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71. 发明授权

US07361723B2 Low-viscosity allophanates containing actinically curable groups 有权
标题翻译：含有光化固化基团的低粘度脲基甲酸酯
公开(公告)号：US07361723B2
公开(公告)日：2008-04-22
申请号：US11080706
申请日：2005-03-14
申请人： Christophe Dètrembleur , Jan Weikard , Dorota Greszta-Franz , Frank Richter , Wolfgang Fischer , Jörg Schmitz , Holger Mundstock
发明人： Christophe Dètrembleur , Jan Weikard , Dorota Greszta-Franz , Frank Richter , Wolfgang Fischer , Jörg Schmitz , Holger Mundstock
IPC分类号： C08G18/18 , C08G18/67 , C08G18/78 , C08G18/79 , C09D175/16 , C08F2/46
CPC分类号： C08G18/7837 , B33Y70/00 , C08G18/1816 , C08G18/1875 , C08G18/672 , C08G18/798 , C09D175/16
摘要： A process for preparing binders containing allophanate groups which contain, at the oxygen atom of the allophanate group that is bonded via two single bonds, organic radicals with activated groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation; the process includes reacting A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and C) optionally further NCO-reactive compounds, and D) in the presence of one or more compounds containing phenoxide groups, as catalysts. The binders can be used in preparing coatings, coating materials, coating compositions, adhesives, printing inks, casting resins, dental compounds, sizes, photoresists, stereolithography systems, resins for composite materials and sealants.
摘要翻译：一种制备含有脲基甲酸酯基团的粘合剂的方法，其在通过两个单键键合的脲基甲酸酯基的氧原子上含有具有活化基团的活性基团，所述活性基团在与光化辐射接触时可与烯属不饱和化合物进行聚合反应; 该方法包括使A）一种或多种含有脲二酮基团的化合物与B）一种或多种OH官能化合物，其含有能够在暴露于光化辐射下与烯键式不饱和化合物进行聚合反应的基团，和C）任选地进一步的NCO- 活性化合物和D）在一种或多种含有酚氧化物的化合物的存在下作为催化剂。粘合剂可用于制备涂料，涂料，涂料组合物，粘合剂，印刷油墨，浇铸树脂，牙科化合物，尺寸，光致抗蚀剂，立体光刻系统，复合材料和密封剂的树脂。

72. 发明申请

US20070191570A1 Low viscosity allophanates containing actinically curable groups 有权
标题翻译：含有光化学可固化基团的低粘度脲基甲酸酯
公开(公告)号：US20070191570A1
公开(公告)日：2007-08-16
申请号：US11217727
申请日：2005-09-01
申请人： Jan Weikard , Frank Richter , Christoph Gurtler , Wolfgang Fischer , Jorg Schmitz , Holger Mundstock
发明人： Jan Weikard , Frank Richter , Christoph Gurtler , Wolfgang Fischer , Jorg Schmitz , Holger Mundstock
IPC分类号： C08G18/22
CPC分类号： C08G18/798 , C07C275/60 , C08G18/1825 , C08G18/1875 , C08G18/671 , C08G18/672 , C08G18/7837 , C08G18/8166 , C08G73/00 , C08L75/00 , C08L75/14 , C08L75/16 , C09D175/00 , C09D175/14 , C09D175/16
摘要： The present invention relates to a process for preparing radiation-curing binders containing allophanate groups by reacting at temperatures of ≦130° C. A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation, (radiation-curing groups), C) optionally NCO-reactive compounds other than B), in the presence D) a catalyst containing at least one tetrasubstituted ammonium or phosphonium salt of an aliphatic or cycloaliphatic carboxylic acid, to form allophanate groups by opening the uretdione ring. The present invention also relates to the binders obtained by the process of the invention.
摘要翻译：本发明涉及一种通过在<= 130℃的温度下反应制备含有脲基甲酸酯基的辐射固化粘合剂的方法。A）一种或多种含有脲二酮基团的化合物与B）一种或多种含OH官能化合物，在曝光于光化辐射下与烯键式不饱和化合物反应（辐射固化基团），C）任选除B）之外的NCO-反应性化合物，在存在的情况下D）含有至少一种四取代的铵或鏻盐的催化剂的脂族或脂环族羧酸，通过打开脲二酮环形成脲基甲酸酯基团。本发明还涉及通过本发明的方法获得的粘合剂。

