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61. 发明授权

US4906758A Preparation of pyrroles from dialkoxytetrahydrofurans 失效
标题翻译：从二烷氧基四氢呋喃制备吡咯
公开(公告)号：US4906758A
公开(公告)日：1990-03-06
申请号：US231259
申请日：1988-08-12
申请人： Wolfgang Hoelderich , Michael Hesse , Hardo Siegel
发明人： Wolfgang Hoelderich , Michael Hesse , Hardo Siegel
IPC分类号： C07D207/32 , C07D207/323 , C07B43/04
CPC分类号： C07D207/323 , Y02P20/582
摘要： Pyrroles of the formula I ##STR1## are prepared by a process in which a dialkoxytetrahydrofuran of the formula II ##STR2## where R.sup.2 to R.sup.5 in the formulae (I) and (II) are identical or different and are each hydrogen, a straight-chain or branched alkyl or alkenyl radical of not more than 12 carbon atoms, a cycloalkyl or cycloalkenyl radical of 5 to 8 carbon atoms, an aryl, alkylaryl or aralkyl radical of 6 to 16 carbon atoms, and two non-adjacent radicals R.sup.6 to R.sup.9 are alkoxy and the other two radicals R.sup.6 to R.sup.9 are hydrogen, is reacted with ammonia or a primary amine H.sub.2 NR.sup.1, where R.sup.1 in formula (I) is hydrogen, alkyl, aryl, alkylaryl, aralkyl or cycloalkyl, in the presence of an acidic, solid, heterogeneous catalyst. Zeolites, for example those of the pentasil type or faujasite type, or phosphates, acidic oxides, phosphoric acid or boric acid on a carrier can be used as the solid heterogeneous catalysts.
摘要翻译：式I（I）的吡咯可以通过其中式II（II）的二烷氧基四氢呋喃与式（I）和（II）中的R 2至R 5相同或不同的方法制备，每个氢，不超过12个碳原子的直链或支链烷基或烯基，5-8个碳原子的环烷基或环烯基，6-16个碳原子的芳基，烷芳基或芳烷基，相邻的基团R6至R9为烷氧基，另外两个基团R6至R9为氢，与氨或伯胺H 2 N R 1反应，其中式（I）中的R 1为氢，烷基，芳基，烷基芳基，芳烷基或环烷基，酸性，固体，非均相催化剂的存在。作为固体多相催化剂，可以使用沸石，例如pentasil类型或八面沸石型沸石，或载体上的磷酸盐，酸性氧化物，磷酸或硼酸。

62. 发明申请

US20140046110A1 ISOMERIZATION OF LIGHT ALPHA-OLEFINS TO LIGHT INTERNAL OLEFINS 有权
标题翻译：轻质烯丙醇与轻质内脂的同位素
公开(公告)号：US20140046110A1
公开(公告)日：2014-02-13
申请号：US14113829
申请日：2012-04-27
申请人： Stefan Iselborn , Michael Hesse , Piotr Makarczyk
发明人： Stefan Iselborn , Michael Hesse , Piotr Makarczyk
IPC分类号： C07C5/25 , C07C6/04
CPC分类号： C07C5/2512 , B01J23/44 , B01J27/0573 , B01J27/0576 , C07C5/13 , C07C6/04 , C07C2521/04 , C07C2521/08 , C07C2523/30 , C07C2523/36 , C07C2523/44 , C07C2523/882 , C07C2527/057 , Y02P20/52 , C07C11/08 , C07C11/10 , C07C11/107 , C07C11/02
摘要： The present invention relates to a process for isomerizing linear alpha-olefins having from 4 to 8 carbon atoms over a heterogeneous catalyst, wherein the catalyst comprises a hydrogenation metal and a selectivity promoter selected from among selenium and tellurium on a support, and also a process for preparing 1-olefins by a metathesis reaction of 2-olefins with ethene, wherein the 2-olefins are prepared by the above mentioned isomerization process.
摘要翻译：本发明涉及在非均相催化剂上异构化具有4至8个碳原子的直链α-烯烃的方法，其中催化剂包含氢化金属和在载体上选自硒和碲的选择性促进剂，以及工艺用于通过2-烯烃与乙烯的复分解反应制备1-烯烃，其中2-烯烃通过上述异构化方法制备。

