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71. 发明授权

US4508913A Dialkoxymethyl-butyrolactones 失效
标题翻译：二烷氧基甲基丁内酯
公开(公告)号：US4508913A
公开(公告)日：1985-04-02
申请号：US520676
申请日：1983-08-05
申请人： Dieter Arlt
发明人： Dieter Arlt
IPC分类号： C07C69/65 , C07C51/00 , C07C51/093 , C07C53/19 , C07C53/50 , C07C57/52 , C07C57/76 , C07C67/00 , C07C69/757 , C07D307/33 , C07D407/04 , C07D307/32
CPC分类号： C07D307/33 , C07C51/093 , C07C53/19 , C07C53/50 , C07C57/76
摘要： The following process steps are shown: ##STR1## Intermediates I, II, and VI are new. End product IV is a known intermediate in the preparation of known pyrethroid-like cyclopropanecarboxylic acid ester insecticides.
摘要翻译：显示以下过程步骤：中间体I，II和VI是新的。终产物IV是已知的拟除虫菊酯类环丙烷羧酸酯类杀虫剂的制备中的已知中间体。

72. 发明授权

US4440955A Process for the preparation of 2,2-dimethyl-3-vinyl-cyclopropanecarboxylic acids and esters 失效
标题翻译： 2,2-二甲基-3-乙烯基 - 环丙烷羧酸和酯的制备方法
公开(公告)号：US4440955A
公开(公告)日：1984-04-03
申请号：US443840
申请日：1982-11-22
申请人： Manfred Jautelat , Dieter Arlt
发明人： Manfred Jautelat , Dieter Arlt
IPC分类号： C07C49/16 , B01J23/72 , B01J23/74 , B01J27/02 , B01J27/08 , B01J27/24 , B01J31/02 , B01J31/04 , B01J31/22 , C07C43/225 , C07C45/51 , C07C45/69 , C07C51/00 , C07C61/40 , C07C69/747
CPC分类号： C07C45/69 , C07C43/225 , C07C45/513 , C07C51/00
摘要： A process for the production of 2,2-dimethyl-3-vinyl-cyclopropanecarboxylic acid derivative of the formula ##STR1## in which R.sup.1 is a hydrogen atom, an alkyl group or a radical of an alcohol which can be used in pyrethroids, andX.sup.1 and X.sup.2 each independently is a halogen atom or a fluorine-substituted alkyl radical,comprising adding (a) a polyhalogenoalkene of the formula ##STR2## in which X.sup.3 and X.sup.4 each independently is a halogen atom,to 1-chloro-3,3-dimethyl-pent-4-en-2-one of the formula ##STR3## in the presence of a catalyst which yields free radicals, or in the presence of a metal salt of the VIII main group or of the sub-group IVa, VIIa or Ib of the periodic system, thereby to obtain a mixture of compounds of the formula ##STR4## (b) reacting either or both of such compounds with a base of the formula(R.sup.1 --O.sup..crclbar.).sub.n M.sup.n+in whichM is an alkali metal or alkaline earth metal, andn is 1 or 2.The end products are known insecticides and intermediates therefor, while the intermediates produced by (a) are novel compounds.
摘要翻译：制备式“IMAGE”的2,2-二甲基-3-乙烯基 - 环丙烷羧酸衍生物的方法，其中R 1是可用于拟除虫菊酯的氢原子，烷基或醇基，以及 X 1和X 2各自独立地为卤素原子或氟取代的烷基，其包括将（X3）和X4各自独立地为卤素原子的式（a）的多卤代烯烃加入到1-氯-3,3 在产生自由基的催化剂的存在下，或在VIII主族或亚组IVa的金属盐存在下，式“IMAGE”的2-二甲基 - 戊-4-烯-2-酮， VIIa或Ib化合物，从而得到下式化合物的混合物：（b）使这些化合物中的一种或两者与式（R1-O（ - ））nMn +的碱反应，其中M为碱金属或碱土金属，n为1或2.最终产物为已知的杀虫剂及其中间体，而中间体（a）产生的是新化合物。

