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71. 发明申请

US20080314245A1 Process for removing a target gas from a mixture of gases by thermal swing adsorption 有权
标题翻译：通过热变形吸附从气体混合物中除去目标气体的方法
公开(公告)号：US20080314245A1
公开(公告)日：2008-12-25
申请号：US12152870
申请日：2008-05-16
申请人： Frank Hershkowitz , Harry W. Deckman , Paul S. Northrop , Bruce T. Kelley
发明人： Frank Hershkowitz , Harry W. Deckman , Paul S. Northrop , Bruce T. Kelley
IPC分类号： B01D53/04
CPC分类号： B01D53/0423 , B01D53/02 , B01D53/0462 , B01D2253/108 , B01D2253/308 , B01D2253/311 , B01D2253/342 , B01D2256/10 , B01D2257/102 , B01D2257/304 , B01D2257/504 , C10L3/10 , C10L3/102 , Y02C10/08
摘要： The separation of a target gas from a mixture of gases using a thermal swing adsorption process wherein a thermal wave is used, primarily in the desorption step. The process of this invention enables one to separately remove multiple contaminants from a treated gaseous stream.
摘要翻译：使用其中使用热波的热变形吸附方法将主要气体与气体混合物分离，主要在解吸步骤中。本发明的方法使得能够从经处理的气流中分离除去多种污染物。

72. 发明申请

US20080282888A1 Temperature swing adsorption of CO2 from flue gas using a parallel channel contractor 有权
标题翻译：使用平行通道承包商从烟道气中温度变化吸附二氧化碳
公开(公告)号：US20080282888A1
公开(公告)日：2008-11-20
申请号：US12152875
申请日：2008-05-16
申请人： Harry W. Deckman , Bruce T. Kelley , Frank Hershkowitz , Ronald R. Chance , Paul S. Northrop , Edward W. Corcoran, JR.
发明人： Harry W. Deckman , Bruce T. Kelley , Frank Hershkowitz , Ronald R. Chance , Paul S. Northrop , Edward W. Corcoran, JR.
IPC分类号： B01D53/62 , B01D53/04 , B01D53/46 , B01D53/96
CPC分类号： B01D53/0423 , B01D53/02 , B01D53/0462 , B01D2253/108 , B01D2253/311 , B01D2253/342 , B01D2257/504 , B01D2259/4143 , Y02C10/04 , Y02C10/08
摘要： The adsorption of CO2 from flue gas streams using temperature swing adsorption. Adsorbent contactors are used in the temperature swing adsorption unit that contain a plurality of substantially parallel channels comprised of or coated with an adsorbent material that is selective for adsorbing CO2 from flue gas.
摘要翻译：使用变温吸附从烟气流中吸附CO 2。吸附剂接触器用于变温吸附单元，其包含多个基本上平行的通道，该通道由吸附剂材料组成或涂覆，所述吸附材料选择性地从烟道气中吸附CO 2。

73. 发明申请

US20080282887A1 Removal of CO2, N2, and H2S from gas mixtures containing same 有权
标题翻译：从含有它们的气体混合物中除去CO 2，N 2和H 2 S.
公开(公告)号：US20080282887A1
公开(公告)日：2008-11-20
申请号：US12080783
申请日：2008-04-04
申请人： Ronald R. Chance , Sebastian C. Reyes , Harry W. Deckman , Gregory DeMartin , Bruce T. Kelley , Paul S. Northrop , Eugene R. Thomas
发明人： Ronald R. Chance , Sebastian C. Reyes , Harry W. Deckman , Gregory DeMartin , Bruce T. Kelley , Paul S. Northrop , Eugene R. Thomas
IPC分类号： B01D53/047
CPC分类号： B01D53/0423 , B01D53/02 , B01D53/047 , B01D2253/108 , B01D2253/308 , B01D2253/342 , B01D2257/102 , B01D2257/304 , B01D2257/504 , C10L3/10 , C10L3/102 , Y02C10/04 , Y02C10/08
摘要： The removal of one or more of the gases CO2, N2 and H2S from gas mixtures containing at least one of said gases with use of an 8-ring zeolite having a Si:Al ratio from about 1:1 to about 1000:1. The preferred gas mixture is a natural gas feedstream and the preferred 8-ring zeolite is DDR.
摘要翻译：从包含至少一种所述气体的气体混合物中除去一种或多种气体CO 2 N 2 N 2和H 2 S，使用Si:Al比为约1:1至约1000:1的8-环沸石。优选的气体混合物是天然气进料流，优选的8-环沸石是DDR。

