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61. 发明授权

US06348307B1 Silver halide photographic light-sensitive material 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US06348307B1
公开(公告)日：2002-02-19
申请号：US09625324
申请日：2000-07-25
申请人： Takanori Hioki
发明人： Takanori Hioki
IPC分类号： G03C112
CPC分类号： G03C1/14
摘要： An object of the present invention is to provide a silver halide photographic light-sensitive material which exhibits a high sensitivity and less residual color. A silver halide photographic light-sensitive material is described, comprising at least one compound represented by the following general formula (I): wherein dye1 represents a methine dye; M1 represents a charge-balanced counter ion; m1 represents the number of M1 required to neutralize the charge of the molecule; q and p each represents an integer of 1 or more; R1 represents an alkyl group represented by R1a, R1b, R1c, or R1d: R1a: (Qa)rCON−SO2Ra R1b: (Qb)sSO2N−CORb R1c: (Qc)tCON−CORc R1d: (Qd)uSO2N−SO2Rd wherein Ra, Rb, Rc and Rd each represents an alkyl group, aryl group, heterocyclic group, alkoxyl group, aryloxy group, heterocyclyloxy group or amino group; Qa, Qb, Qc or Qd each represents a methylene group; and r, s, t and u each represents an integer of 1 or more; and R2 represents an alkyl group represented by the following general formula: R2a: A1—SO3− R2b: A2—X wherein A1 represents a connecting group containing at least one atom other than carbon atom; A2 represents a connecting group; and X represents a carboxyl group, sulfate group, phosphoric acid group or boric acid group.
摘要翻译：本发明的目的是提供一种表现出高灵敏度和较少残留颜色的卤化银照相感光材料。描述了卤化银照相感光材料，其包含至少一种由以下通式（I）表示的化合物：其中染料1表示次甲基染料; M1表示电荷平衡的抗衡离子; m1表示中和分子电荷所需的M1数; q和p分别表示1以上的整数， R1表示由R1a，R1b，R1c或R1d表示的烷基：R1a：（Qa）rCON-SO2RaR1b :( Qb）sSO2N-CORbR1c：（Qc）tCON-CORcR1d：（Qd）uSO2N-SO2Rd，其中Ra，Rb，Rc 和Rd各自表示烷基，芳基，杂环基，烷氧基，芳氧基，杂环氧基或氨基; Qa，Qb，Qc或Qd各自表示亚甲基; 并且r，s，t和u各自表示1以上的整数。 R2表示由以下通式表示的烷基：R2a：A1-SO3-R2b：A2-X，其中A1表示含有除碳原子以外的至少一个原子的连接基团; A2表示连接组; X表示羧基，硫酸基，磷酸基或硼酸基。

62. 发明授权

US6103461A Silver halide photographic material 失效
标题翻译：卤化银照相材料
公开(公告)号：US6103461A
公开(公告)日：2000-08-15
申请号：US140799
申请日：1998-08-26
申请人： Takanori Hioki , Shigeru Shibayama
发明人： Takanori Hioki , Shigeru Shibayama
IPC分类号： G03C1/08 , G03C1/16 , G03C1/29 , G03C1/34 , G03C1/33
CPC分类号： G03C1/34 , G03C1/16
摘要： A silver halide photographic material is described, which contains at least one compound represented by the following formula (I) and at least one compound represented by the following formula (II): ##STR1## wherein Ar.sub.1 and Ar.sub.2 each represents an aryl group or a heterocyclic group; R.sub.1 and R.sub.2 each represents an alkyl group; M.sub.1 represents a counter ion for charge balance; and m.sub.1 represents a number of 0 or more necessary for balancing a charge in the molecule of the compound; ##STR2## wherein either Z.sub.1 or Z.sub.2 represents an oxygen atom and the other represents a sulfur atom; V represents a monovalent substituent; R.sub.3 and R.sub.4 each represents an alkyl group; M.sub.2 represents a counter ion for charge balance; and m.sub.2 represents a number of 0 or more necessary for balancing a charge in the molecule of the compound.
摘要翻译：描述了卤化银照相材料，其含有至少一种由下式（I）表示的化合物和至少一种由下式（II）表示的化合物：其中Ar1和Ar2各自表示芳基或杂环基; R1和R2各自表示烷基; M1代表电荷平衡的抗衡离子; m1表示化合物的分子中的电荷平衡所需的0以上的数; 其中Z1或Z2表示氧原子，另一个表示硫原子; V表示一价取代基; R3和R4各自表示烷基; M2代表电荷平衡的抗衡离子; m2表示化合物的分子中的电荷平衡所需的0以上的数。