73. 发明授权

US4399309A Preparation of 1-aryloxy-methyl ketones 失效
标题翻译： 1-芳氧基 - 甲基酮的制备
公开(公告)号：US4399309A
公开(公告)日：1983-08-16
申请号：US335942
申请日：1981-12-30
申请人： Manfred Jautelat , Jorg Stetter , Dieter Arlt
发明人： Manfred Jautelat , Jorg Stetter , Dieter Arlt
IPC分类号： C07C49/175 , C07C43/225 , C07C45/00 , C07C45/42 , C07C49/255 , C07C49/35 , C07C67/00 , C07C201/00 , C07C205/37 , C07C205/39 , C07C45/51
CPC分类号： C07C41/16 , C07C45/42
摘要： A process for the preparation of a 1-aryloxy-methyl ketone of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 each independently is hydrogen, optionally substituted alkyl, alkenyl, alkynyl or optionally substituted aryl, orR.sup.1 and R.sup.2 together are an alkylene chain,R.sup.4 each independently is halogen, alkyl, alkoxy, optionally substituted aryl or nitro, andn is 0, 1, 2 or 3,comprising hydrolyzing a 1-halogeno-2-aryloxy-1-alkene of the formula ##STR2## in which Hal is chlorine or bromine, under acidic conditions at a temperature from about 20.degree. to 150.degree. C. until it is about 95 to 100% complete, adding a base, and then bringing the reaction to completion under weakly alkaline conditions at about 20.degree. to 150.degree. C. Advantageously all stages of the reaction are effected in a single vessel at a temperature from about 40.degree. to 100.degree. C. and in the presence of an inert organic solvent, optionally in admixture with water as a solution or as a two-phase system, about 1 mol of a monobasic acid and 2 mols of alkali metal carbonate being employed per mol of the 1-halogeno-2-aryloxy-1-alkene. The end products are known intermediates for fungicides.
摘要翻译：制备式“IMAGE”的1-芳氧基甲基酮的方法，其中R 1，R 2和R 3各自独立地为氢，任选取代的烷基，烯基，炔基或任选取代的芳基，或者R 1和R 2一起是亚烷基链，R4各自独立地为卤素，烷基，烷氧基，任选取代的芳基或硝基，n为0,1,2或3，包括水解式IMAMA的1-卤代-2-芳氧基-1-烯烃，其中Hal为氯或溴，在酸性条件下，在约20℃至150℃的温度下，直到其完全达到约95-100％，加入碱，然后使反应在弱碱性条件下在约有利的是，反应的所有阶段在单一容器中在约40℃至100℃的温度下进行，并且在惰性有机溶剂的存在下，任选与水作为溶液的混合物或作为两相体系，约1摩尔一元酸每摩尔1-卤代-2-芳氧基-1-烯烃使用2摩尔碱金属碳酸盐。最终产品是已知的杀真菌剂中间体。

74. 发明授权

US4159324A Combating insects, acarids and nematodes with O-(1-fluoro-2-halo-ethyl)(thiono)phosphoric(phosphonic) acid ester-amides 失效
标题翻译：用O-（1-氟-2-卤代 - 乙基）（硫杂）磷酸（膦酸）酸酯 - 酰胺与昆虫，螨类和线虫抗性
公开(公告)号：US4159324A
公开(公告)日：1979-06-26
申请号：US806888
申请日：1977-06-15
申请人： Dieter Arlt , Hellmut Hoffmann , Bernhard Homeyer , Wolfgang Behrenz , Ingeborg Hammann
发明人： Dieter Arlt , Hellmut Hoffmann , Bernhard Homeyer , Wolfgang Behrenz , Ingeborg Hammann
IPC分类号： A01N57/26 , A01N57/28 , A01N57/32 , A01P5/00 , A01P7/02 , A01P7/04 , C07F9/24 , C07F9/26 , C07F9/44 , C07F9/59 , C07F9/6533 , A01N9/36 , C07F9/65
CPC分类号： C07F9/6533 , C07F9/2408 , C07F9/2458 , C07F9/591
摘要： O-(1-Fluoro-2-halo-ethyl)(thiono)phosphoric(phosphonic) acid ester-amides of the formula ##STR1## in which R and R.sup.1 independently represent hydrogen, alkyl, haloalkyl or cyanoalkyl, orR and R.sup.1 conjointly with the nitrogen atom form a heterocyclic ring which can optionally be interrupted by further hetero-atoms,R.sup.2 represents ##STR2## alkoxy, halogenalkoxy or alkyl, Hal represents chlorine or bromine, andX represents oxygen or sulphur, which possess insecticidal acaricidal and nematocidal properties.
摘要翻译：其中R和R 1独立地代表氢，烷基，卤代烷基或氰基烷基或R（R）的O-（1-氟-2-卤代乙基）（硫代）磷酸（膦酸）并且R 1与氮原子一起形成杂环，其可任选被其它杂原子间隔，R 2表示烷氧基，卤代烷氧基或烷基，Hal表示氯或溴，X表示氧或硫，其具有杀虫杀螨剂和杀线虫属性。

