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71. 发明申请

US20090203941A1 DIRECT HYDROCARBON AMINATION 审中-公开
标题翻译：直接碳氢化合物
公开(公告)号：US20090203941A1
公开(公告)日：2009-08-13
申请号：US12064635
申请日：2006-08-21
申请人： Frederik Van Laar , Ekkehard Schwab , Hartwig Voss , Joachim-Thierry Anders , Sven Crone , Wolfgang Mackenroth
发明人： Frederik Van Laar , Ekkehard Schwab , Hartwig Voss , Joachim-Thierry Anders , Sven Crone , Wolfgang Mackenroth
IPC分类号： C07C209/02
CPC分类号： C07C209/02 , B01D53/228 , B01D67/0072 , B01D69/10 , B01D71/022 , B01D2323/12 , B01D2325/10 , C01B3/505 , C01B2203/041 , C01B2203/0465 , C01B2203/048 , C07C211/44 , C07C211/45 , C07C211/46
摘要： A process for aminating hydrocarbons comprises physically removing hydrogen from the reaction mixture.
摘要翻译：用于胺化胺的方法包括物理地从反应混合物中除去氢。

72. 发明申请

US20090030237A1 METHOD FOR PRODUCING ETHYLENE AMINES AND ETHANOL AMINES BY THE HYDROGENATING AMINATION OF MONOETHYLENE GLYCOL AND AMMONIA IN THE PRESENCE OF A CATALYST 有权
标题翻译：通过催化剂存在下单乙基甘氨酸和氨基甲酸的加氢胺化生产乙烯胺和乙醇胺的方法
公开(公告)号：US20090030237A1
公开(公告)日：2009-01-29
申请号：US12279215
申请日：2007-02-08
申请人： Gunther van Cauwenberge , Johann-Peter Melder , Bram Willem Hoffer , Thomas Krug , Karin Pickenaecker , Frank-Friedrich Pape , Ekkehard Schwab
发明人： Gunther van Cauwenberge , Johann-Peter Melder , Bram Willem Hoffer , Thomas Krug , Karin Pickenaecker , Frank-Friedrich Pape , Ekkehard Schwab
IPC分类号： C07C209/14
CPC分类号： C07C209/16 , C07C211/10 , C07C211/14
摘要： A process for preparing ethylene amines and ethanolamines by hydrogenative amination of monoethylene glycol and ammonia in the presence of a catalyst, wherein a catalyst having an active composition comprising ruthenium and cobalt and no further additional metal of group VIII and also no metal of group IB is used in the form of shaped catalyst bodies which in the case of a spherical shape or rod shape in each case have a diameter of
摘要翻译：一种在催化剂存在下通过单乙酰胺和氨的氢化胺化制备乙烯胺和乙醇胺的方法，其中具有包含钌和钴的活性组合物以及没有另外的另外的第VIII族金属以及也没有IB族金属的催化剂是使用成形催化剂体的形式，在球形或棒状的情况下，每种情况具有<3mm的直径，在颗粒形状的情况下具有<3mm的高度，并且在全部情况下每种情况下的其他几何形状具有等效直径L = 1 / a'<0.70mm，其中a'是每单位体积的外表面积（mms2 / mmp3），并且： $a'=\frac{其中Ap是成形催化剂体的外表面面积（mms2），Vp是（mms2），其中Ap是成形催化剂体的外表面积（mms2），Vp是}{提出了成形催化剂体的体积（mmp3）。}$

73. 发明授权

US07468461B2 Method for the production of amines 有权
标题翻译：制备胺的方法
公开(公告)号：US07468461B2
公开(公告)日：2008-12-23
申请号：US12057617
申请日：2008-03-28
申请人： Frederik Van Laar , Ekkehard Schwab , Steffen Oehlenschlaeger , Hartwig Voss , Wolfgang Mackenroth , Konrad Morgenschweis , Ulrich Penzel , Bernd Weidner
发明人： Frederik Van Laar , Ekkehard Schwab , Steffen Oehlenschlaeger , Hartwig Voss , Wolfgang Mackenroth , Konrad Morgenschweis , Ulrich Penzel , Bernd Weidner
IPC分类号： C07C209/00 , B01J23/89
CPC分类号： C07C209/36 , B01J21/18 , B01J23/892 , B01J37/03 , B01J37/14 , B01J37/18 , C07C211/51
摘要： The present invention provides a process for hydrogenating aromatic nitro compounds to the corresponding amines in the presence of hydrogenation catalysts, which comprises using hydrogenation catalysts in which nickel and platinum are present on a support in the form of an alloy having an atomic ratio of nickel to platinum in the alloy of between 30:70 and 70:30.
摘要翻译：本发明提供了在氢化催化剂存在下将芳族硝基化合物氢化成相应的胺的方法，该方法包括使用氢化催化剂，其中镍和铂以合金的形式存在于载体上，其原子比为镍与合金中的铂在30:70和70:30之间。

