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71. 发明授权

US4647679A Platinum and/or palladium containing organopolysiloxane-ammonium compounds, method for their preparation and uses 失效
标题翻译：铂和/或钯的有机聚硅氧烷 - 铵化合物，其制备方法和用途
公开(公告)号：US4647679A
公开(公告)日：1987-03-03
申请号：US699968
申请日：1985-02-08
申请人： Peter Panster , Marlies Englisch , Peter Kleinschmit
发明人： Peter Panster , Marlies Englisch , Peter Kleinschmit
IPC分类号： C08G77/00 , B01J23/42 , B01J23/44 , B01J31/02 , B01J31/12 , B01J31/16 , B01J31/30 , C07F7/14 , C08G77/08 , C08G77/26 , C08G77/28 , C08G77/32 , C08G77/38 , C08G77/388 , C08G77/54 , C08G77/58 , C07F15/00
CPC分类号： C08G77/58 , B01J31/0239 , B01J31/124 , B01J31/30 , C07F7/14 , C08G77/54 , B01J2231/323 , Y02P20/582
摘要： Platinum and/or palladium containing organopolysiloxane-ammonium compounds containing units represented by the structural formula: ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 represent:R.sup.5 --SiO.sub.3/2 (2)wherein R.sup.5 is an alkylene group and the free valences of oxygen are satisfied by silicon atom and additional groups of the structural formula (2), optionally with the introduction of a crosslinking agent,R.sup.4 can be R.sup.1, R.sup.2, R.sup.3 or hydrogen, alkyl, cycloalkyl or benzyl,Y.sup.x- is MeX.sub.4.sup.2- or MeX.sub.6.sup.2-, wherein Me is platinum or palladium andX is chlorine or bromine, and can further denote a 1 to 3 valent anion of a protonic acid capable of forming a stable salt with an amine, or the hydroxy group, andx is a number from 1 to 3. Methods for the obtaining the polymeric organosiloxane-ammonium-noble metal complexes and as well as the use thereof as catalysts for hydrosilylation and hydrogenation reactions are disclosed.
摘要翻译：含有以下结构式表示的单元的铂和/或钯的有机聚硅氧烷 - 铵化合物：其中R1，R2和R3表示：R5-SiO3 / 2（2），其中R5是亚烷基，通过硅原子和结构式（2）的另外的基团，任选地引入交联剂，R4可以是R1，R2，R3或氢，烷基，环烷基或苄基，Yx-是MeX42- 或MeX62-，其中Me是铂或钯，X是氯或溴，并且还可以表示能够与胺或羟基形成稳定盐的质子酸的1至3价阴离子，x是公开了获得聚合物有机硅氧烷 - 铵 - 贵金属络合物的方法及其作为氢化硅烷化和氢化反应的催化剂的用途。

72. 发明授权

US4578496A Polymeric metal-amine complex compounds, processes for their preparation and use 失效
标题翻译：聚合金属 - 胺络合物，其制备和使用方法
公开(公告)号：US4578496A
公开(公告)日：1986-03-25
申请号：US543720
申请日：1983-10-20
申请人： Peter Panster , Peter Kleinschmit
发明人： Peter Panster , Peter Kleinschmit
IPC分类号： C07F7/02 , B01J27/00 , B01J31/16 , B01J31/18 , B01J31/22 , C07B61/00 , C07C29/44 , C07C45/50 , C07C47/02 , C07F1/10 , C07F1/12 , C07F7/12 , C07F7/14 , C07F11/00 , C07F13/00 , C07F15/00 , C07F15/02 , C07F15/04 , C07F15/06 , C08G77/398 , C08G77/58 , C07F7/08 , C07C5/02 , C07C45/00 , C07C69/02
CPC分类号： C08G77/58 , B01J31/1675 , B01J31/1805 , C07C29/16 , C07C45/50 , C07C67/303 , C07F7/14 , C08G77/398 , B01J2231/20 , B01J2231/321 , B01J2231/323 , B01J2231/52 , B01J2231/543 , B01J2231/645 , B01J2531/64 , B01J2531/66 , B01J2531/72 , B01J2531/74
摘要： Polymeric complex compounds of molybdenum, tungsten, manganese, rhenium and of the metals of the sub-groups VIII and I of the Periodic Table of Elements, which complex compounds have a silica-type structure are disclosed. At least one amine ##STR1## is bonded coordinately to the central metal atom. The atomic ratio of metal to nitrogen is from 1:1 to 1:10.sup.6. The required charge compensation is effected by means of an anion. In (1), R.sup.1 and R.sup.2 represent a group ##STR2## and R.sup.4 is an alkylene grouping. The oxygen atoms are saturated by silicon atoms of further groups (2), if appropriate with incorporation of crosslinking agents. R.sup.3 may have the meaning of R.sup.1 and R.sup.2, or represents hydrogen, an alkyl group, a cycloalkyl group or the benzyl group. The polymers can contain several metals. The invention also relates to processes for their preparation, and uses in catalysis.
摘要翻译：公开了复合化合物具有二氧化硅型结构的钼，钨，锰，铼和元素周期表第VIII族和第Ⅰ族的金属的高分子复合化合物。至少一个胺（1）与中心金属原子配位结合。金属与氮的原子比为1:1至1:106。所需的电荷补偿通过阴离子进行。在（1）中，R1和R2表示基团（2），R4是亚烷基。氧原子被其他基团（2）的硅原子饱和，如果合适的话，加入交联剂。 R3可以具有R 1和R 2的含义，或表示氢，烷基，环烷基或苄基。聚合物可以含有几种金属。本发明还涉及其制备方法和催化剂中的用途。

