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    • 62. 发明授权
    • Simplified efficient process for reducing NO.sub.x, SO.sub.x, and
particulates
    • 用于减少NOx,SOx和微粒的简化有效过程
    • US5658547A
    • 1997-08-19
    • US406206
    • 1995-03-16
    • Stanislaw MichalakJoseph R. ComparatoJohn E. Hofmann
    • Stanislaw MichalakJoseph R. ComparatoJohn E. Hofmann
    • B01D53/50B01D53/56B01D53/60F23J7/00F23J15/00C01B17/22
    • F23J7/00B01D53/501B01D53/505B01D53/565B01D53/60F23J15/006B01D2251/206F23J2215/101F23J2215/20F23J2217/101F23J2900/15081
    • The removal of SO.sub.x and particulates, and preferably also NO.sub.x, from the combustion gases of a large boiler, is simplified while efficiency is improved. In a primary treatment zone, a slurry comprising an alkaline SO.sub.x -reducing composition and preferably a nitrogen-containing composition effective to reduce NO.sub.x, is introduced into combustion gases at a temperature of from about 900.degree. to about 1300.degree. C. The gases are cooled by initial contact with steam-generating means, and then by contact with an gas-to-gas heat exchanger. Cooled gases are then subjected to a secondary treatment in which they are first humidified and further cooled by introduction of a water spray or aerosol to reduce the temperature to 100.degree. C. or below. Contact between the SO.sub.x -reducing composition and the humidified gases is maintained for a reaction period of at least 2 seconds. Particulate solids are then separated from the gases with a fabric filter. The cleaned gases are reheated by the gas-to-gas heat exchanger prior to discharge to the atmosphere. Reductions of SO.sub.x of greater than 80% are achieved, preferably 90 to 95%.
    • 从大型锅炉的燃烧气体中除去SOx和微粒,最好是除去NO x也被简化,同时提高了效率。 在初级处理区中,在约900℃至约1300℃的温度下将包含碱性SOx还原组合物和优选含有有效降低NOx的含氮组合物的浆料引入燃烧气体中。将气体冷却 通过与蒸汽发生装置的初始接触,然后通过与气体 - 气体热交换器接触。 然后对冷却的气体进行二次处理,其中它们首先被加湿并通过引入喷水或气溶胶进一步冷却,以将温度降至100℃或更低。 SO x还原组合物与加湿气体之间的接触保持至少2秒的反应时间。 然后用织物过滤器将颗粒状固体与气体分离。 清洁的气体在排放到大气中之前由气体 - 气体热交换器再加热。 实现了大于80%的SOx的减少,优选为90〜95%。
    • 63. 发明授权
    • Exhaust gas purification device
    • 废气净化装置
    • US08656705B2
    • 2014-02-25
    • US12918649
    • 2009-02-20
    • Taisuke Ono
    • Taisuke Ono
    • F01N3/00F01N3/02F01N3/20
    • B01D53/9495B01D2257/404F01N3/0814F01N3/0842F01N3/0871F01N3/0878F01N3/2033F01N3/30F01N3/36F01N3/38F01N9/00F01N13/011F01N2240/14F01N2560/06F01N2900/1404F01N2900/1614F23G7/065F23J15/08F23J2215/101F23J2219/20F23J2900/15081Y02T10/26Y02T10/47
    • A method for controlling an exhaust gas purification device 1 equipped with branch exhaust passages 2 and 3 connected to an exhaust passage 100 on the engine side; a shutoff valve 4 capable of shutting off exhaust gas at the exhaust inlets 2a and 3a of the branch exhaust passages 2 and 3; a nitrogen oxide adsorbing material 5, disposed inside each of the branch exhaust passages 2 or 3, temporarily adsorbing nitrogen oxides in an excess air atmosphere, and detaching the adsorbed nitrogen oxides in a rising temperature atmosphere or a reducing atmosphere; a first combustion device 6, disposed on the exhaust upstream side of the nitrogen oxide adsorbing material 5 inside each of the branch exhaust passages 2 or 3, having an air nozzle 61, and changing the air supplied from the air nozzle 61 into the rising temperature atmosphere or the reducing atmosphere; and a second combustion device 7, disposed on the exhaust downstream side of the nitrogen oxide adsorbing material 5 inside each of the branch exhaust passages 2 or 3 and including an air nozzle 71, a fuel nozzle 72 and an ignition nozzle 73, wherein the ratio of fuel and air supplied from the first combustion device 6 is controlled within the range of 0.6
    • 一种排气净化装置1的控制方法,其具备与发动机侧的排气通路100连接的分支排气通路2和3, 能够切断分支排气通路2,3的排气入口2a,3a的废气的截止阀4; 在每个分支排气通道2或3内设置的氮氧化物吸附材料5,在过量空气气氛中临时吸附氮氧化物,并在升温温度或还原气氛中分离吸附的氮氧化物; 第一燃烧装置6,设置在每个分支排气通道2或3内的氮氧化物吸附材料5的排气上游侧,具有空气喷嘴61,并且将从空气喷嘴61供应的空气改变为上升温度 气氛或还原气氛; 以及设置在每个分支排气通道2或3内的氮氧化物吸附材料5的排气下游侧并且包括空气喷嘴71,燃料喷嘴72和点火喷嘴73的第二燃烧装置7,其中, 从第一燃烧装置6供应的燃料和空气被控制在0.6 <λ1<1.0的范围内,其中λ1是过量空气比。