74. 发明申请

US20080242537A1 Method for Producing Amines with a Catalyst Containing Platinum, Nickel and an Additional Metal 有权
标题翻译：用含有铂，镍和附加金属的催化剂生产胺的方法
公开(公告)号：US20080242537A1
公开(公告)日：2008-10-02
申请号：US12065285
申请日：2006-08-21
申请人： Petr Kubanek , Ekkehard Schwab , Frederik van Laar , Wolfgang Mackenroth
发明人： Petr Kubanek , Ekkehard Schwab , Frederik van Laar , Wolfgang Mackenroth
IPC分类号： B01J23/42 , C07C209/36
CPC分类号： C07C209/36 , B01J21/18 , B01J23/892 , B01J23/8953 , B01J37/0201 , B01J37/16 , Y02P20/52 , C07C211/50
摘要： The invention provides a process for preparing aromatic amines by catalytically hydrogenating the corresponding nitro compounds, especially for preparing tolylenediamine by hydrogenating dinitrotoluene, which comprises using hydrogenation catalysts in which the active component present is a mixture of platinum, nickel and an additional metal on a support.
摘要翻译：本发明提供了一种通过催化氢化相应的硝基化合物，特别是通过氢化二硝基甲苯来制备甲苯二胺来制备芳族胺的方法，其包括使用存在的活性组分是铂，镍和另外的金属在载体上的混合物的氢化催化剂。

75. 发明申请

US20070149814A1 Method for the production of amines 审中-公开
标题翻译：制备胺的方法
公开(公告)号：US20070149814A1
公开(公告)日：2007-06-28
申请号：US10575924
申请日：2004-10-15
申请人： Frederik van Laar , Ekkehard Schwab , Steffen Oehlenschlager , Hartwig Voss , Wolfgang Mackenroth , Konrad Morgenschweis , Ulrich Penzel , Bernd Weidner
发明人： Frederik van Laar , Ekkehard Schwab , Steffen Oehlenschlager , Hartwig Voss , Wolfgang Mackenroth , Konrad Morgenschweis , Ulrich Penzel , Bernd Weidner
IPC分类号： C07C209/36 , B01J21/00
CPC分类号： C07C209/36 , B01J21/18 , B01J23/892 , B01J37/03 , B01J37/14 , B01J37/18 , C07C211/51
摘要： The present invention provides a process for hydrogenating aromatic nitro compounds to the corresponding amines in the presence of hydrogenation catalysts, which comprises using hydrogenation catalysts in which nickel and platinum are present on a support in the form of an alloy having an atomic ratio of nickel to platinum in the alloy of between 30:70 and 70:30.
摘要翻译：本发明提供了在氢化催化剂存在下将芳族硝基化合物氢化成相应的胺的方法，该方法包括使用氢化催化剂，其中镍和铂以合金的形式存在于载体上，其原子比为镍与合金中的铂在30:70和70:30之间。

76. 发明授权

US07091383B2 Method for the production of amines 有权
标题翻译：制备胺的方法
公开(公告)号：US07091383B2
公开(公告)日：2006-08-15
申请号：US10500862
申请日：2003-01-30
申请人： Dominic Vanoppen , Ekkehard Schwab , Frederick van Laar , Hartwig Voss , Steffen Oehlenschlaeger , Wolfgang Mackenroth , Konrad Morgenschweis , Ulrich Penzel , Bernd Weidner
发明人： Dominic Vanoppen , Ekkehard Schwab , Frederick van Laar , Hartwig Voss , Steffen Oehlenschlaeger , Wolfgang Mackenroth , Konrad Morgenschweis , Ulrich Penzel , Bernd Weidner
IPC分类号： C07C209/36
CPC分类号： C07C209/36 , C07C209/86 , C07C211/50 , C07C211/46
摘要： The invention provides a process for preparing amines by catalytic hydrogenation of nitroaromatics and subsequent removal of the catalysts from the reaction mixture, which contains at least one aromatic amine and water, which comprises carrying out the removal of the catalysts by means of membrane filtration, which is carried out at a pressure on the suspension side of from 5 to 50 bar, a pressure difference between the suspension side and the permeate side of at least 0.3 bar and a flux rate on the suspension side of from 1 to 6 m/s.
摘要翻译：本发明提供了一种通过硝基芳族化合物的催化氢化和随后从含有至少一种芳族胺和水的反应混合物中除去催化剂来制备胺的方法，该方法包括通过膜过滤进行催化剂的除去，在悬浮侧的压力为5至50巴，悬浮液侧和渗透侧之间的压力差为至少0.3巴，悬浮侧的通量速率为1至6m / s。

