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71. 发明专利

AU2003276258A1 SUPPORTED CATALYST CONTAINING RHENIUM AND METHOD FOR HYDROGENATION OF CARBONYL COMPOUNDS IN LIQUID PHASE BY MEANS OF SAID CATALYST 未知
公开(公告)号：AU2003276258A1
公开(公告)日：2004-06-03
申请号：AU2003276258
申请日：2003-11-06
申请人： BASF AG
发明人： SCHUBERT MARKUS , HESSE MICHAEL , FISCHER ROLF-HARTMUTH , CONSTANTINESCU TAKE
IPC分类号： B01J21/18 , B01J23/00 , B01J23/656 , B01J23/68 , B01J23/84 , B01J23/889 , B01J35/00 , B01J37/02 , C07D307/08 , C07D307/33 , C07D315/00
摘要： A supported rhenium containing catalyst (I) contains a further metal from Group 8 or 1b, preferably ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os,) iridium (Ir), platinum (Pt), copper (Cu), silver (Ag) or cobalt (Co) in the form of at least one bimetallic precursor compound applied to the support. An Independent claim is also included for a process for the production of mixtures of tetrahydrofuran and gamma-butyrolactone by catalytic hydrogenation of carbonyl compounds using the catalyst (I).

72. 发明专利

CA2546327C METHOD OF STORING AND RELEASING GASES IN A CONTROLLED MANNER USING AN ELECTROCHEMICALLY PREPARED CRYSTALLINE POROUS METAL-ORGANIC FRAMEWORK 未知
公开(公告)号：CA2546327C
公开(公告)日：2013-09-03
申请号：CA2546327
申请日：2004-11-24
申请人： BASF AG
发明人： MUELLER ULRICH , PUETTER HERMANN , HESSE MICHAEL , WESSEL HELGE , HUFF JUERGEN , GUZMANN MARCUS , SCHUBERT MARKUS
IPC分类号： C01B3/00 , C25B3/13 , B01J20/22 , B01J20/28 , B01J31/16 , B01J31/18 , B01J31/22 , C01B32/40 , C01B32/50 , H01M8/04
摘要： The present invention relates to a method of absorbing and/or storing gases, in which the gas to be stored is brought into contact with an electrochemically prepared metal-organic framework under conditions suitable for absorption of the gas, with absorption of the gas into the metal-organic framework occurring, and, if appropriate, the conditions are subsequently changed so that release of the stored gas occurs.

73. 发明专利

CA2640294A1 PROCESS FOR PREPARING POROUS METAL-ORGANIC FRAMEWORK MATERIALS 未知
公开(公告)号：CA2640294A1
公开(公告)日：2008-08-16
申请号：CA2640294
申请日：2007-02-05
申请人： BASF AG
发明人： SCHUBERT MARKUS , MULLER ULRICH , DIEHLMANN UWE , HESSE MICHAEL
IPC分类号： C07C51/41 , B01J20/26 , C07C63/307 , C07F3/00
摘要： The present invention relates to a method for producing a porous metal-organic framework material comprising the step reacting a reaction mixture in the liquid phase of at least one copper compound having at least one at least bidentate, organic compound which can bind by coordination to the copper in the presence of a nonaqueous solvent, the at least one at least bidentate, organic compound being derived from a polycarboxylic acid having at least three carboxyl groups, and the reaction proceeding at atmospheric pressure above 80° C.

74. 发明专利

CA2666481A1 ALUMINUM NAPHTHALENEDICARBOXYLATE AS A POROUS METAL-ORGANIC FRAMEWORK MATERIAL 未知
公开(公告)号：CA2666481A1
公开(公告)日：2008-05-08
申请号：CA2666481
申请日：2007-10-24
申请人： BASF AG
发明人： SCHUBERT MARKUS , MUELLER ULRICH , MARX STEFAN , KIENER CHRISTOPH , KRENNRICH GERHARD , BROWN JAMES REUBEN
IPC分类号： B01J20/22 , B01J20/26 , B01J31/16 , C01B3/00 , C01B32/50 , F17C11/00
摘要： The present invention relates to a porous organometallic framework materi al comprising a bidentate organic compound bound coordinatively to a metal i on, where the metal ion is Al3+ and the bidentate compound is 2,6-naphthalen edicarboxylate. The invention further relates to moldings comprising such a framework material, to processes for producing the framework material and to the use of the framework material or of the proposed molding.

75. 发明专利

DE502005002594D1 未知
公开(公告)号：DE502005002594D1
公开(公告)日：2008-03-06
申请号：DE502005002594
申请日：2005-08-06
申请人： BASF AG
发明人： SIGL MARCUS , SCHUBERT MARKUS , STEPHAN JUERGEN , PAPP RAINER , POPLOW FRANK
IPC分类号： C10G45/40 , C07C6/04 , C07C45/50
摘要： Processes for preparing a C5 aldehyde and propene are disclosed, the processes comprising: (a) providing a feedstream, the feedstream comprising butane, 1-butene, 2-butene and 1,3-butadiene, the 1,3-butadiene present in the feedstream in an amount up to 1000 ppm; (b) contacting the feedstream with hydrogen and carbon monoxide in the presence of a hydroformylation catalyst to form a 2-butene-rich butane stream and a C5 aldehyde; (c) separating the 2-butene-rich butane stream and the C5 aldehyde; and (d) contacting the 2-butene-rich butane stream with ethene in the presence of a metathesis catalyst to form a propene-containing hydrocarbon stream.

