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    • 62. 发明授权
    • Nano-sized particles for stabilizing viscoelastic surfactant fluids
    • 用于稳定粘弹性表面活性剂流体的纳米级颗粒
    • US08278252B2
    • 2012-10-02
    • US11849820
    • 2007-09-04
    • James B. CrewsTianping HuangJames H. TreadwayJohn R. Willingham
    • James B. CrewsTianping HuangJames H. TreadwayJohn R. Willingham
    • C09K8/58C09K8/68
    • C09K8/602C09K8/665C09K8/68C09K8/74C09K8/845C09K8/86C09K2208/10C09K2208/30
    • An aqueous, viscoelastic fluid gelled with a viscoelastic surfactant (VES) is stabilized and improved with an effective amount of an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxides, alkali metal hydroxides, transition metal oxides, transition metal hydroxides, post-transition metal oxides, and post-transition metal hydroxides. These fluids are more stable and have a reduced or no tendency to precipitate, particularly at elevated temperatures. The additives may reduce the amount of VES required to maintain a given viscosity. These stabilized, enhanced, aqueous viscoelastic fluids may be used as treatment fluids for subterranean hydrocarbon formations, such as in hydraulic fracturing. The particle size of the magnesium oxide or other agent may be nanometer scale, which scale may provide unique particle charges that use chemisorption, crosslinking and/or other chemistries to associate and stabilize the VES fluids.
    • 用粘弹性表面活性剂(VES)凝胶化的水性粘弹性体,用有效量的碱土金属氧化物,碱土金属氢氧化物,碱金属氧化物,碱金属氢氧化物,过渡金属氧化物,过渡金属氢氧化物,柱 过渡金属氧化物和过渡后金属氢氧化物。 这些流体更稳定,并且具有降低或没有沉淀的倾向,特别是在升高的温度下。 添加剂可以减少维持给定粘度所需的VES的量。 这些稳定的,增强的水性粘弹性流体可以用作地下烃地层的处理流体,例如在水力压裂中。 氧化镁或其它试剂的粒径可以是纳米级,其规模可以提供使用化学吸附,交联和/或其它化学物质来缔合和稳定VES流体的独特的颗粒电荷。
    • 64. 发明申请
    • Particles in Oil for Viscoelastic Surfactant Gelled Fluids
    • 用于粘弹性表面活性剂凝胶液的油中的颗粒
    • US20110224110A1
    • 2011-09-15
    • US13113375
    • 2011-05-23
    • Tianping HuangJames B. Crews
    • Tianping HuangJames B. Crews
    • C09K8/82
    • C09K8/506C09K8/5045C09K8/68C09K2208/10C09K2208/26C09K2208/30
    • Fluids viscosified with viscoelastic surfactants (VESs) may have their fluid loss properties improved with the presence of at least one mineral oil in combination with at least one particulate fluid loss control agent that may be an alkaline earth metal oxides, alkaline earth metal hydroxides, transition metal oxides, transition metal hydroxides, and mixtures thereof. The mineral oil may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the mineral oil is added to the fluid after it has been substantially gelled. The particulate fluid loss control agent may be added in any order relative to the VES and the mineral oil fluid loss control agent. The mineral oil may enhance the ability of a particulate fluid loss control agent to reduce fluid loss. The presence of the mineral oil may also eventually reduce the viscosity of the VES-gelled aqueous fluid.