74. 发明申请

US20080282884A1 Removal of heavy hydrocarbons from gas mixtures containing heavy hydrocarbons and methane 有权
标题翻译：从含重烃和甲烷的气体混合物中除去重质烃
公开(公告)号：US20080282884A1
公开(公告)日：2008-11-20
申请号：US12080660
申请日：2008-04-04
申请人： Bruce T. Kelley , Paul S. Northrop , Ronald R. Chance , Harry W. Deckman , Edward W. Corcoran, JR. , Eugene R. Thomas
发明人： Bruce T. Kelley , Paul S. Northrop , Ronald R. Chance , Harry W. Deckman , Edward W. Corcoran, JR. , Eugene R. Thomas
IPC分类号： B01D53/047
CPC分类号： B01D53/02 , B01D53/0423 , B01D53/047 , B01D2253/108 , B01D2253/308 , B01D2253/342 , B01D2256/24 , B01D2257/702 , C10L3/10
摘要： A process for the separation of one or more heavy hydrocarbon gases from a gas mixture containing heavy hydrocarbon gas components and methane. The process is conducted in swing adsorption apparatus containing adsorbent contactor having a plurality of flow channels and wherein 20 volume percent or less of the open pore volume of the contactors, is in the mesopore and macropore range.
摘要翻译：一种从含有重质烃气体组分和甲烷的气体混合物分离一种或多种重质烃气体的方法。该方法在包含具有多个流动通道的吸附剂接触器的回转式吸附装置中进行，其中接触器的开孔体积的20体积％以下在中孔和大孔范围内。

75. 发明授权

US06267912B1 Distributed injection catalytic partial oxidation process and apparatus for producing synthesis gas 失效
标题翻译：分布式注入催化部分氧化工艺和生产合成气的设备
公开(公告)号：US06267912B1
公开(公告)日：2001-07-31
申请号：US08845700
申请日：1997-04-25
申请人： Frank Hershkowitz , Harry W. Deckman , Robert P. Reynolds , Constantine P. Gonatas , John W. Fulton , Leonard Schoenman , Jack I. Ito , Leroy R. Clavenna
发明人： Frank Hershkowitz , Harry W. Deckman , Robert P. Reynolds , Constantine P. Gonatas , John W. Fulton , Leonard Schoenman , Jack I. Ito , Leroy R. Clavenna
IPC分类号： C07C102
CPC分类号： C01B3/386 , B01F3/02 , B01F5/0682 , B01J8/0278 , C01B2203/0261 , C01B2203/062 , C01B2203/065 , C01B2203/085 , C01B2203/1023 , C01B2203/1052 , C01B2203/1064 , C01B2203/1241 , C01B2203/1276
摘要： A novel injector/reactor apparatus and an efficient process for the partial oxidation of light hydrocarbon gases, such as methane, to convert such gases to useful synthesis gas for recovery and/or subsequent hydrocarbon synthesis. Sources of a light hydrocarbon gas, such as methane, and oxygen or an oxygen-containing gas are preheated and pressurized and injected through an injector means at high velocity into admixture with each other in the desired relative proportions, at a plurality of mixing nozzles which are open to the catalytic partial oxidation reaction zone and are uniformly-spaced over the face of the injector means, to form a reactant gaseous premix having a pressure drop equal to at least about 3% of the lowest upstream pressure of either of said gases. The gaseous premix is injected in a time period which is less than its autoignition time, preferably less than 9 milliseconds, at a velocity between about 25 to 1000 feet/second, into a catalytic partial oxidation zone so that the gaseous premix reacts in the presence of the fixed catalyst to reduce the amounts of CO2, H2O and heat produced by the partial oxidation reaction, to form a useful syngas which is cooled and recovered.
摘要翻译：一种新颖的注射器/反应器装置以及用于部分氧化轻质烃气体（例如甲烷）的有效方法，以将这种气体转化成有用的合成气以用于回收和/或随后的烃合成。来自诸如甲烷和氧气或含氧气体的轻质烃气体在多个混合喷嘴处被预热和加压并通过喷射器装置以高速度以所需的相对比例彼此混合，对催化部分氧化反应区开放，并且在喷射器装置的表面上均匀间隔开，形成具有等于任一气体的最低上压压力的至少约3％的压降的反应物气态预混物。将气体预混物在小于其自燃时间（优选小于9毫秒）的时间内以约25至1000英尺/秒的速度注入到催化部分氧化区中，使得气态预混物在存在下反应的固定催化剂以减少CO 2，H 2 O的量和由部分氧化反应产生的热量，以形成冷却和回收的有用的合成气。

