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    • 65. 发明授权
    • Solid electrolyte with high ion conductivity and electrochemical system using the solid electrolyte
    • 具有高离子电导率的固体电解质和使用固体电解质的电化学系统
    • US07238445B2
    • 2007-07-03
    • US10401700
    • 2003-03-31
    • Haruo Sawa
    • Haruo Sawa
    • H01M6/04
    • H01M10/056H01M6/18H01M8/1023H01M8/1048H01M2300/0082H01M2300/0091
    • It is an object to provide a high ion conductive solid electrolyte which uses organic and inorganic complex compound having water absorption and water resistance and to provide an electrochemical system using the high ion conductive solid electrolyte. The high ion conductive solid electrolyte is composed a complex compound including water that has zirconic acid compound and polyvinyl alcohol and compound having carboxyl group or metal salt of the compound having carboxyl group. An aqueous solution in which zirconium salt or oxyzirconnium salt and polyvinyl alcohol and compound having carboxyl group or metal salt of the compound having carboxyl group are dissolved is neutralized by alkali. After removing water used as solvent, unnecessary salts are removed from the neutralized solution. The high ion conductive solid electrolyte is obtained which is composed of the complex compound. Various electrochemical systems are obtained each of which use the high ion conductive solid electrolyte.
    • 本发明的目的是提供使用具有吸水性和耐水性的有机和无机复合化合物的高离子传导性固体电解质,并提供使用高离子传导性固体电解质的电化学系统。 高离子传导性固体电解质由具有锆酸化合物和聚乙烯醇的水和具有羧基的化合物的具有羧基或金属盐的化合物构成的复合化合物构成。 其中锆盐或氧化锆鎓盐和聚乙烯醇以及具有羧基的化合物的羧基或金属盐的化合物溶解的水溶液被碱中和。 除去用作溶剂的水后,从中和溶液中除去不需要的盐。 得到由络合物构成的高离子传导性固体电解质。 获得各种使用高离子传导性固体电解质的电化学系统。