    • 用粘弹性表面活性剂(VES)粘稠的流体可以使至少一种矿物油与至少一种颗粒状流体损失控制剂(其可以是碱土金属氧化物,碱土金属氢氧化物,过渡金属) 金属氧化物,过渡金属氢氧化物及其混合物。 矿物油可以最初分散在液体的内部不连续相中。 在一个非限制性实施方案中,矿物油在其基本上凝胶化之后加入到流体中。 颗粒状流体损失控制剂可以相对于VES和矿物油损失控制剂以任何顺序加入。 矿物油可以增强颗粒状流体损失控制剂减少流体损失的能力。 矿物油的存在也可能最终降低VES-凝胶水溶液的粘度。
    • 66. 发明授权
    • Particles in oil for viscoelastic surfactant gelled fluids
    • 用于粘弹性表面活性剂凝胶液的油中的颗粒
    • US07967068B2
    • 2011-06-28
    • US12047090
    • 2008-03-12
    • Tianping HuangJames B. Crews
    • Tianping HuangJames B. Crews
    • E21B43/22
    • C09K8/506C09K8/5045C09K8/68C09K2208/10C09K2208/26C09K2208/30
    • Fluids viscosified with viscoelastic surfactants (VESs) may have their fluid loss properties improved with the presence of at least one mineral oil in combination with at least one particulate fluid loss control agent that may be an alkaline earth metal oxides, alkaline earth metal hydroxides, transition metal oxides, transition metal hydroxides, and mixtures thereof. The mineral oil may initially be dispersed oil droplets in an internal, discontinuous phase of the fluid. In one non-limiting embodiment, the mineral oil is added to the fluid after it has been substantially gelled. The particulate fluid loss control agent may be added in any order relative to the VES and the mineral oil fluid loss control agent. The mineral oil may enhance the ability of a particulate fluid loss control agent to reduce fluid loss. The presence of the mineral oil may also eventually reduce the viscosity of the VES-gelled aqueous fluid.
    • 用粘弹性表面活性剂(VES)粘稠的流体可以使至少一种矿物油与至少一种可能是碱土金属氧化物,碱土金属氢氧化物,过渡金属的颗粒状流体损失控制剂 金属氧化物,过渡金属氢氧化物及其混合物。 矿物油可以最初分散在液体的内部不连续相中。 在一个非限制性实施方案中,矿物油在其基本上凝胶化之后加入到流体中。 颗粒状流体损失控制剂可以相对于VES和矿物油损失控制剂以任何顺序加入。 矿物油可以增强颗粒状流体损失控制剂减少流体损失的能力。 矿物油的存在也可能最终降低VES-凝胶水溶液的粘度。
    • 67. 发明授权
    • Drilling fluids for oil and gas reservoirs with high carbonate contents
    • 含碳酸盐含量高的油气藏钻井液
    • US07942215B2
    • 2011-05-17
    • US12606502
    • 2009-10-27
    • Tianping HuangJames B. CrewsJohn R. Willingham
    • Tianping HuangJames B. CrewsJohn R. Willingham
    • E21B21/00C09K8/06
    • C09K8/12C09K8/506C09K8/524C09K2208/26C09K2208/30
    • Compositions including relatively low reactivity acids, mixed with viscoelastic surfactants (VESs) and internal breakers may serve as drilling fluids to open underground hydrocarbon reservoirs with carbonate contents of 10 wt % or above. The drilling fluids have low viscosities in the drilling pipe. After the fluid flows out of the drill bit, the acids react with carbonates in the formation thereby increasing the pH of the drilling fluids causing the VES to gel the fluid at the bottom of the hole and the downhole annulus between the drilling pipe and the formation rock. The viscosified drilling fluid will reduce fluid loss and will carry no dissolved drilling debris to the surface. After drilling through the targeted formation, the internal breakers in the viscosified drilling fluids will break down the fluids to permit their removal, and the well is ready to produce with very little or no near well bore damage.
