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    • 67. 发明授权
    • Light-sensitive photographic material with cationic polyurethane mordant
    • 具有阳离子聚氨酯媒染剂的感光感光材料
    • US3877945A
    • 1975-04-15
    • US45330474
    • 1974-03-21
    • AGFA GEVAERT AG
    • ROSENHAHN LOTHARBERGTHALLER PETER
    • G03C8/56C08G18/08G03C1/825G03C1/835G03C7/388G03C1/84
    • C08G18/0814G03C1/835G03C7/3882Y10S430/142
    • A photographic material comprising at least one silver halide emulsion layer and at least one anionic organic compound such as dyes or color couplers and as mordant therefor at least one water soluble or water dispersible cationic polyurethane which has an average molecular weight of 10,000 to 60,000 which contains repeating units, in polymerized form, which are derived from (a) an alkanediol component of which at least 80 mols % is one or more amino containing diols of the formula

      AND UP TO 20 MOLS % IS ONE OR MORE DIOLS OF THE FORMULA HO + R3 - OH and (b) a diisocyanate component selected from the group consisting of aliphatic, cycloaliphatic and/or aromatic diisocyanates, but at least 40 mol % must be aliphatic or cycloaliphatic and not more than 20 mols % can be cycloaliphatic; at least 40% of all the tertiary amino groups in the polyurethane being quaternized in in which formulae R1 and R3 the meanings as defined hereinafter. The mordants are photographically inert and may be used with advantages in any photographic layer.
    • 一种照相材料,其包含至少一种卤化银乳剂层和至少一种阴离子有机化合物如染料或着色剂,并且作为媒染剂至少一种水溶性或水分散性阳离子聚氨酯,其平均分子量为10,000至60,000,其含有 聚合形式的重复单元,其衍生自(a)至少80摩尔%的链烷二醇组分,其中一个或多个氨基含有下式的二醇和高达20摩尔%是式I的一个或多个二醇, R3-OH和(b)选自脂肪族,脂环族和/或芳族二异氰酸酯的二异氰酸酯成分,但至少40摩尔%必须是脂族或脂环族,不超过20摩尔%可以是脂环族的; 聚氨酯中所有叔氨基中至少40%被季铵化,其中式R1和R3定义如下。 媒染剂是照相惰性的,可用于任何照相层的优点。