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    • 72. 发明授权
    • Durable and scratch-resistant anti-reflective articles
    • 耐用且耐刮擦的防反光制品
    • US09335444B2
    • 2016-05-10
    • US14706505
    • 2015-05-07
    • CORNING INCORPORATED
    • Shandon Dee HartKarl William Koch, IIICharles Andrew PaulsonJames Joseph Price
    • G02B1/11G02B1/14G02B5/02
    • G02B1/115C03C17/3435C03C21/002C03C2217/734C03C2217/78G02B1/11G02B1/14G02B1/18G02B5/0221G02B5/0278G02B27/0025
    • Embodiments of durable, anti-reflective articles are described. In one or more embodiments, the article includes a substrate and an optical coating disposed on the major surface. The optical coating includes an anti-reflective coating and a scratch-resistant coating forming an anti-reflective surface. The article exhibits a maximum hardness of 12 GPa or greater, as measured on the anti-reflective surface by a Berkovich Indenter Hardness Test along an indentation depth of about 100 nm or greater. The articles of some embodiments exhibit a single side average light reflectance measured at the anti-reflective surface of about 8% or less over an optical wavelength regime in the range from about 400 nm to about 800 nm and a reference point color shift in transmittance or reflectance of less than about 2. In some embodiments, the article exhibits an angular color shift of about 5 or less at all angles from normal incidence to an incident illumination angle that is 20 degrees or greater.
    • 描述了耐用的抗反射制品的实施例。 在一个或多个实施例中,制品包括设置在主表面上的基底和光学涂层。 光学涂层包括形成抗反射表面的抗反射涂层和耐刮擦涂层。 通过Berkovich压头硬度试验在约100nm或更大的压痕深度下,在抗反射表面上测量的最大硬度为12GPa或更高。 一些实施例的制品在约400nm至约800nm范围内的光波长范围内在抗反射表面测量的单侧平均光反射率为约8%或更小,透射率的参考点颜色偏移或 反射率小于约2.在一些实施例中,制品在从法向入射到20度或更大的入射照明角度的所有角度处呈现约5或更小的角度色偏。
    • 73. 发明申请
    • SCRATCH-RESISTANT MATERIALS AND ARTICLES INCLUDING THE SAME
    • 耐切割材料和包括它的文章
    • US20160083835A1
    • 2016-03-24
    • US14812562
    • 2015-07-29
    • CORNING INCORPORATED
    • Kaveh AdibRobert Alan BellmanCharles Andrew PaulsonJames Joseph Price
    • C23C16/30C23C16/40C23C16/32C23C16/34C23C16/36
    • C23C16/308C23C16/30C23C16/325C23C16/345C23C16/36C23C16/402
    • Embodiments of this disclosure pertain to a coating material comprising silicon and/or aluminum, hydrogen and any two or more of oxygen, nitrogen, carbon, and fluorine. The coating material exhibits a hardness of about 17 GPa or greater and an optical band gap of about 3.5 eV or greater. In some embodiments, the coating material includes, in atomic %, silicon and/or aluminum in an amount of about 40 or greater, hydrogen in an amount in the range from about 1 to about 25, nitrogen in an amount of about 30 or greater, oxygen in an amount in the range from about 0 to about 7.5, and carbon in an amount in the range from about 0 to about 10. The coating material may optionally include fluorine and/or boron. Articles including the coating material are also described and exhibit an average transmittance of about 85% or greater over an optical wavelength regime in the range from about 380 nm to about 720 nm and colorlessness.
    • 本公开的实施方案涉及包含硅和/或铝,氢和氧,氮,碳和氟中的任何两种或更多种的涂料。 涂层材料表现出约17GPa或更大的硬度和约3.5eV或更大的光学带隙。 在一些实施方案中,涂层材料以原子%包含约40或更大量的硅和/或铝,其量为约1至约25,氮为约30或更大 ,量为约0至约7.5的量的氧,以及约0至约10的量的碳。涂层材料可任选地包括氟和/或硼。 还描述了包括涂料的制品,并且在约380nm至约720nm范围内的光波长范围内呈现约85%或更大的平均透射率和无色性。