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61. 发明申请

US20080020948A1 Sulfonated Graft Copolymers 有权
标题翻译：磺化接枝共聚物
公开(公告)号：US20080020948A1
公开(公告)日：2008-01-24
申请号：US11780493
申请日：2007-07-20
申请人： Klin A. Rodrigues , Jannifer Sanders
发明人： Klin A. Rodrigues , Jannifer Sanders
IPC分类号： C09K8/08 , C02F5/10 , C04B12/00 , C11D3/37 , C08G75/00
CPC分类号： C11D3/3788 , C02F5/10 , C02F5/12 , C03C25/26 , C04B24/161 , C04B28/02 , C08F8/44 , C08F251/00 , C08F291/08 , C08F2800/20 , C08F2810/50 , C08L51/02 , C09K8/035 , C09K8/40 , C09K8/467 , C09K8/501 , C09K8/528 , C04B24/383 , C08F220/06
摘要： Sulfonated graft copolymer obtained by radical graft copolymerization of one or more synthetic monomers in the presence of hydroxyl-containing naturally derived materials. The graft copolymer includes 0.1 to 100 wt %, based on weight of the total synthetic monomers, of at least one monoethylenically unsaturated monomer having a sulfonic acid group, monoethylenically unsaturated sulfuric acid ester or salt thereof, with the monomer and hydroxyl-containing naturally derived materials present in a weight ratio of 5:95 to 95:5.
摘要翻译：通过在含羟基的天然衍生物质的存在下，通过一种或多种合成单体的自由基接枝共聚得到的磺化接枝共聚物。接枝共聚物包含0.1至100重量％，基于总合成单体的重量，至少一种具有磺酸基，单烯属不饱和硫酸酯或其盐的单烯属不饱和单体与单体和含羟基的天然衍生物材料以5:95至95:5的重量比存在。

62. 发明授权

US5438099A Particulate graft copolymer and thermoplastic molding materials obtained therefrom 失效
标题翻译：从其获得的颗粒接枝共聚物和热塑性成型材料
公开(公告)号：US5438099A
公开(公告)日：1995-08-01
申请号：US165465
申请日：1993-12-13
申请人： Wolfgang Fischer , Norbert Guentherberg
发明人： Wolfgang Fischer , Norbert Guentherberg
IPC分类号： C08F2/22 , C08F265/04 , C08F279/02 , C08F291/08 , C08L25/12 , C08L51/00 , C08L51/04 , C08L55/02 , C08L69/00 , C08L71/12 , C08F291/02
CPC分类号： C08L51/04 , C08F265/04 , C08F279/02 , C08F291/08 , C08L25/12 , C08L51/003 , C08L55/02 , C08L69/00 , C08L71/123
摘要： Abstract of the disclosure: A particulate graft copolymer comprises 30 to 90% by weight of at least one elastomeric grafting base A having a weight average particle size of from 30 to 1,000 nm comprising, based on A, 85 to 99.8% by weight of at least one alkyl acrylate A11 having 1 to 8 carbon atoms in the alkyl radical, 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A12, and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or hydroxyalkyl methacrylate A13 or at least 50% by weight of one or more dienes A111, up to 50% by weight of one or more ethylenically unsaturated monomers A112, and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or hydroxyalkyl methacrylate A113 and10 to 70% by weight of a graft sheath B comprising, based on B, up to 99.9% by weight of at least one aromatic vinyl monomer B1, up to 99.9% by weight of at least one polar, copolymerizable, ethylenically unsaturated monomer B2, and 0.1 to 20% by weight of at least one monomer B3 containing one or more basic or acid groups.
摘要翻译：本发明摘要：一种颗粒状接枝共聚物包含30-90％重量的至少一种重均粒径为30至1,000nm的弹性体接枝基体A，其基于A为85-99.8％（重量），基于A 烷基中具有1至8个碳原子的丙烯酸烷基酯A11和0.1至5重量％的至少一种多官能交联单体A12和0.1至10重量％的至少一种丙烯酸羟烷基酯或甲基丙烯酸羟烷基酯A13或至少50重量％的一种或多种二烯A111，至多50重量％的一种或多种烯属不饱和单体A112和0.1至10重量％的至少一种丙烯酸羟烷基酯或甲基丙烯酸羟烷基酯A113和10至70重量％的移植鞘B，其包含基于B的至多一种芳族乙烯基单体B1至多99.9重量％的至多99.9重量％的至少一种极性，可共聚的烯键式不饱和单体B2和0.1至 20重量％的至少一个mo 含有一个或多个碱性或酸性基团的聚合物B3。

