kJ/-mol and having at least one ethylenic double bond, for crosslinking, with or without free-radical initiators, by means of heat, high-energy radiation or heat and high-energy radiation.
摘要翻译： PCT No.PCT / EP96 / 05769 Sec。 371日期：1998年9月30日 102（e）1998年9月30日PCT PCT 1996年12月20日PCT公布。公开号WO97 / 25361 日期1997年7月17日本发明涉及使用反应性预聚物有机化合物，其含有具有至少一种容易提取的氢的结构单元，其键能不超过397kJ / mol，并具有至少一个烯属双键，用于交联，有或没有自由基引发剂，通过热，高能辐射或热和高能辐射。

75. 发明授权

US6106905A Coating articles using radiation-curable powder coatings 失效
标题翻译：使用可辐射固化粉末涂料的涂料制品
公开(公告)号：US6106905A
公开(公告)日：2000-08-22
申请号：US101289
申请日：1999-01-08
申请人： Rainer Blum , Christopher Hilger , Joachim Woltering
发明人： Rainer Blum , Christopher Hilger , Joachim Woltering
IPC分类号： B05D7/24 , C09D5/03 , C09D5/46 , C09D133/00 , C09D133/06 , B05D3/06
CPC分类号： C09D133/06
摘要： The invention relates to a method of coating articles with powder coatings which contain polymers, are applied to the surface of the substrate to be coated, are melted and are crosslinked by UV irradiation, wherein the polymers employed are copolymers ofa) at least one monomer of the general formula (I) ##STR1## where R.sup.1 =H or CH.sub.3 and R.sup.2 =H, C.sub.n H.sub.2n+1 where n=from 1 to 30, or is an alicyclic, araliphatic or heterocyclic radical, hydroxyalkyl, alkoxyalkyl, glycidyl or aminoalkyl, or of the general formula (II) ##STR2## where R.sup.1 =H or CH.sub.3 and where R.sup.3 and R.sup.4 may be identical to or different from one another and are H, CH.sub.2 OH, C.sub.n H.sub.2n+1 where n=1 to 30 or CH.sub.2 OR.sup.5 where R.sup.5 =C.sub.m H.sub.2m+1 where m=1 to 12, andb) at least one copolymerizable, ethylenically unsaturated organic compound of the general formula (A) ##STR3## where R' and R" can be identical to or different from one another and are H, C.sub.p H.sub.2p+1 where p=1 to 6, cycloalkyl, aryl or aralkyl and R'" is acryloyl, methacryloyl, ethacryloyl or cinnamoyl, it being possible for this compound to be replaced in part by one or more other copolymerizable, ethylenically unsaturated organic compounds which are different from (a).
摘要翻译： PCT No.PCT / EP96 / 05864 Sec。 371日期1999年1月8日第 102（e）日期1999年1月8日PCT 1996年12月30日PCT公布。公开号WO97 / 25157 日期1997年7月17日本发明涉及一种涂覆具有粉末涂料的制品的方法，该粉末涂料含有聚合物，被施加到待涂覆的基材的表面上，被熔化并通过UV照射进行交联，其中所用的聚合物是）至少一种通式（I）的单体，其中R1 = H或CH3，R2 = H，CnH2n + 1，其中n = 1至30，或为脂环族，芳脂族或杂环基，羟烷基，烷氧基烷基，缩水甘油基或氨基烷基或通式（II）其中R 1 = H或CH 3，并且其中R 3和R 4可以彼此相同或不同，是H，CH 2 OH，C n H 2n + 1，其中n = 1-30或CH 2 OR 5，其中R 5 = CmH2m + 1，其中m = 1至12，以及b）至少一种通式（A）的可共聚的烯属不饱和有机化合物，其中R'和R“可以彼此相同或不同，为H，CpH2p +1，其中p = 1至6，环烷基，芳基或芳烷基，R“'是丙烯酰基，甲基丙烯酰基，乙酰丙烯酰基或肉桂酰基，它bei 该化合物可能部分被一种或多种不同于（a）的可共聚的烯属不饱和有机化合物所替代。

