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61. 发明授权

US07112363B2 Porous or non-porous substrate coated with a polymeric composition having hydrophilic functional groups and process 失效
公开(公告)号：US07112363B2
公开(公告)日：2006-09-26
申请号：US10203269
申请日：2001-01-31
申请人： Wilson Moya
发明人： Wilson Moya
IPC分类号： B32B5/18 , B32B27/26
CPC分类号： C08J7/047 , B01D2323/30 , B32B27/08 , C08J2327/12 , C08J2427/00 , Y10T428/249953 , Y10T428/249991 , Y10T428/3154 , Y10T428/31906
摘要： A crosslinked fluorocarbon such as perfluorocarbon, polymeric composition is provided having hydrophilic functional groups, which is crosslinked with fluorinated such as perfluorinated crosslinking groups. Also provided is a branched fluorocarbon such as perfluorocarbon, polymeric composition having hydrophilic functional groups.

62. 发明授权

US07094469B2 Porous or non-porous substrate coated with an immobilized polymeric composition having sulfonyl groups and hydrophilic functional groups and process 有权
标题翻译：涂覆有具有磺酰基和亲水官能团的固定化聚合物组合物的多孔或无孔基材和方法
公开(公告)号：US07094469B2
公开(公告)日：2006-08-22
申请号：US10344058
申请日：2001-08-28
申请人： Wilson Moya
发明人： Wilson Moya
IPC分类号： B32B27/08 , B32B27/28 , C08J5/20 , C08J5/22 , C08F214/18
CPC分类号： B01D67/0088 , B01D67/0093 , B01D69/141 , B01D71/32 , B01D71/82 , B01D2323/30 , B01D2323/38 , C08F8/36 , C08F259/08 , C08F290/00 , C08J7/047 , C08J2327/12 , C08J2427/00 , C08L51/003 , C08L51/04 , Y10T428/249953 , Y10T428/249954 , Y10T428/249987 , Y10T428/249991 , Y10T428/249992 , Y10T428/3154 , Y10T428/31544
摘要： A porous or non-porous polymeric substrate having its surface modified with an immobilized fluorocarbon such as perfluorocarbon, polymeric composition is provided. The immobilized fluorocarbon is formed from a monomer having formula: [T—SO2Y—SO2T′]−M+ in which —T and T′ are identical or different and comprise an organic radical bearing at least one active polymerization function such as an unsaturation or a ring that can be opened; —M+ comprises an inorganic cation. —Y comprises N or CQ in which Q comprises H, CN, F, SO2R3, substituted or unsubstituted C1-20 alkyl, substituted or unsubstituted C1-20 aryl, substituted or un-substituted C1-20 alkylene, in which the substituent comprises one or more halogens, and in which the chain comprises one or more F, SO2R, aza, oxa, thia or dioxathia substituents; and —R3 comprises F, substituted or unsubstituted C1-20 alkyl, in which the substituted or unsubstituted C1-20 aryl, substituted or unsubstituted C1-20 alkylene, in which the substituent comprises one or more halogens.
摘要翻译：提供其表面用固定的氟碳化合物如全氟化碳改性的多孔或非多孔聚合物基质，聚合物组合物。固定的氟碳化合物由具有下式的单体形成：[T-SO 2 Y-SO 2 T'] - O - 其中-T和T'相同或不同，并且包含具有至少一个活性聚合功能的有机基团，例如不饱和键或可以打开的环; -M ^{+ 包括无机阳离子。 -Y包括N或CQ，其中Q包括H，CN，F，SO 2 R 3，取代或未取代的C 1-12烷基取代或未取代的C 1-20烷基，取代或未取代的C 1-20烷基，其中取代基包含一个或多个卤素，并且其中链包含一个或多个F，SO 2 R，氮杂，氧杂，硫杂或二氧杂锇取代基; 且R 3包括F，取代或未取代的C 1-20烷基，其中取代或未取代的C 1-20烷基，被取代的或未取代的C 1-20烷基，其中取代基包含一个或多个卤素。}

