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    • 71. 发明申请
    • ADHESION STRENGTHENING AGENT FOR EPOXY RESIN AND STRUCTURE BONDING COMPOSITION BASED ON EPOXY RESIN CONTAINING SAID AGENT
    • 基于含有环氧树脂的环氧树脂和结构粘结组合物的粘合强化剂
    • WO1994028082A1
    • 1994-12-08
    • PCT/JP1994000828
    • 1994-05-24
    • NIPPON ZEON CO., LTD.NAKAYAMA, AkiraNAGASE, ToshioASHIDA, TadashiOHNISHI, Masahiko
    • NIPPON ZEON CO., LTD.
    • C09J163/00
    • C09J123/26C08L2666/04C09J163/00Y10S525/902
    • An adhesion strengthening agent for epoxy resins comprising ionically cross-linked resin particles prepared by adding mono- or divalent metal cations to copolymer resin particles composed of a core component and a shell component in a weight ratio of 5/1 to 1/4, wherein the core component comprises a polymer having a glass transition point of -30 DEG C or below and composed of a diene monomer and optionally a cross-linking monomer, while the shell component comprises a copolymer having a glass transition point of 70 DEG C or above and composed of 100 parts by weight of a (meth)acrylate monomer and 0.01-20 parts by weight of a C3-C8 radical-polymerizable unsaturated carboxylic acid monomer having a free carboxyl group. A composition comprising 100 parts by weight of an epoxy resin, 15-60 parts by weight of the strengthening agent and 3-30 parts by weight of a heat-activable curing agent is useful bonding automobile structural parts.
    • 一种用于环氧树脂的粘合强化剂,其包含通过将重量比为5/1至1/4的由核心组分和壳组分组成的共聚物树脂颗粒加成一价或二价金属阳离子制备的离子交联树脂颗粒,其中 核心组分包括具有-30℃或更低的玻璃化转变点并由二烯单体和任选的交联单体组成的聚合物,而壳组分包含玻璃化转变点为70℃或更高的共聚物 由(甲基)丙烯酸酯单体100重量份和游离羧基的C3〜C8自由基聚合性不饱和羧酸单体0.01-20重量份组成。 包含100重量份环氧树脂,15-60重量份强化剂和3-30重量份可热活化固化剂的组合物可用于粘合汽车结构部件。