63. 发明授权

US4954560A Stable polymer/polyols made without macromonomer 失效
标题翻译：不使用大分子单体制成稳定的聚合物/多元醇
公开(公告)号：US4954560A
公开(公告)日：1990-09-04
申请号：US373923
申请日：1989-06-30
申请人： Richard M. Gerkin , Michael W. Jorgenson , Paul W. Leuzzi, II
发明人： Richard M. Gerkin , Michael W. Jorgenson , Paul W. Leuzzi, II
IPC分类号： C08J9/02 , C08F291/08 , C08G18/50 , C08G18/63 , C08G18/81
CPC分类号： C08G18/632 , C08F291/08 , C08G18/636 , C08G18/638
摘要： A stable polymer polyol made by the in situ polymerization of two or more monomers in a polyol blend wherein at least one monomer is a bifunctional compound containing both an isocyanate group and an ethylinically unsaturated group and wherein the polyol blend contains a base polyol and an amine terminated polyether which is more reactive with the bifunctional compound than is the base polyol.

64. 再颁专利

USRE33291E Process for the preparation of white graft polymer dispersions and flame-retardant polyurethane foams 失效
标题翻译：制备白色接枝聚合物分散体和阻燃聚氨酯泡沫的方法
公开(公告)号：USRE33291E
公开(公告)日：1990-08-07
申请号：US730085
申请日：1985-05-03
申请人： Gerhard G. Ramlow , Duane A. Heyman , Oscar M. Grace , Curtis J. Reichel , Robert J. Hartman
发明人： Gerhard G. Ramlow , Duane A. Heyman , Oscar M. Grace , Curtis J. Reichel , Robert J. Hartman
IPC分类号： C08F291/08 , C08G18/63 , C08G63/676
CPC分类号： C08F291/08 , C08G18/635 , C08G63/676
摘要： White graft polymer dispersions in polyoxyalkylene polyether polyols are employed together with flame retardant compounds to prepare flame retardant polyurethane foams. The polymer dispersions employ less than 0.1 mole of induced unsaturation per mole of polyol mixture. Improved processes for the reparation of these polymer dispersions employ either isomerized maleate containing polyetherester polyols or polyetherester polyols prepared by reacting a polyoxyalkylene polyether polyol, a polycarboxylic acid anhydride and an alkylene oxide in the presence of salts and oxides of divalent metals.