63. 发明授权

US06179132B2 Surface modified polymeric substrate and process 失效
标题翻译：表面改性聚合物基材和工艺
公开(公告)号：US06179132B2
公开(公告)日：2001-01-30
申请号：US09041699
申请日：1998-03-13
申请人： Wilson Moya
发明人： Wilson Moya
IPC分类号： B01D7126
CPC分类号： B01D67/0088 , B01D71/32 , B01D71/36 , C08J5/2293 , C08J2327/12
摘要： A porous membrane is provided which is formed from a porous polyperfluorocarbon membrane substrate having its surface modified with a perfluorocarbon polymer composition. The modified surface is directly wet with an aqueous liquid.
摘要翻译：提供一种多孔膜，其由具有用全氟化碳聚合物组合物改性的多孔聚氟碳膜基材形成。改性表面直接用水性液体润湿。

64. 发明授权

US5814372A Process for forming porous composite membrane 失效
标题翻译：多孔复合膜形成工艺
公开(公告)号：US5814372A
公开(公告)日：1998-09-29
申请号：US718980
申请日：1996-09-26
申请人： Wilson Moya
发明人： Wilson Moya
IPC分类号： B01D67/00 , B01D69/12 , B32B3/26 , B32B5/14
CPC分类号： B01D67/0088 , B01D69/125
摘要： A composite porous membrane is provided which comprises a porous membrane substrate having an average pore size between 0.01 and 10 microns formed of a first polymer which is coated over its entire surface with a crosslinked second polymer. The second polymer is dissolved in a solvent with a free radical polymerization initiator in the absence of a crosslinking agent. The second polymer is crosslinked in situ and rendered insoluble by mild heating and/or exposure to ultraviolet light.
摘要翻译：提供了一种复合多孔膜，其包括由第一聚合物形成的平均孔径为0.01至10微米的多孔膜基材，该第一聚合物在其整个表面上用交联的第二聚合物涂覆。第二种聚合物在不存在交联剂的情况下用自由基聚合引发剂溶解在溶剂中。第二聚合物原位交联并通过温和加热和/或暴露于紫外光使其变得不溶。

65. 发明授权

US5554414A Process for forming membrane having a hydrophobic fluoropolymer surface 失效
标题翻译：用于形成具有疏水性含氟聚合物表面的膜的方法
公开(公告)号：US5554414A
公开(公告)日：1996-09-10
申请号：US421126
申请日：1995-04-12
申请人： Wilson Moya , Philip M. Goddard
发明人： Wilson Moya , Philip M. Goddard
IPC分类号： B01D67/00 , B05D5/08 , B05D5/00
CPC分类号： B01D67/0088 , B05D5/08
摘要： A composite porous article is formed from a porous polymeric substrate having its entire surface modified with a cross-linked polymer which results in a hydrophobic and oleophobic surface. The composite retains substantially all of the other original properties of the substrate. The cross-linked polymer is formed in situ on the polymeric substrate from a reactant system comprising an ethylenically unsaturated monomer having at least one fluoroalkyl group, a cross-linker, and, if needed, a polymerization initiator, dissolved in a polar solvent system. The porous substrate saturated with the reactant system is exposed to a suitable energy source to effect polymerization and cross-linking of the monomer.
摘要翻译：复合多孔制品由其整个表面用交联聚合物改性的多孔聚合物基材形成，其导致疏水和疏油表面。复合材料基本上保留了基材的所有其它原始性能。交联聚合物在聚合物基材上由包含具有至少一个氟代烷基的烯属不饱和单体，交联剂和如果需要的溶解在极性溶剂体系中的聚合引发剂的反应体系原位形成。用反应物系统饱和的多孔基材暴露于合适的能量源以实现单体的聚合和交联。

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