73. 发明申请

US20070034588A1 Upper chord cross-section for telescopic parts of a crane 有权
标题翻译：起重机伸缩部件的上弦横截面
公开(公告)号：US20070034588A1
公开(公告)日：2007-02-15
申请号：US11481052
申请日：2006-07-06
申请人： Frank Richter , Enno Siebels , Rocco Staatz , Franz Paschke
发明人： Frank Richter , Enno Siebels , Rocco Staatz , Franz Paschke
IPC分类号： B66C23/04
CPC分类号： B66C23/701
摘要： An upper cross-sectional part for a telescopic part of a crane comprises a central flat cross-sectional element and, connected to the central flat cross-sectional element on each side thereof, a first outwardly curved cross-sectional element; a second flat cross-sectional element; a second outwardly curved cross-sectional element; and a third flat cross-sectional element.
摘要翻译：起重机的伸缩部分的上部横截面部分包括中心平坦的横截面元件，并且在其每侧与中心平坦的横截面元件连接有第一向外弯曲的横截面元件; 第二扁平横截面元件; 第二向外弯曲的横截面元件; 和第三扁平横截面元件。

74. 发明申请

US20060079694A1 Process for preparing polyisocyanates containing iminooxadiazinedione groups 有权
标题翻译：制备含有亚氨基恶二嗪二酮基团的多异氰酸酯的方法
公开(公告)号：US20060079694A1
公开(公告)日：2006-04-13
申请号：US11238375
申请日：2005-09-29
申请人： Frank Richter
发明人： Frank Richter
IPC分类号： C07D263/46
CPC分类号： C08G18/022 , C08G18/02 , C08G18/1883 , C08G18/7887
摘要： The present invention relates to process for preparing a polyisocyanate containing an iminooxadiazinedione group by trimerizing a portion of the isocyanate groups of a polyisocyanate, which does not contain iminooxadiazinedione groups, in the presence of a catalyst containing an anion corresponding to formula I) (Rf)n—CR′(3-n)—C(O)O− (I) wherein Rf is a perfluorinated C1-C30 radical which is optionally branched, cyclic and/or unsaturated, R′ are identical or different, optionally heteroatom-containing substituents selected from H, C1-C20 alkyl and/or aryl and n is 1 or 2.
摘要翻译：本发明涉及制备含有亚氨基恶二嗪二酮基团的多异氰酸酯的方法，该方法是在含有对应于式I）的α的阴离子的催化剂存在下，将不含有亚氨基恶二嗪二酮基团的多异氰酸酯的一部分异氰酸酯基团三聚 -line-formula description =“In-line Formulas”end =“lead”？>（R ^{f ）（I）<βin-line-formula description =“In-line Formulas”end =“tail”？>其中R f' SUP>是任选支链，环状和/或不饱和的全氟化C 1 -C 30基团，R'相同或不同，任选地含杂原子的取代基选自 H，C 1 -C 20烷基和/或芳基，n是1或2。}

75. 发明授权

US06797800B2 Method of dimerizing isophorone diisocyanate 失效
标题翻译：二异氰酸异佛尔酮二异氰酸酯的方法
公开(公告)号：US06797800B2
公开(公告)日：2004-09-28
申请号：US10144608
申请日：2002-05-13
申请人： Hans-Josef Laas , Reinhard Halpaap , Frank Richter , Jürgen Köcher
发明人： Hans-Josef Laas , Reinhard Halpaap , Frank Richter , Jürgen Köcher
IPC分类号： C08G1874
CPC分类号： C08G18/798 , C08G18/027
摘要： The invention relates to a method of preparing a polyisocyanate with at least one uretdione group by oligomerizing part of the isocyanate groups of isophorone diisocyanate in the presence of a catalyst which accelerates the dimerization of isocyanate groups, wherein the oligomerization catalyst comprises a saline compound comprising from 10 to 100 wt. % of 1,2,3- and/or 1,2,4-triazolate structures (calculated as C2N3; molecular weight=66) in the anion, and the products prepared by this method.
摘要翻译：本发明涉及一种通过在促进异氰酸酯基团二聚化的催化剂存在下使异佛尔酮二异氰酸酯的一部分异氰酸酯基团低聚来制备具有至少一个脲二酮基团的多异氰酸酯的方法，其中该低聚催化剂包括含有 10〜100重量％阴离子中1,2,3-和/或1,2,4-三唑酸酯结构的％（以C2N3计算;分子量= 66），以及通过该方法制备的产物。

76. 发明授权

US06520359B2 Lateral boom locking and actuating unit 失效
标题翻译：侧臂动臂锁定和执行单元
公开(公告)号：US06520359B2
公开(公告)日：2003-02-18
申请号：US09849993
申请日：2001-05-08
申请人： Frank Richter , Dieter Stuehrwoldt , Jens Ennen
发明人： Frank Richter , Dieter Stuehrwoldt , Jens Ennen
IPC分类号： B66C2304
CPC分类号： B66C23/705 , B66C23/708
摘要： A locking mechanism for telescoping sections, in particular for a mobile crane boom, includes a linearly shiftable locking bolt for connecting and releasing an inner telescoping section with respect to an outer telescoping section, said locking bolt being maintain ed biased in its extended position. The locking bolt is shifted by means of a rotary actuator from its extended position into its retracted position.
摘要翻译：用于伸缩部分的锁定机构，特别是用于移动式起重机吊杆的锁定机构包括用于相对于外部伸缩部分连接和释放内部伸缩部分的线性可移动锁定螺栓，所述锁定螺栓被保持偏压在其延伸位置。锁定螺栓通过旋转致动器从其延伸位置移动到其缩回位置。