63. 发明授权

US07884046B2 Catalyst and process for hydrogenating carbonyl compounds 有权
标题翻译：氢化羰基化合物的催化剂和方法
公开(公告)号：US07884046B2
公开(公告)日：2011-02-08
申请号：US12608125
申请日：2009-10-29
申请人： Sylvia Huber-Dirr , Michael Hesse , Andrea Haunert , Henrik Junicke
发明人： Sylvia Huber-Dirr , Michael Hesse , Andrea Haunert , Henrik Junicke
IPC分类号： B01J21/18 , B01J23/00 , B01J23/10 , B01J23/70 , B01J23/72 , B01J23/08 , B01J23/40
CPC分类号： C07C29/149 , B01J23/83 , C07C31/20
摘要： A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is hydrogenated in the presence of a shaped article which contains (i) an oxidic material comprising copper oxide, aluminum oxide and lanthanum oxide, and (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof, is provided.
摘要翻译：氢化具有至少一个羰基的有机化合物的方法，其中有机化合物在成型制品存在下氢化，所述成型制品包含（i）包含氧化铜，氧化铝和氧化镧的氧化物质和（ii ）粉末状金属铜，铜薄片，水泥粉末，石墨或其混合物。

64. 发明授权

US07850842B2 Zr02-base catalyst carrier and method for the production thereof 有权
标题翻译： ZrO 2 - 基催化剂载体及其制备方法
公开(公告)号：US07850842B2
公开(公告)日：2010-12-14
申请号：US10513041
申请日：2003-05-02
申请人： Otto Hofstadt , Michael Hesse , Götz-Peter Schindler , Klaus Harth , Falk Simon
发明人： Otto Hofstadt , Michael Hesse , Götz-Peter Schindler , Klaus Harth , Falk Simon
IPC分类号： C10G35/06 , B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： C07C5/3332 , B01J21/066 , B01J23/002 , B01J23/63 , B01J35/002 , B01J35/10 , B01J35/109 , B01J37/0009 , B01J37/0018 , B01J2523/00 , C07C2521/06 , Y02P20/52 , C07C11/06 , B01J2523/13 , B01J2523/15 , B01J2523/3706 , B01J2523/41 , B01J2523/43 , B01J2523/48 , B01J2523/828
摘要： The invention relates to a process for preparing a catalyst support, in which zirconium dioxide powder is mixed with a binder, if desired a pore former, if desired an acid, water and, if desired, further additives to give a kneadable composition and the composition is homogenized, shaped to produce shaped bodies, dried and calcined, wherein the binder is a monomeric, oligomeric or polymeric organosilicon compound. Suitable binders are monomeric, oligomeric or polymeric silanes, alkoxysilanes, aryloxysilanes, acryloxysilanes, oximinosilanes, halosilanes, aminoxysilanes, aminosilanes, amidosilanes, silazanes or silicones. The invention also provides the catalyst support which has been prepared in this way, a catalyst comprising the support and its use as dehydrogenation catalyst.
摘要翻译：本发明涉及制备催化剂载体的方法，其中如果需要，二氧化锆粉末与粘合剂混合，如果需要，成孔剂如果需要，可以使用酸，水，并且如果需要，可提供另外的添加剂以得到可捏合组合物和组合物均化，成型以产生成形体，干燥和煅烧，其中粘合剂是单体，低聚或聚合的有机硅化合物。合适的粘合剂是单体，低聚或聚合硅烷，烷氧基硅烷，芳氧基硅烷，丙烯酰氧硅烷，肟基硅烷，卤代硅烷，氨基硅烷，氨基硅烷，酰胺基硅烷，硅氮烷或硅氧烷。本发明还提供了以这种方式制备的催化剂载体，包含载体的催化剂及其作为脱氢催化剂的用途。

