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    • 64. 发明授权
    • Continuous process for the chlorination of 1,1,1,-trichloroethane or
mixtures thereof
    • 1,1,1-三氯乙烷或其混合物氯化的连续方法
    • US4148832A
    • 1979-04-10
    • US318991
    • 1972-12-27
    • Yves Correia
    • Yves Correia
    • C07C17/10C07C17/00
    • C07C17/10
    • A continuous process for chlorination of 1,1,1-trichloroethane alone or in admixture with other aliphatic chlorinated C.sub.1 to C.sub.4 hydrocarbons in a liquid phase reaction with molecular chlorine in the presence of a catalyst selected from the group consisting of ferric chloride, iron oxychloride and mixtures thereof in the absence of light radiations wherein the reaction may be carried out in a single reaction zone at a temperature within the range of 35.degree.-120.degree. C. or in a series of reaction zones in which the effluent from the first reaction zone is introduced into the second reaction zone along with additional chlorine and unsaturated chlorinated hydrocarbon with the temperature in the second reaction zone being less by at least 5.degree. than the temperature in the initial reaction zone.
    • 在选自氯化铁,三氯氧化铁的催化剂存在下,单独或与其它脂族氯化C1-C4烃类物质在分子氯的液相反应中氯化的连续方法 以及它们在不存在光辐射的情况下的混合物,其中反应可以在单一反应区域中在35-120℃的温度范围内进行,或者在一系列反应区域中,其中来自第一反应 区域与附加的氯和不饱和氯化烃一起引入第二反应区,第二反应区的温度比初始反应区的温度低至少5℃。
    • 66. 发明授权
    • Polymerization of vinyl chloride polymers and copolymers and products
    • 氯乙烯聚合物和共聚物和产品的聚合
    • US3879364A
    • 1975-04-22
    • US38035473
    • 1973-07-18
    • PECHINEY SAINT GOBAIN
    • KEMP THOMASBADGUERAHANIAN LEON
    • C08F14/06C08F259/04C08F1/11
    • C08F14/06C08F259/04C08F2/18C08F214/06
    • The invention is addressed to the continuous polymerization of vinyl chloride or vinyl chloride copolymers in the process of suspension or fine suspension wherein a seeding product is first prepared by polymerization or copolymerization of vinyl chloride after which the seeding product is introduced at a continuous rate with water, monomer or a mixture of monomers into a reaction zone which is reacted under autogeneous pressure to effect the desired polymerization with the continuous withdrawal of product and in which the amount of catalyst embodied in the preparation of the seeding product is sufficient to supply the catalyst necessary for the main polymerization or copolymerization whereby a controlled continuous polymerization product is made available to produce a more uniform polymer or copolymer.
    • 本发明涉及氯乙烯或氯乙烯共聚物在悬浮液或细小悬浮液中的连续聚合,其中首先通过氯乙烯的聚合或共聚制备接种产物,之后以连续的速率将接种产物引入到水中 单体或单体混合物加入到反应区中,该反应区在自发压力下反应以产生所需的聚合反应,连续取出产物,其中在制备产物中体现的催化剂的量足以提供必要的催化剂 用于主要的聚合或共聚,由此可以获得受控的连续聚合产物以产生更均匀的聚合物或共聚物。