77. 发明申请

US20050177003A1 Method for the production of amines 有权
标题翻译：制备胺的方法
公开(公告)号：US20050177003A1
公开(公告)日：2005-08-11
申请号：US10500862
申请日：2003-01-30
申请人： Dominic Vanoppen , Ekkehard Schwab , Frederik Laar , Hartwig Voss , Steffen Oehlenschlager , Wolfgang Mackenroth , Konrad Morgenschweis , Ulrich Penzel
发明人： Dominic Vanoppen , Ekkehard Schwab , Frederik Laar , Hartwig Voss , Steffen Oehlenschlager , Wolfgang Mackenroth , Konrad Morgenschweis , Ulrich Penzel
IPC分类号： C07C29/36 , C07C209/36 , C07C209/86
CPC分类号： C07C209/36 , C07C209/86 , C07C211/50 , C07C211/46
摘要： The invention provides a process for preparing amines by catalytic hydrogenation of nitroaromatics and subsequent removal of the catalysts from the reaction mixture, which contains at least one aromatic amine and water, which comprises carrying out the removal of the catalysts by means of membrane filtration, which is carried out at a pressure on the suspension side of from 5 to 50 bar, a pressure difference between the suspension side and the permeate side of at least 0.3 bar and a flux rate on the suspension side of from 1 to 6 m/s.
摘要翻译：本发明提供了一种通过硝基芳族化合物的催化氢化和随后从含有至少一种芳族胺和水的反应混合物中除去催化剂来制备胺的方法，其包括通过膜过滤进行催化剂的除去，在悬浮侧的压力为5至50巴，悬浮液侧和渗透侧之间的压力差为至少0.3巴，悬浮侧的通量速率为1至6m / s。

78. 发明授权

US06350717B1 Catalyst and process for the selective hydrogenation of unsaturated compounds in hydrocarbon streams 失效
标题翻译：用于烃流中不饱和化合物的选择性氢化的催化剂和方法
公开(公告)号：US06350717B1
公开(公告)日：2002-02-26
申请号：US09385458
申请日：1999-08-30
申请人： Andrea Frenzel , Cristina Freire Erdbrügger , Ekkehard Schwab , Michael Hesse , Gerd Linden , Herbert Wanjek , Hans-Martin Allmann
发明人： Andrea Frenzel , Cristina Freire Erdbrügger , Ekkehard Schwab , Michael Hesse , Gerd Linden , Herbert Wanjek , Hans-Martin Allmann
IPC分类号： B01J2358
CPC分类号： C07C7/163 , B01J23/44 , B01J23/50 , B01J37/0201 , C07C5/05 , C07C5/09 , C07C2523/44 , C07C2523/50 , Y02P20/52 , C07C11/06 , C07C11/04
摘要： A catalyst comprising at least one metal of the 10th group of the Periodic Table of the Elements and at least one metal of the 11th group of the Periodic Table of the Elements on an aluminum oxide support, wherein the metal or metals of the 10th group is or are essentially concentrated in an outer layer close to the surface of the catalyst particle, the metal or metals of the 11th group is or are distributed essentially uniformly over the volume of the catalyst particle and the weight ratio of the metal or metals of the 11th group to the metal or metals of the 10th group is not more than 1.95.
摘要翻译：一种催化剂，其包含元素周期表第10族中的至少一种金属和氧化铝载体上元素周期表第11族的至少一种金属，其中第10族的金属或金属为或基本上集中在接近催化剂颗粒表面的外层中，第11组的金属或金属基本均匀地分布在催化剂颗粒的体积上，并且第11位的金属或金属的重量比第10组金属或金属组不超过1.95。

