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71. 发明申请

US20040158014A1 Sulphonic fluorinated ionomers 失效
标题翻译：磺化氟化离聚物
公开(公告)号：US20040158014A1
公开(公告)日：2004-08-12
申请号：US10768690
申请日：2004-02-02
申请人： Ausimont S.p.A.
发明人： Ivan Wlassics , Vito Tortelli
IPC分类号： C08F136/16
CPC分类号： H01M8/1053 , C08F8/18 , C08F214/26 , C08F214/265 , C08J5/2237 , C08J2327/18 , H01M8/1023 , H01M8/1025 , H01M8/1039 , H01M8/106 , H01M8/1072 , H01M8/1088 , H01M2300/0082 , Y02P70/56
摘要： Sulphonic fluorinated ionomers crosslinked by radical crosslinking of: A) crosslinkable sulphonic fluorinated ionomers, having equivalent weight 380-1300 g/eq and comprising: from 48% to 85% by moles of monomeric units deriving from tetrafluoroethylene (TFE); from 15% to 47% by moles of fluorinated monomeric units containing sulphonyl groups nullSO2F; from 0.01% to 5% by moles of monomeric units deriving from a bis-olefin of formula: 1 nullwherein: mnull2-10, preferably 4-8; R1, R2, R5, R6, equal to or different from each other, are H or C1-C5 alkyl groups; B) a fluorinated compound as crosslinking radical initiator; C) a fluorinated bis-olefin of structure (I) as crosslinking agent; the radical crosslinking being carried out at a temperature in the range 250null C.-310null C., preferably 260null C.-300null C.
摘要翻译：通过自由基交联交联的磺化氟化离聚物：A）具有当量重量380-1300g / eq的可交联磺化氟化离聚物，并且包含：衍生自四氟乙烯（TFE）的48％至85％摩尔的单体单元; 含有磺酰基-SO 2 F的氟化单体单元的15％至47％衍生自下式的双烯烃的单体单元的0.01％至5％摩尔：其中：m = 2-10，优选4-8; R 1，R 2，R 5，R 6彼此相同或不同，为H或C 1 -C 5烷基; B）作为交联自由基引发剂的氟化化合物; C）结构（I）的氟化双烯烃作为交联剂; 自由基交联在250℃-310℃，优选260℃-300℃的温度下进行。

72. 发明申请

US20030166751A1 Blends of fluorinated and acrylic elastomers 有权
标题翻译：氟化和丙烯酸弹性体的共混物
公开(公告)号：US20030166751A1
公开(公告)日：2003-09-04
申请号：US09931010
申请日：2001-08-17
申请人： Ausimont S.p.A
发明人： Anna Staccione , Julio Abusleme
IPC分类号： C08K005/15
CPC分类号： C08K5/14 , C08L27/22 , C08L33/04 , C08L27/12 , C08L2666/04
摘要： Compounds comprising a peroxide and a curable blend by peroxidic way, consisting essentially of hydrocarbon elastomers containing at least an acrylic monomer, and of unsaturated fluorinated elastomers obtained by dehydro halogenation of fluorinated VDF-based elastomers, said fluorinated elastomers having in the polymer chain at least 5% by moles of hydrogenated C1 groups of the type nullCHnull, nullCH2null and/or nullCH3, the amount of unsaturated fluorinated elastomer in the elastomeric blend being comprised from 1 to 99% by weight.
摘要翻译：包含过氧化物和通过过氧化方式的可固化共混物的化合物，基本上由至少含有丙烯酸单体的烃弹性体和通过氟化VDF基弹性体的脱氢卤化获得的不饱和氟化弹性体组成，所述氟化弹性体至少在聚合物链中具有 5％（摩尔）类型为-CH-，-CH2-和/或-CH 3的氢化C1基团，弹性体共混物中不饱和氟化弹性体的含量为1至99重量％。