    • 包括相对低反应性酸,与粘弹性表面活性剂(VES)和内部破碎剂混合的组合物可用作钻井液以打开碳酸盐含量为10重量%或更高的地下储层。 钻井液在钻井管中的粘度低。 在液体流出钻头之后,酸与地层中的碳酸盐反应,从而增加钻井液的pH,导致VES凝结孔底部的流体和钻井管与地层之间的井下环隙 岩。 增稠的钻井液将减少流体损失,并且不会在表面上携带溶解的钻屑。 在钻井目标地层之后,粘稠钻井液中的内部破碎机将分解流体以允许它们的移除,并且该井准备好产生很少或没有接近井筒的损坏。
    • 69. 发明申请
    • Lost Circulation Control Fluids for Naturally Fractured Carbonate Formations
    • 自然裂缝碳酸盐岩层的失控循环控制流体
    • US20110083902A1
    • 2011-04-14
    • US12907529
    • 2010-10-19
    • Tianping HuangJames B. CrewsDavid E. Clark
    • Tianping HuangJames B. CrewsDavid E. Clark
    • C09K8/02E21B21/00E21B7/00
    • C09K8/508C09K8/12C09K2208/30
    • Compositions including relatively low reactivity acids and having a pH of from about 2 to about 5, mixed with viscoelastic surfactants (VESs) and internal breakers may serve as fluids, in a non-limiting embodiment as drill-in fluids, to open underground hydrocarbon reservoirs with carbonate contents of 10 wt % or above. The fluids initially have low viscosities. After the fluid flows out of the drill bit, the acids react with carbonates in the formation thereby increasing the pH of the fluids causing the VES to gel the fluid at the bottom of the hole and within the formation rock. Even when the subterranean formation contains naturally-occurring fractures, the viscosified fluid will reduce fluid loss into the formation. After drilling through the targeted formation, internal breakers in the viscosified fluids will break down the fluids to permit their removal, and production of the well with very little or no near well bore damage.
    • 与粘弹性表面活性剂(VES)和内部破碎剂混合的包含相对较低反应性酸并具有约2至约5的pH的组合物在非限制性实施方式中可作为钻井液用于开放地下储层 碳酸盐含量为10重量%以上。 液体最初具有低粘度。 在流体从钻头流出之后,酸与地层中的碳酸盐反应,从而增加流体的pH,导致VES凝结孔底部和地层岩内的流体。 即使当地下地层含有天然裂缝时,粘稠流体也会减少流体进入地层的流失。 在通过目标地层钻井后,粘稠流体中的内部破碎物将分解流体,以允许其移除,并且井的产生很少或没有接近井眼损坏。
    • 70. 发明申请
    • Clay Stabilization with Nanoparticles
    • 粘土稳定与纳米颗粒
    • US20110000672A1
    • 2011-01-06
    • US12277825
    • 2008-11-25
    • Tianping Huang
    • Tianping Huang
    • E21B43/26C09K8/84
    • C09K8/516C09K8/032C09K8/5045C09K8/64C09K8/665C09K8/74C09K8/845C09K2208/10C09K2208/12
    • A treating fluid may contain an effective amount of a particulate additive to stabilize clays, such as clays in a subterranean formation, by inhibiting or preventing them from swelling and/or migrating, where the particulate additive is an alkaline earth metal oxide, alkaline earth metal hydroxide, alkali metal oxide, alkali metal hydroxide, transition metal oxide, transition metal hydroxide, post-transition metal oxide, post-transition metal hydroxide, piezoelectric crystal, and/or pyroelectric crystal. The particle size of the magnesium oxide or other agent may be nanometer scale, which scale may provide unique particle charges that help stabilize the clays. These treating fluids may be used as treatment fluids for subterranean hydrocarbon formations, such as in hydraulic fracturing, completion fluids, gravel packing fluids and fluid loss pills. The carrier fluid used in the treating fluid may be aqueous, brine, alcoholic or hydrocarbon-based.
    • 处理流体可以含有有效量的颗粒状添加剂以稳定粘土,例如地层中的粘土,通过抑制或防止其膨胀和/或迁移,其中颗粒添加剂是碱土金属氧化物,碱土金属 氢氧化物,碱金属氧化物,碱金属氢氧化物,过渡金属氧化物,过渡金属氢氧化物,过渡后金属氧化物,后过渡金属氢氧化物,压电晶体和/或热电晶体。 氧化镁或其它试剂的粒度可以是纳米级,其规模可以提供有助于稳定粘土的独特的颗粒电荷。 这些处理流体可以用作地下烃地层的处理流体,例如在水力压裂,完井液,砾石填充液和流体损失丸中。 在处理流体中使用的载体流体可以是水性,盐水,醇或烃类。