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71. 发明申请

US20120232293A1 PROCESS FOR PREPARING DI-, TRI- AND POLYAMINES BY HOMOGENEOUSLY CATALYZED ALCOHOL AMINATION 有权
标题翻译：通过均相催化的醇醇胺化制备二 - ，三 - 和二亚胺的方法
公开(公告)号：US20120232293A1
公开(公告)日：2012-09-13
申请号：US13415466
申请日：2012-03-08
申请人： Thomas SCHAUB , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
发明人： Thomas SCHAUB , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
IPC分类号： C07C213/02 , C07C209/16 , C07D307/52
CPC分类号： C07C213/02 , C07C209/16 , C07C2601/14 , C07D205/04 , C07D207/02 , C07D207/20 , C07D211/06 , C07D223/04 , C07D295/027 , C07D307/52 , C07C217/08 , C07C215/08 , C07C211/09 , C07C211/10 , C07C211/18 , C07C215/20 , C07C211/12
摘要： Process for preparing primary amines which have at least one functional group of the formula (—CH2—NH2) and at least one further primary amino group by alcohol amination of starting materials having at least one functional group of the formula (—CH2—OH) and at least one further functional group (—X), where (—X) is selected from among hydroxyl groups and primary amino groups, by means of ammonia with elimination of water, wherein the reaction is carried out homogeneously catalyzed in the presence of at least one complex catalyst comprising at least one element selected from groups 8, 9 and 10 of the Periodic Table and also at least one donor ligand.
摘要翻译：具有至少一个式（-CH 2 -NH 2）官能团和至少一个另外的伯氨基的伯胺的方法，其通过具有至少一个式（-CH 2 -OH）官能团的原料醇醇胺化，和至少一个另外的官能团（-X），其中（-X）选自羟基和伯氨基，通过氨除去水，其中反应在存在下进行均匀催化至少一种复合催化剂，其包含至少一种选自元素周期表第8,9和10族的元素，以及至少一种供体配体。

72. 发明授权

US07973198B2 Method for synthesizing optically active carbonyl compounds 有权
标题翻译：光学活性羰基化合物的合成方法
公开(公告)号：US07973198B2
公开(公告)日：2011-07-05
申请号：US12597025
申请日：2008-04-17
申请人： Joachim Schmidt-Leithoff , Christoph Jäkel , Rocco Paciello
发明人： Joachim Schmidt-Leithoff , Christoph Jäkel , Rocco Paciello
IPC分类号： C07C45/62
CPC分类号： C07C29/172 , C07B53/00 , C07B2200/07 , C07C29/56 , C07C45/62 , C07C2601/14 , C07C35/12 , C07C35/17 , C07C47/21
摘要： The present invention relates to a process for preparing optically active carbonyl compounds by asymmetrically hydrogenating α,β-unsaturated carbonyl compounds in the presence of optically active transition metal catalysts which are soluble in the reaction mixture and have at least one carbon monoxide ligand, the optically active catalyst which has at least one carbon monoxide ligand and is to be used in each case being prepared by pretreating a catalyst precursor with a gas mixture comprising carbon monoxide and hydrogen and the asymmetric hydrogenation being performed in the presence of carbon monoxide supplied additionally to the reaction mixture.
摘要翻译：本发明涉及一种通过在光学活性的过渡金属催化剂的存在下不对称氢化α，β-不饱和羰基化合物来制备光学活性的羰基化合物的方法，其可溶于反应混合物并具有至少一种一氧化碳配体，具有至少一种一氧化碳配体并且在每种情况下使用的光学活性催化剂通过用包含一氧化碳和氢气的气体混合物预处理催化剂前体而制备，并且在另外提供的一氧化碳的存在下进行不对称氢化反应混合物。