73. 发明申请

US20030136533A1 Dispersions of fluorinated polymers 有权
标题翻译：氟化聚合物的分散体
公开(公告)号：US20030136533A1
公开(公告)日：2003-07-24
申请号：US10183350
申请日：2002-06-28
申请人： Ausimont S.p.A.
发明人： Stefano Turri , Tania Trombetta , Paolo Iengo
IPC分类号： D21H017/08 , D21H017/07 , D21H019/00
CPC分类号： D21H17/57 , C08G18/0823 , C08G18/5015 , D21H21/16
摘要： Use for the paper sizing of aqueous polyurethane dispersions from (per)fluoropolyethers obtainable by reaction among the following compounds: a) (per)fluoropolyether diols having a number average molecular weight from 400 to 5,000; b) diisocyanates having formula:OCNnullRnullNCOnullnull(VIa)wherein R is an aliphatic, cycloaliphatic bifunctional radical; or an aromatic bifunctional radical; c) diols containing one carboxylic function and optionally one or both the following components: d) hydrazine and/or aliphatic diamines; e) monofunctional hydroxylic (per)fluoropolyethers having a number average molecular weight in the range 300-1,000.
摘要翻译：用于通过以下化合物之间的反应可得到的（全）氟聚醚的水性聚氨酯分散体的纸张尺寸：a）数均分子量为400至5,000的（全）氟聚醚二醇; b）具有式OCN-R-NCO（VIa）的二异氰酸酯，其中R是脂族，脂环族双官能团; 或芳族双功能基团; c）含有一个羧基官能团的二醇和任选的一种或两种以下组分：d）肼和/或脂族二胺; e）数均分子量在300-1,000范围内的单官能羟基（全）氟聚醚。

74. 发明申请

US20030127623A1 Use of fluorinated liquids 有权
标题翻译：使用氟化液体
公开(公告)号：US20030127623A1
公开(公告)日：2003-07-10
申请号：US10334059
申请日：2002-12-31
申请人： AUSIMONT S.p.A.
发明人： Patrizia Maccone , Rossella Silvani
IPC分类号： C09K005/10 , C09K005/00
CPC分类号： C09K5/10
摘要： Use of one or more fluorinated liquids as dielectric working fluids in plants or heat transfer circuits comprising parts formed by polymer compound in contact with said fluids, said fluorinated liquids having: boiling point in the range 50null C.-250null C., formulaRnull-Rf-Rnullnull(I)wherein: R, Rf and Rnull are as defined in the description.
摘要翻译：使用一种或多种氟化液体作为植物或传热回路中的介电工作流体，包括由与所述流体接触的聚合物化合物形成的部分，所述氟化液体具有沸点在50℃-250℃范围内，式R '-R f -R（I）其中：R，R f和R'如说明书中所定义。

75. 发明申请

US20030004273A1 Fluoroelastomeric compositions 失效
标题翻译：氟弹性组合物
公开(公告)号：US20030004273A1
公开(公告)日：2003-01-02
申请号：US10151886
申请日：2002-05-22
申请人： AUSIMONT S.p.A.
发明人： Marco Apostolo , Margherita Albano , Stefano Arrigoni
IPC分类号： C08L027/12
CPC分类号： C08L27/16 , C08L27/18 , C08L2205/02 , Y10T428/1352 , Y10T428/249921 , Y10T428/249953 , C08L2666/04
摘要： Fluoroelastomeric compositions comprising: A) a fluoroelastomeric matrix; B) a semi-crystalline fluoropolymer, in an amount from higher than 40% to 90% by weight based on the total of A)nullB); the fluoroelastomer A) incorporates the fluoropolymer B), the fluoropolymer B) being formed by tetrafluoroethylene (TFE) homopolymers, or by TFE by copolymers with one or more monomers containing at least one unsaturation of ethylene type, the average sizes of the semi-crystalline fluoropolymer particles being from 10 to 100 nm, preferably from 10 to 60 nm.
摘要翻译：含氟弹性体组合物，其包含：A）含氟弹性体基质; B）半结晶含氟聚合物，其量相对于A）+ B）的总量高于40重量％至90重量％; 含氟弹性体A）包含含氟聚合物B），含氟聚合物B）由四氟乙烯（TFE）均聚物形成，或通过与一种或多种含有至少一种乙烯不饱和键的单体的共聚物与TFE形成，半结晶的平均尺寸含氟聚合物粒子为10〜100nm，优选为10〜60nm。