    • 64. 发明授权
    • Exhaust gas treating method and apparatus
    • 废气处理方法及装置
    • US08302388B2
    • 2012-11-06
    • US12516845
    • 2007-12-24
    • Kazuki KobayashiHirofumi KikkawaHiroshi IshizakaHiroshi TakezakiHiroyuki Nosaka
    • Kazuki KobayashiHirofumi KikkawaHiroshi IshizakaHiroshi TakezakiHiroyuki Nosaka
    • F01N3/00
    • F23J15/003B01D53/10B01D53/50B01D53/64B01D53/8625B01D2257/602F23J15/006F23J15/025F23J2215/60F23J2217/10F23J2219/40F23J2219/60F23J2219/70F23J2900/15081
    • After adjusting an exhaust gas temperature at an exit of a heat recovery unit (11) of an exhaust gas treating apparatus to not more than a dew point temperature of sulfur trioxide (SO3), a heavy metal adsorbent is supplied from a heavy metal adsorbent supply unit (16) disposed in an exhaust gas at an entrance of a precipitator (4) or an intermediate position within the precipitator (4), and the exhaust gas containing the heavy metal adsorbent is supplied into the precipitator (4). Preferably at this stage, the heavy metal adsorbent is supplied into the exhaust gas at the entrance of the precipitator (4) 0.1 seconds after the exhaust gas temperature at the exit of the heat recovery unit (11) has been adjusted to not more than the dew point temperature of SO3. Further preferably, in order to prevent acid corrosion of equipment, the heavy metal adsorbent is supplied after spraying an alkali into the exhaust gas at the entrance or exit of the heat recovery unit (11) and adjusting the exhaust gas temperature at the exit of the heat recovery unit to not more than the dew point temperature of SO3. Accordingly, even when coal with a high sulfur content is used as fuel, heavy metals in the exhaust gas can be removed effectively.
    • 在废气处理装置的热回收单元(11)的出口处的排气温度调节至三氧化硫(SO3)的露点温度以下之前,重金属吸附剂由重金属吸附剂供给源 设置在除尘器(4)的入口处的排气中或者除尘器(4)内的中间位置的单元(16),并且将含有重金属吸附剂的排气供给到除尘器(4)中。 优选在此阶段,在热回收单元(11)的出口处的排气温度已经调整到不超过该温度的0.1秒之后,将重金属吸附剂供入到除尘器(4)入口处的废气中 露点温度SO3。 进一步优选为了防止设备的酸腐蚀,在热回收单元(11)的入口或出口处的排气中喷入碱后,再供给重金属吸附剂,并调节出口处的排气温度 热回收单位不得超过SO3的露点温度。 因此,即使使用具有高硫含量的煤作为燃料,也能够有效地除去废气中的重金属。
    • 68. 发明申请
    • Exhaust smoke-processing system
    • 排烟处理系统
    • US20060099902A1
    • 2006-05-11
    • US10527034
    • 2003-09-08
    • Hirofumi KikkawaTakanori NakamotoToshio Katsube
    • Hirofumi KikkawaTakanori NakamotoToshio Katsube
    • F23J13/08
    • F23J15/02F23J15/006F23J15/08F23J2215/60F23J2219/40F23J2900/15081F23L2900/15043F23N2025/10Y02E20/348
    • An exhaust smoke processing system capable of economically removing heavy metal, comprising a air preheater 3 for heating combustion air by exhaust smoke discharged from a boiler 1, a heat recoverer 11 for heating a heat medium by exhaust smoke discharged from the air preheater 3, a dust collector 4 for collecting soot and dust in exhaust smoke discharged from the heat recoverer 11, a wet-type exhaust smoke processing apparatus for processing exhaust smoke discharged from the dust collector 4, a reheater 13 for heating exhaust smoke discharged from the wet-type exhaust smoke processing apparatus by the heat medium, and a heat medium circulation pipe passage 15 for circulating the heating medium between the reheater 13 and the heat recoverer 11, wherein the heating medium circulation pipe 15 is provided with temperature control means which measures a heavy metal concentration in exhaust smoke discharged from any one or more of the dust collector 4, the wet-type exhaust smoke processing apparatus 6 and the reheater 13, and adjust the temperature of exhaust smoke at an outlet of the heat recoverer 11 such that the measured value falls within a predetermined range.
    • 能够经济地除去重金属的排烟处理系统,包括:通过从锅炉1排出的排气烟加热燃烧空气的空气预热器3;用于通过从空气预热器3排出的排气烟加热热介质的热回收器11; 用于收集从热回收器11排出的废烟中的灰尘的集尘器4,用于处理从集尘器4排出的排烟的湿式排气烟处理装置,用于加热从湿式排出的排气烟的再热器13 通过热介质的废烟处理装置,以及用于在再热器13和热回收器11之间循环加热介质的热介质循环管道15,其中,加热介质循环管15设置有温度控制装置,其测量重金属 从任一个或多个集尘器4排出的废气中的浓度,湿式排烟处理 装置6和再热器13,并且调节热回收器11的出口处的排烟温度,使得测量值落在预定范围内。