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61. 发明授权

US4124694A Process for the oxidation of hydrogen sulfide to sulfur trioxide 失效
标题翻译：硫化氢氧化成三氧化硫的工艺
公开(公告)号：US4124694A
公开(公告)日：1978-11-07
申请号：US858558
申请日：1977-12-08
申请人： James M. Whelan
发明人： James M. Whelan
IPC分类号： B01D53/86 , B01D53/94 , B01J23/10 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/78 , B01J23/83 , B01J23/835 , C01B5/00 , C01B17/69 , C01B17/78 , C01B21/22 , C01B21/26 , C01B32/50 , C01B17/68 , B01D53/34
CPC分类号： B01J23/835 , B01D53/864 , B01D53/9418 , B01D53/9436 , B01J23/10 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/78 , B01J23/83 , C01B17/78 , C01B21/265 , C01B31/20 , C01B5/00 , B01D2255/2042 , B01D2255/2061 , B01D2255/2063 , B01D2255/2065 , B01D2255/2068 , B01D2255/20707 , B01D2255/2073 , B01D2255/20746 , B01D2255/20753 , B01D2255/20784 , Y02C20/10
摘要： A process for the oxidation of hydrogen sulfide to sulfur trioxide in the presence of elemental nitrogen with minimal oxidation thereof which comprises combining the hydrogen sulfide with a predetermined amount of oxygen containing gas to give at least 1% stoichiometric excess of oxygen for the oxidation of hydrogen sulfide to sulfur trioxide and passing the resulting mixture over a ceramic catalyst of the following empirical formula at a temperature between about 100.degree. C and about 700.degree. C.;w.sub.k X.sub.n J(1-k-n).sup.ZO (3.+-.m)whereinW is Zirconium, Tin or Thorium or mixtures thereof;X is an alkaline earth metal or mixture thereof;J is scandium, yttrium, a rare-earth element or mixture thereof;Z is a metal of the first transition series orA mixture thereof, at least 0.01% of said metalHaving an oxidation state other than +3;k is a number having a value between 0 and about 0.1;m is a number having a value of from 0 to 0.26; andn is a number having a value from 0 to about 0.51,Provided when n has a value of 0, k has a value between 0 and about 0.05.
摘要翻译：一种在元素氮存在下将硫化氢氧化成三氧化硫的方法，其中氧化最小，其中包括将硫化氢与预定量的含氧气体组合，得到至少1％化学计量过量的氧气用于氢氧化硫化物至三氧化硫，并将所得混合物在约100℃至约700℃的温度下通过以下经验式的陶瓷催化剂。

62. 发明授权

US3448061A Process for the manufacture of catalysts supported on carriers of large dimensions 失效
标题翻译：用于制造大尺寸载体的催化剂的制备方法
公开(公告)号：US3448061A
公开(公告)日：1969-06-03
申请号：US3448061D
申请日：1966-11-01
申请人： HOECHST AG
发明人： MIKA GEORG
IPC分类号： B01J23/22 , C01B17/78 , B01J11/06
CPC分类号： B01J23/22 , C01B17/78

63. 发明授权

US2863838A Production of catalysts containing vanadium 失效
标题翻译：生产含钒催化剂
公开(公告)号：US2863838A
公开(公告)日：1958-12-09
申请号：US52711955
申请日：1955-08-08
申请人： ICI LTD
发明人： CLARKSON VINCENT GEORGE
IPC分类号： B01J23/22 , C01B17/78
CPC分类号： B01J23/22 , C01B17/78

64. 发明授权

US2016222A Catalytic production of sulphur trioxide 失效
标题翻译：催化生产三氧化硫
公开(公告)号：US2016222A
公开(公告)日：1935-10-01
申请号：US59612932
申请日：1932-03-01
申请人： BASSETT HARRY P
发明人： BASSETT HARRY P
IPC分类号： C01B17/78
CPC分类号： C01B17/78 , Y10S423/02

65. 发明授权

US1855412A Process for the production of alpha gaseous catalyst 失效
标题翻译：生产α气态催化剂的方法
公开(公告)号：US1855412A
公开(公告)日：1932-04-26
申请号：US27982128
申请日：1928-05-22
申请人： INT PRECIPITATION CO
发明人： ERICH OPPEN
IPC分类号： B01J37/34 , C01B17/74 , C01B17/78
CPC分类号： C01B17/78 , B01J37/34 , C01B17/74

66. 发明申请

US20170252697A1 METHOD FOR THE CATALYTIC REMOVAL OF SULPHUR DIOXIDE FROM WASTE GASES 有权
公开(公告)号：US20170252697A1
公开(公告)日：2017-09-07
申请号：US15511857
申请日：2015-09-16
申请人： CPPE CARBON PROCESS & PLANT ENGINEERING S.A.
发明人： Alain STRICKROTH
IPC分类号： B01D53/75 , C01B17/80 , C01B17/765 , C01B17/78 , B01D53/86 , B01D53/50
CPC分类号： B01D53/75 , B01D53/507 , B01D53/8609 , B01D2251/506 , B01D2255/702 , C01B17/765 , C01B17/78 , C01B17/803
摘要： The present invention relates to a method for the catalytic removal of sulfur dioxide from waste gases in two reactors, wherein the first reactor is charged with an activated carbon catalyst. The method comprises: a. provision of a waste gas with a water content of less than 1 g H2O/Nm3 and an SO2 content of at least 5 ppm, b. introduction of the waste gases into a first reactor, c. catalytic conversion of the SO2 into gaseous SO3 in the first reactor by the activated carbon catalyst, wherein catalytic conversion on the activated carbon catalyst proceeds at a temperature of below 100° C., d. introduction of the prepurified waste gases from the first reactor into a second reactor, e. conversion of the SO3 with water into H2SO4 in the second reactor.