73. 发明申请

US20080269528A1 Method for the Production of Optically Active Carbonyl 有权
标题翻译：光活性羰基生产方法
公开(公告)号：US20080269528A1
公开(公告)日：2008-10-30
申请号：US11577068
申请日：2005-10-08
申请人： Christoph Jakel , Rocco Paciello
发明人： Christoph Jakel , Rocco Paciello
IPC分类号： C07C29/136 , C07C45/27
CPC分类号： B01J31/20 , B01J31/1845 , B01J31/189 , B01J31/2221 , B01J31/2409 , B01J31/2495 , B01J2231/643 , B01J2531/0205 , B01J2531/0255 , B01J2531/0263 , B01J2531/0266 , B01J2531/0272 , B01J2531/822 , B01J2531/827 , C07B53/00 , C07B2200/07 , C07C29/172 , C07C29/56 , C07C45/62 , C07C2601/14 , C07C49/395 , C07C49/21 , C07C35/12 , C07C35/17
摘要： The present invention relates to a process for preparing optically active carbonyl compounds by asymmetrically hydrogenating α,β-unsaturated carbonyl compounds in the presence of optically active transition metal catalysts which are soluble in the reaction mixture and have at least one carbon monoxide ligand. The present invention especially relates to a process for preparing optically active aldehydes or ketones, in particular citronellal, by asymmetrically hydrogenating the corresponding optically active α,β-unsaturated aldehydes or ketones.
摘要翻译：本发明涉及一种通过在光学活性的过渡金属催化剂存在下不溶性氢化α，β-不饱和羰基化合物来制备旋光性羰基化合物的方法，其可溶于反应混合物并具有至少一种一氧化碳配体。本发明特别涉及通过不对称氢化相应的光学活性α，β-不饱和醛或酮而制备光学活性醛或酮，特别是香茅醛的方法。

74. 发明申请

US20080108117A1 Method for Producing an Optically Active 2-Methyl-Alkane-1-Ol from the Corresponding 2-Methylalk-2-En-1-Al, Comprising Carbonyl-Selective Reduction, Enantioselective Hydration and Lipase-Catalyzed Stereoselective Acylation in Order to Enrich the Desired 有权
标题翻译：从相应的2-甲基烷基-2-烯-1-Al制备光学活性2-甲基 - 烷-1-醇的方法，包括羰基选择性还原，对映选择性水合和脂肪酶催化的立体选择性酰化以丰富所需的
公开(公告)号：US20080108117A1
公开(公告)日：2008-05-08
申请号：US11576317
申请日：2005-09-22
申请人： Christoph Jakel , Gunnar Heydrich , Rainer Sturmer , Rocco Paciello
发明人： Christoph Jakel , Gunnar Heydrich , Rainer Sturmer , Rocco Paciello
IPC分类号： C12P7/04
CPC分类号： C12P7/04 , C07B2200/07 , C07C29/14 , C07C29/141 , C07C29/172 , C12C11/02 , C07C33/025 , C07C31/125
摘要： A process for preparing optically active 2-methylalkan-1-ol of the general formula (III) comprising the following steps: (i) carbonyl-selective reduction of 2-methylalk-2-en-1-al of the general formula (I) to 2-methylalk-2-en-1-ol of the general formula (II), (ii) enantioselective hydrogenation of 2-methylalk-2-en-1-ol to the general formula (iii), (iii) increasing the optical yield of the optically active 2-methylalkan-1-ol (III) obtained in step (ii) by a lipase-catalyzed acylation reaction, where the radical R means C1-C10-alkyl.
摘要翻译：一种制备通式（III）的光学活性2-甲基烷-1-醇的方法，包括以下步骤：（i）通式（I）的2-甲基-α-烯-1-醇的羰基选择性还原）到通式（II）的2-甲基-2-烯-1-醇，（ii）2-甲基烯-2-烯-1-醇与通式（iii）的对映选择性氢化，（iii）增加通过脂肪酶催化的酰化反应在步骤（ii）中获得的光学活性2-甲基烷-1-醇（III）的光学收率，其中基团R表示C 1 -C 3 - 10个 - 烷基。

75. 发明授权

US07173138B2 Ligands for pnicogen chelate complexes with a metal of subgroup VIII and use of the complexes as catalysts for hydroformylation, carbonylation, hydrocyanation or hydrogenation 有权
标题翻译：用于第VIII族金属的pnicogen螯合物的配体和该配合物用作加氢甲酰化，羰基化，氢氰化或氢化的催化剂
公开(公告)号：US07173138B2
公开(公告)日：2007-02-06
申请号：US10473216
申请日：2002-03-28
申请人： Wolfgang Ahlers , Rocco Paciello , Dieter Vogt , Peter Hofmann
发明人： Wolfgang Ahlers , Rocco Paciello , Dieter Vogt , Peter Hofmann
IPC分类号： C07F9/572 , C07C29/00 , C07C29/03 , B01J31/02
CPC分类号： C07F15/065 , B01J31/186 , B01J31/187 , B01J31/28 , B01J2231/321 , B01J2231/323 , B01J2231/645 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/845 , C07C29/141 , C07C29/16 , C07C45/50 , C07C45/505 , C07F9/572 , C07F9/5728 , C07F9/65522 , C07F9/65586 , C07F9/65842 , C07F9/65848 , C07F9/6596 , C07F15/004 , C07F15/0053 , C07F15/0066 , C07C31/125 , C07C47/02
摘要： Pnicogen chelate compounds which have two pnicogen-containing groups joined to one another via a xanthene-like or triptycene-like molecular skeleton and in which at least one pyrrole group is covalently bound via its nitrogen atom to each pnicogen atom form complexes with metals of transition group VIII which are useful as catalysts for the hydroformylation of olefins.
摘要翻译：具有两个含有气相的基团的Pnicogen螯合物通过呫吨样或类三环类似的分子骨架彼此连接，并且其中至少一个吡咯基团通过其氮原子与每个原子核原子共价结合形成与过渡金属的复合物可用作烯烃加氢甲酰化的催化剂的VIII族。

