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    • 71. 发明授权
    • 일체형 기액 분리기
    • 一体式气液分离器
    • KR101584584B1
    • 2016-01-13
    • KR1020140022317
    • 2014-02-26
    • (주) 테크윈
    • 정붕익김정식이명헌김민용신현수
    • B01D19/00
    • 기액분리기본체(1)의내부공간에하부분리판(2)과상부분리판(3)을설치하여 3개의공간부로분할하여, 중간저장조에서기액분리된액체가저장되는하부저장조(4)와; 유입구(7)를통해외부에서공급된액체중에기체가포함된혼합액체를내부에설치된사이클론(12)을통해기액분리하는중간저장조(5) 및중간저장조의사이클론에서기액분리되어상부로분리배출된기체및 일부액체가저장되는상부저장조(6)로구성하고, 상기상부저장조(6)로배출되는기체는상부저장조의상부에설치되어액체수위에따라승하강하는부구(91)가기체배출커버(92)에형성된기체배출홀(921)을개폐하도록장치된기체분출부(9)를통해배출되도록구성하고, 상기하부저장조(4)에저장된액체는하부저장조에설치된제 1 액체배출구(8)를통해배출되고, 상기상부저장조(6)에저장된액체는그 하부중간저장조(5)에설치되어연통되는제 2 액체배출구(11)를통해외부로배출되도록구성된것을특징으로하는일체형기액분리기.
    • 73. 发明公开
    • 3격실 전해조를 이용한 차염발생장치
    • SODIUM HYPOCHLORITE发电机使用电动汽车与3室
    • KR1020150123998A
    • 2015-11-05
    • KR1020140049776
    • 2014-04-25
    • (주) 테크윈
    • 신현수김정식정붕익
    • C25B9/08C25B1/26
    • C25B9/08C25B1/26
    • 본발명은 3격실로이루어진염화물수용액의전기분해용격막식전기분해조에관한것으로, 그목적은 2개의양이온교환막으로이루어진 3격실전해조를구비하여염화물수용액의전기분해시양극과음극반응으로생성된물질간의 pH 차이를완충할수 있는중성영역의 pH를가지는중간실을두어양극실염화물속에포함된불순물이양이온교환막내부에축적되지않고중간실을통해배출되도록한 차염발생장치를제공하는데있다. 본발명은염화물수용액의전기분해를이용한차염발생장치에있어서, 전해조본체내부에양극과음극이설치되고, 양극과음극사이에 2장의양이온교환막이설치되어전해조본체내부를양극실(15), 음극실(17) 및중간실(16)로분할구성한 3격실전해조(1)와; 상기양극실(15)로양극수를순환공급하는양극수조(2)와; 상기음극실(17)로음극수를순환공급하는음극수조(3)와; 상기중간실(16)로염용액을순환공급하는염용액저장수조(4);를포함하여구성된 3격실전해조를이용한차염발생장치를발명의특징으로한다.
    • 本发明涉及具有三个用于电解氯化物溶液的隔室的隔膜式电解槽。 提供一种次氯酸钠发生器,其中制备具有三个隔室并由两个阳离子交换膜组成的电解器,并且具有能够缓冲由正极和负极产生的材料之间的pH差异的中性区域的pH的中间室 形成电解氯化物溶液时的反应,因此正极室的氯化物中所含的杂质不会积聚在阳离子交换膜中,而是通过中间室排出。 根据本发明的使用电解氯化物溶液的次氯酸钠发生器包括:具有三个隔室的电解器(1),包括形成在其本体中的正极和负极,以及形成在阳极之间的两片阳离子交换膜 电极和负极,因此其主体内侧分为正极室(15),负极室(17)和中间室(16)。 用于将正极水循环供给正极室(15)的正极水箱(2)。 用于向负极室(17)循环供给负极水的负极水箱(3); 以及盐溶液储存罐(4),用于将盐溶液循环并供给到中间室(16)。
    • 74. 发明公开
    • 바이폴라막 및 이의 제조방법
    • 双极膜及其制备方法
    • KR1020150106032A
    • 2015-09-21
    • KR1020140027835
    • 2014-03-10
    • 한남대학교 산학협력단(주) 테크윈
    • 임지원박찬종조은혜김지선강수연정붕익김정식신현수
    • C25B13/04C25B1/26
    • C25B13/04C25B1/26
    • 본 발명은 바이폴라막 및 이의 제조방법에 관한 것으로, 더욱 상세하게는 술폰화된 폴리페닐렌옥사이드 또는 술폰화된 폴리에테르에테르케톤으로 이루어진 양이온교환막; 및 상기 양이온교환막 상에 형성되고, 아민화된 폴리설폰 또는 아민화된 폴리에테르이미드로 이루어진 음이온교환막을 포함하고, 상기 양이온교환막과 음이온교환막은 표면이 불소화 처리된 바이폴라막 및 이의 제조방법에 관한 것이다.