63. 发明授权

US6048682A Silver halide photographic material and image-forming method using same material 失效
标题翻译：卤化银照相材料和使用相同材料的成像方法
公开(公告)号：US6048682A
公开(公告)日：2000-04-11
申请号：US301122
申请日：1999-04-28
申请人： Katsuhisa Ohzeki , Takanori Hioki
发明人： Katsuhisa Ohzeki , Takanori Hioki
IPC分类号： G03C5/26 , G03C1/00 , G03C1/005 , G03C1/035 , G03C1/07 , G03C1/08 , G03C1/12 , G03C1/14 , G03C1/16 , G03C1/18 , G03C1/20 , G03C7/38
CPC分类号： G03C1/07 , G03C1/0053 , G03C1/14 , G03C1/08 , G03C1/127 , G03C1/16 , G03C1/18 , G03C5/26 , G03C7/3825
摘要： A silver halide photographic material is disclosed, comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein at least 80% of the entire projected area of the silver halide grains contained in said silver halide emulsion layer are occupied by tabular silver halide grains having an aspect ratio of 2 or more and main planes of {111} faces, said silver halide grains comprise at least 80 mol % of silver chloride, and said tabular silver halide grains are spectrally sensitized with the dye represented by formula (S); ##STR1## wherein Z.sub.1 and Z.sub.2 each represents a sulfur atom, a selenium atom, an oxygen atom or a nitrogen atom; and V.sub.1 and V.sub.2 each represents a monovalent substituent, provided that V.sub.1 and V.sub.2 each does not represent an aromatic group and adjacent two or more groups represented by V.sub.1 or V.sub.2 are not bonded to each other to form a condensed ring; I.sub.1 and I.sub.2 each represents 0, 1, 2, 3 or 4; L.sub.1, L.sub.2 and L.sub.3 each represents a methine group; R.sub.1 and R.sub.2 each represents an alkyl group; n.sub.1 represents 0, 1 or 2; m.sub.1 represents a number of 0 or more necessary to neutralize the charge of the molecule; and M.sub.1 represents a charge balancing counter ion, and further an image-forming method is disclosed, which comprises imagewise exposing and development processing the above silver halide photographic material.
摘要翻译：公开了一种卤化银照相材料，其包括其上具有至少一种感光卤化银乳剂层的载体，其中包含在所述卤化银乳剂层中的卤化银颗粒的整个投影面积的至少80％被片状长宽比为2以上且{111}面的主平面的卤化银颗粒，所述卤化银颗粒包含至少80mol％的氯化银，并且所述片状卤化银颗粒用式（ S）; 其中Z1和Z2各自表示硫原子，硒原子，氧原子或氮原子; V1和V2各自表示一价取代基，条件是V1和V2各自不表示芳族基团，并且相邻的两个或更多个由V1或V2表示的基团彼此不结合以形成稠环; I1和I2各自表示0,1,2,3或4; L1，L2和L3各自表示次甲基; R1和R2各自表示烷基; n1表示0,1或2; m1表示中和分子的电荷所需的0以上的数; 并且M1表示电荷平衡反离子，并且还公开了一种图像形成方法，其包括对上述卤化银照相材料进行成像曝光和显影处理。