76. 发明授权

US5558911A Coating articles using radiation-curable powder coatings 失效
标题翻译：使用可辐射固化粉末涂料的涂料制品
公开(公告)号：US5558911A
公开(公告)日：1996-09-24
申请号：US422861
申请日：1995-04-17
申请人： Rainer Blum
发明人： Rainer Blum
IPC分类号： B05D1/06 , B05D1/24 , B05D3/06 , C08F2/06 , C09D4/06 , C09D5/46 , C09D133/06
CPC分类号： C09D133/062 , B05D3/067 , C09D4/06 , B05D1/06 , B05D1/24 , B05D2401/32
摘要： The invention relates to a method of coating articles with powder coatings which contain polymers and are applied to the surface of the substrate to be coated, are melted and are crosslinked by UV radiation, the polymers employed being copolymers of(a) at least one monomer of the general formula (I)CH.sub.2 .dbd.C(R.sup.1)--CO--OR.sup.2 (I) whereR.sup.1 =H or CH.sub.3 andR.sup.2 =H, C.sub.n H.sub.2n+1 where n=from 1 to 30, or is an alicyclic, araliphatic or heterocyclic radical, hydroxyalkyl, alkoxyalkyl, glycidyl or aminoalkyl, or of the general formula IICH.sub.2 .dbd.C(R.sup.1)--CO--NR.sup.3 R.sup.4 (II) where R.sup.3 =H or CH.sub.3 and where R.sup.3 and R.sup.4 may be identical to or different from one another and are H, CH.sub.2 OH, C.sub.n H.sub.2n+1 where n=1 to 30(b) at least one copolymerizable, ethylenically unsaturated, organic compound which is different from (a)and(c) at least one copolymerizable, ethylenically unsaturated, aromatic or partially aromatic ketone which is capable of abstracting hydrogen in the excited triplet state.
摘要翻译：本发明涉及一种涂覆具有粉末涂料的制品的方法，所述粉末涂料含有聚合物并被施加到待涂覆的基材的表面上，被熔化并通过UV辐射交联，所使用的聚合物是（a）至少一种单体通式（I）CH 2 = C（R 1）-CO-OR 2（I）其中R 1 = H或CH 3且R 2 = H，C n H 2n + 1其中n = 1至30，或为脂环族，芳脂族或杂环基团，羟基烷基，烷氧基烷基，缩水甘油基或氨基烷基，或通式为IICH2 = C（R1）-CO-NR3R4（Ⅱ），其中R3 = H或CH3，其中R3和R4可以彼此相同或不同， H，CH 2 OH，C n H 2n + 1其中n = 1-30（b）至少一种可共聚的烯属不饱和有机化合物，其不同于（a）和（c）至少一种可共聚的烯属不饱和，芳族或部分芳族酮其能够提取激发三重态的氢。