      본 발명의 바이폴라막은 차아염소산 생성능이 우수하고 내구성이 뛰어나, 차아염소산나트륨 생산과 같은 화학합성분야 공정에 적용되어 이온교환막 국산화에 크게 기여할 수 있다.
    • 双极性膜及其制造方法技术领域本发明涉及双极性膜及其制造方法。 更具体地说,本发明涉及一种双极膜,其包括阳离子交换膜,其包含磺化聚苯醚或磺基聚醚醚酮,以及在阳离子交换膜上形成的含有胺化聚砜或酰胺化聚醚酰亚胺的阴离子交换膜, 的阳离子交换膜和阴离子交换膜被氟化,以及其制造方法。 双极膜具有优异的次氯酸生产能力,耐用性高。 因此,双极膜可以应用于化学合成领域的过程,例如产生次氯酸,并且可以显着地有助于离子交换膜的定位。
    • 76. 发明授权
    • 양극성 막을 사용하는 해수 전해 장치 및 이를 사용한 차아염소산 용액과 수소의 제조방법
    • 使用具有双极膜的电解质的装置以及生产氢氧化物溶液和氢气的方法
    • KR101361651B1
    • 2014-02-12
    • KR1020120107842
    • 2012-09-27
    • 한국원자력연구원(주) 테크윈
    • 김광욱신현수김정식정붕익
    • C25B9/08C25B1/04C25B1/26C02F1/461
    • C25B1/10B01D19/0057C25B1/265C25B9/08C25B13/02
    • The purpose of the present invention is to provide a seawater electrolysis device using a bipolar membrane and a method for producing hypochlorite and hydrogen using the same. For the purpose, the present invention provides a seawater electrolysis device using a bipolar membrane, comprising an electrolysis reaction part which is separated into an anode part and a cathode part by a bipolar membrane in the middle, wherein the anode part includes an anode to generate a hypochlorite solution and oxygen gas by receiving and electrolyzing seawater, and the cathode part includes a cathode to generate hydrogen gas by receiving and electrolyzing seawater; and a first gas-liquid separator for receiving the hydrogen gas generated by the cathode part of the electrolysis reaction part and the seawater and separating the hydrogen gas and the seawater. Also, the present invention provides a method for producing hypochlorite and hydrogen via seawater electrolysis using the device. According to the present invention, the reproduction of ocean life can be prevented in a seawater inflow pipe for cooling a power plant condenser by producing a hypochlorite solution and high-purity hydrogen and oxygen simultaneously from seawater. And additional electricity can be produced using the generated hydrogen and oxygen. [Reference numerals] (100) Electrolytic cell; (200) First gas-liquid separator; (300) Second gas-liquid separator; (AA) O_2 (Discharge); (BB) Seawater cooling water; (CC) Fuel cell; (DD) NaCl (Discharge)
    • 本发明的目的是提供一种使用双极性膜的海水电解装置和使用其的次氯酸盐和氢气的制造方法。 为此目的,本发明提供了一种使用双极性膜的海水电解装置,其包括在中间由双极性膜分离成阳极部分和阴极部分的电解反应部分,其中阳极部分包括阳极以产生 次氯酸盐溶液和氧气通过接收和电解海水,并且阴极部分包括通过接收和电解海水产生氢气的阴极; 以及用于接收由电解反应部分和阴极部分产生的氢气并分离氢气和海水的第一气液分离器。 另外,本发明提供使用该装置通过海水电解生产次氯酸盐和氢气的方法。 根据本发明,通过从海水中同时生成次氯酸盐溶液和高纯度氢气和氧气,可以防止用于冷却发电厂冷凝器的海水流入管道中的海洋生物的再生。 并且可以使用产生的氢气和氧气产生额外的电力。 (附图标记)(100)电解槽; (200)第一气液分离器; (300)第二气液分离器; (AA)O_2(放电); (BB)海水冷却水; (CC)燃料电池; (DD)NaCl(放电)
    • 77. 发明授权
    • 부산물 저감형 차아염소산나트륨 발생장치
    • 用于减少副产物的生产系统
    • KR101326272B1
    • 2013-11-11
    • KR1020120032398
    • 2012-03-29
    • (주) 테크윈
    • 정붕익김정식신현수이은경
    • C25B1/26C25B1/34C25B15/02C02F1/461