75. 发明授权

US4131724A Crosslinked acrylonitrile copolymers 失效
标题翻译：交联丙烯腈共聚物
公开(公告)号：US4131724A
公开(公告)日：1978-12-26
申请号：US797818
申请日：1977-05-18
申请人： Eduard Radlmann , Ulrich Reinehr , Peter Hoffmann , Dieter Arlt , Gunther Nischk
发明人： Eduard Radlmann , Ulrich Reinehr , Peter Hoffmann , Dieter Arlt , Gunther Nischk
IPC分类号： C08F8/00 , C08F8/30 , D01F6/38 , D01F6/54 , C07D85/36 , D01D5/14
CPC分类号： D01F6/54
摘要： The invention relates to a process for the production of crosslinked fibres or filaments by spinning an acrylonitrile copolymer containing at least 20 mVal of carboxyl groups per kg of polymer together with a polyoxazoline in a polar organic solvent and thereafter crosslinking at temperatures of from 120 to 190.degree. C.The invention also relates to crosslinked acrylonitrile fibres and filaments obtainable by this process.
摘要翻译：本发明涉及一种生产交联纤维或长丝的方法，该方法是通过将含有每千克聚合物至少20mV的羧基与聚恶唑啉一起在极性有机溶剂中纺丝的丙烯腈共聚物，然后在120至190℃的温度下进行交联 DEG C.

76. 发明授权

US4119715A Pesticidally active O-(1-fluoro-2-halogeno-ethyl)-thionophosphoric (phosphonic) acid esters 失效
标题翻译：杀虫活性O-（1-氟-2-卤代乙基） - 硫代磷酸（膦酸）酯
公开(公告)号：US4119715A
公开(公告)日：1978-10-10
申请号：US808227
申请日：1977-06-20
申请人： Hellmut Hoffmann , Dieter Arlt , Bernhard Homeyer , Ingeborg Hammann
发明人： Hellmut Hoffmann , Dieter Arlt , Bernhard Homeyer , Ingeborg Hammann
IPC分类号： A01N57/12 , A01N57/06 , A01N57/14 , A01N57/20 , C07F9/165 , C07F9/20 , C07F9/40 , C07F9/42 , A01N9/36
CPC分类号： C07F9/425 , A01N57/06 , C07F9/1651 , C07F9/20 , C07F9/4075
摘要： O-(1-Fluoro-2-halogeno-ethyl)-thionophosphoric (phosphonic) acid esters of the formula ##STR1## in which R is alkyl, phenyl or phenyl carrying at least one substituent selected from the group consisting of halogen, alkyl, alkylthio and nitro,R.sup.1 is alkyl or alkoxy, andHal is halogen,Which possess arthropodicidal and nematicidal properties.
摘要翻译：式（I）的O-（1-氟-2-卤代乙基） - 硫代磷酸（膦酸）酯，其中R是烷基，苯基或苯基，其携带至少一个选自卤素，烷基，烷硫基和硝基，R1是烷基或烷氧基，Hal是卤素，具有极性的抗坏血酸和碱性。

77. 发明授权

US4101569A Process for the preparation of 4,4'-dinitrodiphenyl carbonate 失效
标题翻译：制备4,4 {40-二硝基二苯基碳酸酯的方法
公开(公告)号：US4101569A
公开(公告)日：1978-07-18
申请号：US735715
申请日：1976-10-26
申请人： Jan Mazanek , Johannes Blahak , Dieter Arlt
发明人： Jan Mazanek , Johannes Blahak , Dieter Arlt
IPC分类号： C07C205/43 , C07C20060101 , C07C67/00 , C07C68/06 , C07C201/00
CPC分类号： C07C205/43
摘要： A process for preparing 4,4'-dinitro-diphenyl carbonate which comprises adding to a sulfuric acid solution of diphenyl carbonate maintained at a temperature between -40 and +40.degree. C a nitric acid in a stoichiometric or slight stoichiometric excess.
摘要翻译：制备4,4'-二硝基二苯基碳酸酯的方法，其包括在化学计量或略微化学计量过量的硝酸中将保持在-40至+ 40℃温度的碳酸二苯酯的硫酸溶液加入。