76. 发明专利

CA2658757A1 PROCESS FOR PREPARING COPPER-COMPRISING METAL ORGANIC FRAMEWORKS 未知
公开(公告)号：CA2658757A1
公开(公告)日：2008-01-31
申请号：CA2658757
申请日：2007-07-13
申请人： BASF AG
发明人： TONIGOLD MARKUS , MULLER ULRICH , KIENER CHRISTOPH , OZKIRIM FARUK , SCHUBERT MARKUS
IPC分类号： C07F1/00
摘要： The present invention relates to methods for producing a porous, organome tallic framework material containing a first and at least one second at leas t bidentate organic compound coordinatively bound to at least one copper ion , including the following steps: (a) Reaction of a reaction mixture in the l iquid phase containing at least one copper compound and the first at least b identate organic compound with formation of a complex intermediate containin g at least one copper ion and the first at least bidentate organic compound, wherein the first at least bidentate organic compound derives from a dicarb oxylic acid and has a hydrocarbon framework, and (b) Reaction of the complex intermediate with the at least second at least bidentate organic compound, wherein the at least second at least bidentate organic compound is an option ally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbon atoms are replaced by heteroa toms selected from the group consisting of N, O and S, wherein the reaction mixture in step (a) has less than a threefold excess amount of 25 formic aci d based on the copper used in the copper compound.

77. 发明专利

CA2651948A1 PROCESS FOR PREPARING POROUS METAL ORGANIC FRAMEWORKS 未知
公开(公告)号：CA2651948A1
公开(公告)日：2007-11-22
申请号：CA2651948
申请日：2007-05-11
申请人： BASF AG
发明人： PUETTER HERMANN , TRUKHAN NATALIA , MUELLER ULRICH , RICHTER INGO , SCHUBERT MARKUS
IPC分类号： C25B3/13
摘要： The present invention relates to a process for preparing a porous metal o rganic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least on e anode containing metal corresponding to the at least one metal ion in a re action medium in the presence of at least a first organic compound, where th e first organic compound is an optionally substituted monocyclic, bicyclic o r polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons are replaced by heteroatoms selected from the group consisting of N , O and S, to form a reaction intermediate containing at least one metal ion and the first organic compound; and (b) reaction of the reaction intermedia te at a prescribed temperature with an at least second organic compound whic h coordinates to the at least one metal ion, where the second organic compou nd is derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.

78. 发明专利

DE102006020849A1 未知
公开(公告)号：DE102006020849A1
公开(公告)日：2007-11-08
申请号：DE102006020849
申请日：2006-05-04
申请人： BOSCH GMBH ROBERT , BASF AG
发明人： GRAEHN JAN-MICHAEL , GRUENWALD WERNER , FAYE IAN , LEUTHNER STEPHAN , OERTEL KAI , ALLGEIER THORSTEN , MUELLER ULRICH , HESSE MICHAEL , SCHUBERT MARKUS
IPC分类号： F17C5/00 , F17C11/00 , F17C13/02

79. 发明专利

DE102005054523A1 未知
公开(公告)号：DE102005054523A1
公开(公告)日：2007-05-16
申请号：DE102005054523
申请日：2005-11-14
申请人： BASF AG
发明人： MUELLER ULRICH , HESSE MICHAEL , SCHUBERT MARKUS , URTEL MELANIE , ASMANN JENS , DESBOIS PHILIPPE
IPC分类号： C07C63/28 , B01D15/08 , B01D53/02 , B01J20/282 , C07C51/41 , C07C63/33 , C07F3/06 , C08F212/08 , C08F212/36 , C08G63/12 , C08G69/28 , C08J5/20
摘要： The invention relates to a porous metal-organic framework material for taking up at least one substance, the framework material comprising at least one at least bidentate organic compound bound by coordination to at least one metal ion, and the framework material having at least in part pores which comprise a polymer which is suitable to adsorb the at least one substance. In addition, the invention relates to a method for producing the framework material, a method for taking up at least one substance by the framework material and also to the use of the framework material, in particular for the storage, separation, controlled release or chemical reaction of a substance taken up.

80. 发明专利

CA2620113A1 METHOD FOR PRODUCING ORGANOMETALLIC FRAMEWORK MATERIALS CONTAINING MAIN GROUP METAL IONS 未知
公开(公告)号：CA2620113A1
公开(公告)日：2007-03-01
申请号：CA2620113
申请日：2006-08-18
申请人： BASF AG
发明人： MUELLER ULRICH , RUETZ ROGER , TONIGOLD MARKUS , SCHUBERT MARKUS
IPC分类号： C07C51/41 , C01B3/00 , C07F5/06
摘要： The present invention relates to a method for producing a porous organometallic framework material by reacting at least one metal compound, t he metal being Be, Mg, Ca, Sr, Ba, AI, Ga or In, with at least one at least bidentate organic compound. The invention also relates to the use of such porous organometallic framework materials.

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