76. 发明申请

US20020193495A1 PTFE-based polymers 失效
标题翻译： PTFE基聚合物
公开(公告)号：US20020193495A1
公开(公告)日：2002-12-19
申请号：US10097622
申请日：2002-03-15
申请人： Ausimont S.p.A.
发明人： Giovanna Palamone , Valery Kapeliouchko
IPC分类号： C08K003/20
CPC分类号： C08L51/003 , C08F259/08 , C08L55/02 , Y10S525/902 , C08L2666/02
摘要： Compositions containing core-shell particles having a core polytetrafluoroethylene-based polymers (PTFE) and shell styrene-based polymers (PS), wherein the particles contain an amount by weight of PTFE from 3 to 50%, preferably from 5 to 30% by weight, wherein the core PTFE particles have an average diameter from 5 to 100 nm, preferably from 10 to 70 nm, the core-shell particles having an average diameter from 10 to 170 nm, preferably from 20 to 100 nm.
摘要翻译：含有核聚四氟乙烯基聚合物（PTFE）和壳苯乙烯基聚合物（PS）的核 - 壳颗粒的组合物，其中颗粒含有3至50重量％，优选5至30重量％其中，核心PTFE粒子的平均直径为5〜100nm，优选为10〜70nm，核 - 壳粒子的平均直径为10〜170nm，优选为20〜100nm。

77. 发明申请

US20020173679A1 Process for the preparation of fluoropolyoxyalkylenes having one end group -CH2OH and the other end group containing chlorine 失效
标题翻译：制备具有一个端基-CH 2 OH并且另一个端基含有氯的氟代聚氧化烯的方法
公开(公告)号：US20020173679A1
公开(公告)日：2002-11-21
申请号：US10146044
申请日：2002-05-16
申请人： AUSIMONT S.P.A.
发明人： Antonio Russo , Claudio Tonelli
IPC分类号： C07C043/11
CPC分类号： C07C41/26 , C07C41/48 , C07C43/137 , C07C43/315
摘要： A process to obtain fluoropolyoxyalkylenes having the structure: TnullOnull(CF2CF(CF3)O)n-1null(CF(CF3)O)mnullCF2nullCH2OHnullnull(I) wherein: TnullC1-C3 perfluoroalkyl containing one Cl atom; nnullan integer from 1 to 15; m/nnull0-0.5, mnulln such to have a number molecular weight in the range 280-4,000; said process comprising: a) the gradual addition of a metal hydride in admixture with a solvent to an ester precursor having the structure TnullOnull(CF2CF(CF3)O)n-1null(CF(CF3)O)mnullCF2nullCOORnullnull(II) nullwherein RnullC1-C20 alkyl, or aromatic, cycloalkyl or heterocyclic residue, b) the hydrolysis of the reaction mixture obtained in step a) with an aqueous acid solution, the subsequent separation from the obtained organic phase of the compounds of structure (I).
摘要翻译：得到具有以下结构的氟代聚亚烷基的方法：（1）（式（2）中的（式（2））TO-（CF 2 CF（CF 3）O）n-1-（CF（CF 3）O）m -CF 2 -CH 2 OH I）其中：T =含有一个Cl原子的C 1 -C 3全氟烷基; n = 1〜15的整数; m / n = 0-0.5，m + n，其数均分子量为280-4,000; 所述方法包括：a）将金属氢化物与溶剂的混合物逐渐加入到具有结构式（TO-（CF 2 CF（CF 3）O）n的结构的酯前体 -1-（CF（CF 3）O）m -CF 2 -COOR（II）其中R = C 1 -C 20烷基或芳族，环烷基或杂环残基，b）反应混合物的水解在步骤a）中用酸水溶液获得，随后从结构（I）化合物的所得有机相分离。