    • 유입되는 공급원수를 처리하는 원수처리부와, 소금물 공급관이 연결되는 소금물 저장조와, 유입되는 희석수를 전기분해하며 전기분해하여 발생하는 차아염소산나트륨을 배출하는 배출관이 연결되는 전기분해조, 전기분해조의 배출관에 연결되어 생성된 차아염소산나트륨을 저장하는 차아염소산나트륨 저장조와, 원수 공급관과 소금물 공급관에 연결되어 소금물과 원수가 희석된 희석수를 전기분해조로 공급하는 희석수 공급관과, 전기분해조로 유입되는 희석수의 온도를 감지하는 제1온도센서와, 제1온도센서에서 측정된 정보를 근거로 하여 희석수의 온도를 조절하도록 구동되는 희석수 온도조절부와, 전기분해조로 직류전원을 공급하는 전원공급부와, 제1온도센서에서 감지된 측정온도를 근거로 하여 희석수 온도조절부를 제어하고 전원공급부� � 제어하여 전기분해조로 공급되는 전류를 제어하는 제어부를 포함하는 것을 특징으로 하는 부산물 저감형 차아염소산나트륨 발생장치가 개시된다.
    • 79. 发明授权
    • 질소 폐수 처리장치 및 그 방법
    • 硝酸废水处理设备及方法
    • KR101269948B1
    • 2013-05-31
    • KR1020120005728
    • 2012-01-18
    • (주) 테크윈
    • 정붕익김정식신현수이미경
    • C02F1/76
    • C02F1/76C02F2201/002
    • PURPOSE: A nitrogen wastewater treatment apparatus and a method thereof are provided to be able to neutralize pH without adding a separate chemical, to minimize generation of wastewater and to treat ammonia wastewater with a high efficiency. CONSTITUTION: A nitrogen wastewater treatment method comprises the following steps: a step of electrolyzing saturated saline water of 25-30% concentration and water supplied to a diaphragm electrolyzer to produce chlorine gas and sodium hydroxide, and supplying to a wastewater treatment bath and a pH control bath respectively(S100); a step of removing ammonia by supplying chlorine gas generated in the diaphragm electrolyzer to the ammonia wastewater stored in the wastewater treatment bath(S200); and a step of neutralizing pH in the pH control bath where the discharged wastewater without ammonia is stored by supplying sodium hydroxide generated in the diaphragm electrolyzer(S300). A gas-liquid separator separates gas generated in the diaphragm electrolyzer from liquid, re-circulates the saline water to a salt storage bath, and supplies only chlorine gas to the wastewater treatment bath. [Reference numerals] (S100) Step of electrolyzing saturated saline water of 25-30% concentration and water supplied to a diaphragm electrolyzer to produce chlorine gas and sodium hydroxide, and supplying to a wastewater treatment bath and a pH control bath, respectively; (S200) Step of removing ammonia by supplying the chlorine gas generated in the diaphragm electrolyzer to ammonia wastewater stored in the wastewater treatment bath; (S300) Step of neutralizing pH in the pH control bath where the discharged wastewater without ammonia is stored by supplying the sodium hydroxide generated in the diaphragm electrolyzer; (S400) Step of gas-liquid separating gas generated from the anode of the diaphragm electrolyzer into the chlorine gas and the saline water by a gas-liquid separator, supplying the chlorine gas to the wastewater treatment bath, and returning the saline water to a salt storage which supplies the saturated saline water to the diaphragm electrolyzer; (S500) Step of neutralizing residual chlorine dissolved and remained in anode water using a