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71. 发明授权

US08034735B2 Catalyst component for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：US08034735B2
公开(公告)日：2011-10-11
申请号：US12312592
申请日：2007-11-14
申请人： Masaki Fushimi , Maria Schmitt , Martin Schneider , Giampiero Morini
发明人： Masaki Fushimi , Maria Schmitt , Martin Schneider , Giampiero Morini
IPC分类号： C08F2/00 , B01J37/00 , B01J31/00
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/651 , C08F4/6494 , C08F2500/12 , C08F2500/18 , C08F210/08
摘要： A catalyst component for the polymerization of olefins comprises Mg, Ti, halogen, and an alpha-omega-diether represented by the general formula: (RO)—(CR1R2)n—(OR), wherein the number of n is from 5 to 10, R is an alkyl, cycloalkyl or aryl radical containing 1 to 12 carbons, and R1 and R2 are independently from each other hydrogen, an alkyl, cycloalkyl or aryl radical containing 1 to 12 carbons. The catalysts prepared with such component provide a high mileage for the production of polyolefins with a high bulk density of the polymer produced in gas-phase polymerization process or in slurry polymerization process. Such catalyst produces narrower MWD PE, if compared with other catalyst systems.
摘要翻译：用于烯烃聚合的催化剂组分包括由通式（RO） - （CR 1 R 2）n - （OR）表示的Mg，Ti，卤素和α-ω-二醚，其中n的数目为5〜 10，R为含有1至12个碳的烷基，环烷基或芳基，R 1和R 2彼此独立地为氢，含有1至12个碳的烷基，环烷基或芳基。用这种组分制备的催化剂为在气相聚合法或淤浆聚合方法中生产的聚合物的高堆积密度的聚烯烃的生产提供了很高的里程。如果与其他催化剂体系相比，这种催化剂产生较窄的MWD PE。

72. 发明授权

US07999047B2 Magnesium methoxide based catalyst precursors and catalyst components obtained therefrom 有权
标题翻译：基于甲醇镁的催化剂前体和由其获得的催化剂组分
公开(公告)号：US07999047B2
公开(公告)日：2011-08-16
申请号：US12311079
申请日：2007-09-18
申请人： Dario Liguori , Giampiero Morini
发明人： Dario Liguori , Giampiero Morini
IPC分类号： C08F4/50
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F4/6548 , C08F2500/12 , C08F2500/18
摘要： Catalyst precursors comprising Mg, Ti, OMe and OR groups that are in molar ratios defined by the formula MgTin(OMe)(p)(OR)x in which n is from 0.1 to 1, p is ≧(2+4n), x is from 0 to 1 and R is C2-C15 hydrocarbon groups can be easily transformed, with high yields, in solid catalyst components to be advantageously used in the polymerization of both ethylene and alpha olefins.
摘要翻译：包含Mg，Ti，OMe和OR基团的催化剂前体，其摩尔比由式MgTin（OMe）（p）（OR）x定义，其中n为0.1至1，p为≥（2 + 4n），x 0至1，并且R是C 2 -C 15烃基可以容易地以高收率转化成固体催化剂组分，以有利地用于乙烯和α-烯烃的聚合。

73. 发明申请

US20110092656A1 CATALYST SYSTEM FOR THE POLYMERIZATION OF OLEFINS 有权
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：US20110092656A1
公开(公告)日：2011-04-21
申请号：US12996683
申请日：2009-06-08
申请人： Masaki Fushimi , Gerhardus Meier , Maclovio Herrera Salinas , Martin Schneider , Giampiero Morini
发明人： Masaki Fushimi , Gerhardus Meier , Maclovio Herrera Salinas , Martin Schneider , Giampiero Morini
IPC分类号： C08F2/34 , B01J31/14 , B01J35/10
CPC分类号： C08F10/02 , C08F4/6493
摘要： The present invention relates to catalysts systems for the polymerization of olefins CH2═CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising (A) a solid catalyst component comprising Ti, Mg, and halogen (B) an aluminum alkyl compound and (C) a mono or dihalogenated hydrocarbon compound. Said catalyst systems have improved polymerization activity.
摘要翻译：本发明涉及用于烯烃CH 2 = CHR聚合的催化剂体系，其中R是具有1-12个碳原子的烷基，环烷基或芳基，其包含（A）包含Ti，Mg和卤素（B ）烷基铝化合物和（C）单或二卤化烃化合物。所述催化剂体系具有改善的聚合活性。

