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    • 74. 发明申请
    • ETHYLENE-PROPYLENE-DIENE RUBBER, ELASTOMER COMPOSITION, AND VULCANIZED RUBBER PREPARED THEREFROM
    • 乙烯 - 丙烯 - 二烯橡胶,弹性体组合物和由其制备的硫化橡胶
    • WO1991005010A1
    • 1991-04-18
    • PCT/JP1990001291
    • 1990-10-05
    • MITSUI PETROCHEMICAL INDUSTRIES, LTD.NAKAHAMA, HidenariMISHIMA, Takashi
    • MITSUI PETROCHEMICAL INDUSTRIES, LTD.
    • C08L23/16
    • C08J3/215B60C1/0016B60C1/0025C08J2323/16C08K3/06C08L23/16C08L2205/02C08L2205/025C08L2666/04
    • An ethylene-propylene-diene rubber which can endure the use under harsh conditions requiring dynamic and mechanical durability wherein it has been believed that only a natural rubber or a blend therewith is durable and which can impart excellent heat resistance, weather resistance and dynamic fatigue resistance. This rubber is characterized by containing sulfur dispersed therein. A preferred form of the ethylene-propylene-diene rubber comprises 90 to 40 % by weight of a high molecular weight ethylene-propylene-diene rubber (A) having an ethylene content of 60 to 82 mol.%, a limiting viscosity number [θ] of 3.0 to 5.0 dl/g as measured at 135 °C in decalin and an iodine value of 8 to 35; and 10 to 60 % by weight of a low molecular weight ethylene-propylene-diene rubber (B) having an ethylene content of 60 to 82 mol.%, a limiting viscosity number [θ] of 0.15 to 0.8 dl/g as measured at 135 °C in decalin and an iodine value of 8 to 35, the Mooney viscosity, ML1+4 (100 °C), of which is in the range of 60 to 120, and wherein sulfur is dispersed. The vulcanized rubber is suited for use in various fields, such as tire, automobile parts, general engineering parts and civil engineering building materials, especially in the fields where dynamic fatigue resistance is demanded, e.g., a muffler hanger, a belt, a rubber vibration insulator, an engine mount, a tread of a pneumatic tire, a side wall of a pneumatic tire and a white side wall.
    • 本发明涉及一种乙烯 - 丙烯 - 二烯橡胶,其能够承受苛刻的操作条件,这要求动态和机械耐久性,其中据信只有天然橡胶或橡胶化合物 天然耐用,可能具有优异的耐热性,耐候性和抗动态疲劳特性。 这种橡胶的特点是含有硫分散在橡胶中。 这种乙烯 - 丙烯 - 二烯橡胶的优选实施方案包含:90-40重量%的乙烯含量高的分子量乙烯 - 丙烯 - 二烯橡胶(A) 对应于60和82之间的摩尔百分比,在135℃的十氢萘中测得的特性粘数η在3.0和5.0dl / g之间,碘值为 在8和35之间; 和10-60重量%乙烯含量相当于摩尔百分数为60-82的低分子量乙烯 - 丙烯 - 二烯橡胶(B),特性粘数η 包括0.15和0.8分升/克在135℃萘烷中的温度和8和35之间,它的门尼粘度的碘值测定,ML1 + 4(100℃)是 在60和120之间,并且其中硫分散。 这样的硫化橡胶是适合于在各种应用中使用,例如用于物品,例如在土建工程中一般和建材机械技术旧轮胎,汽车配件,部件的制造, 特别是用于制造需要抗动态疲劳性的制品,例如消声器吊架,皮带,橡胶隔振器,发动机支架,轮胎胎面,轮胎侧壁 和白色的侧翼