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    • 73. 发明申请
    • Flowable Polyester Molding Compositions With Asa/Abs And San
    • 可流动的聚酯成型组合与Asa / Abs和San
    • US20080076859A1
    • 2008-03-27
    • US11659625
    • 2005-08-02
    • Andreas EipperBernd BruchmannCarsten WeissJean-Francois Stumbe
    • Andreas EipperBernd BruchmannCarsten WeissJean-Francois Stumbe
    • C08K3/34C08K3/26C08K5/09C08L51/00C08K5/17C08K3/30
    • C08L67/02C08G64/0216C08G64/183C08L25/12C08L51/04C08L101/005C08L2666/02
    • Thermoplastic molding compositions, comprising A) from 10 to 98.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 1 to 60% by weight of at least one graft polymer, composed of c1) from 20 to 80% by weight of a graft base composed of an elastomeric polymer based on alkyl acrylates having from 1 to 8 carbon atoms in the alkyl moiety and having a glass transition temperature below 10° C. c2) from 20 to 80% by weight of a graft composed of c21) from 60 to 95% by weight of styrene or of substituted styrenes of the general formula I where R is an alkyl radical having from 1 to 8 carbon atoms or a hydrogen atom, and R1 is an alkyl radical having from 1 to 8 carbon atoms, and n is 1, 2, or 3, and c22) from 5 to 40% by weight of at least one unsaturated nitrile, D) from 0 to 60% by weight of a copolymer composed of d1) from 60 to 95% by weight of styrene or of substituted styrenes of the general formula 1, or a mixture of these, d2) from 5 to 40% by weight of at least one unsaturated nitrile, E) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to E) is 100%.
    • 热塑性成型组合物,其包含A)10至98.99重量%的至少一种热塑性聚酯,B)0.01至50重量%的B1)至少一种高度支化或超支化的聚碳酸酯,其OH值为1至600 mg KOH / g聚碳酸酯(根据DIN 53240第2部分)或B2)至少一种高度支化或超支化的A x B B y Y y型聚酯,其中x为 至少1.1,y为至少2.1,或这些的混合物,C)1至60重量%的至少一种接枝聚合物,由C 1 O 3组成),20至80%由 接枝基质的重量由基于丙烯酸烷基酯的烷基部分中具有1至8个碳原子并具有低于10℃的玻璃化转变温度的丙烯酸烷基酯的弹性体聚合物组成。c 20 C 20 重量%的由c 21 C 21组成的接枝物),60至95重量%的苯乙烯或通式I的取代苯乙烯,其中R是具有1至8个碳原子的烷基或 一个 氢原子,R 1是具有1至8个碳原子的烷基,n是1,2或3,c 22)5至40 重量%的至少一种不饱和腈,D)0至60重量%的由d-1组成的共聚物),60至95重量%的苯乙烯或一般的取代苯乙烯 式1或这些的混合物,d 2/2)5至40重量%的至少一种不饱和腈,E)0至60重量%的其它添加剂,其中总计 组分A)至E)的重量百分比为100%。
    • 75. 发明授权
    • High-functionality polyisocyanates
    • 高官能度聚异氰酸酯
    • US07339020B2
    • 2008-03-04
    • US09811987
    • 2001-03-19
    • Bernd BruchmannHans RenzRainer KönigerUlrike EheUlrich TreulingRudolf Müller-Mall
    • Bernd BruchmannHans RenzRainer KönigerUlrike EheUlrich TreulingRudolf Müller-Mall
    • C08G18/10C08G18/72C08J9/04C07C269/02C07C271/06
    • C08G18/8022C09D175/04
    • High-functionality polyisocyanates are prepared by a process which comprises (i) preparation of an addition product (A) which contains one group which is reactive toward isocyanate and at least two isocyanate groups by reacting (a) a diisocyanate or polyisocyanate I with (b1) compounds having at least three groups which are reactive toward isocyanate or (b2) compounds containing two groups which are reactive toward isocyanate or mixtures of (b1) and (b2), where at least one of the components (a) or (b) has functional groups having differing reactivities toward the functional groups of the other component and the reaction ratio is selected so that the addition product (A) contains an average of one group which is reactive toward isocyanate, (ii) if desired, intermolecular addition reaction of the addition product (A) to form a polyaddition product (P) containing an average of one group which is reactive toward isocyanate and an average of more than two isocyanate groups, and (iii) reaction of the addition product (A) and/or the polyaddition product (P) with a diisocyanate or polyisocyanate II.
    • 通过以下方法制备高官能度多异氰酸酯:(i)通过使(a)二异氰酸酯或多异氰酸酯I与(b1)反应,制备含有一个对异氰酸酯和至少两个异氰酸酯基反应的基团的加成产物(A) )具有至少三个对异氰酸酯反应的基团的化合物或(b2)含有对异氰酸酯或(b1)和(b2)的混合物具有反应性的两个基团的化合物,其中至少一种组分(a)或(b) 具有与其他成分的官能团反应性不同的官能团,选择反应比,使加成产物(A)含有对异氰酸酯具有反应性的一个基团的平均值,(ii)如果需要,分子内加成反应 加成产物(A)形成含有平均一个对异氰酸酯反应的基团和平均多于两个异氰酸酯基团的加聚产物(P),和(iii)反应 加成产物(A)和/或加聚产物(P)与二异氰酸酯或多异氰酸酯II的离子。