78. 发明申请

US20020168529A1 Multilayer composition comprising fluoropolymers and hydrogenated polymers 有权
标题翻译：包含含氟聚合物和氢化聚合物的多层组合物
公开(公告)号：US20020168529A1
公开(公告)日：2002-11-14
申请号：US09951580
申请日：2001-09-14
申请人： Ausimont S.p.A.
发明人： Julio A. Abusleme , Claudia Manzoni
IPC分类号： B32B027/00
CPC分类号： B32B27/28 , B32B1/08 , F16L2011/047 , Y10T428/1393 , Y10T428/31504 , Y10T428/31507 , Y10T428/31511 , Y10T428/3154 , Y10T428/31551 , Y10T428/31721 , Y10T428/31786 , Y10T428/31855 , Y10T428/31931 , Y10T428/31935 , Y10T428/31938 , Y10T428/31971
摘要： A multilayer composition comprising: A) a first layer based on copolymers of ethylene (E) with tetrafluoroethylene (TFE) and/or chorotrifluoroethylene (CTFE); B) a second intermediate layer comprising thermoprocessable copolymers of ethylene (E) with tetrafluoroethylene (TFE) and/or chorotrifluoroethylene (CTFE) modified with acrylic monomers; C) a third layer based on hydrogenated polymers; said multilayer composition containing in layer B) and/or in layer C) one or more crosslinking agents.
摘要翻译：一种多层组合物，其包含：A）基于乙烯（E）与四氟乙烯（TFE）和/或三氟氯乙烯（CTFE）的共聚物的第一层; B）包含用丙烯酸单体改性的乙烯（E）与四氟乙烯（TFE）和/或三氟乙烯（CTFE）的热可加工共聚物的第二中间层; C）基于氢化聚合物的第三层; 所述多层组合物含有层B）和/或层C）一种或多种交联剂。

79. 发明申请

US20020156138A1 Semipermeable porous membranes of semi-crystalline fluoropolymers 有权
标题翻译：半结晶含氟聚合物半透膜多孔膜
公开(公告)号：US20020156138A1
公开(公告)日：2002-10-24
申请号：US10083294
申请日：2002-02-27
申请人： Ausimont S.p.A.
发明人： Patrizia Maccone , Paolo Fossati
IPC分类号： C08J009/00
CPC分类号： B01D71/32 , B01D67/003 , B01D69/02 , B01D2323/12
摘要： Semipermeable porous membranes having an average pore diameter in the range 0.01-3 nullm, and porosity in the range 30%-90%, based on semi-crystalline fluoropolymers and the respective preparation process, wherein the semi-crystalline fluoropolymers comprise: (a) from 10 to 70% by moles of ethylene, (b) from 30 to 90% by moles of a fluorinated monomer selected from tetrafluoroethylene, chlorotrifluoroethylene, or mixtures thereof, (c) from 0.1 to 30% by moles, with respect to the total amount of monomers (a) and (b), of a hydrogenated monomer of formula: CH2nullCHnull(CH2)nnullR1nullnull(I) wherein R1nullnullOR2, or null(O)tC(O)pR2 wherein t and p are integers equal to 0.1 and R2 is a linear or branched C1-C20 alkyl, or a cycloalkyl, optionally containing heteroatoms and/or chlorine atoms, preferably heteroatoms are O or N; R2 can optionally contain one or more functional groups, preferably selected from OH, COOH, epoxy, ester and ether group; R2 can optionally contain double bonds, or it can be H; n is an integer in the range 0-10.
摘要翻译：基于半结晶含氟聚合物和相应的制备方法，平均孔径在0.01-3μm范围内，孔隙率在30％-90％范围内的半透性多孔膜，其中半结晶含氟聚合物包括：（a） 10至70摩尔％的乙烯，（b）30至90摩尔％的选自四氟乙烯，氯三氟乙烯或其混合物的氟化单体，（c）0.1至30摩尔％单体（a）和（b）的量为：式（1）所示的氢化单体：（1）式中：CH 2 = CH-（CH 2）n -R 1（I）其中R 1 = -OR 2或 - （O）t C（O）p R 2，其中t和p是等于0.1的整数，R 2是直链或支链C 1 -C 20烷基或环烷基，任选地含有杂原子和/ 或氯原子，优选杂原子是O或N; R2可以任选地含有一个或多个官能团，优选选自OH，COOH，环氧基，酯和醚基团; R2可以任选地含有双键，或者它可以是H; n是0-10的整数。