64. 发明授权

US5958665A Sultone compound, quaternary salt compound and methine compound, production process thereof, and silver halide photographic light-sensitive material containing the quaternary salt compound and/or methine compound 失效
标题翻译：磺内酯化合物，季盐化合物和次甲基化合物，其制备方法和含有季盐化合物和/或次甲基化合物的卤化银照相感光材料
公开(公告)号：US5958665A
公开(公告)日：1999-09-28
申请号：US943157
申请日：1997-10-03
申请人： Takanori Hioki , Tetsuya Watanabe
发明人： Takanori Hioki , Tetsuya Watanabe
IPC分类号： C09B23/01 , C09B23/02 , C09B23/10 , G03C1/005 , G03C1/12 , G03C1/16 , G03C1/18 , G03C1/20 , G03C1/22 , G03C1/26 , G03C1/485 , G03C8/08
CPC分类号： C09B23/10 , C09B23/0066 , C09B23/0083 , C09B23/02 , G03C1/12 , G03C1/0051 , G03C1/127 , G03C1/16 , G03C1/18 , G03C1/20 , G03C1/22 , G03C1/26 , G03C1/48576 , G03C8/08
摘要： A sultone compound represented by formula (I) or (I'), a quaternary salt compound represented by formula (II) or (II'), a methine compound represented by formula (III) or (III'), production processes thereof and a silver halide photographic light-sensitive material comprising a quaternary salt compound represented by formula (II) or (II') and/or a methine compound represented by formula (III) or (III') are disclosed.
摘要翻译：由式（I）或（I'）表示的磺内酯化合物，由式（II）或（II'）表示的季盐化合物，由式（III）或（III'）表示的次甲基化合物，其制备方法和公开了包含由式（II）或（II'）表示的季盐化合物和/或由式（III）或（III'）表示的次甲基化合物的卤化银照相感光材料。

65. 发明授权

US5527914A Methine compounds 失效
标题翻译：甲基化合物
公开(公告)号：US5527914A
公开(公告)日：1996-06-18
申请号：US238023
申请日：1994-05-03
申请人： Takanori Hioki , Tadashi Ikeda
发明人： Takanori Hioki , Tadashi Ikeda
IPC分类号： C09B23/00 , C09B23/01 , C09B67/12 , G03C1/12 , G03C1/40 , C07D413/08
CPC分类号： G03C1/127 , C09B23/0066 , C09B67/0016 , Y10S430/145
摘要： Methine compounds are described, which can be represented by general formula [Ic]: ##STR1##
摘要翻译：描述了甲基化合物，其可以由通式[Ic]表示： [Ic]

66. 发明授权

US5514533A Silver halide photographic photosensitive materials and a method for their processing 失效
标题翻译：卤化银照相感光材料及其加工方法
公开(公告)号：US5514533A
公开(公告)日：1996-05-07
申请号：US317776
申请日：1994-10-04
申请人： Takanori Hioki , Tetsuo Yoshida
发明人： Takanori Hioki , Tetsuo Yoshida
IPC分类号： G03C1/00 , C09B23/01 , G03C1/09 , G03C1/18 , G03C1/26 , G03C5/16 , G03C5/26 , G03C5/31 , G03C5/395 , G03C1/10
CPC分类号： C09B23/0075 , G03C1/26 , G03C1/09 , G03C5/16
摘要： A silver halide photographic photosensitive material comprises a silver halide photographic emulsion layer and a compound represented by general formula (I): ##STR1## wherein V.sub.1 and V.sub.2 each represents a hydrogen atom, an alkyl group or an alkoxy group; at least one of V.sub.1 and V.sub.2 is an alkyl group or an alkoxy group; Z.sub.1 represents a group of atoms which is required to form a five- or six-membered nitrogen-containing heterocyclic ring; Z.sub.2 represents a group of atoms which is required to form a five- or six-membered nitrogen-containing heterocyclic ring; Z.sub.3 represents an oxygen atom, a sulfur atom or a selenium atom; R.sub.1 and R.sub.3 each represents an alkyl group; R.sub.2 represents an alkyl group, an aryl group or a heterocyclic group; L.sub.1, L.sub.2 and L.sub.3 each represents a methine group; M.sub.1 represents a charge neutralizing counter-ion; and m.sub.1 is a number having a value zero or above which is required to neutralize the charge within the molecule.
摘要翻译：卤化银照相感光材料包括卤化银照相乳剂层和由通式（I）表示的化合物：其中V1和V2各自表示氢原子，烷基或烷氧基; V1和V2中的至少一个是烷基或烷氧基; Z1表示形成五元或六元含氮杂环所需的一组原子; Z2表示形成五元或六元含氮杂环所需的一组原子; Z 3表示氧原子，硫原子或硒原子; R1和R3各自表示烷基; R2表示烷基，芳基或杂环基; L1，L2和L3各自表示次甲基; M1表示电荷中和反离子; 并且m1是具有零或以上值的数字，其用于中和分子内的电荷。

