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    • 65. 发明授权
    • Removal process for tungsten etchback precipitates
    • 钨回蚀沉淀物的去除工艺
    • US5670019A
    • 1997-09-23
    • US606831
    • 1996-02-26
    • Yuan-Chang Huang
    • Yuan-Chang Huang
    • H01L21/02H01L21/3213H01L21/00B44C1/22C23F1/00
    • H01L21/02071
    • This invention provides a method of cleaning integrated circuit wafers which effectively removes precipitates formed as a result of the tungsten etchback process. When tungsten is used to fill via holes in an inter-metal dielectric layer an adhesion layer of titanium nitride, TiN, is required to provide good adhesion. As a result of the tungsten etchback, wherein fluorine based etchants are used, precipitates of TiF.sub.3 can form which are extremely difficult to remove. Methods, such as in-situ bake after the tungsten etchback, are used to prevent the formation of the precipitates but do not remove them after they are formed. This invention teaches a method using a strong oxidizing agent, such as H.sub.2 O.sub.2, to cause an oxidation-reduction reaction which converts the precipitates to a water soluble form. The water soluble form of the precipitates are then removed using a water rinse and spin dry process.
    • 本发明提供了一种清洁集成电路晶片的方法,其有效地去除了由钨回蚀工艺形成的沉淀物。 当钨用于填充金属间电介质层中的通孔时,需要氮化钛(TiN)的粘合层以提供良好的粘附性。 作为钨回蚀的结果,其中使用氟基蚀刻剂,可以形成极难去除的TiF 3的析出物。 使用诸如在钨回蚀之后的原位烘烤的方法来防止沉淀物的形成,但是在它们形成之后不能将其去除。 本发明教导了使用强氧化剂如H 2 O 2的方法引起将沉淀物转化为水溶性形式的氧化还原反应。 然后使用水冲洗和旋转干燥方法除去沉淀物的水溶性形式。