chlorine neutralizing device before saline water(anode water) through the gas-liquid separator is supplied to the saline water storage; (S700) Step of diluting hydrogen included in cathode water to be lower than or equal to explosion liquid and discharging using a hydrogen dilution discharger; (S800) Step of circulating sodium hydroxide generated from the cathode of the diaphragm electrolyzer to the diaphragm electrolyzer by a separate sodium hydroxide storage, manufacturing sodium hydroxide of predetermined concentration, and intermittently injecting into the wastewater treatment bath
    • 目的:提供一种氮废水处理装置及其方法,以便能够在不添加单独化学品的情况下中和pH,以最小化废水的产生并且高效率地处理氨废水。 构成:氮污水处理方法包括以下步骤:将浓度为25-30%的饱和盐水电解电解到隔膜电解槽中供给氯气和氢氧化钠,供给废水处理池和pH值 控制浴(S100); 通过将在隔膜电解器中产生的氯气供给到废水处理槽中的氨废水中除去氨的步骤(S200)。 以及通过供给在隔膜电解器中产生的氢氧化钠来中和pH控制浴中没有氨的排出废水被储存的步骤(S300)。 气液分离器将隔膜电解槽中产生的气体与液体分离,将盐水再循环至盐储存槽,仅向废水处理池供给氯气。 (附图标记)(S100)电解浓度为25〜30%的饱和盐水的电解步骤,供给隔膜电解器的水分别生成氯气和氢氧化钠,并分别供给废水处理槽和pH控制浴; (S200)通过将在隔膜式电解槽中产生的氯气供给到废水处理槽中的氨废水中除去氨的工序; (S300)通过供给在隔膜电解槽中生成的氢氧化钠,中和pH控制浴中没有氨的排出废水的pH的步骤; (S400)通过气液分离器从隔膜电解器的阳极产生的气液分离成氯气和盐水的工序,向废水处理槽供给氯气,并将盐水返回到 将饱和盐水供给隔膜电解槽的盐储存器; (S500)在通过气液分离器的盐水(阳极水)之前,使用氯中和装置中和残存在阳极水中的残留氯的工序供给盐水储存器; (S700)将包含在阴极水中的氢稀释至低于或等于爆炸液体并使用氢稀释放电器排出的步骤; (S800)将通过隔膜电解槽的阴极生成的氢氧化钠通过单独的氢氧化钠保存循环至隔膜电解槽,制造预定浓度的氢氧化钠,并间歇地注入废水处理槽的步骤
    • 80. 发明公开
    • 해수전해 및 연료전지 복합시스템
    • 海水电解质和燃料电池复合体系
    • KR1020120114182A
    • 2012-10-16
    • KR1020120036069
    • 2012-04-06
    • (주) 테크윈
    • 신현수김정식정붕익
    • C25B1/04H01M8/04H01M8/06C25B9/04
    • Y02E60/366H01M8/0656B01D19/0057C25B1/265C25B9/10C25B15/08
    • PURPOSE: Seawater electrolysis and a fuel cell hybrid system are provided to discharge hydrogen gas with high purity without installing a hydrogen filter. CONSTITUTION: Seawater electrolysis and a fuel cell hybrid system(100) comprise a seawater electrolysis unit(110), a seawater supply unit(120), a gas-liquid separator(130), a sodium hypochlorite storage tank(140), a moisture removing unit(150), a gas purifier(160), and a fuel cell(170). The seawater supply unit supplies seawater to the seawater electrolysis unit. The gas-liquid separator separates the electrolyzed water into the liquid and gas. The sodium hypochlorite storage tank holds a sodium hypochlorite solution separated from the gas-liquid separator. The moisture removing unit removes the moisture separated from the gas-liquid separator. The gas purifier refines the hydrogen gas with high purity from the gas without moisture. The fuel cell generates electricity by the hydrogen gas supplied from the gas purifier.
    • 目的:提供海水电解和燃料电池混合系统,以高纯度排放氢气,无需安装氢过滤器。 构成:海水电解和燃料电池混合系统(100)包括海水电解单元(110),海水供应单元(120),气液分离器(130),次氯酸钠储存箱(140),水分 去除单元(150),气体净化器(160)和燃料电池(170)。 海水供应单元向海水电解装置供应海水。 气液分离器将电解水分离成液体和气体。 次氯酸钠储存罐装有与气 - 液分离器分离的次氯酸钠溶液。 除湿装置除去与气液分离器分离的水分。 气体净化器从没有水分的气体中提炼出高纯度的氢气。 燃料电池通过从气体净化器供给的氢气发电。