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61. 发明授权

US07416867B2 Enzymatic production of (meth)acrylic acid esters 有权
标题翻译：（甲基）丙烯酸酯的酶促生产
公开(公告)号：US07416867B2
公开(公告)日：2008-08-26
申请号：US10545075
申请日：2004-01-28
申请人： Dietmar Haering , Eva Wagner , Bernd Bruchmann , Erich Beck , Bernhard Hauer
发明人： Dietmar Haering , Eva Wagner , Bernd Bruchmann , Erich Beck , Bernhard Hauer
IPC分类号： C12P7/64 , C12P7/62 , C12N9/18 , C12N9/20
CPC分类号： C08F220/26 , C12P7/04 , C12P7/06 , C12P7/62 , C12P17/181 , Y02E50/17 , Y02T50/678
摘要： A method for the production of partially esterified (meth)acrylic acid esters of polyalcohols and the use thereof.
摘要翻译：一种多元醇部分酯化（甲基）丙烯酸酯的制造方法及其用途。

62. 发明授权

US06410130B1 Coatings with a cholesteric effect and method for the production thereof 有权
标题翻译：具有胆甾醇效果的涂料及其制造方法
公开(公告)号：US06410130B1
公开(公告)日：2002-06-25
申请号：US09486695
申请日：2000-03-02
申请人： Peter Schuhmacher , Norbert Schneider , Volker Richter , Harald Keller , Peter Blaschka , Günter Bettinger , Frank Meyer , Erich Beck , Karl Siemensmeyer , Helmut Steininger , Wolfgang Best
发明人： Peter Schuhmacher , Norbert Schneider , Volker Richter , Harald Keller , Peter Blaschka , Günter Bettinger , Frank Meyer , Erich Beck , Karl Siemensmeyer , Helmut Steininger , Wolfgang Best
IPC分类号： B32B516
CPC分类号： C09K19/38 , C08G63/68 , C08G64/045 , C09B67/0098 , C09D5/36 , C09K19/00 , Y10T428/1005 , Y10T428/24901 , Y10T428/254 , Y10T428/265 , Y10T428/2982 , Y10T428/2998
摘要： Improved cholesteric special-effect layers are obtainable by comminuting cholesteric layers. These cholesteric layers are produced by applying at least one layer of a reactive, pourable cholesteric mixture to a moving substrate, by casting, and forming a solid cholesteric layer.
摘要翻译：通过粉碎胆甾醇层获得改进的胆甾型特殊效果层。通过将至少一层反应性可倾倒的胆固醇混合物施加到移动的基底上，通过浇铸和形成固体胆甾醇层来制备这些胆甾型层。

63. 发明授权

US06319983B1 (Meth)acrylic esters containing urethane groups, their preparation, radiation-curable coating compositions and a process for preparing these coating compositions 失效
标题翻译：（甲基）丙烯酸酯，其制备方法，可辐射固化涂料组合物和制备这些涂料组合物的方法
公开(公告)号：US06319983B1
公开(公告)日：2001-11-20
申请号：US09539321
申请日：2000-03-30
申请人： Matthias Lokai , Erich Beck , Wolfgang Reich , Peter Enenkel , Herbert Marky , Rainer Königer
发明人： Matthias Lokai , Erich Beck , Wolfgang Reich , Peter Enenkel , Herbert Marky , Rainer Königer
IPC分类号： C09D17514
CPC分类号： C08G18/68 , C07C269/02 , C09D175/16 , C07C271/08
摘要： The present invention relates to a process for preparing nondispersing (meth)acrylic esters containing urethane groups, comprising a) reacting at least one hydroxyl-containing compound with (meth)acrylic acid in a solvent, to form an ester; b) removing the solvent and optionally a part of unreacted (meth) acrylic acid; c) reacting the mixture resulting from stage a) or b) with at least one epoxy-functional compound in an amount corresponding to the acid number of the mixture; and d) reacting the mixture resulting from stage c) with at least one compound containing isocyanate groups, and such esters obtainable in this way, and radiation-curable coating compositions comprising said esters, and a process for preparing these coating compositions.
摘要翻译：本发明涉及一种制备含有氨基甲酸酯基团的不分散（甲基）丙烯酸酯的方法，包括：a）使至少一种含羟基化合物与（甲基）丙烯酸在溶剂中反应形成酯; b）除去溶剂和使任选的一部分未反应的（甲基）丙烯酸; c）使由步骤a）或b）得到的混合物与至少一种与混合物的酸值相当的量的环氧官能化合物反应; 和d）将由步骤c）得到的混合物与至少一种含有异氰酸酯基团的化合物反应，以及以这种方式获得的这些酯，以及包含所述酯的可辐射固化涂料组合物，以及制备这些涂料组合物的方法。