80. 发明申请

US20020146576A1 Treatment of metal substrata with (per) fluoropolyether compounds 审中-公开
标题翻译：用（全）氟聚醚化合物处理金属基质
公开(公告)号：US20020146576A1
公开(公告)日：2002-10-10
申请号：US10062415
申请日：2002-02-05
申请人： Ausimont S.p.A.
发明人： Mattia De Dominicis , Gabriella Carignano
IPC分类号： B32B015/04
CPC分类号： F28F19/04 , C08G65/007 , C08G65/327 , C08G2650/48 , C09D171/00 , Y10T428/31504 , Y10T428/31663
摘要： Use in the treatment of metal substrata and their alloys, of mono- and bifunctional (per)fluoropolyether compounds having the following structures: nullRfnullCFYnullLnullOnullmP(O)(OnullZnull)3-mnullnull(A) (OnullZnull)2P(O)nullOnullLnullYFCnullOnullRfnullCFYnullLnullOnullP(O)(OnullZnull)nullmnullnullnullOnullLnullYFCnullOnullRfnullCFYnullLnullOnullP(O)(OnullZnull)2nullnull(B) RfnullCFYnullLnullWnullnull(C) WnullLnullYFCnullOnullRfnullCFYnullLnullWnullnull(D) wherein: mnullnull0-20; nnull0-8; qnull1-8; L is an organic group selected from nullCH2null(OCH2CH2)nnull, nullCOnullNRnullnull(CH2)qnull, with RnullnullH or C1-C4 alkyl; ZnullH, alkaline metal or NR4 group with RnullH or C1-C4 alkyl; YnullF, CF3; mnull1, 2, 3, preferably 1, 2; W is a group nullSi(R1)null(OR2)3-null with nullnull0, 1, 2, R1 and R2 equal to or different from each other are C1-C6 alkyl groups optionally containing one or more ether O, C6-C10 aryl groups, C7-C12 alkyl-aryl or aryl-alkyl groups; Rf is a perfluoropolyether chain comprising the following units: (CFXO), (CF2CF2O), (CF2CF2CF2O), (CF2CF2CF2CF2O), (CR4R5CF2CF2O), (CF(CF3)CF2O), (CF2CF(CF3)O).
摘要翻译：用于处理具有以下结构的单功能和双功能（全）氟代聚醚化合物的金属基质及其合金： [Rf-CFY-LO] mP（（O-Z +）3-m（A） <段落lvl =“0”> （O-Z +）2P（O） O-Rf-CFY-LOP（O）（O-Z +）] m' - [OL-YFC-O-Rf-CFY-LO] P（O）（O-Z +）2（B） -formula> <段落lvl =“0”> Rf-CFY-LW（C） <段落lvl =“0”> WL -YFC-O-Rf-CFY-LW（D）其中：m'= 0-20; n = 0-8; q = 1-8; L是选自-CH 2 - （OCH 2 CH 2）n - ， - CO-NR' - （CH 2）q - ，其中R'= H或C 1 -C 4烷基的有机基团; Z = H，碱金属或NR4基团，其中R = H或C 1 -C 4烷基; Y = F，CF3; m = 1,2,3，优选1,2; W是具有等于或不同的α= 0,1,2，R 1和R 2的基团-Si（R 1）a（OR 2）3-α，任选地含有一个或多个醚O，C 6的C 1 -C 6烷基 -C 10芳基，C7-C12烷基 - 芳基或芳基 - 烷基; Rf是包含以下单元的全氟聚醚链：（CFXO），（CF 2 CF 2 O），（CF 2 CF 2 CF 2 O），（CF 2 CF 2 CF 2 CF 2 O），（CR 4 R 5 CF 2 CF 2

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