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61. 发明专利

GB1320907A POLYMERS OF N-SUBSTITUTED ACRYLAMIDES 未知
公开(公告)号：GB1320907A
公开(公告)日：1973-06-20
申请号：GB1320907D
申请日：1969-08-25
申请人： BP CHEM INT LTD
IPC分类号： C08F20/52 , C08F7/02 , C08F1/08 , C08F19/00

62. 发明专利

GB1316387A ORGANIC PHOTOCONDUCTIVE MATERIALS 未知
公开(公告)号：GB1316387A
公开(公告)日：1973-05-09
申请号：GB2651571
申请日：1971-04-19
申请人： HITACHI LTD
IPC分类号： C08F12/32 , G03G5/07 , G03G5/06 , C08F7/02 , C07C1/20 , C07C1/26 , C07C15/28
摘要： 1316387 Photoconductive material HITACHI Ltd 19 April 1971 [8 April 1970 7 Dec 1970(3)] 26515/71 Heading H1K [Also in Divisions C3 and C5] Photoconductive material comprises a polymer or copolymer of 9(p-vinylphenyl)anthracene and optionally 10-90 wt. per cent terphenyl by wt. of the polymer. Sensitizers, e.g. nitroanthraquinone, chloroaniline tetracyanoethylene, tetracyanoquinodimethane, phthalic anhydride, trichloroacetic acid or a Lewis acid may be present in amount 1-80 wt. per cent and a dye sensitizer may be present in amount 0À1-10 wt. per cent.

63. 发明专利

DE2146104A1 (co)polyvinyl cpds - useful as photoconductors, org semiconductors electrophotographic matls and in scintillation counters 未知
公开(公告)号：DE2146104A1
公开(公告)日：1972-07-06
申请号：DE2146104
申请日：1971-04-07
申请人： HITACHI LTD
IPC分类号： C08F12/32 , G03G5/07 , C08F7/02
摘要： The vinyl (co)polymers have pendant gps. of (brominated) 9-phenylanthracene: They give films of high transparency and good sensitivity.

64. 发明专利

DE2117058A1 未知
公开(公告)号：DE2117058A1
公开(公告)日：1972-04-20
申请号：DE2117058
申请日：1971-04-07
IPC分类号： C08F12/32 , G03G5/07 , C08F7/02
摘要： A novel compound 9-(p-vinylphenyl)anthracene is prepared by the reaction of anthrone or 9-substituted anthracene with a p-substituted styrene. Polymers or copolymers of 9-(p-vinylphenyl)anthracene or brominated thereof show excellent photoconductivity.

65. 发明专利

DE1795261A1 未知
公开(公告)号：DE1795261A1
公开(公告)日：1972-02-10
申请号：DE1795261
申请日：1968-08-30
申请人： HOECHST AG
发明人： HAHN HELMUT DR , REBSDAT SIEGFRIED DR , RUCHLAK KASIMIR DR , SCHUIERER ERICH DR
IPC分类号： C08G18/62 , C08G18/80 , D06M15/576 , C08F7/02
摘要： Polymers of the formula IN WHICH Rf is perfluoroalkyl of six to 12 carbon atoms, n is an integer of 1 to 4, m is 0 or 1 and x is a number of about 10 to about 300, are useful as water- and oil-repellent agents for fibrous materials, especially materials consisting of or containing cotton or wool. The agents are used in aqueous dispersions or solutions in organic solvents.

66. 发明专利

NL7108182A 未知
公开(公告)号：NL7108182A
公开(公告)日：1971-12-21
申请号：NL7108182
申请日：1971-06-15
IPC分类号： C08F2/16 , C08F2/20 , C08F7/02

67. 发明专利

NL7007001A 未知
公开(公告)号：NL7007001A
公开(公告)日：1971-11-16
申请号：NL7007001
申请日：1970-05-14
IPC分类号： C08F2/00 , C08F2/16 , C08J9/00 , C08J9/16 , C08J9/20 , C08F47/10 , C08K1/34 , C08F7/02
摘要： 1300233 Expandable thermoplastic polymer beads KANEGAFUCHI KAGAKU KOGYO KK 23 Dec 1969 62675/69 Heading C3C An expandable styrene and/or its derivative polymer bead contains a homogenous mixture of a metal salt of an aliphatic or aromatic carboxylic acid in amount of 2% by wt. or less, the metal of the salt belonging to Group II of the Mendeleef Periodic Table, and an expanding agent which is gaseous at 10 C. and atmospheric pressure. The expandable beads may be made by polymerizing the monomers in aq. suspension in the presence of the metal salt and either in the presence of the expanding agent, or if in its absence then impregnating the resultant beads with the expanding agent. In examples the polymer was polystyrene or a copolymer of styrene and methyl methacrylate, the expanding agent was butane and/or pentane, and/or tetrachloroethylene, and the metal salt was calcium stearate, palmitate or laurate, cadmium cumate or n-butyl-benzoate, or zinc p-tert.- butyl-benzoate.