64. 发明授权

US06207727B1 Photoinitiator mixtures containing acylphosphinoxides and benzophenone derivatives 有权
标题翻译：含有酰基膦氧化物和二苯甲酮衍生物的光引发剂混合物
公开(公告)号：US06207727B1
公开(公告)日：2001-03-27
申请号：US09147459
申请日：1998-12-30
申请人： Erich Beck , Christof Kandzia , Bernhard Prantl , Matthias Lokai , Peter Enenkel , Edmund Keil , Klaus Menzel
发明人： Erich Beck , Christof Kandzia , Bernhard Prantl , Matthias Lokai , Peter Enenkel , Edmund Keil , Klaus Menzel
IPC分类号： C08F246
CPC分类号： G03F7/029 , C08F2/50
摘要： A photoinitiator mixture comprising a) at least one acyl- or diacylphosphine oxide of the formula I and b) at least one benzophenone derivative of the formula
摘要翻译：一种光引发剂混合物，其包含a）至少一种式I和b的酰基或二酰基氧化膦，b）至少一种式

65. 发明授权

US6103453A Photoinitiator blends 失效
公开(公告)号：US6103453A
公开(公告)日：2000-08-15
申请号：US268725
申请日：1999-03-17
申请人： Bernhard Prantl , Erich Beck , Matthias Lokai , Christof Kandzia
发明人： Bernhard Prantl , Erich Beck , Matthias Lokai , Christof Kandzia
IPC分类号： C07F9/53 , C08F2/50 , G03F7/029 , G03C1/73
CPC分类号： C08F2/50 , G03F7/029 , Y10S430/117 , Y10S522/908
摘要： A photoinitiator blend, containinga) at least one monoacylphosphine oxide of formula I ##STR1## in which R.sup.1 denotes C.sub.1 -C.sub.18 alkyl; C.sub.1 -C.sub.4 alkyl, C.sub.5 -C.sub.8 cycloalkyl, C.sub.7 -C.sub.9 phenylalkyl, phenyl, naphthyl, biphenyl, all substituted by halogen or C.sub.1 -C.sub.6 alkoxy; phenyl, naphthyl or biphenylyl, all mono- or poly-substituted by halogen, C.sub.1 -C.sub.12 alkyl and/or C.sub.1 -C.sub.12 alkoxy; or a monovalent N--, O--, or S--containing 5-membered or 6-membered heterocyclic radical,R.sup.2 denotes phenyl, naphthyl, biphenylyl; phenyl, naphthyl or biphenylyl, all mono- or poly-substituted by halogen, C.sub.1 -C.sub.12 alkyl and/or C.sub.1 -C.sub.12 alkoxy; a monovalent N--, O--, or S--containing 5-membered or 6-membered heterocyclic radical, C.sub.1 -C.sub.18 alkoxy, phenoxy; phenoxy substituted by halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy; benzyloxy, cyclohexyloxy or R.sup.2 and R.sup.1 form a ring together with the phosphorus atom,R.sup.3 denotes C.sub.1 -C.sub.18 alkyl; C.sub.1 -C.sub.4 alkyl, C.sub.5 -C.sub.8 cycloalkyl, C.sub.7 -C.sub.9 phenylalkyl, phenyl, naphthyl, biphenylyl, all substituted by halogen or C.sub.1 -C.sub.6 alkoxy; phenyl, naphthyl or biphenylyl, all mono- or poly-substituted by halogen, C.sub.1 -C.sub.12 alkyl and/or C.sub.1 -C.sub.12 alkoxy; a monovalent N--, O--, or S--containing 5-membered or 6-membered heterocyclic radical or a group ##STR2## in which X C.sub.2 -C.sub.8 alkene, cyclohexylene or unsubstituted or; phenylene, or biphenylene, both substituted by halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy;b) at least one diacylphosphine oxide of formula II ##STR3## in which R.sup.4 denotes C.sub.1 -C.sub.18 alkyl; C.sub.1 -C.sub.4 alkyl, C.sub.5 -C.sub.8 cycloalkyl, C.sub.7 -C.sub.9 phenylalkyl, phenyl, naphthyl, biphenylyl, all substituted by halogen or C.sub.1 -C.sub.6 alkoxy; phenyl, naphthyl or biphenylyl, all mono- or poly-substituted by halogen, C.sub.1 -C.sub.12 alkyl and/or C.sub.1 -C.sub.12 alkoxy; a monovalent N--, O--, or S--containing 5-membered or 6-membered heterocyclic radical, C.sub.1 -C.sub.18 alkoxy, phenoxy; phenoxy substituted by halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy; benzyloxy, cyclohexyloxy andR.sup.5 and R.sup.6 independently denote C.sub.1 -C.sub.18 alkyl; C.sub.1 -C.sub.4 alkyl, C.sub.5 -C.sub.8 cycloalkyl, C.sub.7 -C.sub.9 phenylalkyl, phenyl, naphthyl, biphenylyl, all substituted by halogen or C.sub.1 -C.sub.6 alkoxy; phenyl, naphthyl or biphenylyl, all mono- or poly-substituted by halogen, C.sub.1 -C.sub.12 alkyl and/or C.sub.1 -C.sub.12 alkoxy; a monovalent N--, O--, or S--containing 5-membered or 6-membered heterocyclic radical.