67. 发明授权

US5489505A Silver halide photographic material 失效
标题翻译：卤化银照相材料
公开(公告)号：US5489505A
公开(公告)日：1996-02-06
申请号：US397725
申请日：1995-03-02
申请人： Takashi Kato , Takanori Hioki , Tadashi Ikeda
发明人： Takashi Kato , Takanori Hioki , Tadashi Ikeda
IPC分类号： C09B23/00 , G03C1/12 , G03C1/20 , G03C1/26 , G03C1/28 , G03C1/805 , G03C11/12 , G03F3/10 , G03F7/07
CPC分类号： G03F3/10 , G03C1/127 , G03C1/26 , G03C1/28 , G03C1/805 , G03C11/12 , G03F7/07
摘要： A silver halide photographic material which contains methine dyes represented by formula (I) to obtain high sensitivity and excellent storage stability: ##STR1## wherein Z.sub.1 and Z.sub.2 each represents atoms necessary to complete a 5- or 6-membered nitrogen-containing hetero ring; Q represents atoms necessary to complete a 5- or 6-membered ring; R.sub.1 represents an alkyl group, an aryl group or a heterocyclyl group; R.sub.2 and R.sub.3 each represents an alkyl group; L.sub.1, L.sub.2, L.sub.3, L.sub.4, L.sub.5 and L.sub.6 each represents a methine group; n.sub.1 and n.sub.2 each represents 0 or 1; M represents an ion for neutralizing electric charges; and m is a number necessary for neutralization of electric charges in the dye molecule, including 0.
摘要翻译：含有由式（I）表示的次甲基染料的卤化银照相材料，以获得高灵敏度和优异的储存稳定性：其中Z1和Z2各自表示完成5-或6-元所需的原子含氮杂环; Q表示完成5-或6-元环所必需的原子; R1表示烷基，芳基或杂环基; R2和R3各自表示烷基; L1，L2，L3，L4，L5和L6各自表示次甲基; n1和n2各自表示0或1; M表示用于中和电荷的离子; m是染料分子中的电荷中和所需的数，包括0。

68. 发明授权

US5484683A Dye fixing element with hydrazine 失效
标题翻译：染料固定元素与肼
公开(公告)号：US5484683A
公开(公告)日：1996-01-16
申请号：US238792
申请日：1994-05-06
申请人： Jiro Tsukahara , Takanori Hioki , Koki Nakamura
发明人： Jiro Tsukahara , Takanori Hioki , Koki Nakamura
IPC分类号： C09B67/00 , B41M5/382 , B41M5/50 , B41M5/52 , G03C8/24 , G03C8/26 , G03C8/40 , G03C8/56
CPC分类号： B41M5/5227 , G03C8/246 , G03C8/4066
摘要： There is disclosed a dye fixing element containing a novel compound which improves the light fastness of an image obtained by the method in which the image is formed by transferring. The above dye fixing element contains a novel hydrazine derivative represented by the following Formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent independently a substituted or unsubstituted alkyl group, cycloalkyl group, alkenyl group, or aralkyl group; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be combined with each other to form a ring, provided that this ring is a non-aromatic heterocyclic ring and the atoms constituting the ring other than the nitrogens of Formula (I) are carbon atoms.
摘要翻译：公开了一种含有新化合物的染料固定元件，其改善通过转印形成图像的方法获得的图像的耐光性。上述染料固定元件含有由下式（I）表示的新型肼衍生物：其中R 1，R 2，R 3和R 4分别独立地表示取代或未取代的烷基，环烷基，链烯基或芳烷基如果该环是非芳族杂环，并且构成除式（I）的氮以外的环的原子是碳原子，则R1，R2，R3和R4可以相互结合形成环。