76. 发明授权

US5600017A Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide hydrogen ethylene and acetylene-(LAW072) 失效
标题翻译：含有一氧化碳氢乙烯和乙炔的多组分合成气的直接加氢甲酰化（LAW072）
公开(公告)号：US5600017A
公开(公告)日：1997-02-04
申请号：US563838
申请日：1995-11-28
申请人： Gabor Kiss , Michael G. Matturro , Harry W. Deckman , Istvan T. Horvath , Anthony M. Dean , Frank Hershkowitz , Raymond A. Cook
发明人： Gabor Kiss , Michael G. Matturro , Harry W. Deckman , Istvan T. Horvath , Anthony M. Dean , Frank Hershkowitz , Raymond A. Cook
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , Y02P20/582
摘要： The invention is a process for hydroformylating multicomponent syngas feed streams containing CO, H.sub.2, C.sub.2 to C.sub.5 olefins and mixtures thereof and C.sub.2 to C.sub.5 alkynes and mixtures thereof by contacting the multicomponent syngas feed stream with a solution of an oil soluble rhodium complex catalyst produced by complexing in solution a low valence Rh and an oil soluble triorganophoshorous compound wherein the catalyst has a P/Rh ratio of at least 30, a concentration of Rh in solution from about 1 to about 1000 ppm by weight, a total concentration of coordinatively active P of at least about 0.01 mol/l, and a ratio of [P]/p.sub.co of at least 0.1 mmol/l/kPa, wherein [P] is the total concentration of coordinatively active phosphorous in the solution, and p.sub.co is the partial pressure of CO, to produce the corresponding C.sub.3 to C.sub.6 aldehydes. The process has utility for the hydroformylation of streams that contain olefins and alkynes.
摘要翻译：本发明是一种通过使多组分合成气进料流与油溶性铑配合物催化剂溶液接触而将含有CO，H 2，C 2至C 5烯烃及其混合物和C 2 -C 5炔烃及其混合物的多组分合成气原料流加氢甲酰化的方法，在低价Rh和油溶性三有机磷化合物溶液中络合，其中催化剂的P / Rh比为至少30，溶液中Rh的浓度为约1至约1000重量ppm，配位活性P 至少约0.01mol / l，[P] / pco为至少0.1mmol / l / kPa的比例，其中[P]是溶液中配位活性磷的总浓度，pco是分压的CO，以产生相应的C3至C6醛。该方法可用于含有烯烃和炔烃的物流的加氢甲酰化。

77. 发明授权

US4867840A Method of making artifically textured layered catalyst 失效
标题翻译：制造人造织构层状催化剂的方法
公开(公告)号：US4867840A
公开(公告)日：1989-09-19
申请号：US174723
申请日：1988-03-29
申请人： Charles B. Roxlo , Harry W. Deckman , J. Thomas Tiedje
发明人： Charles B. Roxlo , Harry W. Deckman , J. Thomas Tiedje
IPC分类号： B01J27/02 , B01J27/04 , B01J27/047 , B01J37/34
CPC分类号： B01J27/04 , B01J27/02 , B01J27/047 , B01J37/341 , Y10S502/514
摘要： A method for making a layered metal chalcogenide catalyst wherein the catalyst has a crystalline structure with increased edge sites produced by lithographic methods.
摘要翻译：一种制备层状金属硫族化物催化剂的方法，其中催化剂具有通过光刻方法产生的边缘位置增加的晶体结构。

78. 发明授权

US4608097A Method for producing an electronically passivated surface on crystalline silicon using a fluorination treatment and an organic overlayer 失效
标题翻译：使用氟化处理和有机覆层在晶体硅上制造电子钝化表面的方法
公开(公告)号：US4608097A
公开(公告)日：1986-08-26
申请号：US658357
申请日：1984-10-05
申请人： Bernard R. Weinberger , Harry W. Deckman , Eli Yablonovitch
发明人： Bernard R. Weinberger , Harry W. Deckman , Eli Yablonovitch
IPC分类号： H01L21/312 , H01L21/314 , H01L21/02 , H01L21/48
CPC分类号： H01L21/314 , H01L21/312 , Y10S148/017
摘要： A method is described for producing an electronically passivated stable surface on silicon wafers. The passivation technique consists of first fluorinating the surface of a crystalline silicon wafer under inert atmospheric conditions. Such a treatment may consist of either a vapor phase or liquid phase application of HF at room temperature. The surface fluorinated wafer is then maintained in an inert atmosphere and a thin coating of an organic solid is applied to the wafer which does not disturb the underlying passivated silicon surface. The wafer may then be further processed into a variety of different devices.
摘要翻译：描述了一种在硅晶片上制造电子钝化稳定表面的方法。钝化技术包括首先在惰性大气条件下氟化晶体硅晶片的表面。这种处理可以由在室温下的气相或液相施加HF组成。然后将表面氟化晶片保持在惰性气氛中，并且将有机固体的薄涂层施加到不干扰下面的钝化硅表面的晶片上。然后可以将晶片进一步处理成各种不同的装置。

