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    • 63. 发明授权
    • Certain-3-amino-2-pyridine-sulfonamide intermediates
    • 某些3-氨基-2-吡啶 - 磺酰胺中间体
    • US5336773A
    • 1994-08-09
    • US43231
    • 1993-04-06
    • Werner ForyRolf Schurter
    • Werner ForyRolf Schurter
    • A01N47/36C07D213/71C07D213/73C07D213/74C07D401/12C07D521/00C07D213/69C07D213/70
    • C07D213/73A01N47/36C07D213/74C07D521/00
    • N-Pyridinesulfonyl-N'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen, C.sub.1 -C.sub.8 alkyl or C.sub.3 -C.sub.8 cycloalkyl; C.sub.2 -C.sub.8 alkyl or C.sub.3 -C.sub.8 cycloalkyl, each of which is monosubstituted or polysubstituted by halogen; C.sub.1 -C.sub.8 alkyl or C.sub.3 -C.sub.8 cycloalkyl, each of which is substituted by --NR.sub.5 R.sub.6, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkyl--S(O).sub.n --; C.sub.1 -C.sub.4 alkyl or C.sub.3 -C.sub.6 cycloalkyl, each of which is substituted by C.sub.2 -C.sub.4 alkenyl, C.sub.5 -C.sub.6 cycloalkenyl, C.sub.2 -C.sub.6 alkynyl or C.sub.4 -C.sub.8 alkadienyl; it being possible for the C.sub.2 -C.sub.4 alkenyl, C.sub.5 -C.sub.6 cycloalkenyl and C.sub.4 -C.sub.8 alkadienyl radicals to be monosubstituted or polysubstituted by halogen; or R.sub.1 and R.sub.2 together are a 4-5-membered C.sub.4 -C.sub.10 alkylene chain which can be interrupted by oxygen, sulfur or N--R.sub. 7 ; R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylthio; C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylthio, each of which is monosubstituted or polysubstituted by halogen; R.sub.4, R.sub.5, R.sub.6 and R.sub.7 independently of one another are hydrogen or C.sub.1 -C.sub.4 alkyl; n is 0, 1 or 2; X is C.sub.1 -C.sub.3 alkyl, or C.sub.1 -C.sub.3 alkyl which is monosubstituted to trisubstituted by halogen; C.sub.1 -C.sub.3 alkoxy, or C.sub.1 -C.sub.3 alkoxy which is monosubstituted to trisubstituted by halogen; Y is halogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkyl which is monosubstituted to trisubstituted by halogen; C.sub.1 -C.sub.3 alkoxy, or C.sub.1 -C.sub.3 alkoxy which is monosubstituted to trisubstituted by halogen; cyclopropyl, methylamino or dimethylamino; and E is nitrogen or the methine group, and the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases have good selective herbicidal and growth-regulating properties when used pre- and post-emergence.
    • 其中R 1和R 2彼此独立地是氢,C 1 -C 8烷基或C 3 -C 8环烷基的式I(I)的N-吡啶磺酰基-N'-嘧啶基 - 和 - 三嗪基脲; C 2 -C 8烷基或C 3 -C 8环烷基,其各自被卤素单取代或多取代; C 1 -C 8烷基或C 3 -C 8环烷基,其各自被-NR 5 R 6,C 1 -C 4烷氧基或C 1 -C 4烷基-S(O)n - 取代; C 1 -C 4烷基或C 3 -C 6环烷基,其各自被C 2 -C 4烯基,C 5 -C 6环烯基,C 2 -C 6炔基或C 4 -C 8链烯基取代; C2-C4链烯基,C5-C6环烯基和C4-C8链二烯基可能被卤素单取代或多取代; 或R 1和R 2一起是可被氧,硫或N-R 7中断的4-5元C4-C10亚烷基链; R3是氢,卤素,C1-C4烷基,C1-C4烷氧基或C1-C4烷硫基; C 1 -C 4烷基,C 1 -C 4烷氧基或C 1 -C 4烷硫基,其各自被卤素单取代或多取代; R 4,R 5,R 6和R 7彼此独立地是氢或C 1 -C 4烷基; n为0,1或2; X是C 1 -C 3烷基或被卤素单取代至三取代的C 1 -C 3烷基; C 1 -C 3烷氧基或被卤素单取代至三取代的C 1 -C 3烷氧基; Y是卤素,被C 1 -C 3烷基或被卤素单取代至三取代的C 1 -C 3烷基; C 1 -C 3烷氧基或被卤素单取代至三取代的C 1 -C 3烷氧基; 环丙基,甲基氨基或二甲基氨基; E是氮或次甲基,这些化合物与胺,碱金属碱或碱土金属碱或季铵碱的盐在出苗前和出苗后使用时具有很好的选择性除草和生长调节特性。
    • 66. 发明授权
    • 1,5-diphenylpyrazole-3-carboxylic acid derivatives for the protection of
cultivated plants
    • 1,5-二苯基吡唑-3-羧酸衍生物,用于保护栽培植物
    • US4944790A
    • 1990-07-31
    • US325833
    • 1989-03-20
    • Hans MoserBeat BohnerWerner Fory
    • Hans MoserBeat BohnerWerner Fory
    • C07F7/18A01N25/04A01N25/32A01N43/40A01N43/56A01P13/00C07D231/14C07D401/12C07D405/12C07D409/12C07D417/12C07D487/04C07D521/00
    • C07D231/12A01N25/32C07D231/14C07D233/56C07D249/08C07D401/12C07D405/12C07D409/12C07D417/12C07D487/04
