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    • 62. 发明专利
    • Halomethylated aromatic compounds
    • GB772828A
    • 1957-04-17
    • GB3382455
    • 1955-11-25
    • EXXON RESEARCH ENGINEERING CO
    • MIKESKA LOUIS ALOIS
    • C07C17/32C08G61/02C08G63/127C08G63/133C08G69/26C08G75/14
    • Bischloromethyl durene obtainable by an improved process (see Group IV (b)) gives many derivatives convertible into resinous products including polyesters from the corresponding diol and polybasic acids; polyesters from the tetramethyl-terephthalic acid or from bis carboxymethyl durene with diols or polyols; polythioesters from the corresponding bis mercaptomethyl product; polyethers by condensation of the diol with itself; polysulphides by treating bis-chlormethyl durene with alkali sulphides by oxidizing the dimercaptan, e.g. with I2 or by condensing the dimercaptan with sulphur chloride; polyketones or polyglycols by treating a Grignard reagent from the bischloromethyl durene with a dinitrile, or a diketone. The diamines, diacids or di-isocyanates may also be used in making polyamides, polyureas or polyurethanes.ALSO:Bis-halo-methyl aromatic compounds are produced by the reaction between a benzene hydrocarbon with 2 moles. of a halomethylalkyl ether in presence of 2 moles. of an acylating agent to fix the alcohol by-product formed. In examples, durene is treated with chloromethyl ethyl ether with and without (for comparison) acetic anhydride, and in various solvents with Friedel-Craft catalysts (for comparison), and gives bis-chloromethyl and monochloromethyldurene. The bis-product can be converted by usual methods into a number of useful derivatives including: bis-hydroxymethyl durene, bis-acetoxymethyl durene, tetramethylterephthalic acid and bis-cyanomethyl durene.