79. 发明授权

US4404255A Colloidal coating for small three dimensional articles, and particularly for fusion targets having glass shells 失效
公开(公告)号：US4404255A
公开(公告)日：1983-09-13
申请号：US255622
申请日：1981-04-20
申请人： Dennis G. Peiffer , Harry W. Deckman
发明人： Dennis G. Peiffer , Harry W. Deckman
IPC分类号： H05H1/22 , B32B5/16
CPC分类号： G21B1/19 , Y02E30/16 , Y10S376/916 , Y10T428/2996
摘要： Extremely small, three-dimensional articles, such as fusion targets having glass shells (20 to 500 microns in diameter) are coated with alternate layers of colloidal materials. This is accomplished by depositing particles of opposite charge from colloidal suspensions (sols). Articles to be coated are suspended within a drop held in the open end of a closed capillary tube, and colloidal particles are deposited by dipping the capillary into the sols. Alternate monolayers of the particles adhere to the surface of the article. Multilayer coatings are built up by repeated alternate deposition of the monolayers from the sols. Between each deposition, the layers are rinsed with water and the water removed by dipping the capillary tube into a bath of water and then into a bath containing a water displacing agent such as ethanol or dimethyl sulfoxide.

80. 发明授权

US4381963A Micro fabrication molding process 失效
标题翻译：微加工成型工艺
公开(公告)号：US4381963A
公开(公告)日：1983-05-03
申请号：US173533
申请日：1980-07-30
申请人： Irving S. Goldstein , Franklin D. Kalk , Harry W. Deckman
发明人： Irving S. Goldstein , Franklin D. Kalk , Harry W. Deckman
IPC分类号： B29C33/38 , H05H1/22 , B29C1/14
CPC分类号： G21B1/19 , B29C33/3878 , Y02E30/16 , Y10T29/49893
摘要： Identical half-section shells of microscopic size, such as hemispherical shells from which spherical laser fusion targets can be made are capable of mass production by micro fabrication molding techniques. A body (preferably a hollow glass microsphere which is called a glass microballoon) provides a pattern for the hemispherical shells, and is used to produce an original mold section. One or more master molds are formed from this original mold section by replication. Many identical replica molds are made by casting soluble material onto the master mold and removing them therefrom. The replica molds are coated with one or more layers which will form the hemispherical shell wall. The material coating the flat background around the hemispherical cavity is referred to as the flange and is removed to form free standing shells. In order to remove the flange material, the coated replica molds are overcoated with a soluble material which is etched away to the level of the flange. The remaining soluble material acts as a mask for the shell material when the flange material is etched away. The replica mold and overcoating body remain as a protective mask and are dissolved away to release the identical shell sections. These sections can be assembled to provide closed shells. Overlapping lips can be formed during flange removal so as to facilitate the assembly of the sections into the closed shells.
摘要翻译：可以通过微型制造成型技术大量生产具有微小尺寸的相同的半截面壳体，例如可以制造球形激光熔化靶的半球形壳体。身体（优选为称为玻璃微球的中空玻璃微球）为半球形壳提供图案，并用于制造原始模具部分。通过复制从该原始模具部分形成一个或多个主模具。许多相同的复制模具通过将可溶性材料浇铸到母模上并将其从中除去而制成。复制模具涂覆有一层或多层，其将形成半球形壳壁。将半球形腔周围的平坦背景涂覆的材料称为凸缘，并被移除以形成独立的壳体。为了去除凸缘材料，涂覆的复制模具用可蚀刻的材料进行涂覆，该可溶材料被蚀刻到凸缘的水平面上。当法兰材料被蚀刻掉时，剩余的可溶性材料用作壳材料的掩模。复制模具和外涂体保留作为保护面罩，并溶解掉以释放相同的外壳部分。这些部分可以组装以提供封闭的壳。可以在法兰移除期间形成重叠的唇缘，以便于将部件组装到封闭的壳体中。

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