78. 发明授权

US3980738A Process for the preparation of (thio)phosphoric (phosphonic) acid esters 失效
标题翻译：制备（硫代）磷酸（膦酸）酯的方法
公开(公告)号：US3980738A
公开(公告)日：1976-09-14
申请号：US557725
申请日：1975-03-12
申请人： Dieter Arlt , Kurt Ley
发明人： Dieter Arlt , Kurt Ley
IPC分类号： C07F9/06 , C07F9/09 , C07F9/165 , C07F9/38 , C07F9/40 , C08K5/49
CPC分类号： C08K5/49 , C07F9/09 , C07F9/1651 , C07F9/4075
摘要： A process for the preparation of a (thio)phosphoric(phosphonic) acid ester of the formula ##EQU1## in which R.sub.1 is a straight-chain or branched alkyl, alkylmercapto or alkoxy group with up to 8 carbon atoms,R.sub.2 is alkyl with 1 to 8 carbon atoms optionally substituted by chlorine,R.sub.3, r.sub.4, r.sub.5 and R.sub.6 each independently is hydrogen or some other radical,X, y and Z each independently is oxygen or sulfur, andHal is chlorine or bromine,Which comprises reacting an olefin of the formula ##EQU2## in a one-step process with a halogenating agent and a (thio)phosphoric(phosphonic) acid ester of the formula ##EQU3##
摘要翻译：一种制备式XY-R2的（硫代）磷酸（膦酸）酯的方法，其中R 1是直链烷基，具有至多8个碳原子的直链或支链烷基，烷基巯基或烷氧基，R2是任选被氯取代的具有1至8个碳原子的烷基，R 3，R 4，R 5和R 6各自独立地是氢或一些其它基团X，Y和 Z各自独立地是氧或硫，Hal是氯或溴，其包含用卤化剂和（硫代）磷酸（一种或多种）的一步法包含反应式R3R5角C = C角度（II）R4R6的烯烃膦酸）酸酯，式XY-R2并列R1-P型角（III）Y-R2

79. 发明授权

US07981827B2 Chiral phosphanes for use in asymmetric syntheses 有权
标题翻译：用于不对称合成的手性磷烷
公开(公告)号：US07981827B2
公开(公告)日：2011-07-19
申请号：US12578904
申请日：2009-10-14
申请人： Dieter Arlt , Benjamin Meseguer
发明人： Dieter Arlt , Benjamin Meseguer
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J31/00 , B01J27/00
CPC分类号： B01J31/2409 , B01J2231/643 , B01J2231/645 , B01J2531/0266 , B01J2531/821 , C07B53/00 , C07F9/5027 , C07F9/5329 , C07F15/0046
摘要： The present invention relates to biarylbisphosphines and intermediates thereof. Furthermore, the scope of the invention encompasses catalysts which can be prepared from the bisarylphosphines and their use in asymmetric syntheses.
摘要翻译：本发明涉及双芳基双膦及其中间体。此外，本发明的范围包括可由双芳基膦制备的催化剂及其在不对称合成中的用途。

80. 发明授权

US07109344B2 Ruthenium catalyst 有权
标题翻译：钌催化剂
公开(公告)号：US07109344B2
公开(公告)日：2006-09-19
申请号：US11004113
申请日：2004-12-03
申请人： Dieter Arlt
发明人： Dieter Arlt
IPC分类号： C07F15/00 , C07F9/02 , B01J31/00
CPC分类号： C07F15/0046 , B01J31/2269 , B01J31/2273 , B01J2231/543 , B01J2531/822
摘要： The invention relates to new (pre)catalysts of ruthenium complexes of formula 1, wherein L1, X1, X′2, R1, R2, R3, Z and n are as defined in claim 1. The novel ruthenium complexes of formula 1 are convenient (pre)catalysts for metathesis reactions and can be applied i.e. for ring-closing metathesis, cross metathesis or ene-ine metathesis reactions.
摘要翻译：本发明涉及式1的钌络合物的新（预）催化剂，其中L 1，X 1，X 2，R 2， R 1，R 2，R 3，Z 3和Z 3如权利要求1中所定义。式1的新型钌络合物是方便的（预）用于复分解反应的催化剂，并且可以应用于闭环复分解，交叉复分解或烯化复分解反应。

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