68. 发明专利

DE1770411A1 未知
公开(公告)号：DE1770411A1
公开(公告)日：1971-10-21
申请号：DE1770411
申请日：1968-05-14
申请人： SINCLAIR KOPPERS CO
发明人： AUSTIN WRIGHT HAROLD
IPC分类号： C08F2/16 , C08F2/18 , C08F7/02

69. 发明专利

NL7001095A 未知
公开(公告)号：NL7001095A
公开(公告)日：1971-07-29
申请号：NL7001095
申请日：1970-01-27
IPC分类号： C08F2/16 , C08F7/02

70. 发明专利

DE1720485A1 未知
公开(公告)号：DE1720485A1
公开(公告)日：1971-07-01
申请号：DE1720485
申请日：1960-09-29
申请人： DOW CHEMICAL CO
发明人： JAY HATCH MELVIN , LEROY MCMASTER ELMER
IPC分类号： C07C381/12 , C07D327/06 , C07D333/46 , C08F12/04 , C08F28/00 , C09D201/00 , C08F7/02
摘要： Polymers or copolymers of water-soluble vinyl benzyl sulphonium compounds of formula, in which the aromatic nucleus may be substituted by one or more alkyl radicals, X is sulphur which is substituted by two alkyl radicals one or both of which may be substituted, or which sulphur is part of a heterocyclic ring, and Y is an anion (see Group IV(b)) are addition polymerized using ultra-violet or gamma irradiation, or azo- or peroxide catalysts. The polymers are soluble in aqueous solvents but insoluble in organic solvents. Examples describe the preparation of poly(vinylbenzyl (2hydroxyethyl, 2-carbamoylethyl) sulphonium) chloride, polymeric vinylbenzyl(methyl, pentaethylene glyco1) sulphonium chloride, and many compounds which may be polymerized are listed. The polymers may be used as watersoluble cationic thickening agents, for the flocculation of slimes, or to promote gel formation in aqueous media.ALSO:The invention comprises water-soluble vinyl benzyl sulphonium compounds of formula, in which the aromatic nucleus may be substituted by one or more alkyl radicals, X is sulphur which is substituted by two alkyl radicals one or both of which may be substituted, or which sulphur is part of a heterocyclic ring, and Y is an anion, which are prepared by reacting a vinylbenzyl halide and a dialkyl, or a substituted dialkyl sulphide or a heterocyclic sulphur compound, preferably in an aqueous reaction medium or a polar anhydrous organic solvent. The halide ion may be converted to other anions by the use of anion exchange resins, and the product is separated by conversion, for example, into the perchlorate, or a bismuth chloride adduct. X is preferably the radical of an organic sulphur containing compound from sulphides R2SR3, wherein R2 and R3 may be, alkyls (1-6C), haloalkyls (1-6C), hydroxyalkyls (1-6C), aralkyls (7-12C), -CH2,CH2O)mCH2CH2OH, -CnH2nCOOH, -CnH2nCOOCnH2n + 1, -CnH2nCOO alkali metal, -CnH2nCONH2, -CnH2nCO,CnH2n + 1, -CnH2n-O-CnH2n + 1, and -CnH2nCN, wherein m and n are integers 1 to 5 and where the total number of carbon atoms attached to a sulphur atom does not exceed 18; and cyclothio compounds such as, unsubstituted, hydroxy-, halo- and alkyl (1-5C) tetrahydrothiophene, thiacyclohexane and 1-oxa,4-thiacyclohexane. Examples describe the preparation of vinyl benzyl (dimethyl) sulphonium chloride; vinylbenzyl (2-hydroxyethyl, ethyl benzyl) sulphonium chloride; poly[vinylbenzyl (2-hydroxyethyl 2-carbamoylethyl) sulphonium chloride; vinyl benzyl (methyl, pentaethylene glycol) sulphonium chloride; vinylbenzyl tetra-hydrothiophenium chloride; and many other compounds which are listed. The monomers may be homo- or co-polymerised and the polymers are suitable as water-soluble cationic thickening agents and for the flocculation of slimes.

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