65. 发明授权

US4652589A Polymer/polyols having improved combustion resistance and intrinsic viscosity, methods of making same and polyurethanes prepared therefrom 失效
标题翻译：具有改善的耐燃性和特性粘度的聚合物/多元醇，其制备方法和由其制备的聚氨酯
公开(公告)号：US4652589A
公开(公告)日：1987-03-24
申请号：US699970
申请日：1985-02-08
申请人： Donald W. Simroth , Frank E. Critchfield , Richard C. Myerly
发明人： Donald W. Simroth , Frank E. Critchfield , Richard C. Myerly
IPC分类号： C08G18/00 , C08F283/00 , C08F283/06 , C08F291/08 , C08G18/63 , C08G18/14 , C09K3/00
CPC分类号： C08F291/08 , C08F283/06 , C08G18/63 , C08G18/635 , C08G18/636 , Y10S524/923
摘要： A normally liquid, stable polymer/polyol composition which imparts improved combustion resistance to polyurethane foams prepared therefrom while retaining satisfactory foam tensile properties are formed by polymerizing in the presence of a free radical catalyst and in the essential absence of an alkyl mercaptan, (1) from about 25 to about 60 weight percent of an ethylenically unsaturated monomer or monomers, for example, a mixture of acrylonitrile and styrene in a weight ratio respectively of 25:75 to 0:100, dissolved or dispersed in (2) from about 40 to about 75 weight percent of a polyol comprising a base polyol having a hydroxyl number of less than about 150, wherein the polymer is characterized by a crosslinking coefficient of less than 55 and an intrinsic viscosity of at least 0.30.A process for treating the resulting polymer/polyol composition to reduce the product viscosity to essentially the indigenous system viscosity in polymer/polyol compositions of this type is disclosed, as is a stabilizer precursor which assists in stabilizing the resulting polymer/polyol compositions.
摘要翻译：通过在自由基催化剂的存在下和基本不存在烷基硫醇的情况下聚合形成通常液体的，稳定的聚合物/多元醇组合物，其通过在保持令人满意的泡沫拉伸性能的同时保持令人满意的泡沫拉伸性能，约25至约60重量％的烯属不饱和单体或单体，例如丙烯腈和苯乙烯的混合物，其重量比分别为25:75至0:100，溶解或分散于（2）约40至约75重量％的包含羟基数小于约150的基础多元醇的多元醇，其中所述聚合物的特征在于交联系数小于55，特性粘度至少为0.30。公开了一种用于处理所得聚合物/多元醇组合物以将产品粘度降低至基本上这种类型的聚合物/多元醇组合物中的本体系粘度的方法，以及有助于稳定所得聚合物/多元醇组合物的稳定剂前体。

66. 发明授权

US4503207A Process for the preparation of acrylamide graft polymer dispersions 失效
公开(公告)号：US4503207A
公开(公告)日：1985-03-05
申请号：US510565
申请日：1983-07-05
申请人： Duane A. Heyman
发明人： Duane A. Heyman
IPC分类号： C08F291/08 , C08G18/63 , C08L33/26
CPC分类号： C08G18/635 , C08F291/08 , Y10S524/923
摘要： Graft polymer dispersions are prepared by polymerizing aqueous solutions of acrylamide in unsaturation-containing polyols. These dispersions are employed in preparing polyurethane products.

67. 发明授权

US4460715A Stable dispersions of polymers in polyfunctional compounds having a plurality of active hydrogens and polyurethanes produced therefrom 失效
标题翻译：聚合物在具有多种活性氢的多官能化合物和由其制备的聚氨酯中的稳定分散体
公开(公告)号：US4460715A
公开(公告)日：1984-07-17
申请号：US320160
申请日：1981-11-10
申请人： Dwight K. Hoffman , Robert F. Harris , Nancy B. Tefertiller , Randall C. Rains
发明人： Dwight K. Hoffman , Robert F. Harris , Nancy B. Tefertiller , Randall C. Rains
IPC分类号： C08F283/06 , C08F291/08 , C08G18/40 , C08G18/63 , C08G18/81 , C08G18/14 , C08G18/30
CPC分类号： C08F291/08 , C08F283/06 , C08G18/40 , C08G18/63 , C08G18/81
摘要： A stable copolymer dispersion is prepared by addition copolymerization of (1) a monomeric adduct of an active hydrogen compound, e.g., a polyether polyol, and an acrylyl compound such as methacryloyl chloride with (2) ethylenically unsaturated monomer(s), e.g., styrene or a mixture thereof with acrylonitrile, while (1) and (2) are dispersed or dissolved in an excess of an active hydrogen polyfunctional compound such as a polyether polyol. The molar ratio of acrylyl moiety to active hydrogen compound is less than 0.1:1. The resulting dispersion has a controlled particle size and a viscosity such that it is suitably employed in the production of polyurethane foams.
摘要翻译：通过（1）活性氢化合物例如聚醚多元醇和丙烯酰基化合物如甲基丙烯酰氯与（2）烯键式不饱和单体的单体加合物（例如苯乙烯）的加成共聚制备稳定的共聚物分散体或其与丙烯腈的混合物，而（1）和（2）分散或溶解在过量的活性氢多官能化合物如聚醚多元醇中。丙烯酰部分与活性氢化合物的摩尔比小于0.1：1。所得到的分散体具有受控的粒度和粘度，使得它适合用于生产聚氨酯泡沫体。

