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    • 66. 发明授权
    • Hologram recording medium
    • 全息记录介质
    • US08420280B2
    • 2013-04-16
    • US11847819
    • 2007-08-30
    • Jiro YoshinariAtsuko KosudaNaoki Hayashida
    • Jiro YoshinariAtsuko KosudaNaoki Hayashida
    • G03H1/02
    • G03F7/001G03F7/0043
    • The present invention provides a hologram recording medium which can attain high refractive index change, flexibility, high sensitivity, low scattering, environment resistance, durability, low dimension change (low shrinkage) and high multiplicity in holographic memory record using a blue laser. A hologram recording medium (11) comprising at least a hologram recording material layer, wherein the hologram recording material layer (21) comprises at least a metal oxide and a photopolymerizable compound; and said hologram recording medium has a light transmittance of 50% or more at a wavelength of 405 nm, or a light reflectance of 25% or more at a wavelength of 405 nm.
    • 本发明提供一种全息图记录介质,其能够使用蓝色激光获得全息记录记录中的高折射率变化,柔性,高灵敏度,低散射性,耐环境性,耐久性,低尺寸变化(低收缩)和高倍数。 包括至少全息记录材料层的全息记录介质(11),其中全息记录材料层(21)至少包含金属氧化物和可光聚合化合物; 并且所述全息记录介质的波长为405nm时的透光率为50%以上,波长405nm的光反射率为25%以上。
    • 67. 发明授权
    • Hologram recording material, and hologram recording medium
    • 全息记录材料和全息记录介质
    • US08367274B2
    • 2013-02-05
    • US11556813
    • 2006-11-06
    • Jiro YoshinariNaoki Hayashida
    • Jiro YoshinariNaoki Hayashida
    • G03C1/72G03H1/04
    • G03H1/02G03F7/001G03F7/0042G03F7/0757G03H2001/0264G03H2260/12
    • The present invention provides a hologram recording material which attains high refractive index change, flexibility, high sensitivity, low scattering, environment resistance, durability, low shrinkage, and high multiplicity, and is suitable for volume hologram recording. Also, the present invention provides a hologram recording medium. A hologram recording material comprising: an organometallic compound at least containing at least two kinds of metals, oxygen, and an aromatic group, and having an organometallic unit wherein two aromatic groups are bonded directly to one metal; and a photopolymerizable compound containing at least a monofunctional compound (A) having one polymerizable functional group in the molecule. The hologram recording material may comprise, as the photopolymerizable compound, a polyfunctional compound (B) having two or more polymerizable functional groups in the molecule. A hologram recording medium 11 has a hologram recording material layer 21.
    • 本发明提供一种获得高折射率变化,柔韧性,高灵敏度,低散射性,耐环境性,耐久性,低收缩率和高倍数的全息记录材料,适用于体积全息图记录。 此外,本发明提供一种全息记录介质。 一种全息记录材料,包括:至少含有两种金属,氧和芳族基团的有机金属化合物,并且具有有机金属单元,其中两个芳族基团直接键合到一个金属上; 和至少含有分子内具有一个聚合性官能团的单官能化合物(A)的光聚合性化合物。 作为光聚合性化合物,全息记录材料可以包含在分子中具有2个以上聚合性官能团的多官能化合物(B)。 全息记录介质11具有全息记录材料层21。
    • 68. 发明授权
    • Hologram recording material, process for producing the same and hologram recording medium
    • 全息记录材料,其制造方法和全息记录介质
    • US08021800B2
    • 2011-09-20
    • US12109000
    • 2008-04-24
    • Atsuko KosudaNaoki HayashidaJiro Yoshinari
    • Atsuko KosudaNaoki HayashidaJiro Yoshinari
    • G03H1/02
    • G03F7/001G03F7/0042G03F7/0043
    • The present invention provides a hologram recording material which is suitable for volume hologram record and attains high refractive index change, flexibility, high sensitivity, low scattering, environment resistance, durability, low shrinkage and high multiplicity in holographic memory record using not only a green laser but also a blue laser; a process for producing the same; and a hologram recording medium having the hologram recording material. A hologram recording material comprising: a metal oxide containing at least Si and Zr as metals, wherein an aromatic carboxylic acid compound is coordinated to Zr; and a photopolymerizable compound. The aromatic carboxylic acid compound is, for example, toluic acid. A hologram recording medium (11) comprising the hologram recording material layer (21).
    • 本发明提供一种全息记录材料,其适用于体积全息记录,并且在全息记录记录中不仅使用绿色激光,而且获得高折射率变化,柔性,高灵敏度,低散射,环境耐久性,耐久性,低收缩率和高倍数 也是一个蓝色激光; 其制造方法; 以及具有全息图记录材料的全息图记录介质。 一种全息记录材料,包括:至少含有Si和Zr作为金属的金属氧化物,其中芳族羧酸化合物与Zr配位; 和光聚合性化合物。 芳族羧酸化合物是例如甲苯甲酸。 包括全息记录材料层(21)的全息记录介质(11)。
    • 69. 发明授权
    • Hologram recording medium
    • 全息记录介质
    • US07932000B2
    • 2011-04-26
    • US11847831
    • 2007-08-30
    • Naoki HayashidaAtsuko KosudaJiro Yoshinari
    • Naoki HayashidaAtsuko KosudaJiro Yoshinari
    • G03H1/02
    • G03F7/001G03F7/0043G03H2260/12
    • The present invention provides a hologram recording medium which can attain high refractive index change, flexibility, high sensitivity, low scattering, environment resistance, durability, low dimension change (low shrinkage) and high multiplicity in holographic memory record using a blue laser. A hologram recording medium (11) comprising at least a hologram recording material layer, wherein the hologram recording material layer (21) comprises at least: an organometallic compound having at least a Ti—O bond, and a photopolymerizable compound; and said medium has a light transmittance is 50% or more at a wavelength of 405 nm, or a light reflectance is 25% or more at a wavelength of 405 nm. The organometallic compound is favorably obtained by subjecting an alkoxide compound of the corresponding metal(s) to hydrolysis and polymerization reaction in an organic solvent which neither contains cyclic ether skeleton nor carbonyl oxygen.
    • 本发明提供一种全息图记录介质,其能够使用蓝色激光获得全息记录记录中的高折射率变化,柔性,高灵敏度,低散射性,耐环境性,耐久性,低尺寸变化(低收缩)和高倍数。 包括至少全息记录材料层的全息记录介质(11),其中全息记录材料层(21)至少包括:至少具有Ti-O键的有机金属化合物和可光聚合化合物; 并且所述介质在波长405nm下的透光率为50%以上,或者波长405nm下的光反射率为25%以上。 有机金属化合物有利地通过使相应金属的醇盐化合物在不含环状醚骨架和羰基氧的有机溶剂中进行水解和聚合反应而获得。