77. 发明授权

US5286527A Adhesion promoter 失效
标题翻译：粘合促进剂
公开(公告)号：US5286527A
公开(公告)日：1994-02-15
申请号：US873197
申请日：1992-04-24
申请人： Rainer Blum , Hans J. Heller , Hans-Joachim Haehnle , Klaus Lienert
发明人： Rainer Blum , Hans J. Heller , Hans-Joachim Haehnle , Klaus Lienert
IPC分类号： C03C17/34 , C03C25/40 , C09D4/00 , B05D5/10
CPC分类号： C03C25/40 , C03C17/3405 , C09D4/00 , Y10T428/31612 , Y10T428/31663 , Y10T428/31721
摘要： Use of a mixture of from 5 to 95% by weight of an azidosilane of the formulaN.sub.3 --R.sup.3 --Si--R.sup.1.sub.n (OR.sup.2).sub.3-n Iwhere R.sup.1 is C.sub.1 -C.sub.3 -alkyl, phenyl, benzyl or tolyl, R.sup.2 is C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -alkoxyalkyl, phenyl or benzyl, R.sup.3 is C.sub.1 -C.sub.8 -alkylene, which may be interrupted by oxygen, sulfur or --(N--R.sup.4)-- in which R.sup.4 is hydrogen, methyl, ethyl or phenyl, and n is 0, 1 or 2, and from 5 to 95% by weight of an aminoalkoxysilane of the formulaH.sub.2 N--R.sup.5 --Si--R.sup.6.sub.m (OR.sup.7).sub.3-m IIwhere R.sup.5 is C.sub.1 -C.sub.6 -alkylene, C.sub.5 -C.sub.6 -cycloalkylene or C.sub.5 -C.sub.6 -arylene, each of which may be additionally substituted by one or two C.sub.1 -C.sub.3 -alkyl groups, and R.sup.6 and R.sup.7, independently of one another, are C.sub.1 -C.sub.6 -alkyl or C.sub.5 -C.sub.6 -cycloalkyl, each of which may likewise be additionally substituted by one or two C.sub.1 -C.sub.3 -alkyl groups, and m may be 0, 1 or 2, as an adhesion promoter between polycondensates containing, as structural units, heterocyclic ring systems containing nitrogen atoms, or precursors of these polycondensates, and inorganic substrates.
摘要翻译：使用5至95重量％的式N 3 -R 3 -Si-R n（OR 2）3-n I的叠氮硅烷的混合物，其中R 1，是C 1 -C 3烷基，苯基，苄基或甲苯基，R 2是C 1 -C 4 - 烷基，C 2 -C 4 - 烷氧基烷基，苯基或苄基，R 3是C 1 -C 8 - 亚烷基其中R 4可以被氧原子，硫原子或 - （NR 4）基团中断，其中R 4是氢原子或甲基，乙基或苯基，n是0,1或2， 5至95重量％的式H2N-R 5 -Si-R 6（OR 7）3-m II的氨基烷氧基硅烷，其中R 5是C 1 -C 6亚烷基，可以另外被一个或两个C 1 -C 3 - 烷基取代的C 5 -C 6 - 亚环烷基或 - 亚芳基，R 6和R 7彼此独立地是C 1 -C 6烷基或C 5 -C 6 - 环烷基，其也可以另外被一个或两个C 1 -C 3 - 烷基取代，m可以是0,1或2，作为粘合促进剂（偶联剂）在缩聚物之间，所述缩聚物包含作为结构单元的杂环环系含有N-原子的茎，或这些缩聚物的前体，以及无机基。

78. 发明授权

US4613639A Preparation of plastisols and organosols having a long shelf life 失效
标题翻译：具有长寿命的增塑溶胶和有机溶胶的制备
公开(公告)号：US4613639A
公开(公告)日：1986-09-23
申请号：US790800
申请日：1985-10-24
申请人： Rainer Blum , Rolf Osterloh
发明人： Rainer Blum , Rolf Osterloh
IPC分类号： C08J3/11 , C08J3/18 , C08K5/17 , C08K5/12 , C08L33/02 , C08L33/04
CPC分类号： C08J3/11 , C08J3/18
摘要： Plastisols and organosols which have a long shelf life at room temperature, are based on a mixture of a finely divided synthetic resin with a plasticizer and may or may not contain additional pigments, fillers, volatile organic solvents and other assistants are prepared by a process in which an inert or reactive protective colloid or emulsifier, or a mixture of these, is added to a dispersion of a finely divided synthetic resin in a plasticizer, the dispersion as such not having a long shelf life at room temperature.These plastisols can be used as coating materials, sealants and adhesives.
摘要翻译：在室温下具有长保质期的增塑溶胶和有机溶胶基于细分的合成树脂与增塑剂的混合物，并且可以含有或不含有其它颜料，填料，挥发性有机溶剂和其它助剂的方法其中将惰性或反应性保护胶体或乳化剂或它们的混合物加入到细分散的合成树脂在增塑剂中的分散体中，这样的分散体在室温下不具有长的保存期限。这些增塑溶胶可用作涂料，密封剂和粘合剂。

