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    • 78. 发明专利
    • Improvements in and relating to refractories and refractory moulds for casting metallic articles
    • GB536857A
    • 1941-05-29
    • GB554140
    • 1940-03-27
    • TITANIUM ALLOY MFG CO
    • A61K6/027B22C1/02
    • 536,857. Denture and like moulds. TITANIUM ALLOY MANUFACTURING CO. March 27, 1940, No. 5541. Convention date, March 31, 1939. [Class 22] Refractory moulds for casting metal articles such as dentures contain a material which will expand at high temperature as the result of oxidation such as carbon or nitrogen containing compounds of zirconium, titanium, thorium, cerium, hafnium and silicon. Examples of compounds are the carbide, nitride, oxycarbide or cyanonitride of zirconium, the carbide, nitride or cyanonitride of titanium, the carbide of silicon, thorium, cerium or hafnium or the nitride of thorium or hafnium. The amount of the expanding material added is regulated by the amount of expansion desired. A small amount of an oxidizing agent such as red lead or lead peroxide may be added. Impurities such as carbon, carbides of the alkali or alkaline earth metals and iron compounds should be removed by acid leaching. The refractory material used may be zircon, aluminium oxide. silica, quartz, rutile. fused zirconium dioxide, mullite, sillimanite, olivine, forsterite, chromite, refractory clay, kaolin, beryl, spinel, kyanite, thorium oxide, thorite, ceria, feldspar, andalusite, talc, baddeleyite, or porcelain and a bonding agent such as magnesium zirconate, phosphoric acid or water may be used.
    • 79. 发明专利
    • Plastic compositions and methods of making same
    • GB536740A
    • 1941-05-26
    • GB3300339
    • 1939-12-28
    • TITANIUM ALLOY MFG CO
    • B44F1/04C08K3/00
    • 536,740. Cellulose-derivative and syntheticresin compositions ; films. TITANIUM ALLOY MANUFACTURING CO. Dec. 28, 1939, No. 33003. Convention date, Jan. 21. [Classes 2 (ii) and 2 (iii)] [Also in Groups III and XI] A composition capable of being formed into a sheet or film having the property of reflecting yellow light and transmitting blue light, is made by dispersing in a transparent or translucent base material (consisting of a synthetic plastic) a percentage, which is inversely proportional to the thickness of the sheet or film to be formed and is between 0.03 and 0.4 per cent. by volume for a sheet or film 1 mm. in thickness, of a white pigment in the form of particles of a substantially uniform size between 0.4 and 0.6 micron and of isomettic, tetragonal, orthorhombic or hexagonal crystal form and having a refractive index substantially different from that of the base material. Specified plastic base materials are synthetic resins of a phenolic, acrylic, styrene, poly-styrene or urea-formaldehyde base and cellulose nitrate, acetate and xanthate, and specified pigments are cerium dioxide, tin oxide, zirconium dioxide, titanium dioxide, thorium dioxide, antimony oxide, columbium oxide, tantalum oxide, and mixtures or combinations of these oxides with barium sulphate, calcium sulphate, zinc oxide, lithopone and fluorspar. A pigment in suitable form may be prepared by reacting a mixture of zirconium dioxide and soda ash at a temperature between 1660‹ and 1700‹F. until the zirconia grains peptise to form, as nuclei, uniform particles of less than 0.2 micron in size, which are then allowed to grow to the required size, as determined by periodic microscopic examination, the calcine being then cooled, treated with hydrochloric acid, digested with water, washed and dried.