76. 发明申请

US20060122436A1 Method for producing aldehydes from alkanes 审中-公开
标题翻译：从烷烃生产醛的方法
公开(公告)号：US20060122436A1
公开(公告)日：2006-06-08
申请号：US10533959
申请日：2003-11-03
申请人： Götz-Peter Schindler , Rocco Paciello , Klaus Harth
发明人： Götz-Peter Schindler , Rocco Paciello , Klaus Harth
IPC分类号： C07C45/50
CPC分类号： C07C45/72 , C07C5/42 , C07C29/141 , C07C45/50 , Y02P20/125 , C07C31/125 , C07C47/02 , C07C11/06 , C07C11/08
摘要： Process for preparing saturated aliphatic Cn-aldehydes and Cn-1-alkanes, where n is from 4 to 20, which comprises a) providing a feed gas stream comprising one or more Cn-1-alkanes, b) subjecting the Cn-1-alkanes to a catalytic dehydrogenation to give a product gas stream comprising unreacted Cn-1-alkanes, one or more Cn-1-alkenes and secondary constituents, c) at least partly hydroformylating the Cn-1-alkenes in the presence of the Cn-1-alkanes and possibly the secondary constituents by means of carbon monoxide and hydrogen in the presence of a hydroformylation catalyst to give the Cn-aldehydes, d) separating the product mixture obtained to give a stream comprising the Cn-aldehydes and a stream comprising Cn-1-alkanes and possibly secondary constituents, e) recirculating at least part of the gas stream comprising the Cn-1-alkanes and possibly the secondary constituents as recycle gas stream to the catalytic alkane dehydrogenation (step b)).
摘要翻译：制备饱和脂肪族C n - 醛和C n-1-N烷烃的方法，其中n为4至20，其包括a）提供包含一种或更多的C 1〜n烷烃，b）使C 1 -C 12烷烃进行催化脱氢，得到包含未反应的C n的产物气流 -1个 - 烷烃，一个或多个C n-1 - 烯烃和第二组分，c）至少部分地将C 1 -C 6 - 亚烷基在加氢甲酰化催化剂存在下，通过一氧化碳和氢气存在C n-1 - 烷烃并且可能存在第二成分，得到C 1 -C 6烷基，d）将得到的产物混合物分离得到包含C 1 -C 4烷基的物流和包含C 1〜N 2烷烃的物流，并且可能是二级成分，e）循环气流的至少一部分包含C n-1 - 烷烃，并且可能是二级的 y成分作为催化烷烃脱氢的再循环气流（步骤b））。