74. 发明授权

US07544748B2 Components and catalysis for the polymerization of olefins 有权
标题翻译：烯烃聚合的组分和催化剂
公开(公告)号：US07544748B2
公开(公告)日：2009-06-09
申请号：US11547111
申请日：2005-03-08
申请人： Yuri Gulevich , Giulio Balbontin , Giampiero Morini , Ilya Nifant'ev
发明人： Yuri Gulevich , Giulio Balbontin , Giampiero Morini , Ilya Nifant'ev
IPC分类号： C08F4/642
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651
摘要： The present invention relates to a solid catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from β-keto-ester derivatives of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.
摘要翻译：本发明涉及一种用于烯烃CH2-CHR聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和选自β-酮酯的电子给体具体公式的衍生物。当用于烯烃聚合，特别是丙烯时，所述催化剂组分能够以高产率和高二甲苯不溶性表现的高全同立构指数得到聚合物。

75. 发明申请

US20080132661A1 Catalyst System for the Polymerization of Olefins 审中-公开
标题翻译：烯烃聚合催化剂体系
公开(公告)号：US20080132661A1
公开(公告)日：2008-06-05
申请号：US10547658
申请日：2004-02-24
申请人： Vincenzo Busico , Mauro Guardasole , Roberta Cipullo , Luigi Resconi , Giampiero Morini
发明人： Vincenzo Busico , Mauro Guardasole , Roberta Cipullo , Luigi Resconi , Giampiero Morini
IPC分类号： C08F4/52 , C07F5/02 , C07F7/00 , C07F17/00
CPC分类号： C08F10/00 , C07F5/027 , C07F7/1804 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/70 , C08F4/65908 , C08F2500/03 , C08F2500/20 , C08F210/08
摘要： A heterogeneous catalyst component obtainable by contacting: (a) a solid Lewis acid of formula MR1a wherein M is a metal of group 1-12 of the Periodic Table of the Elements; R1 is a fluorine, chlorine, bromine or iodine atom; and a is equal to the valence of the metal M; and (b) at least one ionic compound of formula (I) [((T)pR2)nMI(R3)m]−[D]+(I) wherein: MI is an element belonging to group 13 of the Periodic Table of the Elements; R3, equal to or different from each other, are halogen atoms, halogenated C6-C20 aryl and halogenated C7-C20 alkylaryl groups; two R1 groups, can also form with the element M one condensed ring; R2, equal to or different from each other, are hydrocarbon groups; T is a Lewis base in its neutral form; n ranges from 1 to 4; m ranges from 0 to 3; and m+n=4; p ranges from 1 to 10; and [D]+ is a monovalent cation.
摘要翻译：通过使以下物质接触获得的非均相催化剂组分：（a）式M1的固体路易斯酸其中M是周期表第1-12族的金属，元素; R 1是氟，氯，溴或碘原子; a等于金属M的化合价; 和（b）至少一种式（I）的离子化合物[（（T） P （I）其中：M （R 3） SUP> I 是属于元素周期表第13族的元素; R 3彼此相同或不同，为卤素原子，卤代C 6 -C 20芳基和卤代C 7 C 20 -C 20烷基芳基; 两个R 1个基团也可以与元素M形成一个稠环; R 2彼此相同或不同的是烃基; T是其中性形式的路易斯碱; n范围从1到4; m范围从0到3; 和m + n = 4; p范围从1到10; 和[D] ^{+ 是一价阳离子。}