    • 1,5-diphenylpyrazole-3-carboxylic acid derivatives of the formula ##STR1## in which each of R.sub.a and R.sub.b, independently of the other represents halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -haloalkyl, C.sub.2 -C.sub.5 -alkenyl, C.sub.2 -C.sub.5 -alkynyl or cyano, n represents zero or an integer from 1 to 3, and OR.sub.1 represents hydroxy, a plant-physiologically tolerable salt radical or any desired ester radical, are capable of antagonizing specifically the phytotoxic action of phenoxypropionic acid ester herbicides of the formula II ##STR2## in which G represents ##STR3## in which Hal.sub.1 represents fluorine, chlorine, bromine, iodine or trifluoromethyl, Hal.sub.2 represents hydrogen, fluorine, chlorine, bromine or trifluoromethyl, Z represents nitrogen or methine (--CH.dbd.), X represents an oxygen or sulphur atom, R.sub.1 ' represents halogen, trifluoromethyl, nitro, cyano, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy and n represents 0, 1, 2 or 3 and T represents an ester, amide, cyanamide or oxime radical.Compositions, containing those components, as selective herbicides and the use of those two active ingredients for controlling weeds in crops of useful plants are described, as are also novel 1,5-diphenylpyrazole-3-carboxylic acid derivatives corresponding to the formula I and the preparation thereof.
    • 其中R a和R b各自独立地表示卤素,C 1 -C 5 - 烷基,C 1 -C 5 - 卤代烷基,C 2 -C 5 - 烯基的1,5-二苯基吡唑-3-羧酸衍生物 ,C 2 -C 5炔基或氰基,n表示0或1至3的整数,OR 1表示羟基,植物 - 生理上可耐受的盐基或任何所需的酯基,能够特异性地拮抗苯氧基丙酸酯的植物毒性作用 其中G代表其中Hal1代表氟,氯,溴,碘或三氟甲基的式Ⅱ的除草剂,其中G代表氢,氯,溴,碘或三氟甲基,Hal2代表氢,氟,氯,溴或三氟甲基,Z 表示氮或次甲基(-CH =),X表示氧或硫原子,R1'表示卤素,三氟甲基,硝基,氰基,C1-C4-烷基或C1-C4-烷氧基,n表示0,1,2或3 T代表酯,酰胺,氰胺或肟基。 描述了含有这些成分的作为选择性除草剂的组合物以及这两种活性成分用于控制有用植物作物中的杂草的用途,以及对应于式I的新的1,5-二苯基吡唑-3-羧酸衍生物和 的制备。
    • 67. 发明授权
    • Pyridylsulfonamides
    • 吡啶磺酰胺
    • US4923995A
    • 1990-05-08
    • US221847
    • 1988-07-20
    • Willy MayerWerner Fory
    • Willy MayerWerner Fory
    • C07D251/16A01N47/36C07D213/70C07D213/71C07D239/47C07D239/52C07D251/46C07D401/12C07D521/00
    • C07D213/70A01N47/36C07D521/00
    • Substituted N-arylsulfonyl-N'-pyrimidinylureas and N-arylsulfonyl-N'-triazinylureas of the general formula ##STR1## wherein R.sup.1 is a ##STR2## radical, R.sup.2 is hydrogen, halogen, nitro, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy or --COOR.sup.9,R.sup.3 is hydrogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy,R.sup.4 and R.sup.5 are each independently of the other hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.4 alkoxyalkyl, C.sub.3 -C.sub.6 cycloalkyl or --NR.sup.10 R.sup.11,R.sup.6 is hydrogen or C.sub.1 -C.sub.3 alkyl,R.sup.7 is hydrogen or methyl,R.sup.8 is C.sub.4 -C.sub.6 cycloalkanonyl which is unsubstituted or substituted by C.sub.1 -C.sub.3 alkyl or halogen; C.sub.3 -C.sub.6 cycloalkyl which is unsubstituted or substituted by one or more identical or different members selected from the group consisting of C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy, halogen or cyano; or is C.sub.5 -C.sub.6 cycloalkenyl which is unsubstituted or substituted by C.sub.1 -C.sub.3 alkyl, halogen or cyano,R.sup.9 is C.sub.1 -C.sub.3 alkyl or allyl,R.sup.10 and R.sup.11 are each independently of the other hydrogen or C.sub.1 -C.sub.4 alkyl,n is 0 or 1,X is sulfur or oxygen, andE and Z are each independently of the other nitrogen or the methine bridge, with the proviso that R.sup.8 is only unsubstituted or substituted C.sub.3 -C.sub.6 cycloalkyl if at the same time Z is nitrogen,and the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases, have good pre- and postemergence selective herbicidal and growth regulating properties.