77. 发明授权

US06515097B2 Blocked polyisocyanates based on HDI 有权
标题翻译：基于HDI的封闭多异氰酸酯
公开(公告)号：US06515097B2
公开(公告)日：2003-02-04
申请号：US10014041
申请日：2001-12-11
申请人： Frank Richter , Beate Baumbach , Christian Füssel
发明人： Frank Richter , Beate Baumbach , Christian Füssel
IPC分类号： C08G1880
CPC分类号： C08G18/792 , C08G18/09 , C08G18/168 , C08G18/7887 , C08G18/8064 , C08G2390/40 , Y10T428/31551
摘要： The present invention relates to blocked polyisocyanates which are the reaction product of polyisocyanate resins prepared from HDI and containing iminooxadiazinedione groups in an amount of at least 20 mol %, based on the total moles of iminooxadiazinedione and isocyanurate groups, with alcohols of formula (I) ROH (I), wherein R represents aliphatic, straight chain or branched, optionally cyclic, optionally substituted (O—R1, NR12), C1-C6 radicals, preferably C1-C4 radicals, and R1 has the same meaning as R. The present invention also relates to a process for the preparation of blocked polyisocyanates and to their use for the preparation of polyurethane plastics and coatings, preferably for coating substrates.
摘要翻译：本发明涉及封端的多异氰酸酯，它是由HDI制备并含有亚氨基恶二嗪二酮基团的多异氰酸酯树脂的反应产物，其量为至少20mol％，基于亚氨基恶二嗪二酮和异氰脲酸酯基团的总摩尔数，与式（I）的醇，其中R表示脂族，直链或支链，任选环状，任选取代的（O-R 1，NR 12），C 1 -C 6基团，优选C 1 -C 4基团，R 1具有与R相同的含义。本发明还涉及封端多异氰酸酯的制备及其用于制备聚氨酯塑料和涂料，优选用于涂覆基材的用途。

78. 发明授权

US6107484A Process for preparing polyisocyanates containing iminooxadiazinedione groups 有权
标题翻译：制备含有亚氨基恶二嗪二酮基团的多异氰酸酯的方法
公开(公告)号：US6107484A
公开(公告)日：2000-08-22
申请号：US320366
申请日：1999-05-25
申请人： Frank Richter , Stefan Groth , Eberhard Stelter , Wilfried Litz
发明人： Frank Richter , Stefan Groth , Eberhard Stelter , Wilfried Litz
IPC分类号： B01J31/02 , C07B61/00 , C07C265/14 , C07D251/34 , C07D273/04 , C08G18/02 , C08G18/16 , C08G18/78 , C08G18/79
CPC分类号： C08G18/022 , C07D251/34 , C07D273/04 , C08G18/166 , C08G18/7887 , C08G18/791
摘要： The present invention relates to a process for the production of trimerized polyisocyanates containing at least 30 mole % of iminooxadiazinedione groups (asymmetric trimers) in the trimer mixture by catalytically trimerizing a starting isocyanate selected from organic di- or polyisocyanates having a number average molecular weight of 140 to 600 and containing aliphatically, cycloaliphatically and/or araliphatically bound isocyanate groups in the presence of quaternary ammonium and phosphonium fluoride trimerization catalysts corresponding to the formulaR.sub.4 E.sup.+ F.sup.- (I),whereinE represents N or P andR represents identical or different, optionally branched, aliphatic, aromatic and/or araliphatic C.sub.1 -C.sub.20 groups, or two or more R groups may also form, with one another and with the nitrogen or phosphorus atom, saturated or unsaturated rings, in which the catalysts arei) present in pure form,ii) blended with solvating agents S for the fluoride anion, wherein S is selected from protic compounds having a pK.sub.a value of greater than 2 (determined in H.sub.2 O at 25.degree. C.) or oxalic acid, provided that the molar ratio of organic acid to fluoride ion, F.sup.-, does not exceed 20 and provided that S is not HF or an alcohol having a functionality of 2 or more, oriii) blended with water, wherein the molar ratio of water to fluoride ions (F.sup.-) does not exceed a value of 10.
摘要翻译：本发明涉及通过将起始异氰酸酯催化三聚化来制备三聚体多异氰酸酯的方法，所述多异氰酸酯在三聚体混合物中含有至少30摩尔％的亚氨基恶二嗪二酮基团（不对称三聚体），其起始异氰酸酯选自有机二异氰酸酯或数均分子量为 140至600，并且在对应于式R 4 E + F-（I）的季铵和氟化鏻三聚催化剂存在下含有脂族，环脂和/或芳烷基结合的异氰酸酯基团，其中E表示N或P且R表示相同或不同的，任选的支链，脂族，芳族和/或芳脂族C 1 -C 20基团，或两个或更多个R基团也可以彼此形成，并且与氮或磷原子形成饱和或不饱和环，其中i）存在于纯形式，ii）与氟化物阴离子的溶剂化物S共混，其中S选自质子化合物h 得到大于2的pKa值（在25℃下在H 2 O中测定）或草酸，条件是有机酸与氟离子F-的摩尔比不超过20，条件是S不是HF或官能度为2以上的醇，或iii）与水混合，其中水与氟离子（F-）的摩尔比不超过10。