79. 发明授权

US4596835A Reinforced cellular or noncellular polyurethane molded parts 失效
标题翻译：增强细胞或非细胞聚氨酯模制件
公开(公告)号：US4596835A
公开(公告)日：1986-06-24
申请号：US673974
申请日：1984-11-23
申请人： Frank Werner , Rainer Blum , Peter Horn , Martin Welz , Rolf Osterloh
发明人： Frank Werner , Rainer Blum , Peter Horn , Martin Welz , Rolf Osterloh
IPC分类号： C08G18/00 , C08G18/48 , C08G18/70 , C08G18/72 , C08G18/79 , C08G18/80 , C08J9/02 , C08G18/77 , C08G18/14
CPC分类号： C08G18/707 , C08G18/798 , C08G18/80
摘要： Reinforced cellular or noncellular molded polyurethane parts are prepared by heating a mixture of reinforcing materials and a heat-curable composition of polyisocyanates and polyols in an open or closed mold, said composition being storage-stable at room temperature and containing, optionally, auxiliaries and additives. In said composition, the polyisocyanate is dispersed in the form of discreet particles having particle diameters from 0.1 to 150 .mu.m in the polyol and the polyisocyanate particles are deactivated on their surfaces such that from 0.01 to 20 equivalent percent of the total available isocyanate groups are deactivated and such that the ratio of free isocyanate groups to hydroxyl groups is from 0.7:1 to 2.5:1.The polyurethane molded parts are suitable for use as self-supporting trim parts, reinforcement parts, or molded parts for various applications.
摘要翻译：加强的细胞或非细胞成型的聚氨酯部件通过在开放或闭合的模具中加热增强材料和多异氰酸酯和多元醇的可热固化组合物的混合物来制备，所述组合物在室温下储存稳定并且含有任选的助剂和添加剂。在所述组合物中，多异氰酸酯在多元醇中以粒径为0.1-150μm的分散颗粒的形式分散，多异氰酸酯颗粒在其表面上失活，使得总的可用异氰酸酯基团的0.01至20当量％使游离异氰酸酯基与羟基的比例为0.7:1至2.5:1。聚氨酯模制件适用于各种应用的自支撑饰件，增强件或模制件。

80. 发明授权

US4521555A Plastisols having carbon dust fillers 失效
标题翻译：具有碳粉填料的增塑溶胶
公开(公告)号：US4521555A
公开(公告)日：1985-06-04
申请号：US570307
申请日：1984-01-13
申请人： Rainer Blum , Max Seitz , Friedrich Kaczinski
发明人： Rainer Blum , Max Seitz , Friedrich Kaczinski
IPC分类号： C08K3/00 , C08K3/02 , C08K3/04 , C08L1/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L33/04 , C09D7/00 , C09D7/12 , C09K3/10
CPC分类号： C08K3/04 , Y10T428/26 , Y10T428/2998 , Y10T428/30 , Y10T428/31678 , Y10T428/31699
摘要： Plastisols useful for automobile undercoatings, anti-noise compositions, adhesives, sealing compositions and coatings for untreated, pretreated, phosphated, primed and prelacquered metal bases are improved by the addition of coke dust and coal dust fillers. The carbon dust fillers have a particle size of about 0.5 to 1000 microns and they are used in a concentration of about 9 to 90% by weight based on the total weight of plastisol and carbon dust. The carbon dust filled plastisols have a specific gravity of about 1.1 to 1.3.
摘要翻译：通过添加焦炭粉尘和煤粉填料，改善了用于汽车底漆，抗噪声组合物，粘合剂，密封组合物和用于未处理，预处理，磷酸化，底漆和预浸金属基材的涂料的增塑剂。碳粉填料的粒度为约0.5-1000微米，它们的使用浓度为基于增塑溶胶和碳粉的总重量的约9至90重量％。碳粉填充的增塑溶胶的比重约为1.1〜1.3。

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