69. 发明授权

US5459025A Methine compound and silver halide photographic material comprising same 失效
标题翻译：包含它的甲基化合物和卤化银照相材料
公开(公告)号：US5459025A
公开(公告)日：1995-10-17
申请号：US309672
申请日：1994-09-21
申请人： Takanori Hioki
发明人： Takanori Hioki
IPC分类号： G03C1/015 , C09B23/00 , C09B23/01 , C09B23/02 , C09B23/10 , G03C1/06 , G03C1/12 , G03C1/18 , G03C1/22 , G03C1/26 , G03C1/28
CPC分类号： G03C1/061 , C09B23/0066 , C09B23/0075 , C09B23/02 , C09B23/10 , G03C1/12 , G03C1/28 , G03C1/18 , G03C1/22 , G03C1/26
摘要： A novel silver halide photographic material is provided, comprising at least one methine compound having a methine dye and hydrazine covalently bonded to each other, two nitrogen atoms in said hydrazine being substituted by four substituents. In a preferred embodiment, the methine compound is represented by formula (I): ##STR1## wherein MET represents an atomic group; Q represents a divalent bonding group consisting of atoms or atomic group containing at least one of carbon atom, nitrogen atom, sulfur atom and oxygen atom; Hy represents an atomic group having a hydrazine structure represented by formula (II); k.sub.1 represents 0 or an integer 1 to 4; and k.sub.2 represents 0 or 1, and k.sub.3 represents an integer 1 to 4. ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group, an aryl group or a heterocyclic group, with the proviso that Hy is substituted by at least one --(Q).sub.k2 -(MET).sub.k1. A novel methine compound is also provided represented by the general formula (I).
摘要翻译：提供了一种新型卤化银照相材料，其包含至少一种次甲基化合物和次甲基染料和共价键合的肼，所述肼中的两个氮原子被四个取代基取代。在优选的实施方案中，次甲基化合物由式（I）表示：其中MET表示原子团; Q表示由碳原子，氮原子，硫原子和氧原子中的至少一个原子或原子团构成的二价键合基团; Hy表示具有由式（II）表示的肼结构的原子团; k1表示0或整数1〜4; 其中R 1，R 2，R 3和R 4各自表示烷基，芳基或杂环基，条件是Hy为由至少一个 - （Q）k2-（MET）k1代替。还提供了一种新的次甲基化合物，由通式（I）表示。

70. 发明授权

US5436121A Silver halide color photographic light-sensitive material 失效
标题翻译：卤化银彩色摄影感光材料
公开(公告)号：US5436121A
公开(公告)日：1995-07-25
申请号：US345752
申请日：1994-11-22
申请人： Yoichi Suga , Junji Nishigaki , Takanori Hioki
发明人： Yoichi Suga , Junji Nishigaki , Takanori Hioki
IPC分类号： G03C7/00 , G03C1/16 , G03C1/29 , G03C7/20 , G03C7/30 , G03C1/46
CPC分类号： G03C7/3041 , G03C1/16 , G03C1/29
摘要： Disclosed is a silver halide color photographic light-sensitive material which includes, on a support, at least one blue-sensitive silver halide emulsion layer containing a yellow coupler, at least one green-sensitive silver halide emulsion layer containing a magenta coupler, and at least one red-sensitive silver halide emulsion layer containing a cyan coupler, and in which a weight-averaged wavelength (.lambda..sub.-R) of a spectral sensitivity distribution of magnitude of an interimage effect which the silver halide emulsion layers except for all of the red-sensitive silver halide emulsion layers have on the red-sensitive layers over a range of 500 to 600 nm is 500 nm
摘要翻译：公开了一种卤化银彩色照相感光材料，其在载体上包含至少一种含有黄色成色剂的感蓝卤化银乳剂层，至少一种含有品红色成色剂的感绿卤化银乳剂层，至少一个含有青色成色剂的感红卤化银乳剂层，其中除了所有红色之外的卤化银乳剂层的平面图像效应的光谱灵敏度分布的重均平均波长（λ-R）敏感的卤化银乳剂层在500至600nm的范围内的红色敏感层上具有500nm <λ-R <560nm，并且光谱灵敏度分布的重均平均波长（λG）之间的差异至少一个感绿卤化银乳剂层和λ-R是λ-λ-R-10nm，其中至少一种卤化银乳剂层具有红色敏感性卤化银乳剂层包含用至少一种由下式（I）表示的化合物和至少一种由下式（II）表示的化合物进行光谱增感的卤化银乳剂。公式（I）公式（II）

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