    • 68. 发明授权
    • N-heterocyclosulfonyl-N'-triazinylureas
    • N-杂环磺酰基-N'-三嗪基脲
    • US4854963A
    • 1989-08-08
    • US198030
    • 1988-05-24
    • Werner ForyWilly Meyer
    • Werner ForyWilly Meyer
    • A01N47/36C07D521/00
    • C07D521/00A01N47/36
    • N-(3,4-Dihydro-2,2-dioxo-1,2-benzoxathiin-8-ylsulfonyl)-N'-pyrimidinylureas, N-(3,4-dihydro-2,2-dioxo-1,2-benzoxathiin-8-yl-sulfonyl)-N'-triazolylureas and N-(3,4-dihydro-2,2-dioxo-1,2-benzoxathiin-8-ylsulfonyl)-N'-triazinylureas of the formula ##STR1## wherein R.sup.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl or C.sub.2 -C.sub.5 alkoxyalkoxy,R.sup.2 and R.sup.3 are each independently of the other hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.4 is hydrogen, methyl or ethyl,W is oxygen or sulfur, andA is a radical ##STR2## in which formulae the substituents E.sup.1, E.sup.2, X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, X.sup.8, Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.6, Y.sup.6 1, Y.sup.8, Y.sup.8 1, Z.sup.3 and Z.sup.5 are customary organic radicals,and the salts thereof with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases have good pre- and postemergence selective herbicidal and growth regulating properties.
    • N-(3,4-二氢-2,2-二氧代-1,2-苯并恶嗪-8-基磺酰基)-N'-嘧啶基脲,N-(3,4-二氢-2,2-二氧代-1,2 - 苯并恶嗪-8-基 - 磺酰基)-N'-三唑基和N-(3,4-二氢-2,2-二氧代-1,2-苯并恶嗪-8-基磺酰基)-N'-三嗪基脲, (I)其中R1是氢,卤素,硝基,C1-C4烷基,C1-C4卤代烷基,C1-C4烷氧基,C1-C4卤代烷氧基,C1-C4烷氧基羰基,C1-C4烷硫基,C1-C4烷基亚磺酰基,C1-C4烷基磺酰基或C2-C5烷氧基烷氧基 中,R 2和R 3各自独立地为氢或C 1 -C 4烷基,R 4为氢,甲基或乙基,W为氧或硫,并且A为基团 + TR 取代基E1,E2,X1,X2,X3,X4,X5,X6,X7,X8,Y1,Y2,Y3,Y4,Y6,Y6 1,Y8,Y8 1,Z3和Z5为式 常规有机基团及其与胺,碱金属碱或碱土金属碱基或季铵碱的盐具有良好的芽前和芽后选择性除草和生长调节性质 ies。
    • 69. 发明授权
    • N-heterocyclosulfonyl-N'-pyrimidinylureas
    • N-杂环磺酰基-N'-嘧啶基脲
    • US4759791A
    • 1988-07-26
    • US872799
    • 1986-06-11
    • Werner ForyWilly Meyer
    • Werner ForyWilly Meyer
    • A01N47/36C07D521/00C07D411/12A01N43/54
    • C07D521/00A01N47/36
    • N-(3,4-Dihydro-2,2-dioxo-1,2-benzoxathiin-8-ylsulfonyl)-N'-pyrimidinylureas, N-(3,4-dihydro-2,2-dioxo-1,2-benzoxathiin-8-yl-sulfonyl)-N'-triazolylureas and N-(3,4-dihydro-2,2-dioxo-1,2-benzoxathiin-8-ylsulfonyl)-N'-triazinylureas of the formula ##STR1## wherein R.sup.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl or C.sub.2 -C.sub.5 alkoxyalkoxy,R.sup.2 and R.sup.3 are each independently of the other hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.4 is hydrogen, methyl or ethyl,W is oxygen or sulfur, andA is a radical ##STR2## in which formulae the substituents E.sup.1, E.sup.2, X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, X.sup.8, Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.6, Y.sup.61, Y.sup.8, Y.sup.81, Z.sup.3 and Z.sup.5 are customary organic radicals,and the salts thereof with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases have good pre- and postemergence selective herbicidal and growth regulating properties.