76. 发明申请

US20050171379A1 Separation of diastereoisomers 有权
标题翻译：非对映异构体的分离
公开(公告)号：US20050171379A1
公开(公告)日：2005-08-04
申请号：US10499273
申请日：2002-12-20
申请人： Giampiero Morini , Fabrizio Piemontesi , Antonio Cristofori , Stefania Milani
发明人： Giampiero Morini , Fabrizio Piemontesi , Antonio Cristofori , Stefania Milani
IPC分类号： C07C67/56 , C07B57/00 , C07C41/40 , C07C41/44 , C07C41/46 , C07C67/52 , C07C67/58 , C07C67/60 , C07C69/34 , C07C51/353
CPC分类号： C07B57/00
摘要： Process for modifying the relative ratios of the components of a liquid starting mixture of specific diastereoisomers, containing at least two asymmetric carbon atoms comprising contacting said liquid mixture with a Lewis acid compound capable of co-ordinating said specific diastereoisomers and subjecting the resulting mixture to conditions such that a reaction product, having a molar ratio between its diastereoisomeric components different from the corresponding molar ratio in the said liquid starting mixture, becomes separated from the said liquid mixture, said process being carried out using an amount of said Lewis acid not enough to co-ordinate the total amount of the diastereoisomeric components of the liquid starting mixture. This method shows an excellent balance of efficiency and easiness of procedure that cannot be reached with the physical methods of diastereoisomers separation known in the art.
摘要翻译：用于改变含有至少两个不对称碳原子的特定非对映异构体的液体起始混合物的组分的相对比例的方法，包括使所述液体混合物与能够协调所述特定非对映异构体的路易斯酸化合物接触，并将所得混合物进行条件使得具有与所述液体起始混合物中的相应摩尔比不同的非对映异构体的摩尔比的反应产物与所述液体混合物分离，所述方法使用一定量的所述路易斯酸进行，所述量不足以统计液体起始混合物的非对映异构体组分的总量。该方法显示出与本领域已知的非对映异构体分离的物理方法无法达到的效率和程序容易性的极好的平衡。

77. 发明申请

US20050131172A1 Propylene polymers 有权
标题翻译：丙烯聚合物
公开(公告)号：US20050131172A1
公开(公告)日：2005-06-16
申请号：US10965543
申请日：2004-10-14
申请人： Giampiero Morini , Giulio Balbontin
发明人： Giampiero Morini , Giulio Balbontin
IPC分类号： C08F4/651 , C08F4/654 , C08F10/00 , C08F4/44
CPC分类号： C08F10/00 , C08F4/651 , C08F4/6545
摘要： The present invention relates to catalyst components for the polymerization of olefins comprising Mg, Ti, halogen and at least two electron donor compounds, said catalyst component being characterized by the fact that at least one of the electron donor compounds, present in an amount from 20 to 50% by mol with respect to the total amount of donors, is selected from esters of succinic acids which are not extractable, for more than 25% by mol and at least another electron donor compound which is extractable, for more than 35%. The said catalyst component-are capable to give polymers with high xylene insolubility, high stereoblock content and broad MWD suitable for making the polymers usable in the BOPP sector.
摘要翻译：本发明涉及包含Mg，Ti，卤素和至少两种电子给体化合物的烯烃聚合的催化剂组分，所述催化剂组分的特征在于至少一种电子给体化合物的存在量为20 相对于供体总量为50摩尔％，选自不可提取的琥珀酸的酯，超过25摩尔％的至少另一种可提取的电子给体化合物，超过35％。所述催化剂组分 - 能够产生具有高二甲苯不溶性，高立体嵌段含量和宽MWD的聚合物，其适合于使聚合物可用于BOPP部分。