73. 发明授权

US4471712A Apparatus for the internal coating of contact tubes 失效
标题翻译：接触管内涂装置
公开(公告)号：US4471712A
公开(公告)日：1984-09-18
申请号：US508133
申请日：1983-06-27
申请人： Carl Voigt , Peter Kleinschmit , Reinhard Manner
发明人： Carl Voigt , Peter Kleinschmit , Reinhard Manner
IPC分类号： B05C7/00 , B01J37/02 , B05C7/04 , B05D7/00 , B05D7/22
CPC分类号： B05C7/04 , B05D7/222
摘要： The previously carried out internal coating of contact tubes not only required very much manual labor and was very time consuming, but it was also unsatisfactory in regard to adhesion of the contact liquid to the surface and homogenity of the catalyst. By the simultaneous action of heat on the liquid interface in the tubes during the lowering of the liquid level as well as by a specially suited apparatus for this purpose which operates according to the principle of communicating tubes there is provided the possibility of a good adhesion to the surface as well as the formation of a homogeneous layer at very little operating expense.
摘要翻译：先前进行的接触管的内部涂层不仅需要非常多的手工劳动，并且非常耗时，而且对于接触液体对表面的粘附和催化剂的均匀性也是不令人满意的。通过在液面降低期间在管中的液体界面上的热同时作用以及根据连通管的原理的特别适合的用于该目的的设备，提供了对表面以及以非常小的操作费用形成均匀的层。

74. 发明授权

US4444936A Bis-(silylethyl)-oligosulphides and process for their production 失效
标题翻译：双（甲硅烷基乙基） - 二硫化物及其生产方法
公开(公告)号：US4444936A
公开(公告)日：1984-04-24
申请号：US461432
申请日：1983-01-27
申请人： Rudolf Schwarz , Peter Kleinschmit , Christa Liedtke , Siegfried Wolff
发明人： Rudolf Schwarz , Peter Kleinschmit , Christa Liedtke , Siegfried Wolff
IPC分类号： C08L7/00 , C07F7/08 , C07F7/12 , C07F7/18 , C08G75/02 , C08G75/14 , C08K5/5425 , C08K5/548 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08K5/06
CPC分类号： C08K5/548 , C07F7/12 , C07F7/182 , C08G75/02 , C08G75/14
摘要： Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH.sub.2 .dbd.CH).sub.m --SiR.sub.n.sup.1 R.sub.4--(m+n) in which R represents chlorine, bromine, iodine, C.sub.1 --C.sub.3 -alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R.sup.1 represents C.sub.1 --C.sub.3 -alkyl, phenyl or C.sub.5 --C.sub.7 -cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100.degree. and 200.degree. C. under pressure of from 1 to 25 bars (total pressure at the reaction) temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.
摘要翻译：通过使式（CH2 = CH）m-SiRn1R4-（m + n）的乙烯基硅烷（其中R表示氯，溴，碘，C1-C3-烷氧基，2-甲基苯基）甲氧基乙氧基，2-乙氧基乙氧基或羟基，R1代表C1-C3-烷基，苯基或C5-C7-环烷基，n是0,1或2，m是1或2，m + n是1,2或3，以及在给定情况下，在约100至200℃的温度下，乙烯基硅烷与硫的摩尔比为1:2.5至1:10的硫化氢和乙烯基硅烷至硫化氢的摩尔比为1:0至1:5 在1至25巴（反应总压力）温度的压力下，在本身已知的硫化催化剂的存在下，在给定的情况下，随后水解或部分水解反应产物。双（甲硅烷基乙基） - 二硫化物用作含有硅酸盐填料的交联性橡胶混合物中的增强添加剂（粘合剂），在给定情况下用于炭黑以及在给定情况下硫和其它常规组分。