79. 发明授权

US6090939A Process for preparing polyisocyanates containing iminooxadiazinedione groups 有权
标题翻译：制备含有亚氨基恶二嗪二酮基团的多异氰酸酯的方法
公开(公告)号：US6090939A
公开(公告)日：2000-07-18
申请号：US318537
申请日：1999-05-25
申请人： Frank Richter , Eberhard Stelter , Wilfried Litz , Stefan Groth
发明人： Frank Richter , Eberhard Stelter , Wilfried Litz , Stefan Groth
IPC分类号： B01J31/02 , C07B61/00 , C07C265/14 , C07D251/34 , C07D273/04 , C08G18/02 , C08G18/16 , C08G18/78 , C08G18/79 , C08G18/72
CPC分类号： C08G18/022 , C07D251/34 , C07D273/04 , C08G18/166 , C08G18/7887 , C08G18/791
摘要： The present invention relates to a process for the preparation of trimerized polyisocyanates that contain at least 30 mole % of iminooxadiazinedione groups (asymmetric trimers) in the trimer mixture, by catalytically trimerizing a starting isocyanate selected from organic di- or polyisocyanates having a number average molecular weight of 140 to 600 and containing aliphatically, cycloaliphatically and/or araliphatically bound isocyanate groups in the presence of a quaternary phosphonium polyfluoride trimerization catalyst corresponding to the formulaR.sub.4 P.sup.+ F.sup.- n(HF)whereinR represents identical or different, optionally branched aliphatic, aromatic and/or araliphatic C.sub.1 -C.sub.20 groups, or two or more R groups may also form, with one another and with the phosphorus atom, saturated or unsaturated rings andn has a value of 0.1 to 20.
摘要翻译：本发明涉及三聚体多异氰酸酯的制备方法，该三聚聚异氰酸酯在三聚体混合物中含有至少30摩尔％的亚氨基恶二嗪二酮基团（不对称三聚体），通过将起始异氰酸酯催化三聚化，所述起始异氰酸酯选自具有数均分子量的有机二异氰酸酯或多异氰酸酯重量为140至600，并且在对应于式R4P + Fn（HF）的季鏻多氟化物三聚催化剂存在下含有脂族，环脂和/或芳烃键合的异氰酸酯基团，其中R表示相同或不同的，任选支链的脂族，芳族和/ 或芳脂族C 1 -C 20基团，或两个或多个R基团也可以彼此形成，并且与磷原子一起形成饱和或不饱和环，并且n具有0.1至20的值。

80. 发明授权

US5882544A Polycyclic iminooxadiazinediones from (cyclo)aliphatic 1,4-diisocyanates 失效
标题翻译：（环）脂族1,4-二异氰酸酯的多环亚氨基恶二嗪二酸酯
公开(公告)号：US5882544A
公开(公告)日：1999-03-16
申请号：US989066
申请日：1997-12-11
申请人： Frank Richter , Dieter Mager , Josef Pedain
发明人： Frank Richter , Dieter Mager , Josef Pedain
IPC分类号： C07D498/04 , C08G18/00 , C08G18/79 , C08G101/00 , C09D175/04 , C09K3/12 , A61K31/535 , C07D267/14 , C07D273/04
CPC分类号： C07D498/04 , C08G18/79 , C08G2101/00 , C08G2150/20
摘要： The present invention relates to polycyclic iminooxadiazinediones A corresponding to formula I ##STR1## The present invention also relates to mixtures of these polycyclic iminooxadiazinediones with other isocyanate derivatives and to their use for the production of optionally foamed polyurethane plastics, for the production of paints and coatings and for the production or formulation of active ingredients, pharmaceutical products, etc.
摘要翻译：本发明涉及对应于式I的多环亚氨基恶二嗪二酮A（I）本发明还涉及这些多环亚氨基恶二嗪二酸与其它异氰酸酯衍生物的混合物及其用于生产任选发泡聚氨酯塑料的用途，用于生产油漆和涂料以及生产或配制活性成分，药品等。

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