    • N-(3,4-二氢-2,2-二氧代-1,2-苯并恶嗪-8-基磺酰基)-N'-嘧啶基脲,N-(3,4-二氢-2,2-二氧代-1,2 - 苯并恶嗪-8-基 - 磺酰基)-N'-三唑基和N-(3,4-二氢-2,2-二氧代-1,2-苯并恶嗪-8-基磺酰基)-N'-三嗪基脲, (I)其中R1是氢,卤素,硝基,C1-C4烷基,C1-C4卤代烷基,C1-C4-烷氧基,C1-C4卤代烷氧基,C1-C4烷氧基羰基,C1-C4烷硫基,C1-C4烷基亚磺酰基,C1-C4烷基磺酰基或C2- C5烷氧基烷氧基,R2和R3各自独立地为另一个氢或C 1 -C 4烷基,R 4是氢,甲基或乙基,W是氧或硫,A是基团。 + TR 其中取代基E1,E2,X1,X2,X3,X4,X5,X6,X7,X8,Y1,Y2,Y3,Y4,Y6,Y61,Y8,Y81,Z3和Z5分别为 常规有机基团及其与胺,碱金属碱或碱土金属碱基或季铵碱的盐具有良好的芽前和芽后选择性除草和生长调节特性 s。
    • 70. 发明授权
    • O-substituted-phenylsulfonamides
    • O-取代苯基磺酰胺
    • US4739068A
    • 1988-04-19
    • US887762
    • 1986-07-21
    • Karl GassWerner ForyWilly MeyerWerner Topfl
    • Karl GassWerner ForyWilly MeyerWerner Topfl
    • C07D251/16A01N47/36C07D211/22C07D213/30C07D213/64C07D213/643C07D239/42C07D251/46C07D251/52C07D301/14C07D303/22C07D307/12C07D309/06C07D317/22C07D333/16C07D401/12C07D405/12C07D409/12C07D521/00C07D213/63C07D319/06
    • C07D213/30C07D213/643C07D301/14C07D303/22C07D307/12C07D309/06C07D317/22C07D333/16C07D521/00
    • N-Phenylsulfonyl-N'-pyrimidinylureas and --N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl,m is 0 or 1,E is nitrogen or the methine group,X is oxygen, sulfur, --SO-- or --SO.sub.2 --, andQ is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.
    • 具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基脲和-N'-三嗪基脲和这些化合物与胺,碱金属碱和碱土金属碱或季铵碱的盐具有良好的选择性除草和植物 应用芽前和芽后的生长调节性质。 式中R 1为氢,卤素,硝基,C 1 -C 4卤代烷基,C 1 -C 4烷基,C 1 -C 4烷氧基,C 2 -C 5烯基或C 1 -C 4烷氧基羰基,R 2为C 1 -C 3烷基或C 1 -C 3烷氧基,各自未被取代或被1至3个卤素 原子,R 3是卤素,氢,-NR 4 R 5,未被取代或被1至3个卤素原子或C 1 -C 4烷氧基取代的C 1 -C 3烷基,或是未被取代或被甲氧基,乙氧基或1至3个卤素原子取代的C 1 -C 3烷氧基, R4是氢或甲基,R5是氢,C1-C2烷基或甲氧基,A是C1-C4亚烷基或C2-C4亚烯基,各自是未取代的或被C1-C4烷基取代,m是0或1,E是氮或次甲基, X是氧,硫,-SO-或-SO 2 - ,Q是羟基,氰基或选自5-或6-元杂环和稠合同系物,胺,缩醛,酯,酮,苯基, 磺酸和羧酸,该基团可进一步被取代并具有官能结构。