75. 发明授权

US4442040A Polymeric rhodium, iridium and ruthenium phosphine complex compounds, processes for their production and use 失效
标题翻译：聚合铑，铱和钌膦络合物，其生产和使用的方法
公开(公告)号：US4442040A
公开(公告)日：1984-04-10
申请号：US283868
申请日：1981-07-16
申请人： Peter Panster , Peter Kleinschmit
发明人： Peter Panster , Peter Kleinschmit
IPC分类号： C08G77/42 , B01J31/16 , B01J31/24 , B01J31/28 , C07F15/00 , C08G79/00
CPC分类号： C07F15/0013 , B01J31/1675 , B01J31/24 , B01J31/2404 , B01J2231/20 , B01J2231/321 , B01J2231/323 , B01J2231/52 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/827
摘要： The invention relates to complex compounds of rhodium, iridium or ruthenium with a silicic acid-like structure with a least one phosphine ligand, the trivalent phosphorus of which is bonded to silicon via at least one divalent organic residue, the remaining three valences of the silicon building, via oxygen bridges arising from the hydrolysis of functional substituents originally bound there, a inter- or intra-molecularly crosslinked polycondensate. The required charge equalization is effected by an anion. Also disclosed are processes for recovery of the polymeric complexes and their use in heterogeneous catalysis of various chemical reactions.
摘要翻译：本发明涉及具有硅酸结构的铑，铱或钌与具有至少一个膦配体的络合物，其三价磷通过至少一个二价有机残基与硅键合，剩余的三价硅通过由原来结合在其上的官能性取代基的水解产生的氧桥构建分子间或分子内交联的缩聚物。所需的电荷均衡由阴离子实现。还公开了回收聚合物络合物的方法及其在各种化学反应的多相催化中的用途。

76. 发明授权

US4390712A Aqueous solution of cationic organosilicon compounds and process for the production of the solutions 失效
标题翻译：阳离子有机硅化合物的水溶液及其制备方法
公开(公告)号：US4390712A
公开(公告)日：1983-06-28
申请号：US298251
申请日：1981-08-31
申请人： Alfons Karl , Wolfgang Buder , Peter Kleinschmit
发明人： Alfons Karl , Wolfgang Buder , Peter Kleinschmit
IPC分类号： B03D1/01 , C07F7/18 , C07F7/10
CPC分类号： C07F7/1892 , B03D1/0046 , B03D1/01
摘要： There are prepared aqueous solutions of cationic organosilicon compounds which are produced by reacting an alkoxysilylalkyl halide of the formula (RO).sub.3-n R.sub.n.sup.1 --Si--R.sup.2 --X (I) where R is C.sub.1 to C.sub.5 alkyl, methoxy, ethoxy, phenyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.1 is C.sub.1 to C.sub.5 alkyl, phenyl, tolyl, benzyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.2 is a divalent ethylenic double bond free hydrocarbon group having 3 to 8 carbon atoms, n is zero, 1 or 2 and X is chlorine, bromine, or iodine with a tertiary amine of the formula R.sup.3 NR.sup.4 R.sup.5 (II) where R.sup.3, R.sup.4, and R.sup.5 are the same or different and each is an alkyl group or benzyl in which the number of carbon atoms of the alkyl group or the alkyl groups together is up to 30 or R.sup.4 and .sup.5 together with the nitrogen atom, as well as in a given case a further hetero atom selected from the group consisting of oxygen, nitrogen, and sulfur is a univalent five to eight membered heterocyclic ring having three to seven --CH.sub.2 -- groups in the heterocyclic ring, or R.sup.5 is a C.sub.3 to C.sub.12 cycloalkyl group in aqueous medium at a temperature from room temperature (e.g. about 20.degree. C.) to 300.degree. C. at a mole ratio of (I) to (II) between 1:0.8 to 1:1,2 and in a given case under pressure.
摘要翻译：制备阳离子有机硅化合物的水溶液，其通过使式（RO）3-nRn1-Si-R2-X（I）的烷氧基甲硅烷基烷基卤化物反应制备，其中R是C1至C5烷基，甲氧基，乙氧基，苯基或 C5至C8环烷基; R 1是C 1至C 5烷基，苯基，甲苯基，苄基或C 5至C 8环烷基; R2是具有3-8个碳原子的二价烯键式双键无键烃基，n为0,1或2，X为氯，溴或碘，与式R3NR4R5（Ⅱ）的叔胺反应，其中R3，R4和 R5相同或不同，并且各自为烷基或苄基，其中烷基或烷基的碳原子数一起为至多30或R4和5以及氮原子以及在给定的在另一个选自氧，氮和硫的杂原子的情况下，杂环中具有三至七个-CH 2 - 基的一价五元至八元杂环，或者R5是水性中的C3至C12环烷基介质在室温（例如约20℃）至300℃的温度下以（I）至（II）的摩尔比为1:0.8至1:1.2，在给定情况下在压力下。