65. 发明授权

US07781368B2 Adsorption composition and method of removing CO from streams 有权
标题翻译：从流中除去CO的吸附组成和方法
公开(公告)号：US07781368B2
公开(公告)日：2010-08-24
申请号：US12279368
申请日：2007-02-07
申请人： Stephan Schlitter , Stephan Hatscher , Michael Hesse , Heiko Urtel
发明人： Stephan Schlitter , Stephan Hatscher , Michael Hesse , Heiko Urtel
IPC分类号： B01J20/00 , B01J38/04
CPC分类号： B01J23/80 , B01D53/02 , B01D53/865 , B01D2255/20715 , B01D2255/20761 , B01D2257/502 , B01J20/06 , B01J20/3007 , B01J20/3078 , B01J20/3236 , B01J20/3433 , B01J20/3458 , B01J20/3483 , B01J2220/56
摘要： Carbon monoxide is removed from streams by adsorption on an adsorption composition which comprises copper, zinc and zirconium oxides and whose copper-comprising component has a degree of reduction, expressed as weight ratio of metallic copper to the sum of metallic copper and copper oxides, calculated as CuO, of at least 45% and not more than 75%.
摘要翻译：通过在包含铜，锌和锆的氧化物的吸附组合物上吸附除去一氧化碳，并且其含铜组分具有减少程度，以金属铜与金属铜和铜氧化物之和的重量比表示，计算作为CuO，为至少45％且不大于75％。

66. 发明申请

US20090312588A1 PROCESS FOR HYDROGENATING UNSATURATED HYDROCARBONS IN THE PRESENCE OF CATALYSTS CONTAINING COPPER AND ZINC 失效
标题翻译：在含有铜和锌的催化剂存在下加氢不饱和烃的方法
公开(公告)号：US20090312588A1
公开(公告)日：2009-12-17
申请号：US12374191
申请日：2007-07-05
申请人： Stephan Hatscher , Michael Hesse
发明人： Stephan Hatscher , Michael Hesse
IPC分类号： C07C5/03
CPC分类号： B01J23/80 , B01J37/0009 , B01J37/03 , B01J37/06 , C07C5/09 , C07C2523/80 , Y02P20/52 , C07C11/06 , C07C11/04
摘要： Unsaturated hydrocarbons are hydrogenated over catalysts which comprise copper and zinc and whose active composition, in unreduced form, consists essentially of from 10 to 95% by weight of copper oxide, calculated as copper(II) oxide (CuO), from 5 to 90% by weight of zinc oxide (ZnO), optionally from 0.1 to 50% by weight of zirconium dioxide (ZrO2) and optionally from 0.1% by weight to 50% by weight of Al2O3, the proportions by weight adding up to 100% by weight.
摘要翻译：不饱和烃在包含铜和锌的催化剂上氢化，并且其未还原形式的活性组合物基本上由10至95重量％的氧化铜计算，氧化铜（II）（CuO）为5-90重量％的氧化锌（ZnO），任选的0.1至50重量％的二氧化锆（ZrO 2）和任选的0.1重量％至50重量％的Al 2 O 3，其重量比加至100重量％。

67. 发明授权

US07544766B2 Method for the polymerization of cyclic ethers 失效
标题翻译：环醚聚合方法
公开(公告)号：US07544766B2
公开(公告)日：2009-06-09
申请号：US10540510
申请日：2003-12-23
申请人： Stephan Schlitter , Martin Haubner , Peter Zehner , Michael Hesse , Alexander Weck , Rolf Pinkos , Thomas Graβler
发明人： Stephan Schlitter , Martin Haubner , Peter Zehner , Michael Hesse , Alexander Weck , Rolf Pinkos , Thomas Graβler
IPC分类号： C08G59/00 , C08G65/00 , C08G65/04 , C08G65/06 , C08G65/10 , C08G65/16 , C08G65/20 , C08G59/68 , C08F2/01 , C07C43/04
CPC分类号： C08G65/2654 , C08G65/2657
摘要： The present invention relates to a process for preparing polytetrahydrofuran, polytetrahydrofuran copolymer, diester or monoester by polymerizing tetrahydrofuran in the presence of at least one telogen and/or comonomer and of an acidic heterogeneous catalyst based on activated sheet silicates or mixed metal oxides in a fluidized bed.
摘要翻译：本发明涉及一种通过在至少一种开环和/或共聚单体存在下使四氢呋喃聚合的基础上制备聚四氢呋喃，聚四氢呋喃共聚物，二酯或单酯的方法，以及基于活化的硅酸盐或混合金属氧化物在流化床床。