68. 发明授权

US4458038A Process for the preparation of white graft polymer dispersions and flame-retardant polyurethane foams 失效
标题翻译：制备白色接枝聚合物分散体和阻燃聚氨酯泡沫的方法
公开(公告)号：US4458038A
公开(公告)日：1984-07-03
申请号：US471722
申请日：1983-03-03
申请人： Gerhard G. Ramlow , Duane A. Heyman , Oscar M. Grace
发明人： Gerhard G. Ramlow , Duane A. Heyman , Oscar M. Grace
IPC分类号： C08F283/06 , C08F291/08 , C08F299/02 , C08G18/63 , C08G63/676 , C08K5/06 , C08K5/10 , C08L29/02 , C08L51/08
CPC分类号： C08G63/676 , C08F283/06 , C08F291/08 , C08F299/022 , C08G18/635
摘要： White graft polymer dispersions in polyoxyalkylene polyether polyols are employed together with flame retardant compounds to prepare flame retardant polyurethane foams. The polymer dispersions employ less than 0.1 mole of induced unsaturation per mole of polyol mixture. Improved processes for the preparation of these polymer dispersions employ either maleate or fumarate derived polyetherester polyols or polyetherester polyols prepared by reacting a polyoxyalkylene polyether polyol with a compound selected from the group consisting of maleic acid, maleic anhydride and fumaric acid and an alkylene oxide in the presence of salts and oxides of divalent metals.
摘要翻译：聚氧亚烷基聚醚多元醇中的白色接枝聚合物分散体与阻燃化合物一起使用以制备阻燃聚氨酯泡沫。聚合物分散体每摩尔多元醇混合物使用少于0.1摩尔的诱导不饱和度。用于制备这些聚合物分散体的改进方法使用通过使聚氧化烯聚醚多元醇与选自马来酸，马来酸酐和富马酸的组分和烯化氧反应制备的马来酸酯或富马酸酯衍生的聚醚酯多元醇或聚醚酯多元醇存在二价金属的盐和氧化物。

69. 发明授权

US4359571A Process for preparing graft polymer dispersions and polyurethanes prepared therefrom 失效
标题翻译：制备接枝聚合物分散体和由其制备的聚氨酯的方法
公开(公告)号：US4359571A
公开(公告)日：1982-11-16
申请号：US298454
申请日：1981-09-02
申请人： William A. Bernstein , John E. Davis , Joseph R. Gregoria, Jr.
发明人： William A. Bernstein , John E. Davis , Joseph R. Gregoria, Jr.
IPC分类号： C08F2/14 , C08F291/08 , C08G18/63 , C08G67/02
CPC分类号： C08F291/08 , C08G18/63
摘要： The present invention relates to a process for the preparation of stable graft polymer dispersions having improved dispersibility by a free radical polymerization of an ethylenically unsaturated monomer under conditions of no-reflux or alternatively under conditions that do not return the evaporated monomer to the dispersion. Polyurethane foams may be prepared from these polymer dispersions.
摘要翻译：本发明涉及通过烯键式不饱和单体的自由基聚合在不回流条件下或在不将蒸发的单体返回至分散体的条件下制备稳定的接枝聚合物分散体的方法。聚氨酯泡沫可以由这些聚合物分散体制备。

70. 发明授权

US3746548A Silver halide emulsion with graft copolymer binders 失效
标题翻译：具有共轭共聚物粘合剂的银盐乳液
公开(公告)号：US3746548A
公开(公告)日：1973-07-17
申请号：US3746548D
申请日：1971-10-08
申请人： POLAROID CORP
发明人： FITZGERALD M , TAYLOR L
IPC分类号： C08F291/08 , G03C1/053 , G03C1/04
CPC分类号： G03C1/053 , C08F291/08 , C08F220/60
摘要： A photosensitive silver halide emulsion wherein the emulsion binder comprises a graft copolymer of an amine acrylamide monomer on a polymer containing a plurality of hydroxyl groups.
摘要翻译：一种感光卤化银乳剂，其中乳液粘合剂包含胺丙烯酰胺单体在含有多个羟基的聚合物上的接枝共聚物。

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