67. 发明授权

US07740827B2 Ruthenium oxide catalysts for conversion of sulfur dioxide to sulfur trioxide 失效
标题翻译：用于将二氧化硫转化为三氧化硫的氧化钌催化剂
公开(公告)号：US07740827B2
公开(公告)日：2010-06-22
申请号：US12067660
申请日：2006-09-25
申请人： Timothy R. Felthouse , Abraham Bino
发明人： Timothy R. Felthouse , Abraham Bino
IPC分类号： B01J23/36 , B01J37/00 , C01B17/74 , C01B17/78
CPC分类号： C01B17/78 , B01J21/06 , B01J21/066 , B01J23/462 , B01J35/006 , B01J35/008 , B01J35/023 , B01J35/026 , B01J35/04 , B01J35/08 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J37/0201 , B01J37/0203 , B01J37/0205 , B01J37/0207 , B01J37/0217 , B01J37/08 , B82Y30/00 , C01G55/004 , C01P2002/72 , C01P2002/85 , C01P2004/03 , C01P2004/04 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12
摘要： The present invention relates generally to catalysts comprising ruthenium oxide and to processes for catalyzing the oxidation and conversion of sulfur dioxide (SO2) to sulfur trioxide (SO3) using such catalysts. SO2 at low concentrations in process gas streams can be effectively oxidized to SO3 at relatively low temperatures using the ruthenium oxide catalysts of the present invention. In one application, the ruthenium oxide catalysts are used in the final contact stage for conversion of SO2 to SO3 in multiple stage catalytic converters used in sulfuric acid manufacture.
摘要翻译：本发明一般涉及包含氧化钌的催化剂以及使用这种催化剂催化二氧化硫（SO2）氧化成三氧化硫（SO 3）的方法。使用本发明的氧化钌催化剂，在工艺气流中低浓度的SO2可在相当低的温度下被有效地氧化成SO 3。在一个应用中，氧化钌催化剂用于在用于硫酸制造的多级催化转化器中用于将SO 2转化为SO 3的最终接触阶段。

68. 发明申请

US20080226540A1 Ruthenium Oxide Catalysts for Conversion of Sulfur Dioxide to Sulfur Trioxide 失效
标题翻译：用于将二氧化硫转化为三氧化硫的氧化钌催化剂
公开(公告)号：US20080226540A1
公开(公告)日：2008-09-18
申请号：US12067660
申请日：2006-09-25
申请人： Timothy R. Felthouse , Abraham Bino
发明人： Timothy R. Felthouse , Abraham Bino
IPC分类号： C01B17/78 , B01J23/46
CPC分类号： C01B17/78 , B01J21/06 , B01J21/066 , B01J23/462 , B01J35/006 , B01J35/008 , B01J35/023 , B01J35/026 , B01J35/04 , B01J35/08 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J37/0201 , B01J37/0203 , B01J37/0205 , B01J37/0207 , B01J37/0217 , B01J37/08 , B82Y30/00 , C01G55/004 , C01P2002/72 , C01P2002/85 , C01P2004/03 , C01P2004/04 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12
摘要： The present invention relates generally to catalysts comprising ruthenium oxide and to processes for catalyzing the oxidation and conversion of sulfur dioxide (SO2) to sulfur trioxide (SO3) using such catalysts. SO2 at low concentrations in process gas streams can be effectively oxidized to SO3 at relatively low temperatures using the ruthenium oxide catalysts of the present invention. In one application, the ruthenium oxide catalysts are used in the final contact stage for conversion of SO2 to SO3 in multiple stage catalytic converters used in sulfuric acid manufacture.
摘要翻译：本发明一般涉及包含氧化钌的催化剂和使用这种催化剂催化二氧化硫（SO 2 H 2）氧化和转化成三氧化硫（SO 3 H 3）的方法。使用本发明的氧化钌催化剂，可以在相对低的温度下将工艺气流中的低浓度的SO 2 SO 2有效地氧化成SO 3。在一个应用中，氧化钌催化剂用于在硫酸制造中使用的多级催化转化器中用于将SO 2 SO 2转化为SO 3的最终接触阶段。