79. 发明授权

US6074472A Hydrolytic preparation of titanium dioxide pigments 失效
标题翻译：二氧化钛颜料的水解制备
公开(公告)号：US6074472A
公开(公告)日：2000-06-13
申请号：US11608
申请日：1998-02-12
申请人： Harald Jachow , Ekkehard Schwab , Claudius Kormann , Wilma Dausch , Karin Sperling , Horst Westenfelder
发明人： Harald Jachow , Ekkehard Schwab , Claudius Kormann , Wilma Dausch , Karin Sperling , Horst Westenfelder
IPC分类号： A61K8/19 , A61K8/00 , A61K8/04 , A61K8/26 , A61K8/29 , A61Q17/04 , A61Q19/00 , C01G23/053 , C09C1/36 , C01B23/047
CPC分类号： A61Q19/004 , A61K8/29 , A61Q19/00 , B82Y30/00 , B82Y5/00 , C01G23/053 , C01G23/0536 , C09C1/3661 , A61K2800/413 , A61K2800/43 , C01P2002/84 , C01P2004/64 , C01P2006/12 , C01P2006/60
摘要： Titanium dioxide pigments are obtainable by complete hydrolysis of a hydrolyzable titanium compound at from 0 to 100.degree. C. with intensive stirring and with setting of a pH in the range from 3 to 8 and maintenance of this pH within a range of 0.3 units.The titanium dioxide pigments can be employed for the production of cosmetic preparations and medicaments.
摘要翻译： PCT No.PCT / EP96 / 03504 Sec。 371日期1998年2月12日 102（e）1998年2月12日PCT PCT 1996年8月8日PCT公布。公开号WO97 / 07058 日期1997年2月27日二氧化钛颜料可通过在剧烈搅拌下在0至100℃下完全水解可水解的钛化合物并将pH调节至3至8，并将该pH维持在一定范围内 0.3单位。二氧化钛颜料可用于制备化妆品制剂和药物。

80. 发明授权

US5484628A Preparation of acicular cobalt-containing magnetic iron oxide 失效
标题翻译：针状钴磁性氧化铁的制备
公开(公告)号：US5484628A
公开(公告)日：1996-01-16
申请号：US291559
申请日：1994-08-16
申请人： Ekkehard Schwab , Ronald J. Veitch , Reinhard Korner , Emil Pfannebecker , Bernd Hoppner
发明人： Ekkehard Schwab , Ronald J. Veitch , Reinhard Korner , Emil Pfannebecker , Bernd Hoppner
IPC分类号： C01G49/00 , C09C1/24 , C09C3/06 , C09D5/23 , C09D7/12 , G11B5/706 , G11B5/84 , H01F1/11 , B05D7/00
CPC分类号： G11B5/70657 , C09C1/24 , C09C3/063 , C01P2004/10 , C01P2004/80 , C01P2006/10 , C01P2006/12 , C01P2006/42
摘要： Acicular cobalt-containing magnetic iron oxides having a high coercive force and a core/shell structure and hence low temperature dependence of the coercive force are prepared by a process in which, in a first stage, surface activation is effected by means of iron(II) and cobalt ions under alkaline conditions on the iron oxide core under an inert gas atmosphere and thereafter, in a second stage, an epitactic coating of cobalt ferrite is applied, which coating is formed oxidatively from iron (II) and cobalt (II) hydroxide, likewise under alkaline reaction conditions. The total amount of cobalt ions used for doping remains unchanged compared with the known doped iron oxides or is even smaller. In the second process stage, the achievable coercive force can be controlled by the proportion of air in the gas mixture during the formation of the epitactic coating.
摘要翻译：通过一种方法制备具有高矫顽力和核/壳结构并因此矫顽力的低温依赖性的针状含钴磁性氧化铁，其中在第一阶段中，通过铁（II）进行表面活化）和钴离子在碱性条件下在惰性气体气氛下在氧化铁芯上，然后在第二阶段施加钴铁氧体的中空涂层，该涂层由铁（II）和氢氧化钴（II）氧化形成，同样在碱性反应条件下。用于掺杂的钴离子的总量与已知的掺杂的氧化铁相比保持不变，或甚至更小。在第二工艺阶段，可以通过在形成外延涂层期间气体混合物中的空气比例来控制可实现的矫顽力。

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