77. 发明授权

US4289741A Process for the production of hydrogen cyanide 失效
标题翻译：生产氰化氢的方法
公开(公告)号：US4289741A
公开(公告)日：1981-09-15
申请号：US133358
申请日：1980-03-24
申请人： Carl Voigt , Peter Kleinschmit , Eberhard Walter
发明人： Carl Voigt , Peter Kleinschmit , Eberhard Walter
IPC分类号： C01C3/02
CPC分类号： C01C3/0233
摘要： The known hydrocyanic acid-methane-ammonia (BMA) process for the production of hydrogen cyanide can now be carried out with liquified gases namely through the presence of additional hydrogen at the beginning of the reaction. The atomic ratio of carbon to nitrogen and hydrogen is from 1:1:7.1 to 1:1.33:13. As additional hydrogen there is the portion of hydrogen present coming out of the reaction "hydrocarbon+NH.sub.3 ". Otherwise the reaction conditions are the same as in the known BMA process.
摘要翻译：用于生产氰化氢的已知氢氰酸 - 甲烷 - 氨（BMA）方法现在可以用液化气体进行，即在反应开始时通过存在另外的氢气来进行。碳与氮和氢的原子比为1:1至7.1:1.33:1。作为另外的氢，存在从反应“烃+ NH 3”出来的部分氢。否则反应条件与已知的BMA方法相同。

78. 发明授权

US5389420A Heat insulator and method of making it 失效
标题翻译：绝热材料及其制作方法
公开(公告)号：US5389420A
公开(公告)日：1995-02-14
申请号：US983216
申请日：1992-11-30
申请人： Gerhard Sextl , Roland Reuter , Hans Strack , Peter Kleinschmit , Rudolf Schwarz
发明人： Gerhard Sextl , Roland Reuter , Hans Strack , Peter Kleinschmit , Rudolf Schwarz
IPC分类号： B32B7/02 , B32B5/16 , B32B27/08 , B65D81/18 , B65D81/38 , C04B14/36 , C04B38/00 , E04B1/80 , F16L59/00 , F16L59/02 , F25D23/06 , B32B1/04 , B32B3/02
CPC分类号： E04B1/80 , B32B5/16 , Y10T428/23 , Y10T428/231 , Y10T428/237 , Y10T428/239 , Y10T428/2933 , Y10T428/31746
摘要： A heat-insulator consisting ofa) A finely distributed, powdery or fibrous substance,b) A microporous casing andc) A gas- and watertight, metal-free casing.The heat insulator is manufactured by optionally drying the powdery or fibrous substance, optionally bringing it into a microporous casing, optionally pressing it and then optionally drying it. The powdery substance is then brought with the microporous casing into a gas- and watertight, metal-free casing. This gas- and watertight casing is optionally evacuated and sealed.
摘要翻译：由a）精细分布的粉末状或纤维状物质构成的隔热材料，b）微孔套管，c）气体和水密的无金属外壳。绝热体通过任选地干燥粉状或纤维状物质，任选地将其带入微孔外壳中，任选地将其压制，然后任选地将其干燥来制造。然后将粉状物质与微孔套管一起放入气密和无水密的无金属外壳中。该气密和防水套管可选择抽真空并密封。