69. 发明申请

US20030069457A1 Preparation and use of non-chrome catalysts for Cu/Cr catalyst applications 有权
标题翻译：用于Cu / Cr催化剂应用的非铬催化剂的制备和使用
公开(公告)号：US20030069457A1
公开(公告)日：2003-04-10
申请号：US10196443
申请日：2002-07-16
发明人： Jianping Chen
IPC分类号： B01J023/72 , C07C027/10 , C07C027/12
CPC分类号： C07C29/154 , B01D53/86 , B01J21/04 , B01J23/002 , B01J23/005 , B01J23/72 , B01J23/755 , B01J23/78 , B01J23/83 , B01J23/8892 , B01J35/10 , B01J35/1014 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J35/109 , B01J37/0009 , B01J37/03 , B01J37/031 , B01J37/038 , B01J2523/00 , C01B17/78 , C07C1/22 , C07C29/149 , C07C37/16 , C07C209/36 , C07C209/48 , C07C231/065 , C07C2521/04 , C07C2523/72 , C07D301/32 , Y02P20/52 , C07C31/125 , B01J2523/17 , B01J2523/31 , B01J2523/3712 , B01J2523/67 , C07C31/04 , C07C39/06 , C07C39/07
摘要： A non-chrome, copper-containing catalyst, CunullAlnullO and method of preparing the same are provided wherein the CunullAlnullO catalyst is prepared by the co-precipitation of copper nitrate (Cu(NO3)2) and sodium aluminate (Na2Al2O4) solutions using sodium carbonate (Na2CO3) as a precipitant. The precipitate is filtered, washed to removed excess sodium, and dried. The dried product, to be used in a powder form, is calcined at a preferred temperature of approximately 700null to 900null C. for approximately 1 to 4 hours. The dry powder, to be tableted or extruded, is calcined at a temperature of approximately 400null to 700null C. The activity of the CunullAlnullO catalyst can be promoted in hydrogenolysis applications by the addition of various agents. The CunullAlnullO catalyst can be employed in applications in place of Cu/Cr, or other copper based catalysts.
摘要翻译：提供了非铬，含铜催化剂Cu-Al-O及其制备方法，其中Cu-Al-O催化剂通过共同沉淀硝酸铜（Cu（NO 3）2）和钠使用碳酸钠（Na 2 CO 3）作为沉淀剂的铝酸盐（Na 2 Al 2 O 4）溶液。将沉淀物过滤，洗涤以除去过量的钠，并干燥。以粉末形式使用的干燥产品在约700℃至900℃的优选温度下煅烧约1至4小时。待压片或挤压的干燥粉末在约400℃至700℃的温度下煅烧。通过添加各种试剂，可以在氢解应用中促进Cu-Al-O催化剂的活性。 Cu-Al-O催化剂可用于代替Cu / Cr或其它铜基催化剂。

70. 发明授权

US5264200A Monolithic catalysts for conversion of sulfur dioxide to sulfur trioxide 失效
标题翻译：用于将二氧化硫转化为三氧化硫的单片催化剂
公开(公告)号：US5264200A
公开(公告)日：1993-11-23
申请号：US915129
申请日：1992-07-14
申请人： Timothy R. Felthouse , Atis Vavere
发明人： Timothy R. Felthouse , Atis Vavere
IPC分类号： B01J23/42 , C01B17/78 , C01B17/69 , B01J35/04 , C01B17/74
CPC分类号： B01J23/42 , C01B17/78 , Y02P20/584 , Y10S502/514 , Y10S502/516
摘要： Chemically and thermally stable monolithic catalysts are disclosed having platinum or alkali metal-vanadium active phases for use in the conversion of sulfur dioxide to sulfur trioxide. The platinum catalyst comprises a foraminous ceramic support which has at its wall surfaces a high surface area substrate for an active catalyst phase, and a combination of a platinum active phase and a promoter on the substrate. The substrate preferably comprises silica, provided, for example, by application of a silica washcoat. The promoter is selected from among compounds of zirconium, hafnium and titanium.The alkali-vanadium catalyst comprises a foraminous ceramic support having a porous silica substrate for the active phase at its foraminal wall surfaces. An alkali metal-vanadium active catalyst is in the pores of the porous silica.Methods for producing the catalysts of the invention are described, as is a method for producing sulfur trioxide with the platinum catalyst, in which the catalyst is regenerated with a mineral acid when activity has declined through aging or exposure to the conditions of the oxidation of sulfur dioxide.
摘要翻译：公开了化学和热稳定的整体式催化剂，其具有用于将二氧化硫转化为三氧化硫的铂或碱金属 - 钒活性相。铂催化剂包括多孔陶瓷载体，其在其壁表面具有用于活性催化剂相的高表面积底物，以及在基材上的铂活性相和促进剂的组合。底物优选包含二氧化硅，例如通过施加二氧化硅修补涂层提供。助催化剂选自锆，铪和钛的化合物。碱 - 钒催化剂包括多孔陶瓷载体，其具有用于活性相在其孔壁表面的多孔二氧化硅基质。碱金属钒活性催化剂在多孔二氧化硅的孔中。对本发明的催化剂的制造方法进行了说明，同时使用铂催化剂制造三氧化硫的方法，其中当活性通过老化下降或暴露于硫的氧化条件时，用无机酸再生催化剂二氧化碳

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