66. 发明授权

US6063957A Preparation of esters of low residual acid content from .alpha., .beta.-ethylenically unsaturated carboxylic acids and hydroxyl-containing polymers 失效
标题翻译：从α，β-烯属不饱和羧酸和含羟基聚合物制备低残留酸含量的酯
公开(公告)号：US6063957A
公开(公告)日：2000-05-16
申请号：US64001
申请日：1998-04-21
申请人： Rainer Koniger , Wolfgang Reich , Erich Beck , Helmut Gruner
发明人： Rainer Koniger , Wolfgang Reich , Erich Beck , Helmut Gruner
IPC分类号： C08G65/32 , C07C67/08 , C08G18/83 , C08G59/00 , C08G59/16 , C08G59/42 , C08G63/21 , C08G63/47 , C08G63/52 , C08G63/78 , C08G63/91 , C08G65/332 , C08G65/48 , C07C67/48
CPC分类号： C08G65/3322 , C07C67/08 , C08G18/831 , C08G59/00 , C08G59/1461 , C08G59/42 , C08G63/21 , C08G63/47 , C08G63/918 , C08G2650/16 , C08G2650/20 , C08L2312/00
摘要： A process for preparing esters E of low residual acid content from .alpha.,.beta.-monoethylenically unsaturated C.sub.3 -C.sub.6 mono- and dicarboxylic acids S and hydroxyl-containing polycondensates P, wherea) the acid S and the polycondensate P or the monomeric and/or oligomeric and/or polymeric components which form the polycondensate P, are reacted in the presence or absence of a solvent and/or of an esterification catalyst and/or of further additives, with removal of the water which forms, andb) the unreacted acid S is removed by distillation,comprises adding water for the distillative removal of the acid S in step b).
摘要翻译：从α，β-单烯属不饱和C3-C6单羧酸和二羧酸S和含羟基的缩聚物P制备低残留酸含量的酯E的方法，其中a）酸S和缩聚物P或单体和/或形成缩聚物P的低聚物和/或聚合物组分在存在或不存在溶剂和/或酯化催化剂和/或其它添加剂的情况下反应，除去形成的水，和b）未反应的酸通过蒸馏除去S，包括在步骤b）中加入用于蒸馏除去酸S的水。