78. 发明申请

US20050080290A1 Process for preparing alkylidene-substituted-1, 4-dions derivatives 失效
标题翻译：制备亚烷基取代-1,4-元素衍生物的方法
公开(公告)号：US20050080290A1
公开(公告)日：2005-04-14
申请号：US10491560
申请日：2003-07-09
申请人： Yuri Gulevich , Giampiero Morini
发明人： Yuri Gulevich , Giampiero Morini
IPC分类号： C07C67/347 , C07C67/343 , C07C69/593 , C07C69/602 , C07C233/49 , C07C45/68 , C07C57/13
CPC分类号： C07C67/343 , C07C69/593 , C07C69/602
摘要： A process for the preparation of an monoalkylidene substituted 1,4-dions derivatives of formula (Ia) or (Ib) or a mixture of (Ia) and (Ib): wherein: R1, R2 and R3, equal to or different from each other, are hydrogen atoms or C1-C20 hydrocarbon groups: T1 and T2, equal to or different from each other, are OR4. R4, NR42, SR4 or PR42; or T1 and T2 can be fused in an oxygen atom or a NR4 group; said process comprises the step of reacting a compound of formula (II), with a compound of formula (IIIa) or (IIIb), in the presence of at least one equivalent with respect to the compound of formula (IIIa) or (IIIb) of a salts of a base or a neutral base at a temperature higher than 70° C.
摘要翻译：制备式（Ia）或（Ib）的单亚烷基取代的1,4-二醇衍生物或（Ia）和（Ib）的混合物的方法：其中：R 1，R 2和R 4， 3>彼此相同或不同的是氢原子或C 1 -C 20烃基：T 1和T 2彼此相同或不同，为OR 4。 R 4，NR 4，SR 4或PR 4; 或T 1和T 2可以稠合在氧原子或NR 4基团中; 所述方法包括使式（II）化合物与式（IIIa）或（IIIb）化合物在相对于式（IIIa）或（IIIb）化合物的至少一当量存在下反应的步骤，的碱或中性碱的盐在高于70℃的温度下进行。

79. 发明授权

US06825309B2 Catalyst components for the polymerization of olefins 有权
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：US06825309B2
公开(公告)日：2004-11-30
申请号：US10149306
申请日：2002-06-10
申请人： Giampiero Morini , Giulio Balbontin
发明人： Giampiero Morini , Giulio Balbontin
IPC分类号： C08F11006
CPC分类号： C08F10/00 , C08F4/651 , C08F4/6545
摘要： The present invention relates to catalyst components for the polymerization of olefins comprising Mg, Ti, halogen and at least two electron donor compounds, said catalyst component being characterized by the fact that at least one of the electron donor compounds, present in an amount from 20 to 50% by mol with respect to the total amount of donors, is selected from esters of succinic acids which are not extractable, for more than 25% by mol and at least another electron donor compound which is extractable, for more than 35%. The said catalyst component are capable to give polymers with high xylene insolubility, high stereoblock content and broad MWD suitable for making the polymers usable in the BOPP sector.
摘要翻译：本发明涉及包含Mg，Ti，卤素和至少两种电子给体化合物的烯烃聚合的催化剂组分，所述催化剂组分的特征在于至少一种电子给体化合物的存在量为20 相对于供体总量为50摩尔％，选自不可提取的琥珀酸的酯，超过25摩尔％的至少另一种可提取的电子给体化合物，超过35％。所述催化剂组分能够产生具有高二甲苯不溶性，高立体嵌段含量和宽MWD的聚合物，其适用于使聚合物可用于BOPP部分。

80. 发明授权

US06699814B2 Catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US06699814B2
公开(公告)日：2004-03-02
申请号：US10455898
申请日：2003-06-06
申请人： Giampiero Morini , Giulio Balbontin , Yuri V. Gulevich
发明人： Giampiero Morini , Giulio Balbontin , Yuri V. Gulevich
IPC分类号： C08F4649
CPC分类号： C08F10/06 , C07C69/63 , C08F4/6365 , C08F4/651
摘要： The present invention relates to catalysts particularly suitable for the sterospecific polymermerization of olefins, comprising Ti, Mg, halogen and an electron donor compound selected from heteroatoms containing esters of malonic acids. Polymers produced by the catalysts have high isotactic index expressed in terms of high xylene insolubility.
摘要翻译：本发明涉及特别适用于包含Ti，Mg，卤素和选自含有丙二酸酯的杂原子的电子给体化合物的烯烃的固相特异性聚酯化的催化剂。由催化剂生产的聚合物具有高的二甲苯不溶性高的全同立构指数。

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