68. 发明授权

US07524444B2 Shaped bodies containing metal-organic frameworks 有权
标题翻译：包含金属 - 有机骨架的成形体
公开(公告)号：US07524444B2
公开(公告)日：2009-04-28
申请号：US10983629
申请日：2004-11-09
申请人： Michael Hesse , Ulrich Mueller , Omar Yaghi
发明人： Michael Hesse , Ulrich Mueller , Omar Yaghi
IPC分类号： B29C43/02
CPC分类号： F17C11/005 , B01J20/0244 , B01J20/226 , B01J20/28011 , B01J20/2803 , B01J20/28042 , B01J20/28057 , B01J20/3007 , B01J20/3035 , B01J20/3042 , B01J31/1691 , B01J35/1028 , B01J37/0009 , B01J2231/005 , B01J2531/26 , Y02E60/324 , Y10T428/249953 , Y10T428/249967 , Y10T428/24997 , Y10T428/25 , Y10T428/298
摘要： The present invention relates to shaped bodies containing a metal-organic framework material (MOF) as well as a process for the preparation thereof and their use especially as catalyst or storage medium.
摘要翻译：本发明涉及含有金属 - 有机骨架材料（MOF）的成形体以及其制备方法及其特别用作催化剂或储存介质的用途。

69. 发明申请

US20080262281A1 Catalyst Used for the Oxidation of Hydrogen, and Method for the Dehydrogenation of Hydrocarbons 审中-公开
标题翻译：用于氧化氢的催化剂和烃脱氢方法
公开(公告)号：US20080262281A1
公开(公告)日：2008-10-23
申请号：US11547500
申请日：2005-03-22
申请人： Christian Walsdorff , Falk Simon , Gerald Vorberg , Gotz-Peter Schindler , Michael Hesse
发明人： Christian Walsdorff , Falk Simon , Gerald Vorberg , Gotz-Peter Schindler , Michael Hesse
IPC分类号： C07C5/327 , B01J23/42
CPC分类号： B01J23/626 , B01J21/04 , B01J35/1009 , B01J35/1014 , B01J37/0009 , C07C5/3337 , C07C2523/60 , C07C15/46
摘要： A catalyst for the oxidation of hydrogen in a process for the dehydrogenation of hydrocarbons, wherein the catalyst comprises, supported on α-aluminum oxide, from 0.01 to 0.1% by weight of platinum and from 0.01 to 0.1% by weight of tin, based on the total weight of the catalyst, a process for the oxidation of hydrogen and a process for the dehydrogenation of hydrocarbons with an integrated oxidation process using the catalyst described.
摘要翻译：一种在烃脱氢方法中氧化氢气的催化剂，其中催化剂包含负载在α-氧化铝上的0.01至0.1重量％的铂和0.01至0.1重量％的锡，基于催化剂的总重量，氢氧化的方法和使用所述催化剂的使用一体化氧化方法使烃脱氢的方法。

70. 发明申请

US20080221302A1 Catalyst and Process for the Polymerization of Cyclic Ethers 有权
标题翻译：催化剂和循环醚聚合方法
公开(公告)号：US20080221302A1
公开(公告)日：2008-09-11
申请号：US12088208
申请日：2006-11-30
申请人： Stephan Hatscher , Michael Hesse , Tobias Wabnitz , Stefan Kashammer , Rolf Pinkos
发明人： Stephan Hatscher , Michael Hesse , Tobias Wabnitz , Stefan Kashammer , Rolf Pinkos
IPC分类号： C08G65/20
CPC分类号： B01J21/16 , B01J23/40 , B01J23/745 , B01J23/75 , B01J37/0009 , B01J37/0036 , C08G65/10 , C08G65/20 , C08G65/2642
摘要： The present invention provides a catalyst comprising a mixture of at least one acid-activated sheet silicate with a transition metal oxide of groups 8 and/or 9 of the Periodic Table of the Elements and also a process for preparing polytetrahydrofuran, polytetrahy-drofuran copolymers, diesters or monoesters of these polymers, in which tetrahydrofuran is polymerized in the presence of at least one telogen and/or comonomer over such a catalyst.
摘要翻译：本发明提供一种催化剂，其包含至少一种酸活化的硅酸盐与元素周期表第8和/或9族的过渡金属氧化物的混合物，以及制备聚四氢呋喃，聚四氢呋喃共聚物的方法，这些聚合物的二酯或单酯，其中四氢呋喃在这种催化剂存在下在至少一种开环和/或共聚单体存在下聚合。

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