67. 发明授权

US5859084A Radiation-curable compositions containing photoinitiators linked by a covalent bond 失效
标题翻译：含有通过共价键连接的光引发剂的可辐射固化组合物
公开(公告)号：US5859084A
公开(公告)日：1999-01-12
申请号：US679570
申请日：1996-07-15
申请人： Jochen Schroder , Wolfgang Reich , Erich Beck , Martin Fischer , Wolfram Weiss
发明人： Jochen Schroder , Wolfgang Reich , Erich Beck , Martin Fischer , Wolfram Weiss
IPC分类号： C07C45/63 , C07C225/16 , C07C323/22 , C08F2/48 , C08F2/50 , C09D4/00 , C09D4/02 , G03F7/039 , C07C69/96
CPC分类号： G03F7/039 , C07C225/16 , C07C323/22 , C07C45/63 , Y10S522/905
摘要： A process for the preparation of a radiation-curable acrylate composition, wherein to compounds A containing at least 2 acrylic groups there are added benzophenone derivatives which are not copolymerizable by free-radical copolymerization and which contain at least one primary or secondary amino group or a hydroxyl group or a mercapto group.
摘要翻译：一种制备可辐射固化的丙烯酸酯组合物的方法，其中对于含有至少2个丙烯酸基团的化合物A，加入了不能通过自由基共聚反应并且含有至少一个伯或仲氨基的二苯甲酮衍生物或羟基或巯基。

68. 发明授权

US5798147A Process for coating and printing substrates 失效
标题翻译：涂布和印刷基材的工艺
公开(公告)号：US5798147A
公开(公告)日：1998-08-25
申请号：US836874
申请日：1997-05-23
申请人： Erich Beck , Frank Meyer , Ulrich Poth , Karl Siemensmeyer , Claudia Sierakowski , Norbert Greif , Werner Ostertag , Michael Zirnstein , Reinhold Leyrer , Ekkehard Jahns , Karl-Heinz Etzbach , Peter Schuhmacher
发明人： Erich Beck , Frank Meyer , Ulrich Poth , Karl Siemensmeyer , Claudia Sierakowski , Norbert Greif , Werner Ostertag , Michael Zirnstein , Reinhold Leyrer , Ekkehard Jahns , Karl-Heinz Etzbach , Peter Schuhmacher
IPC分类号： C09K19/38 , C08F20/28 , C09B67/00 , C09D4/00 , C09D4/06 , C09D5/29 , C09D5/36 , C09D11/02 , C09D11/10 , C09D11/16 , C09K19/00 , C09K19/54 , C09K19/58 , B05D3/02 , B05D3/06
CPC分类号： C09K19/586 , C08F20/28 , C09B67/0098 , C09D11/101 , C09D11/106 , C09D11/16 , C09D4/06 , C09D5/36 , C09K19/00 , C09K19/542
摘要： A process for coating or printing substrates with a coating or printing composition comprises applying a polymerizable material containing liquid-crystalline, polymerizable monomers which carry at least two polymerizable groups for coating and at least one polymerizable group for printing, to the substrate, and subsequently carrying out the polymerization, where the coating composition or the printing composition comprises a.sub.1) a chiral liquid-crystalline monomer and b) a polymeric binder and/or monomeric compounds which can be converted into the polymeric binder by polymerization, or, in the case of emulsion coatings and printing inks, a dispersion auxiliary d), or the coating composition or the printing composition comprises a.sub.2) an achiral liquid-crystalline monomer, b) a polymeric binder and/or monomeric compounds which can be converted into the polymeric binder by polymerization, or, in the case of emulsion coatings and printing inks, a dispersion auxiliary d), and c) a non-liquid-crystalline chiral compound.
摘要翻译： PCT No.PCT / EP95 / 04576 Sec。 371日期1997年5月23日 102（e）日期1997年5月23日PCT提交1995年11月21日PCT公布。公开号WO96 / 02597 日本1996年2月1日利用涂料或印刷组合物涂布或印刷基材的方法包括将含有至少两个可聚合基团的可液晶聚合单体和至少一个用于印刷的可聚合基团的可聚合材料加入到底物，随后进行聚合，其中涂料组合物或印刷组合物包含a1）手性液晶单体和b）可通过聚合转化为聚合物粘合剂的聚合物粘合剂和/或单体化合物，或者，在乳液涂料和印刷油墨的情况下，分散助剂d）或涂料组合物或印刷组合物包含a2）非手性液晶单体，b）聚合粘合剂和/或单体化合物，其可以转化为聚合物粘合剂，或者在乳液涂料和印刷油墨的情况下，分散助剂d）和 c）非液晶手性化合物。