77. 发明授权

US06642420B1 Method for producing aldehydes and/or alcohols or amines 有权
标题翻译：醛和/或醇或胺的制备方法
公开(公告)号：US06642420B1
公开(公告)日：2003-11-04
申请号：US09762425
申请日：2001-02-07
申请人： Peter Zehner , Armin Ulonska , Rocco Paciello
发明人： Peter Zehner , Armin Ulonska , Rocco Paciello
IPC分类号： C07C4549
CPC分类号： C07C209/60 , B01J10/002 , B01J19/006 , B01J19/246 , B01J19/26 , B01J2219/00103 , B01J2219/0011 , B01J2219/00162 , B01J2219/00777 , C07C45/50 , C07C47/02
摘要： A process for the preparation of aldehydes and/or alcohols or amines by reacting olefins in the liquid phase with carbon monoxide and hydrogen, a part of these gases being dispersed in the form of gas bubbles in the reaction liquid and another part being dissolved in the reaction liquid, in the presence or absence of a primary or secondary amine and in the presence of a cobalt carbonyl, rhodium carbonyl, palladium carbonyl or ruthenium carbonyl complex dissolved homogeneously in the reaction liquid and having a phosphorus-, arsenic-, antimony- or nitrogen-containing ligand, at elevated temperatures and at 1 to 100 bar, wherein the reaction is carried out in a vertically arranged, tubular reactor comprising a reactor body and at least one circulation line, a part of the reaction liquid is fed continuously via the circulation line to at least one nozzle which is mounted in the upper part of the reactor body and is coordinated with a guide member, open at the top and bottom and bounded by parallel walls, in the interior of the reactor and with a baffle present below the lower opening of the guide member, and a downward-directed liquid stream containing dispersed gas bubbles is produced by means of this nozzle in this guide member and, after leaving the guide member, is deflected into a stream flowing upward in the space between the wall of the guide member and the wall of the reactor body and is sucked into the guide member at the upper end of the guide member by the jet of the nozzle coordinated with the guide member.
摘要翻译：通过使液相中的烯烃与一氧化碳和氢气反应制备醛和/或醇或胺的方法，其中一部分气体以气泡的形式分散在反应液体中，另一部分溶于在存在或不存在伯胺或仲胺的情况下和在羰基，羰基铑羰基，羰基钯或羰基钌羰基络合物存在下，均匀地溶解在反应液中并具有磷，砷，锑或含氮配体，在升高的温度和1至100巴，其中反应在垂直布置的管式反应器中进行，其包括反应器主体和至少一个循环管线，部分反应液体经由循环管线至少一个喷嘴，其安装在反应器主体的上部并与引导构件配合，导向构件在顶部和底部开口并且由在反应器内部具有平行的壁，并且在引导构件的下开口下方存在挡板，并且在该引导构件中通过该喷嘴产生包含分散气泡的向下指向的液体流，并且在离开引导构件被偏转到在引导构件的壁和反应器主体的壁之间的空间中向上流动的流中，并且通过与引导构件的喷嘴配合的喷嘴的喷嘴被吸入引导构件的上端处的引导构件导向件。

78. 发明授权

US06639114B2 Hydroformylation catalyst comprising a complex with ligands having a structure derived from bisphenol A 失效
公开(公告)号：US06639114B2
公开(公告)日：2003-10-28
申请号：US10073327
申请日：2002-02-13
申请人： Wolfgang Ahlers , Rocco Paciello , Dieter Vogt , Jarl Ivar van der Vlugt
发明人： Wolfgang Ahlers , Rocco Paciello , Dieter Vogt , Jarl Ivar van der Vlugt
IPC分类号： C07C4549
CPC分类号： B01J31/2409 , B01J2531/822 , C07C45/50 , C07F9/145 , C07F9/5022 , C07F9/5027 , C07C47/02
摘要： Ethylenically unsaturated compounds are hydroformylated in the presence of a hydroformylation catalyst comprising at least one complex of a metal of transition group VIII with at least one phosphorus-containing compound as ligand, where this compound contains two groups which contain P atoms and are bound to a molecular skeleton derived from bisphenol A.