79. 发明授权

US5340895A Formed, polymeric transition-metal complex catalysts with organosiloxane diphenylphosphine ligands 失效
标题翻译：形成的聚合物过渡金属络合物催化剂与有机硅氧烷二苯基膦配体
公开(公告)号：US5340895A
公开(公告)日：1994-08-23
申请号：US43604
申请日：1993-04-05
申请人： Peter Panster , Robert Gradl , Peter Kleinschmit
发明人： Peter Panster , Robert Gradl , Peter Kleinschmit
IPC分类号： C08G77/26 , B01J31/16 , B01J31/18 , B01J31/24 , B01J31/28 , C07C45/50 , C08G77/22 , C08G77/28 , C08G77/30 , C08G77/54 , C08G77/58 , C08G77/06
CPC分类号： C08G77/58 , B01J31/1608 , B01J31/1675 , B01J31/18 , B01J31/1805 , B01J31/2404 , C07C45/50 , C08G77/22 , C08G77/54 , B01J2231/20 , B01J2231/321 , B01J2231/323 , B01J2231/52 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/845 , B01J2531/847
摘要： Formed spherical polymeric complexes of metals of the 8th subgroup of the periodic system with ligands of an organosiloxane copolycondensate optionally cross-linked by means of cross-linking agents containing Si, Ti, Zr and/or Al (statistical, block-shaped or mixed). This copolycondensate consists of the units ##STR1## in which R.sup.1 -R.sup.4 =R.sup.5 -Si ##STR2## in which R.sup.5 =alkylene with C.sub.1 -C.sub.10 directly bound to P or N, cycloalkylene with C.sub.5 -C.sub.8 or ##STR3## The ratio between the number of moles of units (II) and the number of moles of bound metal atoms is 1:1 to 1.000 to 1 and the ratio between units (I) and (II) is preferably 10:90 to 95:5 mole %.The polymeric complex compounds are present macroscopically as spherical particles with a diameter of 0.01. to 3.0 mm, a BET surface of >0 to 1000 m.sup.2 /g, a specific pore volume of 0.01 to 6.5 ml/g, and a bulk density of 50 to 1000 g/l.Several methods of preparing the substance of the invention with special posttreatment stages and the use of the polymeric metal complexes as catalysts in organic chemistry are disclosed.
摘要翻译：通过含Si，Ti，Zr和/或Al的交联剂（统计学，块状或混合）任选地交联的有机硅氧烷共缩聚物的配体，形成周期系统的第8族金属的金属的球形聚合物络合物，。该共缩聚物由其中R1-R4 = R5-与P或N键合的单元（II）和C5-C8的亚环烷基或单元摩尔数（II）的r和结合的金属原子的摩尔数组成为1：1〜1.000〜1，单元（I）和（II）的比优选为10:90〜95:5摩尔％。聚合物络合物在宏观上作为直径为0.01的球形颗粒存在。 3.0mm，BET表面> 0〜1000m2 / g，比孔体积为0.01〜6.5ml / g，堆积密度为50〜1000g / l。公开了几种用特殊后处理阶段制备本发明物质的方法以及在有机化学中使用聚合物金属络合物作为催化剂。

80. 发明授权

US5318765A Monoclinic zirconium dioxide, method of its production and use 失效
标题翻译：单斜色二氧化锆，其生产和使用方法
公开(公告)号：US5318765A
公开(公告)日：1994-06-07
申请号：US842610
申请日：1992-02-27
申请人： Dieter Binder , Peter Kleinschmit , Hans Hoffmeister , Roland Reuter
发明人： Dieter Binder , Peter Kleinschmit , Hans Hoffmeister , Roland Reuter
IPC分类号： C01G25/02 , C04B35/486 , C04B35/48
CPC分类号： C04B35/486 , C01G25/02 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2006/12 , C01P2006/60 , C01P2006/62 , C01P2006/63 , C01P2006/64 , C01P2006/80
摘要： A monoclinic zirconium dioxide with an SiO.sub.2 content below 1.0% by weight is provided which is characterized by dendrite-shaped particles with an average grain size (d.sub.50 value) in a range of 0.5 .mu.m to 3.0 .mu.m and a specific surface (BET) in a range of 3 to 15 m.sup.2 /g. This zirconium dioxide is produced by thermally splitting zirconium silicate in a high-frequency- or medium-frequency induction melting furnace with sintering crust crucible, quenching the melt by blowing on a stream of melt with air and/or spraying it with water and leaching out the thermally split zirconium silicate with concentrated alkali lye at 100.degree. 200.degree. C. The zirconium dioxide of the invention provides a material with improved suitability for the production of zirconium silicate pigments of the host lattice type and inclusion type so as to provide for more color-intensive pigments.
摘要翻译：提供SiO 2含量低于1.0重量％的单斜二氧化锆，其特征在于平均粒径（d50值）在0.5μm至3.0μm范围内的树突状颗粒和比表面积（BET）在3至15m 2 / g的范围内。该二氧化锆是通过在具有烧结外壳的高频或中频感应熔化炉中热分解硅酸锆而制成的，通过用空气吹入熔融物流和/或用水喷洒熔融物并浸出本发明的二氧化锆提供了一种改进适用于生产主晶格型和夹杂物型的硅酸锆颜料的材料，从而提供更多的颜色密集颜料。

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