69. 发明授权

US5496591A Radiation-curable binders 失效
标题翻译：可辐射固化的粘合剂
公开(公告)号：US5496591A
公开(公告)日：1996-03-05
申请号：US239860
申请日：1994-05-09
申请人： Reinhard Lang , Erich Beck , Edmund Keil , Adolf Nuber , Harro Petersen , Hans Renz , Horst Schmidt , Wolfram Weiss
发明人： Reinhard Lang , Erich Beck , Edmund Keil , Adolf Nuber , Harro Petersen , Hans Renz , Horst Schmidt , Wolfram Weiss
IPC分类号： C08F299/02 , C08F290/00 , C08F290/14 , C08G12/40 , C08G12/42 , C08G14/12 , C09D161/34 , C08J7/04
CPC分类号： C08G14/12 , C08F290/14 , C09D161/34
摘要： Radiation-curable binders which are obtained by reactingA) an amine/formaldehyde condensate having a molar ratio of formaldehyde to amino groups of from 1:1 to 2:1 withB) one or more esters, having a free hydroxyl group, of acrylic acid or of methacrylic acid with polyalcohols which contain from two to four alcoholic hydroxyl groups, from 0.1 to 0.3 hydroxyl equivalent of component B) being used per methylol equivalent of component A),in the presence of a strong acid are suitable for use in coating materials.
摘要翻译：通过使A）甲醛与氨基的摩尔比为1：1至2：1的胺/甲醛缩合物与B）一种或多种具有游离羟基的丙烯酸酯反应得到的可辐射固化粘合剂酸或甲基丙烯酸与含有2至4个醇羟基的多元醇，0.1至0.3个羟基当量的组分B）相对于组分A）的羟甲基当量）在强酸存在下使用适用于涂层材料

70. 发明授权

US5366047A Disc brake with ring-shaped pressing element 失效
标题翻译：碟形制动器带环形按压元件
公开(公告)号：US5366047A
公开(公告)日：1994-11-22
申请号：US987467
申请日：1992-12-07
申请人： Erich Beck , Manfred Minning , Emil Naumann , Joseph Wese
发明人： Erich Beck , Manfred Minning , Emil Naumann , Joseph Wese
IPC分类号： F16D65/00 , F16D65/14 , F16D65/18 , F16D65/38
CPC分类号： F16D65/0006 , F16D2125/06
摘要： In disc brakes, disturbing noises, such as whistling or squealing, occurring during braking operations can be prevented if the brake shoe, to be pressed against a brake disc by a pressure member, for example a hydraulically actuated piston, is taken along in the circumferential direction of the latter as soon as the brake shoe comes into contact with the brake disc, and is laid against bearing faces of a brake anchor plate. Accordingly, the pressure member is provided, on its end face facing the brake shoe, a pressing element which projects beyond the end face, is transversely movable to a limited extent and returns automatically to its initial position again, and which is arranged in the pressure member so as to be axially displaceable counter to a return force which, in the event of mutual contact between the pressing element and brake shoe, is lower than the pressing force of the pressure member.
摘要翻译：在盘式制动器中，如果通过压力构件例如液压致动的活塞压在制动盘上的制动蹄沿着圆周方向被取走，则可以防止在制动操作期间发生诸如哨声或尖叫声的干扰噪声一旦制动蹄与制动盘接触，该制动器的方向就放在制动器锚板的轴承面上。因此，压力构件在其面向制动蹄的端面上设置有突出超过端面的按压元件，其横向可移动到有限的程度并且再次自动返回到其初始位置，并且被设置在压力构件相对于在按压元件和制动蹄之间相互接触的情况下低于压力构件的按压力的回复力轴向移动。

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