79. 发明授权

US06310261B1 Method for the production of aldehydes 失效
标题翻译：醛的生产方法
公开(公告)号：US06310261B1
公开(公告)日：2001-10-30
申请号：US09582780
申请日：2000-07-03
申请人： Bernhard Geissler , Michael Röper , Edgar Zeller , Rocco Paciello , Jürgen Decker , Hartwig Voss , Norbert Mahr
发明人： Bernhard Geissler , Michael Röper , Edgar Zeller , Rocco Paciello , Jürgen Decker , Hartwig Voss , Norbert Mahr
IPC分类号： C07C4550
CPC分类号： C08G73/0206 , B01J31/1658 , B01J31/1805 , B01J2231/321 , B01J2531/80 , B01J2531/822 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： The invention relates to a method for the production of aldehydes or aldehydes and alcohols by hydroformylation of olefins in the presence of a complexing catalyst homogeneously dissolved in a reaction mixture, containing a metal of Group VIIIa of the periodic table of the elements and a phosphorus-free, polydentate nitrogen compound suitable for complex formation as ligand at temperatures ranging from 50 to 100° C. and pressures from 20 to 1,000 bar and recirculating the catalyst complex in the hydroformylation reaction, wherein a) derivatized polyamines are used that are substantially non-water soluble and suitable for complex formation and have a mean molecular weight of more than 1,000 Dalton and at least 10 nitrogen atoms; b) the catalyst complex remaining in the bottom of the distillation column and the excess ligands obtained from the reaction mixture are recirculated totally or partially in the hydroformylation once the hydroformylation reaction and the separation or partial separation by distillation of the aldehydes and the alcohols has been completed; c) continues or at least batchwise evacuation of at least part of the high boiler from the bottom of the distillation of the reaction mixture is then carried out.
摘要翻译：本发明涉及通过在均匀溶解在含有元素周期表第Ⅷa族金属的反应混合物的络合催化剂存在下烯烃的加氢甲酰化生产醛或醛和醇的方法，在50至100℃的温度和20至1,000巴的压力下适合于络合物形成配位体的多余的多齿氮化合物，并且在加氢甲酰基化反应中再循环催化剂配合物，其中a）使用基本上不相容的衍生的多胺，水溶性且适合于络合物形成，并且具有大于1,000道尔顿和至少10个氮原子的平均分子量; b）一旦加氢甲酰化反应和通过蒸馏醛和醇的分离或部分分离已经被残留在蒸馏塔底部的催化剂络合物和从反应混合物中得到的过量配体在加氢甲酰化反应中被全部或部分再循环完成 c）然后执行从反应混合物的蒸馏底部继续或至少间歇抽出高锅炉的至少一部分。

80. 发明授权

US06225507B1 Method of preparing aldehydes by hydroformylation with a rhodium catalyst and recovery of the rhodium catalyst by extraction 失效
标题翻译：通过用铑催化剂加氢甲酰化制备醛的方法，并通过萃取回收铑催化剂
公开(公告)号：US06225507B1
公开(公告)日：2001-05-01
申请号：US09117662
申请日：1998-08-04
申请人： Bernhard Giessler , Heinz-Josef Kneuper , Michael Röper , Rocco Paciello , Knut Oppenländer , Wolfgang Günther
发明人： Bernhard Giessler , Heinz-Josef Kneuper , Michael Röper , Rocco Paciello , Knut Oppenländer , Wolfgang Günther
IPC分类号： C07C4550
CPC分类号： B01J31/20 , B01J31/1658 , B01J31/4046 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07F9/3817 , C08G73/0206 , Y02P20/584 , C07C47/02
摘要： A process for the preparation of aldehydes or aldehydes and alcohols by hydroformylation of olefins containing more than 3 carbon atoms, comprising a hydroformylation stage, in which the olefin is hydroformylated under a pressure of form 50 to 1000 bar and at a temperature of from 50° to 180° C. by means of a rhodium catalyst dissolved in a homogenous reaction medium and a catalyst recovery stage comprising extraction of the rhodium catalyst with an aqueous solution of chelating agent, isolation of alcohols and/or aldehyde from the extracted hydroformylation product steam, precarbonylation of the aqueous rhodium-containing extract in the presence of carbon monoxide, synthesis gas as, or a gas mixture containing carbon monoxide under a pressure of from 50 to 1000 bar and at a temperature of from 50° to 180° C., separation of the effluent of the precarbonylation stage into an organic phase containing the major portion of the rhodium and an aqueous phase containing the chelating agent and recycling of the organic phase to the hydroformylation stage, where the rhodium catalyst is extracted from the effluent of the hydroformylation stage using an aqueous solution of a sulfonic acid group-free, water-soluble polymer capable of chelating rhodium.
摘要翻译：一种通过加氢甲酰化含有多于3个碳原子的烯烃制备醛或醛和醇的方法，包括加氢甲酰化阶段，其中烯烃在50至1000巴的压力和50℃的温度下加氢甲酰化通过溶解在均匀的反应介质中的铑催化剂和催化剂回收阶段，包括用螯合剂的水溶液萃取铑催化剂，从提取的加氢甲酰化产物蒸汽中分离出醇和/或醛，在50至1000巴的压力和50至180℃的温度下，在一氧化碳，合成气或含有一氧化碳的气体混合物存在下，含铑水溶液提取物的预羰基化，分离的预羰化阶段的流出物进入含有主要部分铑的有机相和含有螯合剂的水相并将有机相再循环到加氢甲酰化阶段，其中使用不含磺酸基团的能够螯合铑的水溶性聚合物的水溶液从加氢甲酰化阶段的流出物中提取铑催化剂。

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